CN102725317B - 以高产率使α-烯烃(共)聚合的Ziegler-Natta型催化剂 - Google Patents

以高产率使α-烯烃(共)聚合的Ziegler-Natta型催化剂 Download PDF

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CN102725317B
CN102725317B CN201080060520.1A CN201080060520A CN102725317B CN 102725317 B CN102725317 B CN 102725317B CN 201080060520 A CN201080060520 A CN 201080060520A CN 102725317 B CN102725317 B CN 102725317B
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catalyst
solid
precursor
polymerization
temperature
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CN102725317A (zh
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T·潘纳提
F·马希
M·波勒瑟洛
R·法斯考
A·索玛兹
A·A·普罗托
L·梅达
G·康蒂
F·曼考尼
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Versalis SpA
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN201080060520.1A 2009-11-23 2010-11-18 以高产率使α-烯烃(共)聚合的Ziegler-Natta型催化剂 Active CN102725317B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITMI2009A002057A IT1397080B1 (it) 2009-11-23 2009-11-23 Catalizzatore di tipo ziegler-natta per la (co)polimerizzazione delle alfa-olefine con elevata produttivita'
ITMI2009A002057 2009-11-23
PCT/EP2010/007067 WO2011060958A1 (en) 2009-11-23 2010-11-18 Catalysts of the ziegler-natta type for the (co)polymerization of olefins with a high productivity

Publications (2)

Publication Number Publication Date
CN102725317A CN102725317A (zh) 2012-10-10
CN102725317B true CN102725317B (zh) 2014-12-10

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CN201080060520.1A Active CN102725317B (zh) 2009-11-23 2010-11-18 以高产率使α-烯烃(共)聚合的Ziegler-Natta型催化剂

Country Status (17)

Country Link
US (1) US9334341B2 (https=)
EP (1) EP2504366B1 (https=)
JP (1) JP5760002B2 (https=)
KR (1) KR101721717B1 (https=)
CN (1) CN102725317B (https=)
AR (1) AR079119A1 (https=)
BR (1) BR112012012275B1 (https=)
CA (1) CA2781196C (https=)
CL (1) CL2012001335A1 (https=)
EA (1) EA021660B1 (https=)
ES (1) ES2520993T3 (https=)
IT (1) IT1397080B1 (https=)
MX (1) MX2012005989A (https=)
MY (1) MY161841A (https=)
PL (1) PL2504366T3 (https=)
TW (1) TWI519555B (https=)
WO (1) WO2011060958A1 (https=)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2545785C (en) 2003-11-14 2014-01-28 Polimeri Europa S.P.A. Improved solid catalyst component and process for the (co) polymerization of ethylene
JP5695869B2 (ja) * 2010-09-28 2015-04-08 日本ポリエチレン株式会社 チーグラー・ナッタ触媒の改質方法および改質されたチーグラー・ナッタ触媒、並びにそれを用いたオレフィンの重合方法および得られたオレフィン系重合体
IT1403278B1 (it) * 2010-12-20 2013-10-17 Polimeri Europa Spa Precursore di catalizzatore e catalizzatore per la (co)polimerizzazione delle alfa-olefine ad alta temperatura
IT1403290B1 (it) * 2010-12-27 2013-10-17 Polimeri Europa Spa Componente solido di catalizzatore, catalizzatore comprendente detto componente solido, e procedimento di (co)polimerizzazione delle alfa-olefine
JP6397908B2 (ja) 2013-10-18 2018-09-26 中国石油化工股▲ふん▼有限公司 オレフィン重合触媒用球状担体、触媒成分、触媒、及びそれらの調製方法
KR102402009B1 (ko) * 2014-07-31 2022-05-24 베르살리스 에스.피.에이. α-올레핀의 (공)중합을 위한 고체 촉매 및 이를 제조하는 방법
KR102596377B1 (ko) * 2015-01-27 2023-10-30 차이나 페트로리움 앤드 케미컬 코포레이션 탄소성 마그네슘-함유 복합체 물질 및 이의 합성 방법
US10882987B2 (en) 2019-01-09 2021-01-05 Nova Chemicals (International) S.A. Ethylene interpolymer products having intermediate branching
JP7539785B2 (ja) * 2020-03-31 2024-08-26 住友化学株式会社 オレフィン重合用固体触媒成分
EP4596588A4 (en) * 2022-10-26 2026-04-01 China Petroleum & Chem Corp SOLID CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, ITS PREPARATION PROCESS AND ITS USE

