BR112012012275B1 - CATALISADORES DO TIPO ZIEGLER-NATTA PARA A (CO) POLIMERIZAÇÃO DE a-OLEFINAS COM UMA PRODUTIVIDADE ELEVADA - Google Patents
CATALISADORES DO TIPO ZIEGLER-NATTA PARA A (CO) POLIMERIZAÇÃO DE a-OLEFINAS COM UMA PRODUTIVIDADE ELEVADA Download PDFInfo
- Publication number
- BR112012012275B1 BR112012012275B1 BR112012012275-4A BR112012012275A BR112012012275B1 BR 112012012275 B1 BR112012012275 B1 BR 112012012275B1 BR 112012012275 A BR112012012275 A BR 112012012275A BR 112012012275 B1 BR112012012275 B1 BR 112012012275B1
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst
- solid
- aluminum
- polymerization
- titanium
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI2009A002057A IT1397080B1 (it) | 2009-11-23 | 2009-11-23 | Catalizzatore di tipo ziegler-natta per la (co)polimerizzazione delle alfa-olefine con elevata produttivita' |
| ITMI2009A002057 | 2009-11-23 | ||
| PCT/EP2010/007067 WO2011060958A1 (en) | 2009-11-23 | 2010-11-18 | Catalysts of the ziegler-natta type for the (co)polymerization of olefins with a high productivity |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112012012275A2 BR112012012275A2 (pt) | 2018-03-27 |
| BR112012012275B1 true BR112012012275B1 (pt) | 2019-10-08 |
Family
ID=42224498
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112012012275-4A BR112012012275B1 (pt) | 2009-11-23 | 2010-11-18 | CATALISADORES DO TIPO ZIEGLER-NATTA PARA A (CO) POLIMERIZAÇÃO DE a-OLEFINAS COM UMA PRODUTIVIDADE ELEVADA |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US9334341B2 (https=) |
| EP (1) | EP2504366B1 (https=) |
| JP (1) | JP5760002B2 (https=) |
| KR (1) | KR101721717B1 (https=) |
| CN (1) | CN102725317B (https=) |
| AR (1) | AR079119A1 (https=) |
| BR (1) | BR112012012275B1 (https=) |
| CA (1) | CA2781196C (https=) |
| CL (1) | CL2012001335A1 (https=) |
| EA (1) | EA021660B1 (https=) |
| ES (1) | ES2520993T3 (https=) |
| IT (1) | IT1397080B1 (https=) |
| MX (1) | MX2012005989A (https=) |
| MY (1) | MY161841A (https=) |
| PL (1) | PL2504366T3 (https=) |
| TW (1) | TWI519555B (https=) |
| WO (1) | WO2011060958A1 (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2545785C (en) | 2003-11-14 | 2014-01-28 | Polimeri Europa S.P.A. | Improved solid catalyst component and process for the (co) polymerization of ethylene |
| JP5695869B2 (ja) * | 2010-09-28 | 2015-04-08 | 日本ポリエチレン株式会社 | チーグラー・ナッタ触媒の改質方法および改質されたチーグラー・ナッタ触媒、並びにそれを用いたオレフィンの重合方法および得られたオレフィン系重合体 |
| IT1403278B1 (it) * | 2010-12-20 | 2013-10-17 | Polimeri Europa Spa | Precursore di catalizzatore e catalizzatore per la (co)polimerizzazione delle alfa-olefine ad alta temperatura |
| IT1403290B1 (it) * | 2010-12-27 | 2013-10-17 | Polimeri Europa Spa | Componente solido di catalizzatore, catalizzatore comprendente detto componente solido, e procedimento di (co)polimerizzazione delle alfa-olefine |
| JP6397908B2 (ja) | 2013-10-18 | 2018-09-26 | 中国石油化工股▲ふん▼有限公司 | オレフィン重合触媒用球状担体、触媒成分、触媒、及びそれらの調製方法 |
| KR102402009B1 (ko) * | 2014-07-31 | 2022-05-24 | 베르살리스 에스.피.에이. | α-올레핀의 (공)중합을 위한 고체 촉매 및 이를 제조하는 방법 |
| KR102596377B1 (ko) * | 2015-01-27 | 2023-10-30 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 탄소성 마그네슘-함유 복합체 물질 및 이의 합성 방법 |
| US10882987B2 (en) | 2019-01-09 | 2021-01-05 | Nova Chemicals (International) S.A. | Ethylene interpolymer products having intermediate branching |
| JP7539785B2 (ja) * | 2020-03-31 | 2024-08-26 | 住友化学株式会社 | オレフィン重合用固体触媒成分 |
| EP4596588A4 (en) * | 2022-10-26 | 2026-04-01 | China Petroleum & Chem Corp | SOLID CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, ITS PREPARATION PROCESS AND ITS USE |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA920299A (en) | 1968-08-01 | 1973-01-30 | Mitsui Petrochemical Industries | Process for the polymerization and/or copolymerization of olefins with use of ziegler-type catalytsts supported on carrier |
| BE791676A (fr) | 1971-12-08 | 1973-05-21 | Solvay | Procédé pour la polymérisation des oléfines |
| LU64420A1 (https=) | 1971-12-08 | 1973-07-16 | ||
| LU65587A1 (https=) | 1972-06-22 | 1973-12-27 | ||
