JP2008519144A5 - - Google Patents
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- JP2008519144A5 JP2008519144A5 JP2007540392A JP2007540392A JP2008519144A5 JP 2008519144 A5 JP2008519144 A5 JP 2008519144A5 JP 2007540392 A JP2007540392 A JP 2007540392A JP 2007540392 A JP2007540392 A JP 2007540392A JP 2008519144 A5 JP2008519144 A5 JP 2008519144A5
- Authority
- JP
- Japan
- Prior art keywords
- glass container
- acid
- cleaning
- chelating agent
- cleaning method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000011521 glass Substances 0.000 claims 29
- 238000004140 cleaning Methods 0.000 claims 23
- 239000002738 chelating agent Substances 0.000 claims 12
- 239000000243 solution Substances 0.000 claims 8
- 239000012487 rinsing solution Substances 0.000 claims 7
- 239000002253 acid Substances 0.000 claims 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Inorganic materials [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims 3
- 239000003518 caustics Substances 0.000 claims 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 3
- 229910000000 metal hydroxide Inorganic materials 0.000 claims 3
- 150000004692 metal hydroxides Chemical class 0.000 claims 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims 3
- VZCYOOQTPOCHFL-OWOJBTEDSA-N (E)-but-2-enedioate;hydron Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N Gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims 2
- 229910001385 heavy metal Inorganic materials 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- 239000011780 sodium chloride Substances 0.000 claims 2
- ROFVEXUMMXZLPA-UHFFFAOYSA-N 2,2'-bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 claims 1
- JYXGIOKAKDAARW-UHFFFAOYSA-N 2-[carboxymethyl(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 claims 1
- 229960005261 Aspartic Acid Drugs 0.000 claims 1
- 229940022766 EGTA Drugs 0.000 claims 1
- 229960002989 Glutamic Acid Drugs 0.000 claims 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims 1
- 101710038613 MGD1 Proteins 0.000 claims 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N Malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims 1
- FEWJPZIEWOKRBE-XIXRPRMCSA-N Mesotartaric acid Chemical compound OC(=O)[C@@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-XIXRPRMCSA-N 0.000 claims 1
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K [O-]P([O-])([O-])=O Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 235000011054 acetic acid Nutrition 0.000 claims 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- 125000003277 amino group Chemical group 0.000 claims 1
- 235000003704 aspartic acid Nutrition 0.000 claims 1
- 239000007853 buffer solution Substances 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical group 0.000 claims 1
- 235000015165 citric acid Nutrition 0.000 claims 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N edta Chemical group OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims 1
- DEFVIWRASFVYLL-UHFFFAOYSA-N ethylene glycol bis(2-aminoethyl)tetraacetic acid Chemical compound OC(=O)CN(CC(O)=O)CCOCCOCCN(CC(O)=O)CC(O)=O DEFVIWRASFVYLL-UHFFFAOYSA-N 0.000 claims 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N fumaric acid Chemical compound OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 1
- 239000001530 fumaric acid Substances 0.000 claims 1
- 235000011087 fumaric acid Nutrition 0.000 claims 1
- 239000000174 gluconic acid Substances 0.000 claims 1
- 235000012208 gluconic acid Nutrition 0.000 claims 1
- 229950006191 gluconic acid Drugs 0.000 claims 1
- 239000004220 glutamic acid Substances 0.000 claims 1
- 235000013922 glutamic acid Nutrition 0.000 claims 1
- 238000002386 leaching Methods 0.000 claims 1
- 239000011976 maleic acid Substances 0.000 claims 1
- 239000001630 malic acid Substances 0.000 claims 1
- 229940099690 malic acid Drugs 0.000 claims 1
- 235000011090 malic acid Nutrition 0.000 claims 1
- 235000006408 oxalic acid Nutrition 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims 1
- -1 phosphorus-oxygen functional group Chemical group 0.000 claims 1
- 239000001384 succinic acid Substances 0.000 claims 1
- 235000011044 succinic acid Nutrition 0.000 claims 1
