JP2009545659A - 異相プロピレンコポリマーを製造するための気相法 - Google Patents
異相プロピレンコポリマーを製造するための気相法 Download PDFInfo
- Publication number
- JP2009545659A JP2009545659A JP2009523235A JP2009523235A JP2009545659A JP 2009545659 A JP2009545659 A JP 2009545659A JP 2009523235 A JP2009523235 A JP 2009523235A JP 2009523235 A JP2009523235 A JP 2009523235A JP 2009545659 A JP2009545659 A JP 2009545659A
- Authority
- JP
- Japan
- Prior art keywords
- propylene
- polymerization
- reactor
- weight
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims abstract description 90
- 229920001577 copolymer Polymers 0.000 title claims abstract description 58
- 238000000034 method Methods 0.000 title claims abstract description 45
- 230000008569 process Effects 0.000 title claims description 23
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 89
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 72
- 239000003054 catalyst Substances 0.000 claims abstract description 46
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 30
- -1 magnesium halide Chemical class 0.000 claims abstract description 26
- 239000008096 xylene Substances 0.000 claims abstract description 26
- 150000001875 compounds Chemical class 0.000 claims abstract description 16
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 14
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 13
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 12
- 239000002685 polymerization catalyst Substances 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims abstract description 11
- 150000003609 titanium compounds Chemical class 0.000 claims abstract description 9
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims abstract description 5
- 239000011777 magnesium Substances 0.000 claims abstract description 5
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 4
- 229920006126 semicrystalline polymer Polymers 0.000 claims abstract description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 58
- 239000011159 matrix material Substances 0.000 claims description 35
- 239000001294 propane Substances 0.000 claims description 29
- 239000005977 Ethylene Substances 0.000 claims description 19
- 229920001155 polypropylene Polymers 0.000 claims description 18
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 17
- 239000004743 Polypropylene Substances 0.000 claims description 15
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 12
- 239000004711 α-olefin Substances 0.000 claims description 7
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 6
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 5
- 150000002170 ethers Chemical class 0.000 claims description 4
- 229920005606 polypropylene copolymer Polymers 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 150000001298 alcohols Chemical group 0.000 claims description 2
- 150000001408 amides Chemical class 0.000 claims description 2
- 150000002334 glycols Chemical class 0.000 claims description 2
- GJTGYNPBJNRYKI-UHFFFAOYSA-N hex-1-ene;prop-1-ene Chemical compound CC=C.CCCCC=C GJTGYNPBJNRYKI-UHFFFAOYSA-N 0.000 claims description 2
- 150000002825 nitriles Chemical class 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 229920001897 terpolymer Polymers 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 abstract description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract description 4
- 239000007789 gas Substances 0.000 description 51
- 239000012071 phase Substances 0.000 description 38
- 229920000642 polymer Polymers 0.000 description 32
- 239000011949 solid catalyst Substances 0.000 description 25
- 239000000203 mixture Substances 0.000 description 19
- 229920001971 elastomer Polymers 0.000 description 14
