JP2014510197A5 - - Google Patents
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- Publication number
- JP2014510197A5 JP2014510197A5 JP2014500315A JP2014500315A JP2014510197A5 JP 2014510197 A5 JP2014510197 A5 JP 2014510197A5 JP 2014500315 A JP2014500315 A JP 2014500315A JP 2014500315 A JP2014500315 A JP 2014500315A JP 2014510197 A5 JP2014510197 A5 JP 2014510197A5
- Authority
- JP
- Japan
- Prior art keywords
- composition
- less
- zinc
- ions
- phosphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 23
- -1 zinc (II) ions Chemical class 0.000 claims description 12
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 10
- 229910052725 zinc Inorganic materials 0.000 claims description 10
- 239000011701 zinc Substances 0.000 claims description 10
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims description 10
- 229910000165 zinc phosphate Inorganic materials 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 7
- 150000002484 inorganic compounds Chemical class 0.000 claims description 7
- 229910010272 inorganic material Inorganic materials 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 6
- 239000010941 cobalt Substances 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 150000002894 organic compounds Chemical class 0.000 claims description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical group [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 239000008139 complexing agent Substances 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052684 Cerium Inorganic materials 0.000 claims description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- 230000002378 acidificating effect Effects 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 150000001342 alkaline earth metals Chemical group 0.000 claims description 2
- 125000004429 atom Chemical group 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 239000011651 chromium Substances 0.000 claims description 2
- 125000000524 functional group Chemical group 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- 150000008040 ionic compounds Chemical class 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims 1
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 claims 1
- 229920000388 Polyphosphate Polymers 0.000 claims 1
- 229910001297 Zn alloy Inorganic materials 0.000 claims 1
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical group 0.000 claims 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- 125000002091 cationic group Chemical group 0.000 claims 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims 1
- 235000011180 diphosphates Nutrition 0.000 claims 1
- 150000002221 fluorine Chemical class 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000001205 polyphosphate Substances 0.000 claims 1
- 235000011176 polyphosphates Nutrition 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 235000019832 sodium triphosphate Nutrition 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims 1
- FZFRVZDLZISPFJ-UHFFFAOYSA-N tungsten(6+) Chemical compound [W+6] FZFRVZDLZISPFJ-UHFFFAOYSA-N 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229940085991 phosphate ion Drugs 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11159220.0 | 2011-03-22 | ||
| EP11159220.0A EP2503025B1 (de) | 2011-03-22 | 2011-03-22 | Mehrstufige korrosionsschützende Behandlung metallischer Bauteile, die zumindest teilweise Oberflächen von Zink oder Zinklegierungen aufweisen |
| PCT/EP2012/053907 WO2012126734A1 (de) | 2011-03-22 | 2012-03-07 | Mehrstufige korrosionsschützende behandlung metallischer bauteile mit zinkoberflächen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014510197A JP2014510197A (ja) | 2014-04-24 |
| JP2014510197A5 true JP2014510197A5 (enExample) | 2015-04-30 |
| JP5956555B2 JP5956555B2 (ja) | 2016-07-27 |
Family
ID=44357998
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014500315A Active JP5956555B2 (ja) | 2011-03-22 | 2012-03-07 | 亜鉛を有する金属部材の多段耐食処理 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US9534301B2 (enExample) |
| EP (1) | EP2503025B1 (enExample) |
| JP (1) | JP5956555B2 (enExample) |
| KR (1) | KR101858782B1 (enExample) |
| CN (1) | CN103492611B (enExample) |
| BR (1) | BR112013024075A2 (enExample) |
