JP2013544012A - 光電子デバイス及び光電子デバイスの製造方法 - Google Patents
光電子デバイス及び光電子デバイスの製造方法 Download PDFInfo
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- JP2013544012A JP2013544012A JP2013536549A JP2013536549A JP2013544012A JP 2013544012 A JP2013544012 A JP 2013544012A JP 2013536549 A JP2013536549 A JP 2013536549A JP 2013536549 A JP2013536549 A JP 2013536549A JP 2013544012 A JP2013544012 A JP 2013544012A
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Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/84—Passivation; Containers; Encapsulations
- H10K50/844—Encapsulations
- H10K50/8445—Encapsulations multilayered coatings having a repetitive structure, e.g. having multiple organic-inorganic bilayers
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/14—Protective coatings, e.g. hard coatings
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/84—Passivation; Containers; Encapsulations
- H10K50/844—Encapsulations
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
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Abstract
【選択図】図1
Description
−光電子素子を提供する工程と;
−ゲッタ層を設ける工程と;
−異方性粒子を含む横方向拡散層を設ける工程であって、前記異方性粒子は前記横方向拡散層に対して整列されている工程と;
−無機層を設ける工程と;をこの順又は逆順で含み、これらの工程により前記光電子素子、前記ゲッタ層、前記横方向拡散層、及び、前記無機層を順に有する積層体が得られる。
−光電子素子を提供する工程と;
−水分ゲッタ粒子及び異方性粒子の混合物を含む横方向拡散層を設ける工程であって、前記異方性粒子は前記横方向拡散層に対して整列されている工程と;
−無機層を設ける工程と;をこの順又は逆順で含み、これらの工程により前記光電子素子、前記ゲッタ層、前記横方向拡散層、及び、前記無機層を順に有する積層体が得られる。
(A)少なくとも1つの芳香族であるアクリレート又はメタアクリレート成分、或いは、任意のそれらの混合物と;
(B)好ましくは30℃における粘性が100mPa・s未満である、少なくとも1つの1官能性であるアクリレート、メタアクリレート、ビニルアミド、アクリルアミド又はメタアクリルアミド成分、或いは任意のそれらの混合物と;
(C)少なくとも1つの光開始剤、或いは、任意のそれらの混合物と;を含む光硬化性樹脂組成物を、UV照射などの活性光照射により硬化することにより1つ以上の有機層を得る。
(A)30〜90重量%の前記芳香族であるアクリレート又はメタアクリレート成分Aと;
(B)1〜30重量%の前記1官能性であるアクリレート、メタアクリレート、ビニルアミド、アクリルアミド又はメタアクリルアミド成分Bと;
(C)0.1〜10重量%の前記光開始剤Cと;を含む。
(D)少なくとも1つのポリブタジエンアクリレート又はポリブタジエンメタアクリレート成分、或いは、任意のそれらの混合物と;
(E)好ましくは30℃における粘性が100mPa・s未満である、ポリブタジエン基を有さない少なくとも1つのアクリレート又はメタアクリレート成分、或いは、任意のそれらの混合物と;
(C)少なくとも1つの光開始剤、或いは、任意のそれらの混合物と;を含む光硬化性樹脂組成物を、活性光照射により硬化することにより1つ以上の有機層を得る。
(D)10〜60重量%の前記ポリブタジエンアクリレート又はポリブタジエンメタアクリレート成分Dと;
(E)1〜89.9重量%の前記アクリレート又はメタアクリレート成分Eと;
(C)0.1〜10重量%の前記光開始剤Cと;を含む。
(F)少なくとも1つのウレタンアクリレート又はウレタンメタアクリレート成分、或いは、任意のそれらの混合物と;
(E)好ましくは30℃における粘性が100mPa・s未満である、ウレタン基を有さない少なくとも1つのアクリレート又はメタアクリレート成分、或いは、任意のそれらの混合物と;
(C)少なくとも1つの光開始剤、或いは、任意のそれらの混合物と;を含む光硬化性樹脂組成物を、活性光照射により硬化することにより1つ以上の有機層を得る。
