JP2008156461A - 塩化ビニル系樹脂組成物 - Google Patents
塩化ビニル系樹脂組成物 Download PDFInfo
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- JP2008156461A JP2008156461A JP2006346401A JP2006346401A JP2008156461A JP 2008156461 A JP2008156461 A JP 2008156461A JP 2006346401 A JP2006346401 A JP 2006346401A JP 2006346401 A JP2006346401 A JP 2006346401A JP 2008156461 A JP2008156461 A JP 2008156461A
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- Prior art keywords
- vinyl chloride
- resin composition
- acid
- butyl
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/006—Additives being defined by their surface area
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
【解決手段】塩化ビニル系樹脂100重量部に対し、見かけ比重7ml/g以上の合成ケイ酸アルミニウム0.1〜3重量部が配合されてなる塩化ビニル系樹脂組成物である。合成ケイ酸アルミニウムとしては、比表面積が400m2/g以上であるものが好適である。また、上記塩化ビニル系樹脂組成物からなる電線被覆材料である。
【選択図】なし
Description
本発明に使用される塩化ビニル系樹脂としては、塊状重合、溶液重合、懸濁重合、乳化重合などその重合方法には特に限定されず、例えば、ポリ塩化ビニル、塩素化ポリ塩化ビニル、ポリ塩化ビニリデン、塩素化ポリエチレン、塩化ビニル−酢酸ビニル共重合体、塩化ビニル−エチレン共重合体、塩化ビニル−プロピレン共重合体、塩化ビニル−スチレン共重合体、塩化ビニル−イソブチレン共重合体、塩化ビニル−塩化ビニリデン共重合体、塩化ビニル−スチレン−無水マレイン酸三元共重合体、塩化ビニル−スチレン−アクリロニリトル共重合体、塩化ビニル−ブタジエン共重合体、塩化ビニル−イソプレン共重合体、塩化ビニル−塩素化プロピレン共重合体、塩化ビニル−塩化ビニリデン−酢酸ビニル三元共重合体、塩化ビニル−マレイン酸エステル共重合体、塩化ビニル−メタクリル酸エステル共重合体、塩化ビニル−アクリロニトリル共重合体、塩化ビニル−各種ビニルエーテル共重合体などの塩化ビニル系樹脂、およびそれら相互のブレンド品あるいは他の塩素を含まない合成樹脂、例えば、アクリロニトリル−スチレン共重合体、アクリロニトリル−ブタジエン−スチレン共重合体、エチレン−酢酸ビニル共重合体、エチレン−エチル(メタ)アクリレート共重合体、ポリエステルなどとのブレンド品、ブロック共重合体、グラフト共重合体などを挙げることができる。
Mgx1Znx2Al2・(OH)2(x1+x2)+4・(CO3)1-y1/2・mH2O (I)
(式中、x1、x2およびy1は各々下記式、
0≦x2/x1≦10、2≦x1+x2<20、0≦y1≦2
で表される条件を満足する数を示し、mは0または任意の整数を示す。)
下記表1に示す配合物を、160℃、30rpmで5分間ロール上で混練した後、190℃で5分間プレスして厚さ1mmのシートを作製し、このシートから試験片を作製して、JIS K 6723に従い、体積固有抵抗率試験(VR)〔Ωcm〕を行った。
その結果を下記の表2中に示す。
*2)合成ケイ酸アルミニウム2:ケイ酸アルミニウム(見かけ比重7.29ml/g、
比表面積427m2/g)
*3)合成ケイ酸アルミニウム3:ケイ酸アルミニウム(見かけ比重5.09ml/g、比表面積267m2/g)
*4)合成ケイ酸アルミニウム4:ケイ酸アルミニウム(見かけ比重2.21ml/g、比表面積193m2/g)
Claims (3)
- 塩化ビニル系樹脂100重量部に対し、見かけ比重7ml/g以上の合成ケイ酸アルミニウム0.1〜3重量部が配合されてなることを特徴とする塩化ビニル系樹脂組成物。
- 前記合成ケイ酸アルミニウムの比表面積が400m2/g以上である請求項1記載の塩化ビニル系樹脂組成物。
- 請求項1または2に記載の塩化ビニル系樹脂組成物からなることを特徴とする電線被覆材料。
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006346401A JP5094109B2 (ja) | 2006-12-22 | 2006-12-22 | 塩化ビニル系樹脂組成物 |
CNA200780047516XA CN101563418A (zh) | 2006-12-22 | 2007-11-26 | 氯乙烯系树脂组合物 |
US12/520,119 US20090312478A1 (en) | 2006-12-22 | 2007-11-26 | Vinyl chloride resin composition |
PCT/JP2007/072787 WO2008078490A1 (ja) | 2006-12-22 | 2007-11-26 | 塩化ビニル系樹脂組成物 |
