EA201290283A1 - Катализаторы типа циглера-натта для со(полимеризации) олефинов с высокой производительностью - Google Patents

Катализаторы типа циглера-натта для со(полимеризации) олефинов с высокой производительностью

Info

Publication number
EA201290283A1
EA201290283A1 EA201290283A EA201290283A EA201290283A1 EA 201290283 A1 EA201290283 A1 EA 201290283A1 EA 201290283 A EA201290283 A EA 201290283A EA 201290283 A EA201290283 A EA 201290283A EA 201290283 A1 EA201290283 A1 EA 201290283A1
Authority
EA
Eurasian Patent Office
Prior art keywords
olefins
polymerization
zigler
natta
high performance
Prior art date
Application number
EA201290283A
Other languages
English (en)
Other versions
EA021660B1 (ru
Inventor
Тициано Пеннати
Франческо Маси
Марио Полеселло
Роберто Фуско
Анна Соммацци
Антони Альфонсо Прото
Лаура Меда
Джузеппе Конти
Франческо Менкони
Original Assignee
ВЕРСАЛИС С.п.А.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ВЕРСАЛИС С.п.А. filed Critical ВЕРСАЛИС С.п.А.
Publication of EA201290283A1 publication Critical patent/EA201290283A1/ru
Publication of EA021660B1 publication Critical patent/EA021660B1/ru

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Твердый катализатор с высокой тепловой устойчивостью для (со)полимеризации α-олефинов, содержащий титан, магний, по меньшей мере один металл, выбранный из гафния и циркония, алюминий и хлор, в котором по меньшей мере 60 мас.% титана имеет степень окисления +3 и который при исследовании с помощью рентгеновской фотоэлектронной спектроскопии имеет полосу поглощения, характеризующуюся энергией связи от 455 до 458 эВ. Указанный катализатор, использованный в сочетании с подходящим сокатализатором в способах (со)полимеризации α-олефинов при высокой температуре, показывает улучшенную производительность, высокое внедрение сомономеров в сополимеризацию этилена и повышенную тепловую устойчивость по сравнению с до сих пор используемыми системами.
EA201290283A 2009-11-23 2010-11-18 Катализаторы типа циглера-натта для (со)полимеризации олефинов с высокой производительностью EA021660B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI2009A002057A IT1397080B1 (it) 2009-11-23 2009-11-23 Catalizzatore di tipo ziegler-natta per la (co)polimerizzazione delle alfa-olefine con elevata produttivita'
PCT/EP2010/007067 WO2011060958A1 (en) 2009-11-23 2010-11-18 Catalysts of the ziegler-natta type for the (co)polymerization of olefins with a high productivity

Publications (2)

Publication Number Publication Date
EA201290283A1 true EA201290283A1 (ru) 2012-12-28
EA021660B1 EA021660B1 (ru) 2015-08-31

Family

ID=42224498

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201290283A EA021660B1 (ru) 2009-11-23 2010-11-18 Катализаторы типа циглера-натта для (со)полимеризации олефинов с высокой производительностью

Country Status (18)

Country Link
US (1) US9334341B2 (ru)
EP (1) EP2504366B1 (ru)
JP (1) JP5760002B2 (ru)
KR (1) KR101721717B1 (ru)
CN (1) CN102725317B (ru)
AR (1) AR079119A1 (ru)
BR (1) BR112012012275B1 (ru)
CA (1) CA2781196C (ru)
CL (1) CL2012001335A1 (ru)
EA (1) EA021660B1 (ru)
ES (1) ES2520993T3 (ru)
HK (1) HK1171037A1 (ru)
IT (1) IT1397080B1 (ru)
MX (1) MX2012005989A (ru)
MY (1) MY161841A (ru)
PL (1) PL2504366T3 (ru)
TW (1) TWI519555B (ru)
WO (1) WO2011060958A1 (ru)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070072764A1 (en) 2003-11-14 2007-03-29 Polimeri Eurpoa S.P.A. Solid catalyst component and process for the (co) polymerization of ethylene
JP5695869B2 (ja) * 2010-09-28 2015-04-08 日本ポリエチレン株式会社 チーグラー・ナッタ触媒の改質方法および改質されたチーグラー・ナッタ触媒、並びにそれを用いたオレフィンの重合方法および得られたオレフィン系重合体
IT1403278B1 (it) * 2010-12-20 2013-10-17 Polimeri Europa Spa Precursore di catalizzatore e catalizzatore per la (co)polimerizzazione delle alfa-olefine ad alta temperatura
IT1403290B1 (it) * 2010-12-27 2013-10-17 Polimeri Europa Spa Componente solido di catalizzatore, catalizzatore comprendente detto componente solido, e procedimento di (co)polimerizzazione delle alfa-olefine
US9951157B2 (en) 2013-10-18 2018-04-24 China Petroleum & Chemical Corporation Spherical carriers for olefin polymerization catalyst, catalyst components, catalyst, and preparation methods therefor
PL3186290T3 (pl) * 2014-07-31 2020-10-19 Versalis S.P.A Stały katalizator dla (ko)polimeryzacji alfa-olefin i sposób jego wytwarzania
EP3251744B1 (en) 2015-01-27 2020-09-30 China Petroleum & Chemical Corporation Carbon-based magnesium-containing composite material and synthetic method therefor
US10882987B2 (en) 2019-01-09 2021-01-05 Nova Chemicals (International) S.A. Ethylene interpolymer products having intermediate branching

