JP2009537648A - 水溶液用増粘剤としてのカーボンナノチューブをベースにした複合材料の使用 - Google Patents
水溶液用増粘剤としてのカーボンナノチューブをベースにした複合材料の使用 Download PDFInfo
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- JP2009537648A JP2009537648A JP2009510518A JP2009510518A JP2009537648A JP 2009537648 A JP2009537648 A JP 2009537648A JP 2009510518 A JP2009510518 A JP 2009510518A JP 2009510518 A JP2009510518 A JP 2009510518A JP 2009537648 A JP2009537648 A JP 2009537648A
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- 239000002041 carbon nanotube Substances 0.000 title claims abstract description 78
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 229910021393 carbon nanotube Inorganic materials 0.000 title claims abstract description 64
- 239000002131 composite material Substances 0.000 title claims abstract description 37
- 239000007864 aqueous solution Substances 0.000 title claims abstract description 19
- 239000002562 thickening agent Substances 0.000 title claims abstract description 12
- -1 public works Substances 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920001480 hydrophilic copolymer Polymers 0.000 claims abstract description 9
- 239000011230 binding agent Substances 0.000 claims abstract description 3
- 239000004568 cement Substances 0.000 claims abstract description 3
- 239000000919 ceramic Substances 0.000 claims abstract description 3
- 239000012459 cleaning agent Substances 0.000 claims abstract description 3
- 239000000976 ink Substances 0.000 claims abstract description 3
- 239000003973 paint Substances 0.000 claims abstract description 3
- 239000003208 petroleum Substances 0.000 claims abstract description 3
- 239000002966 varnish Substances 0.000 claims abstract description 3
- 239000003292 glue Substances 0.000 claims abstract 2
- 239000000178 monomer Substances 0.000 claims description 78
- 229920000642 polymer Polymers 0.000 claims description 54
- 239000000203 mixture Substances 0.000 claims description 17
- 239000000243 solution Substances 0.000 claims description 16
- 239000002253 acid Substances 0.000 claims description 13
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 12
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 12
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 12
- 238000006386 neutralization reaction Methods 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 7
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
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- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 5
- 150000001993 dienes Chemical class 0.000 claims description 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 5
- MKPHQUIFIPKXJL-UHFFFAOYSA-N 1,2-dihydroxypropyl 2-methylprop-2-enoate Chemical compound CC(O)C(O)OC(=O)C(C)=C MKPHQUIFIPKXJL-UHFFFAOYSA-N 0.000 claims description 4
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
