JP5415287B2 - Ｅｄｄｎを経由するｔｅｔａの新規製法 - Google Patents
Ｅｄｄｎを経由するｔｅｔａの新規製法 Download PDFInfo
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- JP5415287B2 JP5415287B2 JP2009551210A JP2009551210A JP5415287B2 JP 5415287 B2 JP5415287 B2 JP 5415287B2 JP 2009551210 A JP2009551210 A JP 2009551210A JP 2009551210 A JP2009551210 A JP 2009551210A JP 5415287 B2 JP5415287 B2 JP 5415287B2
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- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 125000005237 alkyleneamino group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 229910000071 diazene Inorganic materials 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- XNWKZBZIZGNODF-UHFFFAOYSA-N ethane-1,2-diamine propanenitrile Chemical compound C(CC)#N.C(CN)N XNWKZBZIZGNODF-UHFFFAOYSA-N 0.000 description 1
- HVSGRYKGNAZITB-UHFFFAOYSA-N ethane-1,2-diamine;propanenitrile Chemical compound CCC#N.CCC#N.NCCN HVSGRYKGNAZITB-UHFFFAOYSA-N 0.000 description 1
- IFQUWYZCAGRUJN-UHFFFAOYSA-N ethylenediaminediacetic acid Chemical compound OC(=O)CNCCNCC(O)=O IFQUWYZCAGRUJN-UHFFFAOYSA-N 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000008098 formaldehyde solution Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 238000009904 heterogeneous catalytic hydrogenation reaction Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 238000007327 hydrogenolysis reaction Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 150000002461 imidazolidines Chemical class 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- IWELDVXSEVIIGI-UHFFFAOYSA-N piperazin-2-one Chemical class O=C1CNCCN1 IWELDVXSEVIIGI-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 150000003463 sulfur Chemical class 0.000 description 1
- RUPAXCPQAAOIPB-UHFFFAOYSA-N tert-butyl formate Chemical group CC(C)(C)OC=O RUPAXCPQAAOIPB-UHFFFAOYSA-N 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
- C07C209/48—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/12—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms
- C07D295/125—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms with the ring nitrogen atoms and the substituent nitrogen atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
- C07D295/13—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms with the ring nitrogen atoms and the substituent nitrogen atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/20—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic unsaturated carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07103295.7 | 2007-03-01 | ||
| EP07103295 | 2007-03-01 | ||
| PCT/EP2008/052413 WO2008104582A2 (de) | 2007-03-01 | 2008-02-28 | Neues verfahren zur herstellung von teta über eddn |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010520170A JP2010520170A (ja) | 2010-06-10 |
| JP2010520170A5 JP2010520170A5 (enExample) | 2011-04-14 |
| JP5415287B2 true JP5415287B2 (ja) | 2014-02-12 |
Family
ID=39433821
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009551210A Expired - Fee Related JP5415287B2 (ja) | 2007-03-01 | 2008-02-28 | Ｅｄｄｎを経由するｔｅｔａの新規製法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8299249B2 (enExample) |
| EP (2) | EP2129651B1 (enExample) |
| JP (1) | JP5415287B2 (enExample) |
| KR (1) | KR20090122435A (enExample) |
| CN (1) | CN101622224B (enExample) |
| RU (1) | RU2472772C2 (enExample) |
