JP2010520170A5 - - Google Patents
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- Publication number
- JP2010520170A5 JP2010520170A5 JP2009551210A JP2009551210A JP2010520170A5 JP 2010520170 A5 JP2010520170 A5 JP 2010520170A5 JP 2009551210 A JP2009551210 A JP 2009551210A JP 2009551210 A JP2009551210 A JP 2009551210A JP 2010520170 A5 JP2010520170 A5 JP 2010520170A5
- Authority
- JP
- Japan
- Prior art keywords
- hcn
- formaldehyde
- eda
- fach
- selection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 claims 22
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 21
- 238000000034 method Methods 0.000 claims 21
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims 10
- LTYRAPJYLUPLCI-UHFFFAOYSA-N glycolonitrile Chemical compound OCC#N LTYRAPJYLUPLCI-UHFFFAOYSA-N 0.000 claims 9
- 125000005219 aminonitrile group Chemical group 0.000 claims 7
- 238000005984 hydrogenation reaction Methods 0.000 claims 7
- 239000000203 mixture Substances 0.000 claims 6
- 239000007795 chemical reaction product Substances 0.000 claims 5
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims 4
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- 239000003960 organic solvent Substances 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- LTEQHXNIPJCWSH-UHFFFAOYSA-N 2-(2-piperazin-1-ylethylamino)acetonitrile Chemical compound N#CCNCCN1CCNCC1 LTEQHXNIPJCWSH-UHFFFAOYSA-N 0.000 claims 1
- BZKXKHAECYJBSW-UHFFFAOYSA-N 2-(2-piperazin-1-ylethylamino)butanedinitrile Chemical compound N#CCC(C#N)NCCN1CCNCC1 BZKXKHAECYJBSW-UHFFFAOYSA-N 0.000 claims 1
- OCKYRUXIGBXXSZ-UHFFFAOYSA-N 2-piperazin-1-ylethane-1,1-diamine Chemical compound NC(N)CN1CCNCC1 OCKYRUXIGBXXSZ-UHFFFAOYSA-N 0.000 claims 1
- ULCZBQVKOIFJOM-UHFFFAOYSA-N 4-amino-2-piperazin-1-ylbutanenitrile Chemical compound NCCC(C#N)N1CCNCC1 ULCZBQVKOIFJOM-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 239000007868 Raney catalyst Substances 0.000 claims 1
- 229910000564 Raney nickel Inorganic materials 0.000 claims 1
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 claims 1
- UWFSRRPOUJMFEW-UHFFFAOYSA-N acetonitrile;ethane-1,2-diamine Chemical compound CC#N.NCCN UWFSRRPOUJMFEW-UHFFFAOYSA-N 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- IMUDHTPIFIBORV-UHFFFAOYSA-N aminoethylpiperazine Chemical compound NCCN1CCNCC1 IMUDHTPIFIBORV-UHFFFAOYSA-N 0.000 claims 1
- 239000008346 aqueous phase Substances 0.000 claims 1
- 239000006227 byproduct Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- VIQAOIGVRNWUDN-UHFFFAOYSA-N ethane-1,2-diamine formaldehyde Chemical compound C=O.C(CN)N VIQAOIGVRNWUDN-UHFFFAOYSA-N 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- RMGUVLDKYWEIMN-UHFFFAOYSA-N n'-(2-aminoethyl)-n'-(2-piperazin-1-ylethyl)ethane-1,2-diamine Chemical compound NCCN(CCN)CCN1CCNCC1 RMGUVLDKYWEIMN-UHFFFAOYSA-N 0.000 claims 1
- WBIWIXJUBVWKLS-UHFFFAOYSA-N n'-(2-piperazin-1-ylethyl)ethane-1,2-diamine Chemical compound NCCNCCN1CCNCC1 WBIWIXJUBVWKLS-UHFFFAOYSA-N 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07103295.7 | 2007-03-01 | ||
| EP07103295 | 2007-03-01 | ||
| PCT/EP2008/052413 WO2008104582A2 (de) | 2007-03-01 | 2008-02-28 | Neues verfahren zur herstellung von teta über eddn |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010520170A JP2010520170A (ja) | 2010-06-10 |
| JP2010520170A5 true JP2010520170A5 (enExample) | 2011-04-14 |
| JP5415287B2 JP5415287B2 (ja) | 2014-02-12 |
Family