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- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Substances OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 4
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- XEEYSDHEOQHCDA-UHFFFAOYSA-N 2-methylprop-2-ene-1-sulfonic acid Chemical compound CC(=C)CS(O)(=O)=O XEEYSDHEOQHCDA-UHFFFAOYSA-N 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 3
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- 229920001400 block copolymer Polymers 0.000 claims description 3
- XLPJNCYCZORXHG-UHFFFAOYSA-N 1-morpholin-4-ylprop-2-en-1-one Chemical compound C=CC(=O)N1CCOCC1 XLPJNCYCZORXHG-UHFFFAOYSA-N 0.000 claims description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 2
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 claims description 2
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 claims description 2
- KQHBCOBBLJGPTD-UHFFFAOYSA-N 2-[2-(2-chloropropan-2-yl)phenyl]ethyl 2-methylprop-2-enoate Chemical compound C(C(=C)C)(=O)OCCC1=C(C(C)(C)Cl)C=CC=C1 KQHBCOBBLJGPTD-UHFFFAOYSA-N 0.000 claims description 2
- DKIPRHMNBSJBNB-UHFFFAOYSA-N 2-[2-(2-chloropropan-2-yl)phenyl]ethyl prop-2-enoate Chemical compound CC(C)(Cl)C1=CC=CC=C1CCOC(=O)C=C DKIPRHMNBSJBNB-UHFFFAOYSA-N 0.000 claims description 2
- YDJFNSJFJXJHBG-UHFFFAOYSA-N 2-carbamoylprop-2-ene-1-sulfonic acid Chemical compound NC(=O)C(=C)CS(O)(=O)=O YDJFNSJFJXJHBG-UHFFFAOYSA-N 0.000 claims description 2
- KOQQKLZTINXBAS-UHFFFAOYSA-N 2-hydroxy-3-prop-2-enoxypropane-1-sulfonic acid Chemical compound OS(=O)(=O)CC(O)COCC=C KOQQKLZTINXBAS-UHFFFAOYSA-N 0.000 claims description 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 2
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 claims description 2
- NYUTUWAFOUJLKI-UHFFFAOYSA-N 3-prop-2-enoyloxypropane-1-sulfonic acid Chemical compound OS(=O)(=O)CCCOC(=O)C=C NYUTUWAFOUJLKI-UHFFFAOYSA-N 0.000 claims description 2
- WIYVVIUBKNTNKG-UHFFFAOYSA-N 6,7-dimethoxy-3,4-dihydronaphthalene-2-carboxylic acid Chemical compound C1CC(C(O)=O)=CC2=C1C=C(OC)C(OC)=C2 WIYVVIUBKNTNKG-UHFFFAOYSA-N 0.000 claims description 2
- 229920000028 Gradient copolymer Polymers 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- UDPYEFRYPGXIAL-UHFFFAOYSA-N NC(=O)C(C)=CCS(O)(=O)=O Chemical compound NC(=O)C(C)=CCS(O)(=O)=O UDPYEFRYPGXIAL-UHFFFAOYSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- 125000004104 aryloxy group Chemical group 0.000 claims description 2
- 230000003416 augmentation Effects 0.000 claims description 2
- JUZXDNPBRPUIOR-UHFFFAOYSA-N chlormequat Chemical compound C[N+](C)(C)CCCl JUZXDNPBRPUIOR-UHFFFAOYSA-N 0.000 claims description 2
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 2
- RAJUSMULYYBNSJ-UHFFFAOYSA-N prop-1-ene-1-sulfonic acid Chemical compound CC=CS(O)(=O)=O RAJUSMULYYBNSJ-UHFFFAOYSA-N 0.000 claims description 2