- 239000007788 liquid Substances 0.000 description 13
- 239000001257 hydrogen Substances 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- 239000005060 rubber Substances 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 239000010936 titanium Substances 0.000 description 9
- 150000001335 aliphatic alkanes Chemical class 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000002002 slurry Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- 238000012685 gas phase polymerization Methods 0.000 description 6
- 239000003701 inert diluent Substances 0.000 description 6
- 239000011261 inert gas Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000000806 elastomer Substances 0.000 description 5
- 229920000098 polyolefin Polymers 0.000 description 5
- 229920001384 propylene homopolymer Polymers 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical group CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000009408 flooring Methods 0.000 description 2
- 150000002367 halogens Chemical group 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- 229910003475 inorganic filler Inorganic materials 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 230000000877 morphologic effect Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000002464 physical blending Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000012798 spherical particle Substances 0.000 description 2
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- 229920000034 Plastomer Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/02—Heterophasic composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06118457 | 2006-08-04 | ||
| PCT/EP2007/057539 WO2008015113A2 (en) | 2006-08-04 | 2007-07-20 | Gas-phase process for preparing heterophasic propylene copolymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2009545659A true JP2009545659A (ja) | 2009-12-24 |
| JP2009545659A5 JP2009545659A5 (enExample) | 2010-08-05 |
Family
ID=38596398
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009523235A Pending JP2009545659A (ja) | 2006-08-04 | 2007-07-20 | 異相プロピレンコポリマーを製造するための気相法 |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP2046846B1 (enExample) |
| JP (1) | JP2009545659A (enExample) |
| KR (1) | KR101422554B1 (enExample) |
| CN (1) | CN101522782B (enExample) |
| AT (1) | ATE510868T1 (enExample) |
| BR (1) | BRPI0714250B1 (enExample) |
| CA (1) | CA2659749A1 (enExample) |
| RU (1) | RU2444547C2 (enExample) |
| WO (1) | WO2008015113A2 (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016511322A (ja) * | 2013-03-14 | 2016-04-14 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | プロピレン／ブテンインターポリマー生成システム及び方法 |
| JP2023514429A (ja) * | 2020-02-24 | 2023-04-05 | ボレアリス・アクチェンゲゼルシャフト | 多段階重合プロセスにおいてアルファ－オレフィンポリマーを製造するための方法 |
| JP2023550317A (ja) * | 2020-11-25 | 2023-12-01 | ボレアリス エージー | プロピレンプラント改修プロセス |
| JP2023551548A (ja) * | 2020-12-01 | 2023-12-08 | ボレアリス・アクチェンゲゼルシャフト | 多段方法におけるポリオレフィン組成物の製造方法 |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2563498T3 (es) | 2007-08-27 | 2016-03-15 | Borealis Technology Oy | Equipo y procedimiento para producir gránulos de polímero |
| ES2447571T3 (es) * | 2008-06-16 | 2014-03-12 | Borealis Ag | Poliolefinas termoplásticas con alta fluidez y excelente calidad superficial producidas mediante un proceso multietápico |
| CN102190748B (zh) * | 2010-03-19 | 2013-03-27 | 中国石油天然气股份有限公司 | 一种丙烯/1-丁烯无规共聚树脂的制备方法 |
| EP2368921B1 (en) * | 2010-03-26 | 2014-11-26 | Borealis AG | Process for the preparation of flowable comonomer rich polypropylene |
| CN102399395B (zh) * | 2010-09-07 | 2013-02-13 | 中国石油天然气股份有限公司 | 一种高流动高乙烯含量无规共聚透明聚丙烯树脂的制备方法 |