ID=39433821
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009551210A Expired - Fee Related JP5415287B2 (ja) | 2007-03-01 | 2008-02-28 | Ｅｄｄｎを経由するｔｅｔａの新規製法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8299249B2 (enExample) |
| EP (2) | EP2129651B1 (enExample) |
| JP (1) | JP5415287B2 (enExample) |
| KR (1) | KR20090122435A (enExample) |
| CN (1) | CN101622224B (enExample) |
| RU (1) | RU2472772C2 (enExample) |
| WO (1) | WO2008104582A2 (enExample) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20090125263A (ko) * | 2007-03-01 | 2009-12-04 | 바스프 에스이 | 트리에틸렌테트라민의 제조 방법 |
| ATE482923T1 (de) * | 2007-03-01 | 2010-10-15 | Basf Se | Herstellungsverfahren für ethylenamingemische |
| CN101675025B (zh) * | 2007-03-01 | 2015-04-08 | 巴斯夫欧洲公司 | 制备四亚乙基五胺的方法 |
| JP5480276B2 (ja) | 2008-10-06 | 2014-04-23 | ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー | 担体として酸性混合金属酸化物を含む低金属（ニッケル及びレニウム）触媒組成物 |
| EP2356095B2 (en) * | 2008-10-06 | 2017-09-27 | Union Carbide Chemicals & Plastics Technology LLC | Methods of making cyclic, n-amino functional triamines |
| CN102224129B (zh) | 2008-10-06 | 2015-02-11 | 联合碳化化学品及塑料技术公司 | 制备乙撑胺的方法 |
| CN102239002B (zh) | 2008-10-06 | 2013-10-30 | 联合碳化化学品及塑料技术公司 | 低金属负载的氧化铝载体的催化剂组合物和氨基化方法 |
| JP2012512826A (ja) | 2008-12-19 | 2012-06-07 | ビーエーエスエフ ソシエタス・ヨーロピア | 純粋なトリエタノールアミン（ｔｅｏａ）の製造法 |
| WO2010146009A1 (de) | 2009-06-18 | 2010-12-23 | Basf Se | Methyl-substituierte teta-verbindungen |
| US8766010B2 (en) | 2009-12-02 | 2014-07-01 | Basf Se | Method for distilling mixtures comprising ethylenediamine, N-methylethylenediamine, and water, and mixtures of ethylenediamine and N-methylethylenediamine having a low content of N-methylethylenediamine obtainable thereby |
| KR20130037667A (ko) * | 2010-03-02 | 2013-04-16 | 바스프 에스이 | 에폭시 수지를 위한 경화제로서의 선형 트리에틸렌테트라민의 용도 |
| EP2557074A1 (en) * | 2011-08-11 | 2013-02-13 | Astellas Pharma Inc. | Process for the preparation of N,N,N',N'-tetrakis(3-aminopropyl)-1,4-butanediamine |
| WO2013030259A1 (de) * | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von teta |
| WO2013030287A1 (de) | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von eddn und/oder edmn durch umsetzung von fach und eda |
| CN103764617B (zh) * | 2011-08-31 | 2015-12-02 | 巴斯夫欧洲公司 | 通过使edfa和/或edmfa与hcn反应制备eddn和/或edmn的方法 |
| US8952156B2 (en) | 2011-08-31 | 2015-02-10 | Basf Se | Process for working up reaction outputs from the hydrogenation of EDDN or EDMN |
| WO2013030144A1 (de) * | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von eddn, edmn, teta und deta |
| WO2013030249A1 (de) * | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von aminen durch hydrierung von nitrilen |
| EP2751066A1 (de) * | 2011-08-31 | 2014-07-09 | Basf Se | Verfahren zur herstellung von edfa und/oder edmfa und deta und/oder teta |
| US9012638B2 (en) | 2011-08-31 | 2015-04-21 | Basf Se | Process for preparing EDDN and/or EDMN by conversion of FACH and EDA |
| WO2013030254A1 (de) * | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von teta und/oder deta |
| WO2013030258A1 (de) * | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur aufarbeitung von reaktionsausträgen aus der hydrierung von eddn bzw. edmn |
| WO2013030255A1 (de) * | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von eddn und/oder edmn sowie verfahren zur herstellung von deta und/oder teta |