- XWCIXXXLOAAWPU-UHFFFAOYSA-N prop-1-enylphosphonic acid Chemical compound CC=CP(O)(O)=O XWCIXXXLOAAWPU-UHFFFAOYSA-N 0.000 claims description 2
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 claims description 2
- AYEFIAVHMUFQPZ-UHFFFAOYSA-N propane-1,2-diol;prop-2-enoic acid Chemical compound CC(O)CO.OC(=O)C=C AYEFIAVHMUFQPZ-UHFFFAOYSA-N 0.000 claims description 2
- SZHIIIPPJJXYRY-UHFFFAOYSA-M sodium;2-methylprop-2-ene-1-sulfonate Chemical compound [Na+].CC(=C)CS([O-])(=O)=O SZHIIIPPJJXYRY-UHFFFAOYSA-M 0.000 claims description 2
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 claims 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims 1
- 239000000039 congener Substances 0.000 claims 1
- 230000003472 neutralizing effect Effects 0.000 claims 1
- 239000006185 dispersion Substances 0.000 description 24
- 238000010438 heat treatment Methods 0.000 description 19
- 239000000843 powder Substances 0.000 description 19
- 229920002125 Sokalan® Polymers 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 10
- 238000000034 method Methods 0.000 description 10
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- 238000005406 washing Methods 0.000 description 8
- 239000004584 polyacrylic acid Substances 0.000 description 7
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 239000007787 solid Substances 0.000 description 5
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- 238000010526 radical polymerization reaction Methods 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
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- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 2
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 description 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
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- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
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- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
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- 125000003118 aryl group Chemical group 0.000 description 2
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- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
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- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
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- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
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- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
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- YJCVRMIJBXTMNR-UHFFFAOYSA-N 1,3-dichloro-2-ethenylbenzene Chemical compound ClC1=CC=CC(Cl)=C1C=C YJCVRMIJBXTMNR-UHFFFAOYSA-N 0.000 description 1
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 1
- VYXHVRARDIDEHS-UHFFFAOYSA-N 1,5-cyclooctadiene Chemical compound C1CC=CCCC=C1 VYXHVRARDIDEHS-UHFFFAOYSA-N 0.000 description 1
