JP2007517088A - 紫外線により架橋されたポリマー電解質 - Google Patents

紫外線により架橋されたポリマー電解質 Download PDF

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Publication number
JP2007517088A
JP2007517088A JP2006543845A JP2006543845A JP2007517088A JP 2007517088 A JP2007517088 A JP 2007517088A JP 2006543845 A JP2006543845 A JP 2006543845A JP 2006543845 A JP2006543845 A JP 2006543845A JP 2007517088 A JP2007517088 A JP 2007517088A
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group
typically
polymer
formula
fluoropolymer
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JP2006543845A
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Japanese (ja)
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JP2007517088A5 (enExample
Inventor
ジン，ナイヨン
ジェイ． ハムロック，スティーブン
エー． ヤンドラシッツ，マイケル
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3M Innovative Properties Co
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3M Innovative Properties Co
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Publication of JP2007517088A publication Critical patent/JP2007517088A/ja
Publication of JP2007517088A5 publication Critical patent/JP2007517088A5/ja
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/28—Treatment by wave energy or particle radiation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2243—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
    • C08J5/225—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231 containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Conductive Materials (AREA)
  • Fuel Cell (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
JP2006543845A 2003-12-11 2004-11-22 紫外線により架橋されたポリマー電解質 Withdrawn JP2007517088A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/733,211 US7060738B2 (en) 2003-12-11 2003-12-11 Polymer electrolytes crosslinked by ultraviolet radiation
PCT/US2004/039173 WO2005061593A1 (en) 2003-12-11 2004-11-22 Polymer electrolytes crosslinked by ultraviolet radiation

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2012087545A Division JP2012144740A (ja) 2003-12-11 2012-04-06 紫外線により架橋されたポリマー電解質

Publications (2)

Publication Number Publication Date
JP2007517088A true JP2007517088A (ja) 2007-06-28
JP2007517088A5 JP2007517088A5 (enExample) 2008-01-17

Family

ID=34653050

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2006543845A Withdrawn JP2007517088A (ja) 2003-12-11 2004-11-22 紫外線により架橋されたポリマー電解質
JP2012087545A Pending JP2012144740A (ja) 2003-12-11 2012-04-06 紫外線により架橋されたポリマー電解質

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP2012087545A Pending JP2012144740A (ja) 2003-12-11 2012-04-06 紫外線により架橋されたポリマー電解質

Country Status (8)

Country Link
US (1) US7060738B2 (enExample)
EP (1) EP1692215A1 (enExample)
JP (2) JP2007517088A (enExample)
KR (1) KR20060130095A (enExample)
CN (1) CN1890300B (enExample)
CA (1) CA2549085A1 (enExample)
TW (1) TW200535173A (enExample)
WO (1) WO2005061593A1 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006511919A (ja) * 2002-12-19 2006-04-06 スリーエム イノベイティブ プロパティズ カンパニー 高フッ素化主鎖ポリマー電解質膜
JP2013513667A (ja) * 2009-12-11 2013-04-22 シャンドン・フアシャ・シェンゾウ・ニュー・マテリアル・カンパニー・リミテッド パーフルオロイオン交換樹脂、その調製法および使用
JP2013513707A (ja) * 2009-12-15 2013-04-22 シャンドン・フアシャ・シェンゾウ・ニュー・マテリアル・カンパニー・リミテッド 高交換容量過フッ化イオン交換樹脂、その調製方法、及び使用
JP2014516165A (ja) * 2011-06-08 2014-07-07 スリーエム イノベイティブ プロパティズ カンパニー 湿度センサ及びそのためのセンサ素子

