JP2013511607A5 - - Google Patents
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- Publication number
- JP2013511607A5 JP2013511607A5 JP2012540305A JP2012540305A JP2013511607A5 JP 2013511607 A5 JP2013511607 A5 JP 2013511607A5 JP 2012540305 A JP2012540305 A JP 2012540305A JP 2012540305 A JP2012540305 A JP 2012540305A JP 2013511607 A5 JP2013511607 A5 JP 2013511607A5
- Authority
- JP
- Japan
- Prior art keywords
- range
- solid
- catalyst
- temperature
- olefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010936 titanium Substances 0.000 claims description 49
- 238000000034 method Methods 0.000 claims description 29
- 239000011949 solid catalyst Substances 0.000 claims description 24
- 239000003054 catalyst Substances 0.000 claims description 23
- 238000006116 polymerization reaction Methods 0.000 claims description 18
- 239000004711 α-olefin Substances 0.000 claims description 18
- 229910052782 aluminium Inorganic materials 0.000 claims description 16
- 239000007787 solid Substances 0.000 claims description 16
- 239000011777 magnesium Substances 0.000 claims description 15
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 14
- 229910052719 titanium Inorganic materials 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- -1 aluminum alkyl chloride Chemical class 0.000 claims description 11
- 239000000460 chlorine Substances 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 10
- 239000002243 precursor Substances 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 229910052735 hafnium Inorganic materials 0.000 claims description 8
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 8
- 150000001735 carboxylic acids Chemical class 0.000 claims description 6
- 239000008187 granular material Substances 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 230000000379 polymerizing effect Effects 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 239000012295 chemical reaction liquid Substances 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 238000010521 absorption reaction Methods 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000012442 inert solvent Substances 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 150000007942 carboxylates Chemical class 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- 150000004678 hydrides Chemical class 0.000 claims description 2
- 239000003701 inert diluent Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 150000002736 metal compounds Chemical class 0.000 claims description 2
- 125000000962 organic group Chemical group 0.000 claims description 2
- 150000002902 organometallic compounds Chemical class 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 claims description 2
- 239000011541 reaction mixture Substances 0.000 claims description 2
- 238000004611 spectroscopical analysis Methods 0.000 claims description 2
- 150000003609 titanium compounds Chemical class 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 238000000026 X-ray photoelectron spectrum Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- UNSDWONDAUAWPV-UHFFFAOYSA-N methylaluminum;oxane Chemical compound [Al]C.C1CCOCC1 UNSDWONDAUAWPV-UHFFFAOYSA-N 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000002798 spectrophotometry method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI2009A002057A IT1397080B1 (it) | 2009-11-23 | 2009-11-23 | Catalizzatore di tipo ziegler-natta per la (co)polimerizzazione delle alfa-olefine con elevata produttivita' |
| ITMI2009A002057 | 2009-11-23 | ||
| PCT/EP2010/007067 WO2011060958A1 (en) | 2009-11-23 | 2010-11-18 | Catalysts of the ziegler-natta type for the (co)polymerization of olefins with a high productivity |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013511607A JP2013511607A (ja) | 2013-04-04 |
| JP2013511607A5 true JP2013511607A5 (https=) | 2014-01-16 |
| JP5760002B2 JP5760002B2 (ja) | 2015-08-05 |
Family
ID=42224498
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012540305A Active JP5760002B2 (ja) | 2009-11-23 | 2010-11-18 | 高い生産性を有するオレフィンを（共）重合するためのチーグラー−ナッタ型触媒 |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US9334341B2 (https=) |
| EP (1) | EP2504366B1 (https=) |
| JP (1) | JP5760002B2 (https=) |
| KR (1) | KR101721717B1 (https=) |
| CN (1) | CN102725317B (https=) |
| AR (1) | AR079119A1 (https=) |
| BR (1) | BR112012012275B1 (https=) |
| CA (1) | CA2781196C (https=) |
| CL (1) | CL2012001335A1 (https=) |
| EA (1) | EA021660B1 (https=) |
| ES (1) | ES2520993T3 (https=) |
| IT (1) | IT1397080B1 (https=) |
| MX (1) | MX2012005989A (https=) |
| MY (1) | MY161841A (https=) |
| PL (1) | PL2504366T3 (https=) |
| TW (1) | TWI519555B (https=) |