- 239000004912 1,5-cyclooctadiene Substances 0.000 description 1
- BOVQCIDBZXNFEJ-UHFFFAOYSA-N 1-chloro-3-ethenylbenzene Chemical compound ClC1=CC=CC(C=C)=C1 BOVQCIDBZXNFEJ-UHFFFAOYSA-N 0.000 description 1
- ATJIMRYXCPNUGW-UHFFFAOYSA-N 1-chloro-4-ethenyl-2-methylbenzene Chemical compound CC1=CC(C=C)=CC=C1Cl ATJIMRYXCPNUGW-UHFFFAOYSA-N 0.000 description 1
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- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/42—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells
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Abstract
【解決手段】本発明の複合材料がカーボンナノチューブ(CNT)と少なくとも一種の親水性(コ)ポリマーとから成る。本発明は特に上記複合材料の工業的な使用、例えば製紙業、特に紙加工および紙増量、石油産業、塗料、水処理、洗浄剤、セラミック、セメント、水硬性結合剤、公共事業、インク、ワニスおよび糊剤での増粘剤としての使用に関する。
【選択図】なし
Description
特に、(メタ)アクリレートは:式CH2=C(CH3)−COOR0および式CH2=CH−COO−R0(ここで、R0は直鎖または分岐鎖を有する1〜18の炭素原子を有するアルキル基、第1、第2または第3基、5〜18の炭素原子を有するシクロアルキル基、(C1−C18)アルコキシ(C1−C18)アルキル基、(C1−C18)アルキルチオ(C1−C18)アルキル基、アリール基およびアリールアルキル基の中から選択され、これらの基は必要に応じて少なくとも1つのハロゲン(例えばフッ素)原子および/または少なくとも1つのヒドロキシ基(このヒドロキシ基は保護されている)で置換されていてもよく、上記アルキル基は直鎖でも分岐鎖でもよく)、さらには、グリシジル(メタ)アクリレート、ノルボルニル(メタ)アクリレートまたはイソボルニル(メタ)アクリレートを意味する。
ビニルエステルとしては酢酸ビニル、プロピオン酸ビニル、塩化ビニルおよび弗化ビニルを挙げることができる。
ビニリデンモノマーとしては弗化ビニリデンが挙げられる。
(1)CNTを溶融ポリマー、溶融ポリマーのブレンド物または溶剤中の一種以上のポリマーの溶液と接触/分散させる方法、または
(2)CNTをモノマー、モノマーのブレンド物、溶剤中の一種以上のモノマーの溶液または一種以上のモノマーに溶解した一種以上のポリマーの溶液と接触/分散させる方法。
(1)モノマーまたはポリマーが液状の場合、CNT粉末をモノマーまたはポリマーと接触させる操作は例えばモノマーまたはポリマーを粉末に(またはその逆に)注いで直接導入するか、モノマーまたはポリマーをCNT粉末上に滴下して導入するか、噴霧機を用いてモノマーまたはポリマーをCNT粉末上に噴霧する操作等がある。この分散操作をモノマーまたはポリマーの溶液を固体表面上に広げた流体膜または微細な液滴(露)の形にし、その上にCNT粉末を注入する操作で行なうこともできる。
(3)モノマーまたはポリマーが固体状の場合、CNT粉末をモノマーまたはポリマーと接触させる操作は、各粉末を乾式混合し、その後に熱処理を行なう操作に対応する。熱処理中にモノマーまたはポリマーは液体または気体の状態に変換され、モノマーまたはポリマーとCNTとが確実に均一に混合する。
この第1の接触/分散段階の終了時にCNTとモノマーまたはポリマーとの混合物は固体粉末の形態を維持し、良好な流動特性を維持する(混合物が塊になることはない)。この混合物を必要に応じて機械的に攪拌したり、流動床の形で気体中に浮遊させることもできる。
モノマーがアクリル酸の場合、モノマーの含有率は一般に30〜90重量%である。
接触/分散段階でモノマー(液体のモノマー、モノマー溶液)を含む液体を導入した場合には、この熱処理段階は例えば加熱処理にすることができる。この加熱処理でモノマーを重合させ、および/または、強く物理吸着させ、および/または、化学吸着させることができ、CNTとモノマーまたは形成されたポリマーの一部との間に結合を形成させることができる。
モノマーまたはポリマーが液体であるか溶剤の溶液の場合にも、熱処理によって液体とCNTとの分散性を改良することができる。
本発明複合材料は通常用いられる水溶液用の増粘剤および/またはシックナーの代わりに用いるのが有利である。
本発明はさらに、増粘剤として用いられる、上記複合材料を含む水性分散体に関するものである。分散体中の複合材料の重量%は0.1〜10%、有利には0.1〜5%、好ましくは0.1〜3%である。
以下、本発明の実施例を説明するが、本発明は下記実施例に限定されるものではない。
使用したカーボンナノチューブはCVD法でアルミナ担持鉄触媒担体上で650〜700℃でエチレンを分解して得た。このナノチューブは外径が10〜30nmの多重壁で、酸化鉄および酸化アルミニウムの形をした無機不純物の全含有率は6.4%であった。
Claims (14)
- カーボンナノチューブをベースにした複合材料の水溶液用増粘剤としての使用であって、上記複合材料がカーボンナノチューブ(CNT)と少なくとも一種の親水性(コ)ポリマーとを有する使用。
- (コ)ポリマーがCNTの表面に非可逆的に吸着および/またはグラフトされている請求項1に記載の複合材料の使用。
- CNT/親水性(コ)ポリマー重量比が1〜99%、有利には5〜50%、好ましくは5〜35%である請求項1または2に記載の複合材料の使用。
- 上記(コ)ポリマーが少なくとも50重量%の一種以上の親水性モノマーから成る請求項1〜3のいずれか一項に記載の複合材料の使用。
- 親水性モノマーがイオン性モノマー(A)、中性モノマー(B)および/または両性モノマー(C)である請求項1〜4のいずれか一項に記載の複合材料の使用。