| WO (1) | WO2008104582A2 (enExample) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008104552A1 (de) * | 2007-03-01 | 2008-09-04 | Basf Se | Herstellungsverfahren für ethylenamingemische |
| EP2114861B1 (de) * | 2007-03-01 | 2012-09-05 | Basf Se | Verfahren zur herstellung von triethylentetraamin |
| KR20100014695A (ko) * | 2007-03-01 | 2010-02-10 | 바스프 에스이 | 테트라에틸렌펜타민의 제조 방법 |
| EP2356095B2 (en) * | 2008-10-06 | 2017-09-27 | Union Carbide Chemicals & Plastics Technology LLC | Methods of making cyclic, n-amino functional triamines |
| EP2346809B1 (en) | 2008-10-06 | 2016-01-13 | Union Carbide Chemicals & Plastics Technology LLC | Method of manufacturing ethyleneamines |
| EP2340113B1 (en) | 2008-10-06 | 2020-06-03 | Union Carbide Corporation | Low metal (nickel and rhenium) catalyst compositions including acidic mixed metal oxide as support |
| JP5469173B2 (ja) | 2008-10-06 | 2014-04-09 | ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー | 金属低配合、アルミナ担持触媒組成物及びアミノ化方法 |
| BRPI0922984B1 (pt) | 2008-12-19 | 2017-10-24 | Basf Se | Process for preparing pure triethanolamine |
| EP2443088B1 (de) | 2009-06-18 | 2013-08-14 | Basf Se | Methyl-substituierte teta-verbindungen |
| US8766010B2 (en) | 2009-12-02 | 2014-07-01 | Basf Se | Method for distilling mixtures comprising ethylenediamine, N-methylethylenediamine, and water, and mixtures of ethylenediamine and N-methylethylenediamine having a low content of N-methylethylenediamine obtainable thereby |
| KR20130037667A (ko) * | 2010-03-02 | 2013-04-16 | 바스프 에스이 | 에폭시 수지를 위한 경화제로서의 선형 트리에틸렌테트라민의 용도 |
| EP2557074A1 (en) * | 2011-08-11 | 2013-02-13 | Astellas Pharma Inc. | Process for the preparation of N,N,N',N'-tetrakis(3-aminopropyl)-1,4-butanediamine |
| WO2013030143A1 (de) | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von eddn und/edmn |
| WO2013030144A1 (de) * | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von eddn, edmn, teta und deta |
| WO2013030287A1 (de) | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von eddn und/oder edmn durch umsetzung von fach und eda |
| WO2013030255A1 (de) * | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von eddn und/oder edmn sowie verfahren zur herstellung von deta und/oder teta |
| EP2751067A1 (de) * | 2011-08-31 | 2014-07-09 | Basf Se | Verfahren zur aufarbeitung von reaktionsausträgen aus der hydrierung von eddn bzw. edmn |
| CN103764617B (zh) * | 2011-08-31 | 2015-12-02 | 巴斯夫欧洲公司 | 通过使edfa和/或edmfa与hcn反应制备eddn和/或edmn的方法 |
| US8952156B2 (en) | 2011-08-31 | 2015-02-10 | Basf Se | Process for working up reaction outputs from the hydrogenation of EDDN or EDMN |
| CN103764618A (zh) * | 2011-08-31 | 2014-04-30 | 巴斯夫欧洲公司 | 制备edfa和/或edmfa以及deta和/或teta的方法 |
| US9012638B2 (en) | 2011-08-31 | 2015-04-21 | Basf Se | Process for preparing EDDN and/or EDMN by conversion of FACH and EDA |
| WO2013030254A1 (de) * | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von teta und/oder deta |
| US9096497B2 (en) | 2011-08-31 | 2015-08-04 | Basf Se | Process for preparing EDDN and EDMN |
| US8946459B2 (en) | 2011-08-31 | 2015-02-03 | Basf Se | Process for preparing EDDN and/or EDMN by reacting EDFA and/or EDMFA with HCN |
| WO2013030023A1 (de) * | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von eddn und/oder edmn sowie ein verfahren zur herstellung von deta und/oder teta |
| US20130053536A1 (en) * | 2011-08-31 | 2013-02-28 | Basf Se | Process for preparing eddn and/or edmn and a process for preparing deta and/or teta |