| CA (1) | CA2830676C (enExample) |
| ES (1) | ES2428290T3 (enExample) |
| MX (1) | MX351392B (enExample) |
| PL (1) | PL2503025T3 (enExample) |
| TW (1) | TWI585235B (enExample) |
| WO (1) | WO2012126734A1 (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101479658B1 (ko) * | 2011-11-18 | 2015-01-06 | 제일모직 주식회사 | 가압착 공정성이 개선된 이방성 도전 필름 |
| EP2868719A1 (en) * | 2013-10-31 | 2015-05-06 | PPG Coatings Europe B.V. | A tank or pipe having a coating system |
| US20170009351A1 (en) * | 2014-01-23 | 2017-01-12 | Chemetall Gmbh | Method for Coating Metal Surfaces, Substrates Coated in This Way, and Use Thereof |
| DE102014223169A1 (de) | 2014-11-13 | 2016-05-19 | Henkel Ag & Co. Kgaa | Verfahren zur selektiven Entfernung von Zink-Ionen aus alkalischen Badlösungen in der Oberflächenbehandlung von metallischen Bauteilen in Serie |
| DE102016206418A1 (de) | 2016-04-15 | 2017-10-19 | Henkel Ag & Co. Kgaa | Unterdrückung anlagenbedingter phosphatüberschleppung in einer prozessfolge zur tauchlackierung |
| DE102016206417A1 (de) | 2016-04-15 | 2017-10-19 | Henkel Ag & Co. Kgaa | Fördergestellbehandlung zur unterdrückung anlagenbedingter phosphatüberschleppung in einer prozessfolge zur tauchlackierung |
| CN119194461A (zh) * | 2016-08-24 | 2024-12-27 | Ppg工业俄亥俄公司 | 用于处理金属基材的碱性组合物 |
| EP3569743A1 (de) | 2018-05-16 | 2019-11-20 | Henkel AG & Co. KGaA | Fördergestellreinigung in einer prozessfolge zur elektrotauchlackierung |
| EP4174211A1 (de) * | 2021-11-02 | 2023-05-03 | Henkel AG & Co. KGaA | Mehrstufige behandlung zur aktivierten zinkphosphatierung metallischer bauteile mit zinkoberflächen |
| WO2024208859A2 (en) | 2023-04-04 | 2024-10-10 | Chemetall Gmbh | Cleaning composition and method for cleaning metallic surfaces to prevent rinse bath corrosion |
Family Cites Families (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3181976A (en) | 1961-11-06 | 1965-05-04 | Purex Corp Ltd | Phosphating process and composition |
| SE316668B (enExample) * | 1963-09-23 | 1969-10-27 | Parker Ste Continentale | |
| US3515600A (en) * | 1966-10-19 | 1970-06-02 | Hooker Chemical Corp | Metal treating process and composition |
| US3444007A (en) | 1967-03-13 | 1969-05-13 | Hooker Chemical Corp | Process of forming paint-base coatings on zinc and zinc alloy surfaces |
| US3620949A (en) | 1969-04-11 | 1971-11-16 | Balm Paints Ltd | Metal pretreatment and coating process |
| GB1414484A (en) * | 1972-05-03 | 1975-11-19 | Pyrene Chemical Services Ltd | Treatment of zinc surfaces |
| JPS51135840A (en) | 1975-05-21 | 1976-11-25 | Nippon Packaging Kk | Surface treatment process for zinc or zinc alloy |
| JPS53120644A (en) | 1977-03-31 | 1978-10-21 | Nippon Packaging Kk | Surface treatment method of aluminium and its alloy |
| US4278477A (en) | 1980-03-19 | 1981-07-14 | Amchem Products, Inc. | Metal treatment |
| US4511513A (en) | 1981-03-09 | 1985-04-16 | Johnson & Johnson Baby Products Company | Detergent compounds and compositions |
| SE452018B (sv) | 1981-03-09 | 1987-11-09 | Johnson & Johnson Baby Prod | Komplex av amfoter fettsyra och dess anvendning i detergentkompositioner |
| JPS60152682A (ja) * | 1984-01-20 | 1985-08-10 | Nippon Parkerizing Co Ltd | りん酸塩処理方法 |
| FR2560894B1 (fr) | 1984-03-07 | 1988-11-18 | Parker Ste Continentale | Procede de preparation de surfaces de zinc, d'alliages de zinc et d'acier recouvert de ces materiaux, destinees a recevoir des peintures ou des vernis |
| JPS6123769A (ja) * | 1984-07-09 | 1986-02-01 | Nippon Paint Co Ltd | 化成処理されたアルミニウム含有亜鉛めつき合金鋼板 |
| JPS6220880A (ja) * | 1985-07-19 | 1987-01-29 | Nippon Parkerizing Co Ltd | 亜鉛−アルミニウム合金めつき鋼板の表面処理方法 |
| GB8608508D0 (en) | 1986-04-08 | 1986-05-14 | Pyrene Chemical Services Ltd | Coating metal surfaces |
| US4888386A (en) | 1989-02-21 | 1989-12-19 | Nalco Chemical Company | Composition for the paint detackification for both waterborne and solvent enamels |
| US5294266A (en) | 1989-07-28 | 1994-03-15 | Metallgesellschaft Aktiengesellschaft | Process for a passivating postrinsing of conversion layers |
| DE4017186A1 (de) | 1990-05-29 | 1991-12-05 | Metallgesellschaft Ag | Erzeugung von konversionsueberzuegen auf zink- oder zinklegierungsoberflaechen |