EP07832512A EP2103651A4 (en) | 2006-12-22 | 2007-11-26 | VINYL CHLORIDE RESIN COMPOSITION |
KR1020097014674A KR101473282B1 (ko) | 2006-12-22 | 2007-11-26 | 염화비닐계 수지 조성물 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006346401A JP5094109B2 (ja) | 2006-12-22 | 2006-12-22 | 塩化ビニル系樹脂組成物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2008156461A true JP2008156461A (ja) | 2008-07-10 |
JP5094109B2 JP5094109B2 (ja) | 2012-12-12 |
Family
ID=39562283
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006346401A Active JP5094109B2 (ja) | 2006-12-22 | 2006-12-22 | 塩化ビニル系樹脂組成物 |
Country Status (6)
Country | Link |
---|---|
US (1) | US20090312478A1 (ja) |
EP (1) | EP2103651A4 (ja) |
JP (1) | JP5094109B2 (ja) |
KR (1) | KR101473282B1 (ja) |
CN (1) | CN101563418A (ja) |
WO (1) | WO2008078490A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011168744A (ja) * | 2010-02-22 | 2011-09-01 | Adeka Corp | 耐候性塩化ビニル系樹脂組成物 |
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---|---|---|---|---|
MX2010008963A (es) | 2008-02-15 | 2011-02-24 | Union Carbide Chem Plastic | Sistema plastificante de reemplazo para formulaciones plastificadas con ftalato. |
TWI607048B (zh) | 2009-09-30 | 2017-12-01 | 陶氏全球科技有限責任公司 | 具有經環氧化之脂肪酸酯塑化劑的熱穩定聚合組成物 |
US8552098B2 (en) | 2009-09-30 | 2013-10-08 | Dow Global Technologies Llc | Purified acetylated derivatives of castor oil and compositions including same |
CA2775930C (en) | 2009-09-30 | 2017-02-14 | Dow Global Technologies Inc. | Acetylated derivatives of castor oil and their blends with epoxidized fatty acid esters |
KR101978520B1 (ko) | 2009-09-30 | 2019-05-14 | 다우 글로벌 테크놀로지스 엘엘씨 | 12-히드록시스테아르산의 아세틸화 글리세리드 및 에폭시드화 지방산 에스테르와의 블렌드 |
JP5797260B2 (ja) | 2010-05-10 | 2015-10-21 | ダウ グローバル テクノロジーズ エルエルシー | 再生可能資源から誘導される可塑剤を用いて作製される可撓性pvc組成物 |
TW201209168A (en) | 2010-07-28 | 2012-03-01 | Dow Global Technologies Llc | Plasticizers made from oil extracted from microorganisms and polar polymeric compositions comprising the same |
WO2013119402A1 (en) | 2012-02-08 | 2013-08-15 | Dow Global Technologies Llc | Plasticizer compositions and methods for making plasticizer compositions |
WO2013191812A1 (en) | 2012-06-22 | 2013-12-27 | Dow Global Technologies Llc | Acetylated polyol hydroxystearate plasticizers and plasticized polymeric compositions |
CA2872524C (en) | 2012-06-26 | 2021-02-16 | Dow Global Technologies Llc | Plasticizers and plasticized polymeric compositions |