| EP2751069B1 (de) * | 2011-08-31 | 2017-10-11 | Basf Se | Verfahren zur herstellung von eddn und/oder edmn |
| US8946459B2 (en) | 2011-08-31 | 2015-02-03 | Basf Se | Process for preparing EDDN and/or EDMN by reacting EDFA and/or EDMFA with HCN |
| US9096497B2 (en) | 2011-08-31 | 2015-08-04 | Basf Se | Process for preparing EDDN and EDMN |
| US20130053536A1 (en) * | 2011-08-31 | 2013-02-28 | Basf Se | Process for preparing eddn and/or edmn and a process for preparing deta and/or teta |
| WO2013030023A1 (de) * | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von eddn und/oder edmn sowie ein verfahren zur herstellung von deta und/oder teta |
| US9783486B2 (en) | 2013-12-02 | 2017-10-10 | Dow Global Technologies Llc | Preparation of high molecular weight, branched, acyclic polyalkyleneamines and mixtures thereof |
| US9888584B2 (en) | 2014-12-31 | 2018-02-06 | Invensas Corporation | Contact structures with porous networks for solder connections, and methods of fabricating same |
| KR102067452B1 (ko) | 2016-02-12 | 2020-01-17 | 누리온 케미칼즈 인터내셔널 비.브이. | 고급 에틸렌 아민 및 에틸렌 아민 유도체의 제조 방법 |
| BR112018014267B1 (pt) * | 2016-02-12 | 2021-12-28 | Akzo Nobel Chemicals International B.V. | Processo de preparação de etilenoaminas |
| MX2018009659A (es) | 2016-02-12 | 2018-09-11 | Akzo Nobel Chemicals Int Bv | Proceso para preparar etilenaminas superiores y derivados de etilenaminas. |
| BR112020000020B1 (pt) | 2017-07-10 | 2023-10-17 | Nouryon Chemicals International B.V | Processo para preparar etileno aminas, derivado de ureia de tetraetileno pentamina, derivado de ureia de pentaetileno-hexamina e uso do derivado de ureia |
| WO2019011711A1 (en) * | 2017-07-10 | 2019-01-17 | Akzo Nobel Chemicals International B.V. | PROCESS FOR PREPARING HIGHER ETHYLENEAMINES OR URETH DERIVATIVES |
| WO2019081283A1 (de) | 2017-10-27 | 2019-05-02 | Basf Se | Verfahren zur herstellung von ethylenaminen |
| EP3700886B1 (de) | 2017-10-27 | 2021-10-13 | Basf Se | Verfahren zur herstellung von ethylenaminen |
| EP3700884B1 (de) | 2017-10-27 | 2021-10-13 | Basf Se | Verfahren zur herstellung von ethylenaminen |
| WO2019081284A1 (de) | 2017-10-27 | 2019-05-02 | Basf Se | Abtrennung von n-methylethylendiamin aus eda-haltigen gemischen |
| CN109490453A (zh) * | 2018-11-06 | 2019-03-19 | 广东省安全生产技术中心有限公司 | 一种三乙烯四胺的分离鉴定方法 |
| WO2020251812A1 (en) * | 2019-06-13 | 2020-12-17 | Dow Global Technologies Llc | Making ethylenediaminetetraacetic acid |
| JP2023510492A (ja) | 2019-12-13 | 2023-03-14 | ビーエーエスエフ ソシエタス・ヨーロピア | Ｅｄａ含有混合物からのｎ－メチルエチレンジアミンの分離 |
| CA3201514A1 (en) * | 2020-12-16 | 2022-06-23 | Nouryon Chemicals International B.V. | Manufacture of nitrile compounds |
| EP4547644A1 (en) | 2022-06-29 | 2025-05-07 | Basf Se | Method for manufacture of ethyleneamines |
| JP2025520810A (ja) | 2022-06-29 | 2025-07-03 | ビーエーエスエフ ソシエタス・ヨーロピア | エチレンアミンの製造方法 |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3462493A (en) | 1967-01-16 | 1969-08-19 | Dow Chemical Co | Process for making triethylenetetramine |
| DE2439275B2 (de) * | 1974-08-16 | 1978-09-21 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Diäthylentriamin und Triäthylentetramin aus Äthylendiamin |
| GB1579599A (en) * | 1977-01-28 | 1980-11-19 | Texaco Development Corp | Catalyst pellet stabilization in the preparation of polyamines from polynitriles |
| JPS5459228A (en) * | 1977-10-17 | 1979-05-12 | Showa Denko Kk | Preparation of ethylenediamine diacetonitrile |