| EP2452956A1 (en) * | 2010-11-12 | 2012-05-16 | Borealis AG | Improved process for polymerising propylene |
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| WO2022269364A1 (en) | 2021-06-25 | 2022-12-29 | Braskem S.A. | Propylene preliminary polymerization |
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| CN115926076A (zh) * | 2022-12-05 | 2023-04-07 | 北京鑫美格工程设计有限公司 | 一种聚丙烯合金的生产方法及装置 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03100013A (ja) * | 1989-09-13 | 1991-04-25 | Mitsubishi Petrochem Co Ltd | プロピレンブロック共重合体の製造法 |
| JPH06145270A (ja) * | 1992-11-12 | 1994-05-24 | Tosoh Corp | プロピレンブロック共重合体の製造方法 |
| JP2002528621A (ja) * | 1998-11-03 | 2002-09-03 | モンテック ユーエスエー インコーポレーテッド | 剛性と衝撃強さの調和がとれたポリオレフィン組成物 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1230134B (it) * | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
| IT1246614B (it) * | 1991-06-03 | 1994-11-24 | Himont Inc | Procedimento per la polimerizzazione in fase gas delle olefine |
| IT1271420B (it) * | 1993-08-30 | 1997-05-28 | Himont Inc | Composizioni poliolefiniche aventi un elevato bilancio di rigidita' e resilienza |
| IT1302029B1 (it) * | 1998-08-19 | 2000-07-20 | Montech Usa Inc | Processo per produrre composizioni polimeriche eterofasiche ecomposizioni cosi' ottenute |
| EP1279699A1 (en) * | 2001-07-27 | 2003-01-29 | Baselltech USA Inc. | Soft polyolefin compositions |
-
2007
- 2007-07-20 KR KR1020097002232A patent/KR101422554B1/ko active Active
- 2007-07-20 CN CN2007800366482A patent/CN101522782B/zh active Active
- 2007-07-20 CA CA002659749A patent/CA2659749A1/en not_active Abandoned
- 2007-07-20 AT AT07787787T patent/ATE510868T1/de not_active IP Right Cessation
- 2007-07-20 RU RU2009107703/05A patent/RU2444547C2/ru active
- 2007-07-20 WO PCT/EP2007/057539 patent/WO2008015113A2/en not_active Ceased
- 2007-07-20 JP JP2009523235A patent/JP2009545659A/ja active Pending
- 2007-07-20 EP EP07787787A patent/EP2046846B1/en active Active
- 2007-07-20 BR BRPI0714250-1A patent/BRPI0714250B1/pt active IP Right Grant
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03100013A (ja) * | 1989-09-13 | 1991-04-25 | Mitsubishi Petrochem Co Ltd | プロピレンブロック共重合体の製造法 |
| JPH06145270A (ja) * | 1992-11-12 | 1994-05-24 | Tosoh Corp | プロピレンブロック共重合体の製造方法 |
| JP2002528621A (ja) * | 1998-11-03 | 2002-09-03 | モンテック ユーエスエー インコーポレーテッド | 剛性と衝撃強さの調和がとれたポリオレフィン組成物 |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016511322A (ja) * | 2013-03-14 | 2016-04-14 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | プロピレン／ブテンインターポリマー生成システム及び方法 |
| JP2023514429A (ja) * | 2020-02-24 | 2023-04-05 | ボレアリス・アクチェンゲゼルシャフト | 多段階重合プロセスにおいてアルファ－オレフィンポリマーを製造するための方法 |
| JP7463536B2 (ja) | 2020-02-24 | 2024-04-08 | ボレアリス・アクチェンゲゼルシャフト | 多段階重合プロセスにおいてアルファ－オレフィンポリマーを製造するための方法 |
| JP2023550317A (ja) * | 2020-11-25 | 2023-12-01 | ボレアリス エージー | プロピレンプラント改修プロセス |
| JP7556149B2 (ja) | 2020-11-25 | 2024-09-25 | ボレアリス エージー | プロピレンプラント改修プロセス |
| JP2023551548A (ja) * | 2020-12-01 | 2023-12-08 | ボレアリス・アクチェンゲゼルシャフト | 多段方法におけるポリオレフィン組成物の製造方法 |
| JP7689185B2 (ja) | 2020-12-01 | 2025-06-05 | ボレアリス・アクチェンゲゼルシャフト | 多段方法におけるポリオレフィン組成物の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2444547C2 (ru) | 2012-03-10 |
| WO2008015113A3 (en) | 2008-03-27 |
| EP2046846A2 (en) | 2009-04-15 |
| CN101522782B (zh) | 2011-12-28 |
| KR20090034955A (ko) | 2009-04-08 |
| BRPI0714250A2 (pt) | 2015-04-22 |
| ATE510868T1 (de) | 2011-06-15 |
| CA2659749A1 (en) | 2008-02-07 |
| RU2009107703A (ru) | 2010-09-10 |
| EP2046846B1 (en) | 2011-05-25 |
| CN101522782A (zh) | 2009-09-02 |
| WO2008015113A2 (en) | 2008-02-07 |
| KR101422554B1 (ko) | 2014-07-24 |
| BRPI0714250B1 (pt) | 2018-04-17 |
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