- 239000011975 tartaric acid Substances 0.000 claims 1
- 229960001367 tartaric acid Drugs 0.000 claims 1
- 235000002906 tartaric acid Nutrition 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
Claims (24)
- ガラス容器の洗浄方法であって、
該ガラス容器を、金属水酸化物を含む水性苛性溶液に暴露すること;及び
該ガラス容器を、4〜11のpHを有し、かつ有効量のキレート化剤を含むすすぎ溶液ですすぐことを含んでおり、該キレート化剤が少なくともアミン官能基、カルボン酸官能基又はリン−酸素官能基を有していることを特徴とするガラス容器の洗浄方法。 - 前記すすぎ溶液がさらに酸を含んでいる請求項1に記載のガラス容器の洗浄方法。
- 前記金属水酸化物がアルカリ金属水酸化物である請求項1に記載のガラス容器の洗浄方法。
- 前記アルカリ金属水酸化物がNaOH又はKOHである請求項2に記載のガラス容器の洗浄方法。
- 前記の水性苛性溶液が金属水酸化物1〜5重量%を含んでいる請求項1に記載のガラス容器の洗浄方法。
- 前記アルカリ金属水酸化物がNaOH又はKOHである請求項5に記載のガラス容器の洗浄方法。
- 前記すすぎ溶液が5〜9の範囲内のpHを有する請求項1に記載のガラス容器の洗浄方法。
- 前記すすぎ溶液が6〜8の範囲内のpHを有する請求項1に記載のガラス容器の洗浄方法。
- 前記キレート化剤の量が、前記ガラス容器の表面上に存在し、あるいは後に該表面から浸出する重金属を減少させるのに有効な量である請求項1に記載のガラス容器の洗浄方法。
- 前記キレート化剤の量が、前記すすぎ溶液中に遊離のキレート化剤を供給するのに十分な量である請求項9に記載のガラス容器の洗浄方法。
- 前記すすぎ溶液が少なくとも1ppmの遊離キレート化剤を含む請求項9に記載のガラス容器の洗浄方法。
- 前記すすぎ溶液が少なくとも5ppmの遊離キレート化剤を含む請求項9に記載のガラス容器の洗浄方法。
- 前記すすぎ溶液が0.5〜100ppmの遊離キレート化剤を含む請求項9に記載のガラス容器の洗浄方法。
- 前記すすぎ溶液が5〜10ppmの遊離キレート化剤を含む請求項9に記載のガラス容器の洗浄方法。
- 前記すすぎ溶液が0.0001〜1重量%のキレート化剤を含む請求項1に記載のガラス容器の洗浄方法。
- 前記キレート化剤が、EDTA、EGTA、NTA、DTPA、HEIDA、IDS、MGDA、グルコン酸、2,2’−ビピリジル、ホスホン酸、複合リン酸塩、それらの混合物又はそれらの塩である請求項1に記載のガラス容器の洗浄方法。
- 前記酸がモノ、ジ又はポリカルボン酸である請求項2に記載のガラス容器の洗浄方法。
- 前記酸が、酢酸、シュウ酸、リンゴ酸、マレイン酸、フマル酸、酒石酸、クエン酸、アスパラギン酸、グルタミン酸、コハク酸、それらの2種以上の混合物、又はそれらの塩である請求項2に記載のガラス容器の洗浄方法。
- 前記酸がキレート剤である請求項2に記載のガラス容器の洗浄方法。
- 前記酸の濃度が0.001〜1.0重量%である請求項2に記載のガラス容器の洗浄方法。
- 前記すすぎ溶液がさらに緩衝液を含んでいる請求項1に記載のガラス容器の洗浄方法。
- 前記水性苛性溶液の温度が30℃〜80℃の範囲内である請求項1に記載のガラス容器の洗浄方法。
- 前記ガラス容器がACLを有している請求項1に記載のガラス容器の洗浄方法。
- 前記の暴露され、すすがれたガラス容器が、該ガラス容器中に少なくとも10分間貯蔵された500ppmのリン酸溶液中に20ppb未満の重金属を与える請求項1に記載のガラス容器の洗浄方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US62461604P | 2004-11-03 | 2004-11-03 | |
US60/624,616 | 2004-11-03 | ||
PCT/US2005/039598 WO2006052578A2 (en) | 2004-11-03 | 2005-11-02 | Method of cleaning containers for recycling |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2008519144A JP2008519144A (ja) | 2008-06-05 |
JP2008519144A5 true JP2008519144A5 (ja) | 2008-12-25 |
JP5345321B2 JP5345321B2 (ja) | 2013-11-20 |
Family
ID=35781299
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2007540392A Expired - Fee Related JP5345321B2 (ja) | 2004-11-03 | 2005-11-02 | リサイクル用容器の洗浄方法 |
Country Status (15)
Country | Link |
---|---|
US (2) | US20060111267A1 (ja) |
EP (1) | EP1824958B1 (ja) |
JP (1) | JP5345321B2 (ja) |
KR (1) | KR101142601B1 (ja) |
CN (2) | CN101659521B (ja) |
AR (1) | AR051419A1 (ja) |
AT (1) | ATE455166T1 (ja) |
AU (1) | AU2005305095B2 (ja) |
BR (1) | BRPI0517016A (ja) |
CA (1) | CA2584546A1 (ja) |
DE (1) | DE602005018960D1 (ja) |
ES (1) | ES2356347T3 (ja) |
MX (1) | MX2007005085A (ja) |
WO (1) | WO2006052578A2 (ja) |
ZA (1) | ZA200703570B (ja) |
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2005
- 2005-11-02 JP JP2007540392A patent/JP5345321B2/ja not_active Expired - Fee Related
- 2005-11-02 DE DE602005018960T patent/DE602005018960D1/de active Active
- 2005-11-02 CN CN2009101735324A patent/CN101659521B/zh active Active
- 2005-11-02 EP EP05821031A patent/EP1824958B1/en not_active Not-in-force
- 2005-11-02 KR KR1020077010000A patent/KR101142601B1/ko not_active IP Right Cessation
- 2005-11-02 CN CNA2005800368370A patent/CN101048488A/zh active Pending
- 2005-11-02 BR BRPI0517016-8A patent/BRPI0517016A/pt not_active Application Discontinuation
- 2005-11-02 US US11/265,315 patent/US20060111267A1/en not_active Abandoned
- 2005-11-02 WO PCT/US2005/039598 patent/WO2006052578A2/en active Application Filing
- 2005-11-02 MX MX2007005085A patent/MX2007005085A/es active IP Right Grant
- 2005-11-02 AT AT05821031T patent/ATE455166T1/de not_active IP Right Cessation
- 2005-11-02 ZA ZA200703570A patent/ZA200703570B/xx unknown
- 2005-11-02 ES ES05821031T patent/ES2356347T3/es active Active
- 2005-11-02 AU AU2005305095A patent/AU2005305095B2/en not_active Expired - Fee Related
- 2005-11-02 CA CA002584546A patent/CA2584546A1/en not_active Abandoned
- 2005-11-03 AR ARP050104613A patent/AR051419A1/es active IP Right Grant
-
2007
- 2007-11-19 US US11/942,605 patent/US20080069986A1/en not_active Abandoned
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