| WO2013030259A1 (de) * | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von teta |
| WO2013030249A1 (de) * | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von aminen durch hydrierung von nitrilen |
| US9783486B2 (en) | 2013-12-02 | 2017-10-10 | Dow Global Technologies Llc | Preparation of high molecular weight, branched, acyclic polyalkyleneamines and mixtures thereof |
| US9888584B2 (en) | 2014-12-31 | 2018-02-06 | Invensas Corporation | Contact structures with porous networks for solder connections, and methods of fabricating same |
| BR112018014270B1 (pt) | 2016-02-12 | 2022-10-11 | Akzo Nobel Chemicals International B.V. | Processo de preparação de etilenoaminas |
| US10428011B2 (en) | 2016-02-12 | 2019-10-01 | Nouryon Chemicals International B.V. | Process to prepare higher ethylene amines and ethylene amine derivatives |
| US10844001B2 (en) | 2016-02-12 | 2020-11-24 | Nouryon Chemicals International B.V. | Process to prepare higher ethylene amines and ethylene amine derivatives |
| CN110959000A (zh) | 2017-07-10 | 2020-04-03 | 诺力昂化学品国际有限公司 | 制备高级亚乙基胺的方法 |
| WO2019011711A1 (en) * | 2017-07-10 | 2019-01-17 | Akzo Nobel Chemicals International B.V. | PROCESS FOR PREPARING HIGHER ETHYLENEAMINES OR URETH DERIVATIVES |
| JP7268017B2 (ja) | 2017-10-27 | 2023-05-02 | ビーエーエスエフ ソシエタス・ヨーロピア | エチレンアミンの製造方法 |
| WO2019081285A1 (de) | 2017-10-27 | 2019-05-02 | Basf Se | Verfahren zur herstellung von ethylenaminen |
| WO2019081284A1 (de) | 2017-10-27 | 2019-05-02 | Basf Se | Abtrennung von n-methylethylendiamin aus eda-haltigen gemischen |
| JP7277454B2 (ja) | 2017-10-27 | 2023-05-19 | ビーエーエスエフ ソシエタス・ヨーロピア | エチレンアミンの製造方法 |
| CN109490453A (zh) * | 2018-11-06 | 2019-03-19 | 广东省安全生产技术中心有限公司 | 一种三乙烯四胺的分离鉴定方法 |
| JP2022536735A (ja) * | 2019-06-13 | 2022-08-18 | ダウ グローバル テクノロジーズ エルエルシー | エチレンジアミン四酢酸の作製 |
| EP4073026B1 (en) | 2019-12-13 | 2024-06-05 | Basf Se | Separation of n-methylethylenediamine from eda-containing mixtures |
| US20240132444A1 (en) * | 2020-12-16 | 2024-04-25 | Nouryon Chemicals International B.V. | Manufacture of nitrile compounds |
| WO2024002748A1 (en) | 2022-06-29 | 2024-01-04 | Basf Se | Method for manufacture of ethyleneamines |
| CN119486997A (zh) | 2022-06-29 | 2025-02-18 | 巴斯夫欧洲公司 | 用于制造亚乙基胺的方法 |
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| US3462493A (en) | 1967-01-16 | 1969-08-19 | Dow Chemical Co | Process for making triethylenetetramine |
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| GB1579599A (en) | 1977-01-28 | 1980-11-19 | Texaco Development Corp | Catalyst pellet stabilization in the preparation of polyamines from polynitriles |
| JPS5459228A (en) * | 1977-10-17 | 1979-05-12 | Showa Denko Kk | Preparation of ethylenediamine diacetonitrile |
| US4235821A (en) * | 1979-02-01 | 1980-11-25 | Suntech, Inc. | Hydrogenation of aliphatic nitriles to primary amines |
| US4404167A (en) | 1979-05-14 | 1983-09-13 | Rozenfeld Iosif L | Protecting steel and ferrous metals against H2 S corrosion |
| US4721811A (en) | 1985-08-26 | 1988-01-26 | W. R. Grace & Co. | Synthesis of aliphatic polyamines |
| EP0222934A1 (en) | 1985-09-11 | 1987-05-27 | The Dow Chemical Company | Process for preparation of polyalkylenepolyamines |
| JPH07107025B2 (ja) * | 1986-06-04 | 1995-11-15 | 三井東圧化学株式会社 | ポリエチレンポリアミンの製造方法 |