| US4235821A (en) | 1979-02-01 | 1980-11-25 | Suntech, Inc. | Hydrogenation of aliphatic nitriles to primary amines |
| US4404167A (en) | 1979-05-14 | 1983-09-13 | Rozenfeld Iosif L | Protecting steel and ferrous metals against H2 S corrosion |
| US4721811A (en) | 1985-08-26 | 1988-01-26 | W. R. Grace & Co. | Synthesis of aliphatic polyamines |
| EP0222934A1 (en) | 1985-09-11 | 1987-05-27 | The Dow Chemical Company | Process for preparation of polyalkylenepolyamines |
| JPH07107025B2 (ja) * | 1986-06-04 | 1995-11-15 | 三井東圧化学株式会社 | ポリエチレンポリアミンの製造方法 |
| SU1541204A1 (ru) * | 1988-01-25 | 1990-02-07 | Предприятие П/Я В-8469 | Способ совместного получени триэтилентетрамина и 1-[(2-аминоэтил)-аминоэтил]-пиперазина |
| US5030740A (en) * | 1988-10-14 | 1991-07-09 | The Dow Chemical Company | Process for preparing linearly-extended polyalkylenepolyamines |
| NZ232379A (en) | 1989-02-07 | 1991-05-28 | Grace W R & Co | Batchwise preparation of non-cyclic aliphatic polyamines by catalytic hydrogenation of a non-cyclic aliphatic polynitrile |
| JPH04202163A (ja) * | 1990-11-30 | 1992-07-22 | Mitsui Toatsu Chem Inc | エチレンアミン類の製造法 |
| DE4428004A1 (de) | 1994-08-08 | 1996-02-15 | Basf Ag | Verfahren zur Herstellung von Aminen |
| EP0742045B1 (de) | 1995-05-09 | 2001-12-12 | Basf Aktiengesellschaft | Kobaltkatalysatoren |
| JPH1045682A (ja) * | 1996-08-05 | 1998-02-17 | Tosoh Corp | 高品位ポリエチレンポリアミン類の製造方法 |
| ATE346860T1 (de) * | 1996-12-06 | 2006-12-15 | Univ Minnesota | Mutanten von streptococcaltoxinen und vefahren zu deren anwendung |
| US5869653A (en) | 1997-10-30 | 1999-02-09 | Air Products And Chemicals, Inc. | Hydrogenation of nitriles to produce amines |
| FR2773086B1 (fr) * | 1997-12-29 | 2000-02-11 | Rhone Poulenc Fibres | Procede de regeneration d'un catalyseur d'hydrogenation procede d'hydrogenation de composes comprenant des fonctions nitriles |
| DE19809687A1 (de) * | 1998-03-06 | 1999-09-09 | Basf Ag | Hydrierkatalysator |
| DE19826396A1 (de) | 1998-06-12 | 1999-12-16 | Basf Ag | Verfahren zur Herstellung von Aminen |
| DE10056840A1 (de) | 2000-11-16 | 2002-05-23 | Basf Ag | Verfahren zur Hydrierung von Nitrilen an Raney-Katalysatoren |
| DE10335991A1 (de) * | 2003-08-01 | 2005-02-24 | Basf Ag | Verfahren zur Herstellung von Ethylenaminen |
| WO2005103669A1 (ja) | 2004-04-19 | 2005-11-03 | Matsushita Electric Industrial Co., Ltd. | 血液成分の測定方法、それに用いるバイオセンサおよび測定装置 |
| WO2006027705A2 (en) * | 2004-07-19 | 2006-03-16 | Protemix Corporation Limited | Synthesis of triethylenetetramines |
| KR20090125263A (ko) * | 2007-03-01 | 2009-12-04 | 바스프 에스이 | 트리에틸렌테트라민의 제조 방법 |
| ATE482923T1 (de) * | 2007-03-01 | 2010-10-15 | Basf Se | Herstellungsverfahren für ethylenamingemische |
-
2008
- 2008-02-28 JP JP2009551210A patent/JP5415287B2/ja not_active Expired - Fee Related
- 2008-02-28 WO PCT/EP2008/052413 patent/WO2008104582A2/de not_active Ceased
- 2008-02-28 EP EP08717210.2A patent/EP2129651B1/de not_active Not-in-force
- 2008-02-28 RU RU2009136185/04A patent/RU2472772C2/ru not_active IP Right Cessation
- 2008-02-28 US US12/529,072 patent/US8299249B2/en not_active Expired - Fee Related
- 2008-02-28 CN CN200880006798.3A patent/CN101622224B/zh not_active Expired - Fee Related
- 2008-02-28 EP EP12183433.7A patent/EP2537835B1/de not_active Not-in-force
- 2008-02-28 KR KR1020097018164A patent/KR20090122435A/ko not_active Withdrawn
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