- 親水性モノマーをスチレンスルホネート(A)、アクリル酸、メタクリル酸、イタコン酸、マレイン酸またはその塩、無水マレイン酸、アルキルまたはアルコキシまたはアリールオキシポリアルキレングリコールマレエートまたはヘミマレエート、フマル酸、酸の形のまたは部分中和された2−アクリルアミド−2−メチル−1−プロパンスルホン酸(BまたはA、中和の有無に依存)、酸の形のまたは部分中和された2−メタクリルアミド−2−メチル−1−プロパンスルホン酸(BまたはA、中和の有無に依存)、アリルスルホン酸、メタリルスルホン酸、アリルオキシベンゼンスルホン酸、メタリルオキシベンゼンスルホン酸、2−ヒドロキシ−3−(2−プロペニルオキシ)プロパンスルホン酸、2−メチル−2−プロパン−1−スルホン酸、エチレンスルホン酸、プロペンスルホン酸、2−メチルスルホン酸、スチレンスルホン酸およびその塩(BまたはA、中和の有無に依存)、ビニルスルホン酸、メタリルスルホン酸ナトリウム、スルホプロピルアクリレートまたはメタクリレート(BまたはA、中和の有無に依存)、スルホメチルアクリルアミド、スルホメチルメタクリルアミド(B)の中から選択するか、または、アクリルアミド、メチルアクリルアミド、n−メチロールアクリルアミド、n−アクリロイルモルホリン、エチレングリコールメタクリレート、エチレングリコールアクリレート、プロピレングリコールメタクリレート、プロピレングリコールメタクリレート、プロピレングリコールアクリレート(B)、プロペンホスホン酸(BまたはA、中和の有無に依存)、エチレンまたはプロピレングリコール(B)メタクリレートまたはアクリレート(A)ホスフェートまたはビニルピリジン(B)、ビニルピロリジノン(B)、ビニルピロリドン(B)、アミノアルキルメタクリレート、例えば2−(ジメチルアミノ)エチルメタクリレート(DAEMA)、メタクリレートアミン塩、例えば[2−(メタクリロイルオキシ)エチル]トリメチル塩化または硫酸アンモニウムまたは[2−(メタクリロイルオキシ)エチル]ジメチルベンジルの塩化または硫酸アンモウム、メタアクリルアミドプロピルトリメチル塩化または硫酸アンモニウム(A)、トリメチルアンモニオエチル塩化または硫酸アンモニウム、およびそのアクリレートおよびアクリルアミド同族体(四級化物(A)またはその他)、例えば2−(ジメチルアミノ)エチルアクリレート(DMAEA)、アミン塩のアクリレート、例えば[2−(アクリロイルオキシ)エチル]トリメチルの塩化または硫酸アンモニウム、または[2−(アクリロイルオキシ)エチル]ジメチルベンジルの塩化または硫酸アンモニウム、および/またはジメチルジアリル塩化アンモニウムおよびその混合物(A)の中から選択する請求項1〜5のいずれか一項に記載の複合材料の使用。
- 親水性(コ)ポリマーが勾配コポリマーおよび/またはランダムブロックコポリマーであり、ブロックの一つが親水性で(コ)ポリマーの少なくとも50%である請求項1〜6のいずれか一項に記載の複合材料の使用。
- 残りのブロックが最終コポリマーを水分散性にする、上記親水性モノマーと共重合可能な少なくとも一種の不飽和エチレンモノマーである請求項7に記載の複合材料の使用。
- 不飽和エチレンモノマーをアルキル(メタ)アクリレート、スチレンモノマーおよびその置換誘導体および/またはジエンモノマーの中から選択する請求項8に記載の複合材料の使用。
- CNTを溶融ポリマー、溶融ポリマーのブレンド物または溶剤中の一種以上のポリマーの溶液と接触/分散させて複合材料を得る請求項1〜9のいずれか一項に記載の複合材料の使用。
- CNTをモノマー、モノマーのブレンド物、溶剤中の一種以上のモノマーの溶液または一種以上のモノマーに溶解した一種以上のポリマーの溶液と接触/分散させて複合材料を得る請求項1〜8のいずれか一項に記載の複合材料の使用。
- CNTを粉末状のモノマーまたはポリマーと接触/分散させて複合材料を得る請求項1〜8のいずれか一項に記載の複合材料の使用。
- 石油業、塗料、水処理、洗浄剤、セラミック、セメント、水硬性結合剤、公共事業、インク、ワニスおよび糊剤の中から選択される工業部門での請求項1〜12のいずれか一項に記載の複合材料の使用。
- 製紙業の紙加工および/または紙増量での請求項1〜12のいずれか一項に記載の複合材料の使用。
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PCT/FR2007/051286 WO2007135323A2 (fr) | 2006-05-18 | 2007-05-16 | Utilisation de materiaux composites a base de nanotubes de carbone comme agents viscosifiants de solutions aqueuses |
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US10981790B2 (en) | 2016-12-14 | 2021-04-20 | Lg Chem, Ltd. | Method for preparing functionalized graphene |
Also Published As
Publication number | Publication date |
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US20090306276A1 (en) | 2009-12-10 |
WO2007135323A2 (fr) | 2007-11-29 |
EP2018405A2 (fr) | 2009-01-28 |
CN101490142B (zh) | 2013-06-19 |
KR101213011B1 (ko) | 2012-12-17 |
JP5015240B2 (ja) | 2012-08-29 |
WO2007135323A3 (fr) | 2008-11-27 |
KR20090014200A (ko) | 2009-02-06 |
US20120132843A1 (en) | 2012-05-31 |
CN101490142A (zh) | 2009-07-22 |
FR2901154A1 (fr) | 2007-11-23 |
FR2901154B1 (fr) | 2008-07-18 |
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