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040116742A1 (en) * 2002-12-17 2004-06-17 3M Innovative Properties Company Selective reaction of hexafluoropropylene oxide with perfluoroacyl fluorides
US7071271B2 (en) * 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
US7259208B2 (en) * 2003-11-13 2007-08-21 3M Innovative Properties Company Reinforced polymer electrolyte membrane
US7265162B2 (en) * 2003-11-13 2007-09-04 3M Innovative Properties Company Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam
US7074841B2 (en) * 2003-11-13 2006-07-11 Yandrasits Michael A Polymer electrolyte membranes crosslinked by nitrile trimerization
US7179847B2 (en) * 2003-11-13 2007-02-20 3M Innovative Properties Company Polymer electrolytes crosslinked by e-beam
US7060756B2 (en) * 2003-11-24 2006-06-13 3M Innovative Properties Company Polymer electrolyte with aromatic sulfone crosslinking
US7112614B2 (en) * 2003-12-08 2006-09-26 3M Innovative Properties Company Crosslinked polymer
US7060738B2 (en) 2003-12-11 2006-06-13 3M Innovative Properties Company Polymer electrolytes crosslinked by ultraviolet radiation
US7173067B2 (en) 2003-12-17 2007-02-06 3M Innovative Properties Company Polymer electrolyte membranes crosslinked by direct fluorination
US7304101B2 (en) * 2004-07-19 2007-12-04 3M Innovative Properties Company Method of purifying a dispersion of ionic fluoropolymer
US20060141138A1 (en) * 2004-12-29 2006-06-29 3M Innovative Properties Company Microwave annealing of membranes for use in fuel cell assemblies
US20060264576A1 (en) * 2005-03-24 2006-11-23 Roelofs Mark G Process to prepare stable trifluorostyrene containing compounds grafted to base polymers
US7214740B2 (en) * 2005-05-03 2007-05-08 3M Innovative Properties Company Fluorinated ionomers with reduced amounts of carbonyl end groups
JP5376485B2 (ja) * 2007-02-21 2013-12-25 独立行政法人日本原子力研究開発機構 アルキルグラフト鎖からなる高分子電解質膜、及び、その製造方法
US9287568B2 (en) 2007-04-12 2016-03-15 3M Innovative Properties Company High performance, high durability non-precious metal fuel cell catalysts
WO2009082661A1 (en) * 2007-12-20 2009-07-02 E. I. Du Pont De Nemours And Company Crosslinkable trifluorostyrene polymers and membranes
WO2009082663A1 (en) * 2007-12-20 2009-07-02 E.I. Du Pont De Nemours And Company Process to prepare crosslinkable trifluorostyrene polymers and membranes
CN103788280B (zh) 2008-04-24 2016-08-17 3M创新有限公司 质子传导材料
US8785023B2 (en) 2008-07-07 2014-07-22 Enervault Corparation Cascade redox flow battery systems
US7820321B2 (en) 2008-07-07 2010-10-26 Enervault Corporation Redox flow battery system for distributed energy storage
CN104016891B (zh) 2010-04-16 2016-08-17 3M创新有限公司 质子传导材料
US9893373B2 (en) 2010-05-25 2018-02-13 3M Innovative Properties Company Reinforced electrolyte membrane
EP2583746B1 (en) * 2010-06-18 2019-01-09 Shandong Huaxia Shenzhou New Material Co., Ltd. Fluorine containing ionomer composite with ion exchange function, preparation method and use thereof
US8916281B2 (en) 2011-03-29 2014-12-23 Enervault Corporation Rebalancing electrolytes in redox flow battery systems
US8980484B2 (en) 2011-03-29 2015-03-17 Enervault Corporation Monitoring electrolyte concentrations in redox flow battery systems
EP3138875B1 (en) 2011-08-04 2019-11-20 3M Innovative Properties Company Crosslinked fluorinated polymers with manganese or cerium as additives
CN104448369A (zh) * 2014-11-14 2015-03-25 南京理工大学 一类接枝全交联型质子交换膜及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5728119A (en) * 1980-06-11 1982-02-15 Dow Chemical Co Acid-functional novel polymer
US6254978B1 (en) * 1994-11-14 2001-07-03 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
WO2001096268A2 (fr) * 2000-06-13 2001-12-20 HYDRO-QUéBEC ÉLASTOMÈRES RÉTICULABLES FLUORÉS BROMOSULFONÉS À BASE DE FLUORURE DE VINYLIDÈNE PRÉSENTANT UNE FAIBLE Tg ET PROCÉDÉS POUR LEURS PRÉPARATIONS
JP2003342328A (ja) * 2002-05-30 2003-12-03 Daikin Ind Ltd 成形体及び固体高分子電解質型燃料電池