| IT1136627B (it) | 1981-05-21 | 1986-09-03 | Euteco Impianti Spa | Catalizzatore supportato per la polimerizzazione di etilene |
| IT1212779B (it) | 1983-10-14 | 1989-11-30 | Enichimica Secondaria | Procedimento per la polimerizzazione di etilene e per la copolimerizzazione di etilene con alfa-olefine e catalizzatore relativo. |
| US4562170A (en) | 1984-09-04 | 1985-12-31 | Exxon Research & Engineering Co. | Polymerization catalyst |
| IT1190319B (it) | 1986-04-17 | 1988-02-16 | Enichem Polimeri | Procedimento per la preparazione di polietilene a bassa o media densita' e catalizzatori adatti allo scopo |
| IT1203330B (it) | 1987-02-06 | 1989-02-15 | Enichem Base Spa | Componente di catalizzatore e catalizzatore per la polimerizzazione dell'etilene o la co-polimerizzazione dell-etilene con alfa-olefine |
| IT1251462B (it) | 1991-07-12 | 1995-05-15 | Enichem Polimeri | Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene e delle alfa olefine. |
| IT1311978B1 (it) * | 1999-03-25 | 2002-03-22 | Polimeri Europa Srl | Catalizzatore bimetallico per la (co) polimerizzazione dellealfa-olefine. |
| KR100579843B1 (ko) * | 2003-04-01 | 2006-05-12 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매 및 그의 제조방법과 이를 이용한폴리올레핀의 제조방법 |
| CA2545785C (en) | 2003-11-14 | 2014-01-28 | Polimeri Europa S.P.A. | Improved solid catalyst component and process for the (co) polymerization of ethylene |
-
2009
- 2009-11-23 IT ITMI2009A002057A patent/IT1397080B1/it active
-
2010
- 2010-11-18 MX MX2012005989A patent/MX2012005989A/es active IP Right Grant
- 2010-11-18 MY MYPI2012002252A patent/MY161841A/en unknown
- 2010-11-18 BR BR112012012275-4A patent/BR112012012275B1/pt active IP Right Grant
- 2010-11-18 CN CN201080060520.1A patent/CN102725317B/zh active Active
- 2010-11-18 WO PCT/EP2010/007067 patent/WO2011060958A1/en not_active Ceased
- 2010-11-18 US US13/511,481 patent/US9334341B2/en active Active
- 2010-11-18 KR KR1020127015325A patent/KR101721717B1/ko active Active
- 2010-11-18 CA CA2781196A patent/CA2781196C/en active Active
- 2010-11-18 JP JP2012540305A patent/JP5760002B2/ja active Active
- 2010-11-18 EA EA201290283A patent/EA021660B1/ru not_active IP Right Cessation
- 2010-11-18 ES ES10784264.3T patent/ES2520993T3/es active Active
- 2010-11-18 PL PL10784264T patent/PL2504366T3/pl unknown
- 2010-11-18 EP EP10784264.3A patent/EP2504366B1/en active Active
- 2010-11-22 TW TW099140163A patent/TWI519555B/zh active
- 2010-11-23 AR ARP100104304A patent/AR079119A1/es active IP Right Grant
-
2012
- 2012-05-23 CL CL2012001335A patent/CL2012001335A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP5760002B2 (ja) | 2015-08-05 |
| US20120322959A1 (en) | 2012-12-20 |
| MY161841A (en) | 2017-05-15 |
| HK1171037A1 (en) | 2013-03-15 |
| EA201290283A1 (ru) | 2012-12-28 |
| CL2012001335A1 (es) | 2012-11-30 |
| CN102725317B (zh) | 2014-12-10 |
| JP2013511607A (ja) | 2013-04-04 |
| EA021660B1 (ru) | 2015-08-31 |
| EP2504366B1 (en) | 2014-07-30 |
| BR112012012275A2 (pt) | 2018-03-27 |
| TWI519555B (zh) | 2016-02-01 |
| CN102725317A (zh) | 2012-10-10 |
| US9334341B2 (en) | 2016-05-10 |
| TW201129595A (en) | 2011-09-01 |
| EP2504366A1 (en) | 2012-10-03 |
| ES2520993T3 (es) | 2014-11-12 |
| PL2504366T3 (pl) | 2015-02-27 |
| KR20120091366A (ko) | 2012-08-17 |
| ITMI20092057A1 (it) | 2011-05-24 |
| WO2011060958A1 (en) | 2011-05-26 |
| KR101721717B1 (ko) | 2017-03-30 |
| CA2781196A1 (en) | 2011-05-26 |
| AR079119A1 (es) | 2011-12-28 |
| MX2012005989A (es) | 2012-11-23 |
| IT1397080B1 (it) | 2012-12-28 |
| CA2781196C (en) | 2018-01-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06F | Objections, documents and/or translations needed after an examination request according art. 34 industrial property law | ||
| B06T | Formal requirements before examination | ||
| B09A | Decision: intention to grant | ||
| B16A | Patent or certificate of addition of invention granted |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 18/11/2010, OBSERVADAS AS CONDICOES LEGAIS. (CO) 20 (VINTE) ANOS CONTADOS A PARTIR DE 18/11/2010, OBSERVADAS AS CONDICOES LEGAIS |