| SU1541204A1 (ru) * | 1988-01-25 | 1990-02-07 | Предприятие П/Я В-8469 | Способ совместного получени триэтилентетрамина и 1-[(2-аминоэтил)-аминоэтил]-пиперазина |
| US5030740A (en) | 1988-10-14 | 1991-07-09 | The Dow Chemical Company | Process for preparing linearly-extended polyalkylenepolyamines |
| NZ232379A (en) | 1989-02-07 | 1991-05-28 | Grace W R & Co | Batchwise preparation of non-cyclic aliphatic polyamines by catalytic hydrogenation of a non-cyclic aliphatic polynitrile |
| JPH04202163A (ja) * | 1990-11-30 | 1992-07-22 | Mitsui Toatsu Chem Inc | エチレンアミン類の製造法 |
| DE4428004A1 (de) * | 1994-08-08 | 1996-02-15 | Basf Ag | Verfahren zur Herstellung von Aminen |
| EP0742045B1 (de) | 1995-05-09 | 2001-12-12 | Basf Aktiengesellschaft | Kobaltkatalysatoren |
| JPH1045682A (ja) * | 1996-08-05 | 1998-02-17 | Tosoh Corp | 高品位ポリエチレンポリアミン類の製造方法 |
| AU7625798A (en) * | 1996-12-06 | 1998-06-29 | Regents Of The University Of Minnesota | Mutants of streptococcal toxin A and methods of use |
| US5869653A (en) | 1997-10-30 | 1999-02-09 | Air Products And Chemicals, Inc. | Hydrogenation of nitriles to produce amines |
| FR2773086B1 (fr) * | 1997-12-29 | 2000-02-11 | Rhone Poulenc Fibres | Procede de regeneration d'un catalyseur d'hydrogenation procede d'hydrogenation de composes comprenant des fonctions nitriles |
| DE19809687A1 (de) * | 1998-03-06 | 1999-09-09 | Basf Ag | Hydrierkatalysator |
| DE19826396A1 (de) | 1998-06-12 | 1999-12-16 | Basf Ag | Verfahren zur Herstellung von Aminen |
| DE10056840A1 (de) * | 2000-11-16 | 2002-05-23 | Basf Ag | Verfahren zur Hydrierung von Nitrilen an Raney-Katalysatoren |
| DE10335991A1 (de) * | 2003-08-01 | 2005-02-24 | Basf Ag | Verfahren zur Herstellung von Ethylenaminen |
| CN1938590B (zh) | 2004-04-19 | 2010-05-05 | 松下电器产业株式会社 | 血液成分的测定方法、该方法中使用的生物传感器和测定装置 |
| DK1778618T3 (da) * | 2004-07-19 | 2014-03-10 | Philera New Zealand Ltd | Syntese af triethylentetraminer |
| EP2114861B1 (de) * | 2007-03-01 | 2012-09-05 | Basf Se | Verfahren zur herstellung von triethylentetraamin |
| WO2008104552A1 (de) * | 2007-03-01 | 2008-09-04 | Basf Se | Herstellungsverfahren für ethylenamingemische |
-
2008
- 2008-02-28 WO PCT/EP2008/052413 patent/WO2008104582A2/de not_active Ceased
- 2008-02-28 US US12/529,072 patent/US8299249B2/en not_active Expired - Fee Related
- 2008-02-28 EP EP08717210.2A patent/EP2129651B1/de not_active Not-in-force
- 2008-02-28 KR KR1020097018164A patent/KR20090122435A/ko not_active Withdrawn
- 2008-02-28 RU RU2009136185/04A patent/RU2472772C2/ru not_active IP Right Cessation
- 2008-02-28 CN CN200880006798.3A patent/CN101622224B/zh not_active Expired - Fee Related
- 2008-02-28 EP EP12183433.7A patent/EP2537835B1/de not_active Not-in-force
- 2008-02-28 JP JP2009551210A patent/JP5415287B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP2129651B1 (de) | 2013-04-10 |
| EP2129651A2 (de) | 2009-12-09 |
| WO2008104582A2 (de) | 2008-09-04 |
| WO2008104582A3 (de) | 2009-02-12 |
| EP2537835A1 (de) | 2012-12-26 |
| RU2472772C2 (ru) | 2013-01-20 |
| US8299249B2 (en) | 2012-10-30 |
| CN101622224A (zh) | 2010-01-06 |
| US20100121064A1 (en) | 2010-05-13 |
| RU2009136185A (ru) | 2011-04-10 |
| JP2010520170A (ja) | 2010-06-10 |
| KR20090122435A (ko) | 2009-11-30 |
| CN101622224B (zh) | 2015-10-07 |
| EP2537835B1 (de) | 2014-04-30 |
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