(F)5〜50重量%の前記ウレタンアクリレート又はウレタンメタアクリレート成分Fと;
(E)1〜94.9重量%の前記アクリレート又はメタアクリレート成分Eと;
(C)0.1〜10重量%の前記光開始剤Cと;を含む。
(G)clogP値が>2である、少なくとも1つのアクリレート又はメタアクリレート成分、或いは、任意のそれらの混合物と;
(H)少なくとも1つのチオール成分、或いは、任意のそれらの混合物と;
(C)少なくとも1つの光開始剤、或いは、任意のそれらの混合物と;を含む光硬化性樹脂組成物を、活性光照射により硬化することにより1つ以上の有機層を得る。
(G)20〜98.9重量%の前記アクリレート又はメタアクリレート成分Gと;
(H)1〜20%重量%の前記チオール成分Hと;
(C)0.1〜10重量%の前記光開始剤Cと;を含む。
(I)少なくとも1つのエポキシポリシロキサン成分と;
(J)少なくとも1つのカチオン性光開始剤、或いは、任意のそれらの混合物と;を含む光硬化性樹脂組成物を、活性光照射により硬化することにより1つ以上の有機層を得る。
(I)20〜99.9重量%の前記エポキシポリシロキサン成分Iと;
(K)0.2〜79.9重量%の、ポリシロキサン基を有さないエポキシ官能又はオキセタン官能有機成分、或いは、当該エポキシ官能又はオキセタン官能有機成分の混合物と;
(J)0.1〜10重量%の前記光開始剤Jと;を含む。
Claims (20)
- バリア構造体(20)により包囲された光電子素子(10)を含む光電子デバイスであって、前記バリア構造体は、外部から前記光電子素子への水分の伝達を阻害するためのものであり、前記バリア構造体は、無機層(22)を少なくとも含む層積層体と、前記無機層と前記光電子素子との間に配設された層内に水分ゲッタ材とを含む光電子デバイスであって、
前記層積層体は異方性粒子を含む有機層である横方向拡散層(26)を含み、前記異方性粒子は前記有機層に対して整列されており、
前記ゲッタ材は前記光電子素子(10)と前記横方向拡散層(10)との間に配設された別個のゲッタ層(24)内に存在するか、及び/又は、前記ゲッタ材は前記横方向拡散層(26)内に存在する、光電子デバイス。 - 前記バリア構造体は更なる層(42,46,49)積層体を含み、
前記光電子素子は前記層(22,26)積層体と、少なくとも2つの無機層(42,49)を含む前記更なる層積層体とにより包囲される、請求項1に記載の光電子デバイス。 - 前記更なる層積層体は、複数の前記更なる無機層の間に配設された更なる横方向拡散層を更に含み、
更なるゲッタ材が前記光電子素子と前記更なる横方向拡散層との間に配設された更なる別個のゲッタ層内に存在するか、及び/又は、前記更なるゲッタ材が前記更なる横方向拡散層内に存在する、請求項2に記載の光電子デバイス。 - 前記バリア構造体(20)は金属箔(28)を含み、前記光電子素子は前記層(42,46,49)積層体と前記金属箔(28)とにより包囲されている、請求項1に記載の光電子デバイス。
- (A)少なくとも1つの芳香族であるアクリレート又はメタアクリレート成分、或いは、任意のそれらの混合物と;
(B)好ましくは30℃における粘性が100mPa・s未満である、少なくとも1つの1官能性であるアクリレート、メタアクリレート、ビニルアミド、アクリルアミド又はメタアクリルアミド成分、或いは、任意のそれらの混合物と;
(C)少なくとも1つの光開始剤、或いは、任意のそれらの混合物と;を含む光硬化性樹脂組成物を、活性光照射により硬化することにより得られた1つ以上の有機層を含む、請求項1〜4のいずれか一項に記載の光電子デバイス。 - 前記光硬化性樹脂組成物は、当該樹脂組成物全量に対して、
(A)30〜90重量%の前記芳香族であるアクリレート又はメタアクリレート成分Aと;
(B)1〜30重量%の前記1官能性であるアクリレート、メタアクリレート、ビニルアミド、アクリルアミド又はメタアクリルアミド成分Bと;
(C)0.1〜10重量%の前記光開始剤Cと;を含む、請求項5に記載の光電子デバイス。 - (D)少なくとも1つのポリブタジエンアクリレート又はポリブタジエンメタアクリレート成分、或いは、任意のそれらの混合物と;
(E)好ましくは30℃における粘性が100mPa・s未満である、ポリブタジエン基を有さない少なくとも1つのアクリレート又はメタアクリレート成分、或いは、任意のそれらの混合物と;
(C)少なくとも1つの光開始剤、或いは、任意のそれらの混合物と;を含む光硬化性樹脂組成物を、活性光照射により硬化することにより得られた1つ以上の有機層を含む、請求項1〜4のいずれか一項に記載の光電子デバイス。 - 前記光硬化性樹脂組成物は、当該樹脂組成物全量に対して、
(D)10〜60重量%の前記ポリブタジエンアクリレート又はポリブタジエンメタアクリレート成分Dと;
(E)1〜89.9重量%の前記アクリレート又はメタアクリレート成分Eと;
(C)0.1〜10重量%の前記光開始剤Cと;を含む、請求項7に記載の光電子デバイス。 - (F)少なくとも1つのウレタンアクリレート又はウレタンメタアクリレート成分、或いは、任意のそれらの混合物と;