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA920299A (en) 1968-08-01 1973-01-30 Mitsui Petrochemical Industries Process for the polymerization and/or copolymerization of olefins with use of ziegler-type catalytsts supported on carrier
BE791676A (fr) 1971-12-08 1973-05-21 Solvay Procédé pour la polymérisation des oléfines
LU64420A1 (ru) 1971-12-08 1973-07-16
LU65587A1 (ru) 1972-06-22 1973-12-27
IT1136627B (it) 1981-05-21 1986-09-03 Euteco Impianti Spa Catalizzatore supportato per la polimerizzazione di etilene
IT1212779B (it) 1983-10-14 1989-11-30 Enichimica Secondaria Procedimento per la polimerizzazione di etilene e per la copolimerizzazione di etilene con alfa-olefine e catalizzatore relativo.
US4562170A (en) 1984-09-04 1985-12-31 Exxon Research & Engineering Co. Polymerization catalyst
IT1190319B (it) 1986-04-17 1988-02-16 Enichem Polimeri Procedimento per la preparazione di polietilene a bassa o media densita' e catalizzatori adatti allo scopo
IT1203330B (it) 1987-02-06 1989-02-15 Enichem Base Spa Componente di catalizzatore e catalizzatore per la polimerizzazione dell'etilene o la co-polimerizzazione dell-etilene con alfa-olefine
IT1251462B (it) 1991-07-12 1995-05-15 Enichem Polimeri Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene e delle alfa olefine.
IT1311978B1 (it) * 1999-03-25 2002-03-22 Polimeri Europa Srl Catalizzatore bimetallico per la (co) polimerizzazione dellealfa-olefine.
KR100579843B1 (ko) * 2003-04-01 2006-05-12 주식회사 엘지화학 혼성 담지 메탈로센 촉매 및 그의 제조방법과 이를 이용한폴리올레핀의 제조방법
US20070072764A1 (en) 2003-11-14 2007-03-29 Polimeri Eurpoa S.P.A. Solid catalyst component and process for the (co) polymerization of ethylene

Also Published As

Publication number Publication date
EP2504366B1 (en) 2014-07-30
PL2504366T3 (pl) 2015-02-27
CA2781196A1 (en) 2011-05-26
CN102725317B (zh) 2014-12-10
CL2012001335A1 (es) 2012-11-30
EA021660B1 (ru) 2015-08-31
BR112012012275B1 (pt) 2019-10-08
AR079119A1 (es) 2011-12-28
CN102725317A (zh) 2012-10-10
BR112012012275A2 (pt) 2018-03-27
TWI519555B (zh) 2016-02-01
JP2013511607A (ja) 2013-04-04
US20120322959A1 (en) 2012-12-20
IT1397080B1 (it) 2012-12-28
CA2781196C (en) 2018-01-02
MY161841A (en) 2017-05-15
MX2012005989A (es) 2012-11-23
WO2011060958A1 (en) 2011-05-26
HK1171037A1 (en) 2013-03-15
KR20120091366A (ko) 2012-08-17
JP5760002B2 (ja) 2015-08-05
EP2504366A1 (en) 2012-10-03
TW201129595A (en) 2011-09-01
KR101721717B1 (ko) 2017-03-30
ITMI20092057A1 (it) 2011-05-24
ES2520993T3 (es) 2014-11-12
US9334341B2 (en) 2016-05-10

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