EA201290283A1 - Катализаторы типа циглера-натта для со(полимеризации) олефинов с высокой производительностью - Google Patents
Катализаторы типа циглера-натта для со(полимеризации) олефинов с высокой производительностьюInfo
- Publication number
- EA201290283A1 EA201290283A1 EA201290283A EA201290283A EA201290283A1 EA 201290283 A1 EA201290283 A1 EA 201290283A1 EA 201290283 A EA201290283 A EA 201290283A EA 201290283 A EA201290283 A EA 201290283A EA 201290283 A1 EA201290283 A1 EA 201290283A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- olefins
- polymerization
- zigler
- natta
- high performance
- Prior art date
Links
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 title abstract 2
- 150000001336 alkenes Chemical class 0.000 title 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- 239000004711 α-olefin Substances 0.000 abstract 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 1
- 238000010348 incorporation Methods 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 239000011949 solid catalyst Substances 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Твердый катализатор с высокой тепловой устойчивостью для (со)полимеризации α-олефинов, содержащий титан, магний, по меньшей мере один металл, выбранный из гафния и циркония, алюминий и хлор, в котором по меньшей мере 60 мас.% титана имеет степень окисления +3 и который при исследовании с помощью рентгеновской фотоэлектронной спектроскопии имеет полосу поглощения, характеризующуюся энергией связи от 455 до 458 эВ. Указанный катализатор, использованный в сочетании с подходящим сокатализатором в способах (со)полимеризации α-олефинов при высокой температуре, показывает улучшенную производительность, высокое внедрение сомономеров в сополимеризацию этилена и повышенную тепловую устойчивость по сравнению с до сих пор используемыми системами.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI2009A002057A IT1397080B1 (it) | 2009-11-23 | 2009-11-23 | Catalizzatore di tipo ziegler-natta per la (co)polimerizzazione delle alfa-olefine con elevata produttivita' |
PCT/EP2010/007067 WO2011060958A1 (en) | 2009-11-23 | 2010-11-18 | Catalysts of the ziegler-natta type for the (co)polymerization of olefins with a high productivity |
Publications (2)
Publication Number | Publication Date |
---|---|
EA201290283A1 true EA201290283A1 (ru) | 2012-12-28 |
EA021660B1 EA021660B1 (ru) | 2015-08-31 |
Family
ID=42224498
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA201290283A EA021660B1 (ru) | 2009-11-23 | 2010-11-18 | Катализаторы типа циглера-натта для (со)полимеризации олефинов с высокой производительностью |
Country Status (18)
Country | Link |
---|---|
US (1) | US9334341B2 (ru) |
EP (1) | EP2504366B1 (ru) |
JP (1) | JP5760002B2 (ru) |
KR (1) | KR101721717B1 (ru) |
CN (1) | CN102725317B (ru) |
AR (1) | AR079119A1 (ru) |
BR (1) | BR112012012275B1 (ru) |
CA (1) | CA2781196C (ru) |
CL (1) | CL2012001335A1 (ru) |
EA (1) | EA021660B1 (ru) |
ES (1) | ES2520993T3 (ru) |
HK (1) | HK1171037A1 (ru) |
IT (1) | IT1397080B1 (ru) |
MX (1) | MX2012005989A (ru) |
MY (1) | MY161841A (ru) |
PL (1) | PL2504366T3 (ru) |
TW (1) | TWI519555B (ru) |
WO (1) | WO2011060958A1 (ru) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PT1682587T (pt) | 2003-11-14 | 2018-02-06 | Versalis Spa | Componente de catalisador sólido melhorado |
JP5695869B2 (ja) * | 2010-09-28 | 2015-04-08 | 日本ポリエチレン株式会社 | チーグラー・ナッタ触媒の改質方法および改質されたチーグラー・ナッタ触媒、並びにそれを用いたオレフィンの重合方法および得られたオレフィン系重合体 |
IT1403278B1 (it) * | 2010-12-20 | 2013-10-17 | Polimeri Europa Spa | Precursore di catalizzatore e catalizzatore per la (co)polimerizzazione delle alfa-olefine ad alta temperatura |
IT1403290B1 (it) * | 2010-12-27 | 2013-10-17 | Polimeri Europa Spa | Componente solido di catalizzatore, catalizzatore comprendente detto componente solido, e procedimento di (co)polimerizzazione delle alfa-olefine |
KR102019727B1 (ko) | 2013-10-18 | 2019-09-09 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 올레핀 중합 촉매용 구형 담체, 촉매 구성 성분, 촉매 및 이의 제조 방법 |
CN106715490B (zh) * | 2014-07-31 | 2019-09-10 | 维尔萨利斯股份公司 | 用于α-烯烃的(共)聚合的固体催化剂和用于其制备的工艺 |
JP6649392B2 (ja) * | 2015-01-27 | 2020-02-19 | 中国石油化工股▲ふん▼有限公司 | 炭素質マグネシウム含有複合材料およびその合成プロセス |