| DE4210513A1 (de) * | 1992-03-31 | 1993-10-07 | Henkel Kgaa | Nickel-freie Phosphatierverfahren |
| DE4341041A1 (de) | 1993-12-02 | 1995-06-08 | Henkel Kgaa | Nickelfreies Phosphatierverfahren mit m-Nitrobenzolsulfonat |
| BR9407485A (pt) | 1993-09-06 | 1996-06-25 | Henkel Kgaa | Processo de fosfataçao isento de níquel |
| JPH07173643A (ja) | 1993-12-21 | 1995-07-11 | Mazda Motor Corp | 金属表面の燐酸塩処理方法及び処理液 |
| DE19511573A1 (de) | 1995-03-29 | 1996-10-02 | Henkel Kgaa | Verfahren zur Phosphatierung mit metallhaltiger Nachspülung |
| DE19606017A1 (de) | 1996-02-19 | 1997-08-21 | Henkel Kgaa | Zinkphosphatierung mit geringen Gehalten an Kupfer und Mangan |
| DE19705701A1 (de) | 1997-02-14 | 1998-08-20 | Henkel Kgaa | Verfahren zur Niedrig-Nickel-Phosphatierung mit metallhaltiger Nachspülung |
| DE19733972A1 (de) * | 1997-08-06 | 1999-02-11 | Henkel Kgaa | Alkalische Bandpassivierung |
| US6720032B1 (en) * | 1997-09-10 | 2004-04-13 | Henkel Kommanditgesellschaft Auf Aktien | Pretreatment before painting of composite metal structures containing aluminum portions |
| DE19834796A1 (de) | 1998-08-01 | 2000-02-03 | Henkel Kgaa | Verfahren zur Phosphatierung, Nachspülung und kathodischer Elektrotauchlackierung |
| DE19958192A1 (de) | 1999-12-02 | 2001-06-07 | Henkel Kgaa | Verfahren zur Phosphatierung, Nachspülung und kathodischer Elektrotauchlackierung |
| DE10010355A1 (de) * | 2000-03-07 | 2001-09-13 | Chemetall Gmbh | Verfahren zum Aufbringen eines Phosphatüberzuges und Verwendung der derart phosphatierten Metallteile |
| JP2002206176A (ja) | 2001-01-09 | 2002-07-26 | Nippon Parkerizing Co Ltd | リン酸塩処理用水性表面調整剤及び表面調整方法 |
| US20040112471A1 (en) | 2001-01-09 | 2004-06-17 | Yoshio Moriya | Aqueous surface conditioner and surface conditioning method for phospating treatment |
| JP2003201575A (ja) * | 2002-01-09 | 2003-07-18 | Nippon Steel Corp | 加工性に優れたリン酸塩処理亜鉛系めっき鋼板の製造方法 |
| DE10323305B4 (de) * | 2003-05-23 | 2006-03-30 | Chemetall Gmbh | Verfahren zur Beschichtung von metallischen Oberflächen mit einer Wasserstoffperoxid enthaltenden Phosphatierungslösung, Phosphatierlösung und Verwendung der behandelten Gegenstände |
| JP5051679B2 (ja) | 2003-08-29 | 2012-10-17 | 日本パーカライジング株式会社 | アルミニウムまたはアルミニウム合金製ｄｉ缶のアルカリ洗浄方法 |
| DE102005059314B4 (de) | 2005-12-09 | 2018-11-22 | Henkel Ag & Co. Kgaa | Saure, chromfreie wässrige Lösung, deren Konzentrat, und ein Verfahren zur Korrosionsschutzbehandlung von Metalloberflächen |
| DE102005047424A1 (de) * | 2005-09-30 | 2007-04-05 | Henkel Kgaa | Phosphatierlösung mit Wasserstoffperoxid und chelatbildenden Carbonsäuren |
| JP5198727B2 (ja) | 2005-10-07 | 2013-05-15 | ディップソール株式会社 | 亜鉛又は亜鉛合金上に黒色の６価クロムフリー化成皮膜を形成するための処理溶液 |
| US9574093B2 (en) | 2007-09-28 | 2017-02-21 | Ppg Industries Ohio, Inc. | Methods for coating a metal substrate and related coated metal substrates |
| DE102009047522A1 (de) | 2009-12-04 | 2011-06-09 | Henkel Ag & Co. Kgaa | Mehrstufiges Vorbehandlungsverfahren für metallische Bauteile mit Zink- und Eisenoberflächen |
| DE102010001686A1 (de) * | 2010-02-09 | 2011-08-11 | Henkel AG & Co. KGaA, 40589 | Zusammensetzung für die alkalische Passivierung von Zinkoberflächen |
| DE102010030697A1 (de) * | 2010-06-30 | 2012-01-05 | Henkel Ag & Co. Kgaa | Verfahren zur selektiven Phosphatierung einer Verbundmetallkonstruktion |
-
2011
- 2011-03-22 PL PL11159220T patent/PL2503025T3/pl unknown
- 2011-03-22 EP EP11159220.0A patent/EP2503025B1/de active Active
- 2011-03-22 ES ES11159220T patent/ES2428290T3/es active Active
-
2012
- 2012-03-01 TW TW101106639A patent/TWI585235B/zh not_active IP Right Cessation
- 2012-03-07 CN CN201280018084.0A patent/CN103492611B/zh active Active
- 2012-03-07 WO PCT/EP2012/053907 patent/WO2012126734A1/de not_active Ceased
- 2012-03-07 KR KR1020137027679A patent/KR101858782B1/ko active Active
- 2012-03-07 BR BR112013024075A patent/BR112013024075A2/pt active Search and Examination
- 2012-03-07 CA CA2830676A patent/CA2830676C/en active Active
- 2012-03-07 MX MX2013010758A patent/MX351392B/es active IP Right Grant
- 2012-03-07 JP JP2014500315A patent/JP5956555B2/ja active Active
-
2013
- 2013-09-19 US US14/031,213 patent/US9534301B2/en active Active
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