| WO (1) | WO2011060958A1 (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2545785C (en) | 2003-11-14 | 2014-01-28 | Polimeri Europa S.P.A. | Improved solid catalyst component and process for the (co) polymerization of ethylene |
| JP5695869B2 (ja) * | 2010-09-28 | 2015-04-08 | 日本ポリエチレン株式会社 | チーグラー・ナッタ触媒の改質方法および改質されたチーグラー・ナッタ触媒、並びにそれを用いたオレフィンの重合方法および得られたオレフィン系重合体 |
| IT1403278B1 (it) * | 2010-12-20 | 2013-10-17 | Polimeri Europa Spa | Precursore di catalizzatore e catalizzatore per la (co)polimerizzazione delle alfa-olefine ad alta temperatura |
| IT1403290B1 (it) * | 2010-12-27 | 2013-10-17 | Polimeri Europa Spa | Componente solido di catalizzatore, catalizzatore comprendente detto componente solido, e procedimento di (co)polimerizzazione delle alfa-olefine |
| JP6397908B2 (ja) | 2013-10-18 | 2018-09-26 | 中国石油化工股▲ふん▼有限公司 | オレフィン重合触媒用球状担体、触媒成分、触媒、及びそれらの調製方法 |
| KR102402009B1 (ko) * | 2014-07-31 | 2022-05-24 | 베르살리스 에스.피.에이. | α-올레핀의 (공)중합을 위한 고체 촉매 및 이를 제조하는 방법 |
| KR102596377B1 (ko) * | 2015-01-27 | 2023-10-30 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 탄소성 마그네슘-함유 복합체 물질 및 이의 합성 방법 |
| US10882987B2 (en) | 2019-01-09 | 2021-01-05 | Nova Chemicals (International) S.A. | Ethylene interpolymer products having intermediate branching |
| JP7539785B2 (ja) * | 2020-03-31 | 2024-08-26 | 住友化学株式会社 | オレフィン重合用固体触媒成分 |
| EP4596588A4 (en) * | 2022-10-26 | 2026-04-01 | China Petroleum & Chem Corp | SOLID CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, ITS PREPARATION PROCESS AND ITS USE |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA920299A (en) | 1968-08-01 | 1973-01-30 | Mitsui Petrochemical Industries | Process for the polymerization and/or copolymerization of olefins with use of ziegler-type catalytsts supported on carrier |
| BE791676A (fr) | 1971-12-08 | 1973-05-21 | Solvay | Procédé pour la polymérisation des oléfines |
| LU64420A1 (https=) | 1971-12-08 | 1973-07-16 | ||
| LU65587A1 (https=) | 1972-06-22 | 1973-12-27 | ||
| IT1136627B (it) | 1981-05-21 | 1986-09-03 | Euteco Impianti Spa | Catalizzatore supportato per la polimerizzazione di etilene |
| IT1212779B (it) | 1983-10-14 | 1989-11-30 | Enichimica Secondaria | Procedimento per la polimerizzazione di etilene e per la copolimerizzazione di etilene con alfa-olefine e catalizzatore relativo. |
| US4562170A (en) | 1984-09-04 | 1985-12-31 | Exxon Research & Engineering Co. | Polymerization catalyst |
| IT1190319B (it) | 1986-04-17 | 1988-02-16 | Enichem Polimeri | Procedimento per la preparazione di polietilene a bassa o media densita' e catalizzatori adatti allo scopo |
| IT1203330B (it) | 1987-02-06 | 1989-02-15 | Enichem Base Spa | Componente di catalizzatore e catalizzatore per la polimerizzazione dell'etilene o la co-polimerizzazione dell-etilene con alfa-olefine |
| IT1251462B (it) | 1991-07-12 | 1995-05-15 | Enichem Polimeri | Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene e delle alfa olefine. |
| IT1311978B1 (it) * | 1999-03-25 | 2002-03-22 | Polimeri Europa Srl | Catalizzatore bimetallico per la (co) polimerizzazione dellealfa-olefine. |
| KR100579843B1 (ko) * | 2003-04-01 | 2006-05-12 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매 및 그의 제조방법과 이를 이용한폴리올레핀의 제조방법 |
| CA2545785C (en) | 2003-11-14 | 2014-01-28 | Polimeri Europa S.P.A. | Improved solid catalyst component and process for the (co) polymerization of ethylene |
-
2009
- 2009-11-23 IT ITMI2009A002057A patent/IT1397080B1/it active
-
2010
- 2010-11-18 MX MX2012005989A patent/MX2012005989A/es active IP Right Grant
- 2010-11-18 MY MYPI2012002252A patent/MY161841A/en unknown
- 2010-11-18 BR BR112012012275-4A patent/BR112012012275B1/pt active IP Right Grant
- 2010-11-18 CN CN201080060520.1A patent/CN102725317B/zh active Active
- 2010-11-18 WO PCT/EP2010/007067 patent/WO2011060958A1/en not_active Ceased
- 2010-11-18 US US13/511,481 patent/US9334341B2/en active Active
- 2010-11-18 KR KR1020127015325A patent/KR101721717B1/ko active Active
- 2010-11-18 CA CA2781196A patent/CA2781196C/en active Active
- 2010-11-18 JP JP2012540305A patent/JP5760002B2/ja active Active
- 2010-11-18 EA EA201290283A patent/EA021660B1/ru not_active IP Right Cessation
- 2010-11-18 ES ES10784264.3T patent/ES2520993T3/es active Active
- 2010-11-18 PL PL10784264T patent/PL2504366T3/pl unknown
- 2010-11-18 EP EP10784264.3A patent/EP2504366B1/en active Active
- 2010-11-22 TW TW099140163A patent/TWI519555B/zh active
- 2010-11-23 AR ARP100104304A patent/AR079119A1/es active IP Right Grant
-
2012
- 2012-05-23 CL CL2012001335A patent/CL2012001335A1/es unknown
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