CN104718248B (zh) | 2012-10-18 | 2018-04-13 | 陶氏环球技术有限公司 | 环氧化脂肪酸烷基酯增塑剂和用于制造环氧化脂肪酸烷基酯增塑剂的方法 |
US20140116749A1 (en) * | 2012-10-31 | 2014-05-01 | Polyone Corporation | Use of polycaprolactone plasticizers in poly(vinyl chloride) compounds |
MX2015005984A (es) | 2012-11-12 | 2015-09-10 | Dow Global Technologies Llc | Plastificantes de ester de alquilo de acido graso epoxidado y metodos para fabricar plastificantes de ester de alquilo de acido graso epoxidado. |
CA2891062C (en) | 2012-11-12 | 2020-03-24 | Dow Global Technologies Llc | Methods for making epoxidized fatty acid alkyl esters |
CN103073830B (zh) * | 2013-02-16 | 2015-04-29 | 哈尔滨中大型材科技股份有限公司 | 一种马来酸酐接枝氯化聚氯乙烯复合材料的制备方法 |
CN103375742B (zh) * | 2013-07-23 | 2015-07-15 | 宁波市爱使电器有限公司 | 一种高密封水下led灯 |
CN105785718A (zh) * | 2015-01-09 | 2016-07-20 | 三星显示有限公司 | 光敏树脂组合物、使用所述光敏树脂组合物的颜色转换面板和显示装置 |
KR101892795B1 (ko) * | 2015-10-07 | 2018-08-28 | 주식회사 엘지화학 | 염화비닐계 중합체 및 이의 제조방법 |
KR102075676B1 (ko) * | 2017-09-05 | 2020-02-10 | 주식회사 케이씨씨 | 안정화제 및 이를 이용하여 제조된 폴리염화비닐 시트 |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60127254A (ja) * | 1983-11-08 | 1985-07-06 | 東ソー株式会社 | 難燃性軟質遮音材 |
JPH01236253A (ja) * | 1988-03-17 | 1989-09-21 | Yazaki Corp | 塩化ビニル樹脂組成物 |
JPH0820696A (ja) * | 1994-07-07 | 1996-01-23 | Nitto Kasei Co Ltd | 熱安定性に優れたハロゲン含有樹脂組成物 |
JPH08109298A (ja) * | 1994-10-07 | 1996-04-30 | Asahi Denka Kogyo Kk | 電線被覆用塩化ビニル系樹脂組成物 |
JPH08269280A (ja) * | 1995-02-01 | 1996-10-15 | Mizusawa Ind Chem Ltd | 塩素含有重合体用安定剤、その製法及び塩素含有重合体組成物 |
JPH09324088A (ja) * | 1996-06-06 | 1997-12-16 | Furukawa Electric Co Ltd:The | 塩化ビニル系樹脂組成物被覆電線 |
JPH11189675A (ja) * | 1997-12-26 | 1999-07-13 | Mizusawa Ind Chem Ltd | 塩素含有重合体用配合剤及び該配合剤を含む樹脂組成物 |
JP2004189777A (ja) * | 2002-12-06 | 2004-07-08 | Asahi Denka Kogyo Kk | 電線被覆用塩素含有樹脂組成物 |
JP2005263918A (ja) * | 2004-03-17 | 2005-09-29 | Mizusawa Ind Chem Ltd | 電気絶縁性向上剤及び電気絶縁性が向上した塩素含有樹脂組成物 |
JP2005276699A (ja) * | 2004-03-25 | 2005-10-06 | Asahi Denka Kogyo Kk | 電線用被覆材料組成物 |
JP2006022252A (ja) * | 2004-07-09 | 2006-01-26 | Tatsuta Electric Wire & Cable Co Ltd | 塩化ビニル樹脂組成物およびそれを用いた電線・ケーブル |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5030039B1 (ja) | 1967-07-17 | 1975-09-27 | ||
JPS462280B1 (ja) | 1966-07-25 | 1971-01-20 | ||
JPS5129129B1 (ja) | 1970-12-31 | 1976-08-24 | ||
JPS61115089A (ja) | 1984-11-09 | 1986-06-02 | Mizusawa Ind Chem Ltd | 複合水酸化物、その製造法及び塩素含有重合体用安定剤 |