(E)好ましくは30℃における粘性が100mPa・s未満である、ウレタン基を有さない少なくとも1つのアクリレート又はメタアクリレート成分、或いは、任意のそれらの混合物と;
(C)少なくとも1つの光開始剤、或いは、任意のそれらの混合物と;を含む光硬化性樹脂組成物を、活性光照射により硬化することに得られた1つ以上の有機層を含む、請求項1〜4のいずれか一項に記載の光電子デバイス。 - 前記光硬化性樹脂組成物は、当該樹脂組成物全量に対して、
(F)5〜50重量%の前記ウレタンアクリレート又はウレタンメタアクリレート成分Fと;
(E)1〜94.9重量%の前記アクリレート又はメタアクリレート成分Eと;
(C)0.1〜10重量%の前記光開始剤Cと;を含む、請求項9に記載の光電子デバイス。 - (G)clogP値が>2である、少なくとも1つのアクリレート又はメタアクリレート成分、或いは、任意のそれらの混合物と;
(H)少なくとも1つのチオール成分、又は、任意のそれらの混合物と;
(C)少なくとも1つの光開始剤、或いは、任意のそれらの混合物と;を含む光硬化性樹脂組成物を、活性光照射により硬化することにより得られた1つ以上の有機層を含む、請求項1〜4のいずれか一項に記載の光電子デバイス。 - 前記光硬化性樹脂組成物は、当該樹脂組成物全量に対して、
(G)20〜98.9重量%の前記アクリレート又はメタアクリレート成分Gと;
(H)1〜20%重量%の前記チオール成分Hと;
(C)0.1〜10重量%の前記光開始剤Cと;を含む、請求項11に記載の光電子デバイス。 - (I)少なくとも1つのエポキシポリシロキサン成分と;
(J)少なくとも1つのカチオン性光開始剤、或いは、任意のそれらの混合物と;を含む光硬化性樹脂組成物を、活性光照射により硬化することにより得られた1つ以上の有機層を含む、請求項1〜4のいずれか一項に記載の光電子デバイス。 - 前記光硬化性樹脂組成物は、当該樹脂組成物全量に対して、
(I)20〜99.9重量%の前記エポキシポリシロキサン成分Iと;
(K)0.2〜79.9重量%の、ポリシロキサン基を有さないエポキシ官能又はオキセタン官能有機成分、或いは、当該エポキシ官能又はオキセタン官能有機成分の混合物と;
(J)0.1〜10重量%の前記光開始剤Jと;を含む、請求項13に記載の光電子デバイス。 - clogP値が>2である光構成樹脂組成物を活性光照射により硬化することにより得られた1つ以上の有機層を含む、請求項1〜4のいずれか一項に記載の光電子デバイス。
- −光電子素子を提供する工程と;
−ゲッタ層を設ける工程と;
−異方性粒子を含む有機層である横方向拡散層を設ける工程であって、前記異方性粒子は前記横方向拡散層に対して整列されている工程と;
−無機層を設ける工程と;をこの順又は逆順で含み、これにより、前記光電子素子、前記ゲッタ層、前記横方向拡散層、及び、前記無機層を順に有する積層体を得る、光電子デバイスの製造方法。 - −光電子素子を提供する工程と;
−水分ゲッタ粒子及び異方性粒子の混合物を含む有機層である横方向拡散層を設ける工程であって、前記異方性粒子は前記横方向拡散層に対して整列されている工程と;
−無機層を設ける工程と;をこの順又は逆順で含み、これにより、前記光電子素子、前記ゲッタ層、前記横方向拡散層、及び、前記無機層を順に有する積層体を得る、光電子デバイスの製造方法。 - −前記異方性粒子を、有機材料の液状前駆体に分散させた分散液として提供する工程と;
−前記分散体を層に成膜する工程と;
−成膜された前記層を硬化する工程と;を含む、請求項16又は17に記載の方法。 - 前記横方向拡散層を設ける工程は、
−パターン化無機層を積層する副工程と;
−有機材料の平坦化層を積層する副工程と;
−前記パターン化無機層を積層する副工程と前記平坦化層を積層する副工程とを繰り返す副工程と;を含み、これにより、前記パターン化有機層のパターンとその直前の工程において積層した前記パターン化有機層のパターンとを補完させる、請求項16又は17に記載の方法。 - 前記平坦化層の少なくとも1つはゲッタ材を含む、請求項19に記載の方法。
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EP2445028A1 (en) | 2012-04-25 |
CN103299447A (zh) | 2013-09-11 |
JP6000266B2 (ja) | 2016-09-28 |
TWI606620B (zh) | 2017-11-21 |
WO2012057615A2 (en) | 2012-05-03 |
EP2633567B1 (en) | 2017-11-08 |
TW201232861A (en) | 2012-08-01 |
US9263700B2 (en) | 2016-02-16 |
EP2633567A2 (en) | 2013-09-04 |
KR102027012B1 (ko) | 2019-09-30 |
WO2012057615A3 (en) | 2012-10-18 |
KR20140007340A (ko) | 2014-01-17 |
US20140049825A1 (en) | 2014-02-20 |
CN103299447B (zh) | 2016-04-06 |
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