US10882987B2 (en) | 2019-01-09 | 2021-01-05 | Nova Chemicals (International) S.A. | Ethylene interpolymer products having intermediate branching |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA920299A (en) | 1968-08-01 | 1973-01-30 | Mitsui Petrochemical Industries | Process for the polymerization and/or copolymerization of olefins with use of ziegler-type catalytsts supported on carrier |
BE791676A (fr) | 1971-12-08 | 1973-05-21 | Solvay | Procédé pour la polymérisation des oléfines |
LU64420A1 (ru) | 1971-12-08 | 1973-07-16 | ||
LU65587A1 (ru) | 1972-06-22 | 1973-12-27 | ||
IT1136627B (it) | 1981-05-21 | 1986-09-03 | Euteco Impianti Spa | Catalizzatore supportato per la polimerizzazione di etilene |
IT1212779B (it) | 1983-10-14 | 1989-11-30 | Enichimica Secondaria | Procedimento per la polimerizzazione di etilene e per la copolimerizzazione di etilene con alfa-olefine e catalizzatore relativo. |
US4562170A (en) | 1984-09-04 | 1985-12-31 | Exxon Research & Engineering Co. | Polymerization catalyst |
IT1190319B (it) | 1986-04-17 | 1988-02-16 | Enichem Polimeri | Procedimento per la preparazione di polietilene a bassa o media densita' e catalizzatori adatti allo scopo |
IT1203330B (it) | 1987-02-06 | 1989-02-15 | Enichem Base Spa | Componente di catalizzatore e catalizzatore per la polimerizzazione dell'etilene o la co-polimerizzazione dell-etilene con alfa-olefine |
IT1251462B (it) | 1991-07-12 | 1995-05-15 | Enichem Polimeri | Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene e delle alfa olefine. |
IT1311978B1 (it) * | 1999-03-25 | 2002-03-22 | Polimeri Europa Srl | Catalizzatore bimetallico per la (co) polimerizzazione dellealfa-olefine. |
KR100579843B1 (ko) * | 2003-04-01 | 2006-05-12 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매 및 그의 제조방법과 이를 이용한폴리올레핀의 제조방법 |
PT1682587T (pt) | 2003-11-14 | 2018-02-06 | Versalis Spa | Componente de catalisador sólido melhorado |
-
2009
- 2009-11-23 IT ITMI2009A002057A patent/IT1397080B1/it active
-
2010
- 2010-11-18 WO PCT/EP2010/007067 patent/WO2011060958A1/en active Application Filing
- 2010-11-18 CA CA2781196A patent/CA2781196C/en active Active
- 2010-11-18 KR KR1020127015325A patent/KR101721717B1/ko active IP Right Grant
- 2010-11-18 JP JP2012540305A patent/JP5760002B2/ja active Active
- 2010-11-18 EP EP10784264.3A patent/EP2504366B1/en active Active
- 2010-11-18 US US13/511,481 patent/US9334341B2/en active Active
- 2010-11-18 ES ES10784264.3T patent/ES2520993T3/es active Active
- 2010-11-18 CN CN201080060520.1A patent/CN102725317B/zh active Active
- 2010-11-18 MX MX2012005989A patent/MX2012005989A/es active IP Right Grant
- 2010-11-18 EA EA201290283A patent/EA021660B1/ru not_active IP Right Cessation
- 2010-11-18 MY MYPI2012002252A patent/MY161841A/en unknown
- 2010-11-18 BR BR112012012275-4A patent/BR112012012275B1/pt active IP Right Grant
- 2010-11-18 PL PL10784264T patent/PL2504366T3/pl unknown
- 2010-11-22 TW TW099140163A patent/TWI519555B/zh active
- 2010-11-23 AR ARP100104304A patent/AR079119A1/es active IP Right Grant
-
2012
- 2012-05-23 CL CL2012001335A patent/CL2012001335A1/es unknown
- 2012-11-16 HK HK12111669.3A patent/HK1171037A1/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
HK1171037A1 (en) | 2013-03-15 |
PL2504366T3 (pl) | 2015-02-27 |
BR112012012275B1 (pt) | 2019-10-08 |
US20120322959A1 (en) | 2012-12-20 |
EA021660B1 (ru) | 2015-08-31 |
CA2781196C (en) | 2018-01-02 |
JP2013511607A (ja) | 2013-04-04 |
MX2012005989A (es) | 2012-11-23 |
MY161841A (en) | 2017-05-15 |
US9334341B2 (en) | 2016-05-10 |
EP2504366A1 (en) | 2012-10-03 |
KR20120091366A (ko) | 2012-08-17 |
TW201129595A (en) | 2011-09-01 |
ES2520993T3 (es) | 2014-11-12 |
IT1397080B1 (it) | 2012-12-28 |
EP2504366B1 (en) | 2014-07-30 |
CA2781196A1 (en) | 2011-05-26 |
CN102725317A (zh) | 2012-10-10 |
TWI519555B (zh) | 2016-02-01 |
WO2011060958A1 (en) | 2011-05-26 |
BR112012012275A2 (pt) | 2018-03-27 |
AR079119A1 (es) | 2011-12-28 |
CN102725317B (zh) | 2014-12-10 |
KR101721717B1 (ko) | 2017-03-30 |
ITMI20092057A1 (it) | 2011-05-24 |
CL2012001335A1 (es) | 2012-11-30 |
JP5760002B2 (ja) | 2015-08-05 |
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Legal Events
Date | Code | Title | Description |
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MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AM AZ BY KG MD TJ TM |