JPS61174270A (ja) | 1985-01-29 | 1986-08-05 | Kyowa Chem Ind Co Ltd | 耐発錆性ないし耐着色性賦与剤 |
JP3288739B2 (ja) | 1991-12-26 | 2002-06-04 | 旭電化工業株式会社 | 含ハロゲン樹脂組成物 |
JP3511214B2 (ja) | 1994-10-07 | 2004-03-29 | 旭電化工業株式会社 | 電線被覆用塩化ビニル系樹脂組成物 |
JP4099620B2 (ja) | 1999-10-01 | 2008-06-11 | 戸田工業株式会社 | Mg−Al系ハイドロタルサイト型粒子粉末の製造法、塩素含有樹脂安定剤並びに塩素含有樹脂組成物 |
JP2002053722A (ja) | 2000-08-04 | 2002-02-19 | Toda Kogyo Corp | 塩素含有樹脂組成物 |
-
2006
- 2006-12-22 JP JP2006346401A patent/JP5094109B2/ja active Active
-
2007
- 2007-11-26 EP EP07832512A patent/EP2103651A4/en not_active Withdrawn
- 2007-11-26 CN CNA200780047516XA patent/CN101563418A/zh active Pending
- 2007-11-26 KR KR1020097014674A patent/KR101473282B1/ko active IP Right Grant
- 2007-11-26 WO PCT/JP2007/072787 patent/WO2008078490A1/ja active Application Filing
- 2007-11-26 US US12/520,119 patent/US20090312478A1/en not_active Abandoned
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60127254A (ja) * | 1983-11-08 | 1985-07-06 | 東ソー株式会社 | 難燃性軟質遮音材 |
JPH01236253A (ja) * | 1988-03-17 | 1989-09-21 | Yazaki Corp | 塩化ビニル樹脂組成物 |
JPH0820696A (ja) * | 1994-07-07 | 1996-01-23 | Nitto Kasei Co Ltd | 熱安定性に優れたハロゲン含有樹脂組成物 |
JPH08109298A (ja) * | 1994-10-07 | 1996-04-30 | Asahi Denka Kogyo Kk | 電線被覆用塩化ビニル系樹脂組成物 |
JPH08269280A (ja) * | 1995-02-01 | 1996-10-15 | Mizusawa Ind Chem Ltd | 塩素含有重合体用安定剤、その製法及び塩素含有重合体組成物 |
JPH09324088A (ja) * | 1996-06-06 | 1997-12-16 | Furukawa Electric Co Ltd:The | 塩化ビニル系樹脂組成物被覆電線 |
JPH11189675A (ja) * | 1997-12-26 | 1999-07-13 | Mizusawa Ind Chem Ltd | 塩素含有重合体用配合剤及び該配合剤を含む樹脂組成物 |
JP2004189777A (ja) * | 2002-12-06 | 2004-07-08 | Asahi Denka Kogyo Kk | 電線被覆用塩素含有樹脂組成物 |
JP2005263918A (ja) * | 2004-03-17 | 2005-09-29 | Mizusawa Ind Chem Ltd | 電気絶縁性向上剤及び電気絶縁性が向上した塩素含有樹脂組成物 |
JP2005276699A (ja) * | 2004-03-25 | 2005-10-06 | Asahi Denka Kogyo Kk | 電線用被覆材料組成物 |
JP2006022252A (ja) * | 2004-07-09 | 2006-01-26 | Tatsuta Electric Wire & Cable Co Ltd | 塩化ビニル樹脂組成物およびそれを用いた電線・ケーブル |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011168744A (ja) * | 2010-02-22 | 2011-09-01 | Adeka Corp | 耐候性塩化ビニル系樹脂組成物 |
Also Published As
Publication number | Publication date |
---|---|
CN101563418A (zh) | 2009-10-21 |
EP2103651A1 (en) | 2009-09-23 |
KR20090100396A (ko) | 2009-09-23 |
JP5094109B2 (ja) | 2012-12-12 |
WO2008078490A1 (ja) | 2008-07-03 |
EP2103651A4 (en) | 2011-12-07 |
US20090312478A1 (en) | 2009-12-17 |
KR101473282B1 (ko) | 2014-12-16 |
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