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1345339A (zh) * 1999-03-25 2002-04-17 波利玛利欧洲有限责任公司 用于α－烯烃(共)聚合的双金属催化剂

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA920299A (en) 1968-08-01 1973-01-30 Mitsui Petrochemical Industries Process for the polymerization and/or copolymerization of olefins with use of ziegler-type catalytsts supported on carrier
BE791676A (fr) 1971-12-08 1973-05-21 Solvay Procédé pour la polymérisation des oléfines
LU64420A1 (https=) 1971-12-08 1973-07-16
LU65587A1 (https=) 1972-06-22 1973-12-27
IT1136627B (it) 1981-05-21 1986-09-03 Euteco Impianti Spa Catalizzatore supportato per la polimerizzazione di etilene
IT1212779B (it) 1983-10-14 1989-11-30 Enichimica Secondaria Procedimento per la polimerizzazione di etilene e per la copolimerizzazione di etilene con alfa-olefine e catalizzatore relativo.
US4562170A (en) 1984-09-04 1985-12-31 Exxon Research & Engineering Co. Polymerization catalyst
IT1190319B (it) 1986-04-17 1988-02-16 Enichem Polimeri Procedimento per la preparazione di polietilene a bassa o media densita' e catalizzatori adatti allo scopo
IT1203330B (it) 1987-02-06 1989-02-15 Enichem Base Spa Componente di catalizzatore e catalizzatore per la polimerizzazione dell'etilene o la co-polimerizzazione dell-etilene con alfa-olefine
IT1251462B (it) 1991-07-12 1995-05-15 Enichem Polimeri Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene e delle alfa olefine.
KR100579843B1 (ko) * 2003-04-01 2006-05-12 주식회사 엘지화학 혼성 담지 메탈로센 촉매 및 그의 제조방법과 이를 이용한폴리올레핀의 제조방법
CA2545785C (en) 2003-11-14 2014-01-28 Polimeri Europa S.P.A. Improved solid catalyst component and process for the (co) polymerization of ethylene

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1345339A (zh) * 1999-03-25 2002-04-17 波利玛利欧洲有限责任公司 用于α－烯烃(共)聚合的双金属催化剂

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Enrico Magni,etc.Gold－Induced MgCl2 Reduction by AlEt3.Surface Science Study of a Novel Reaction and Its Potential Application in Ziegler Natta Catalysis.《Langmuir》.2000,第16卷(第21期),8113-8121. *

Also Published As

Publication number Publication date
JP5760002B2 (ja) 2015-08-05
US20120322959A1 (en) 2012-12-20
MY161841A (en) 2017-05-15
HK1171037A1 (en) 2013-03-15
EA201290283A1 (ru) 2012-12-28
CL2012001335A1 (es) 2012-11-30
BR112012012275B1 (pt) 2019-10-08
JP2013511607A (ja) 2013-04-04
EA021660B1 (ru) 2015-08-31
EP2504366B1 (en) 2014-07-30
BR112012012275A2 (pt) 2018-03-27
TWI519555B (zh) 2016-02-01
CN102725317A (zh) 2012-10-10
US9334341B2 (en) 2016-05-10
TW201129595A (en) 2011-09-01
EP2504366A1 (en) 2012-10-03
ES2520993T3 (es) 2014-11-12
PL2504366T3 (pl) 2015-02-27
KR20120091366A (ko) 2012-08-17
ITMI20092057A1 (it) 2011-05-24
WO2011060958A1 (en) 2011-05-26
KR101721717B1 (ko) 2017-03-30
CA2781196A1 (en) 2011-05-26
AR079119A1 (es) 2011-12-28
MX2012005989A (es) 2012-11-23
IT1397080B1 (it) 2012-12-28
CA2781196C (en) 2018-01-02

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