Family Cites Families (114)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3282875A (en) * 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
GB1184321A (en) 1968-05-15 1970-03-11 Du Pont Electrochemical Cells
US3635926A (en) 1969-10-27 1972-01-18 Du Pont Aqueous process for making improved tetrafluoroethylene / fluoroalkyl perfluorovinyl ether copolymers
US3784399A (en) * 1971-09-08 1974-01-08 Du Pont Films of fluorinated polymer containing sulfonyl groups with one surface in the sulfonamide or sulfonamide salt form and a process for preparing such
US4000356A (en) * 1972-06-19 1976-12-28 Dynamit Nobel Aktiengesellschaft Process for the preparation of thermoplastically workable fluoro-olefin polymers
US3853828A (en) * 1973-11-21 1974-12-10 Us Army Process for crosslinking fluorocarbon polymers
US4169023A (en) * 1974-02-04 1979-09-25 Tokuyama Soda Kabushiki Kaisha Electrolytic diaphragms, and method of electrolysis using the same
US4035565A (en) 1975-03-27 1977-07-12 E. I. Du Pont De Nemours And Company Fluoropolymer containing a small amount of bromine-containing olefin units
US4073752A (en) 1975-06-02 1978-02-14 The B. F. Goodrich Company High normality ion exchange membranes containing entrapped electrostatically bulky multicharged ions and method of production
GB1518387A (en) 1975-08-29 1978-07-19 Asahi Glass Co Ltd Fluorinated cation exchange membrane and use thereof in electrolysis of an alkali metal halide
US4508603A (en) 1976-08-22 1985-04-02 Asahi Glass Company Ltd. Fluorinated cation exchange membrane and use thereof in electrolysis of an alkali metal halide
JPS5329291A (en) 1976-09-01 1978-03-18 Toyo Soda Mfg Co Ltd Cation exchange membrane and production of the same
JPS5397988A (en) 1977-02-08 1978-08-26 Toyo Soda Mfg Co Ltd Production of cation exchange membrane
FR2387260A1 (fr) 1977-04-12 1978-11-10 Rhone Poulenc Ind Membranes echangeuses d'ions
JPS53134088A (en) 1977-04-28 1978-11-22 Asahi Glass Co Ltd Production of fluorocopolymer having ion exchange groups and its crosslinked article
US4230549A (en) 1977-05-31 1980-10-28 Rai Research Corporation Separator membranes for electrochemical cells
JPS53149881A (en) 1977-06-03 1978-12-27 Asahi Glass Co Ltd Strengthened cation exchange resin membrane and production thereof
JPS6026145B2 (ja) 1977-10-04 1985-06-21 旭硝子株式会社 改良された含フツ素陽イオン交換膜
EP0029633B1 (en) * 1978-09-05 1983-10-05 Imperial Chemical Industries Plc Polyarylethersulphone copolymers
US4281092A (en) 1978-11-30 1981-07-28 E. I. Du Pont De Nemours And Company Vulcanizable fluorinated copolymers
US4242498A (en) 1979-04-09 1980-12-30 Frosch Robert A Process for the preparation of fluorine containing crosslinked elastomeric polytriazine and product so produced
JPS5672002U (enExample) 1979-11-08 1981-06-13
US4470889A (en) * 1980-06-11 1984-09-11 The Dow Chemical Company Electrolytic cell having an improved ion exchange membrane and process for operating
US4334082A (en) 1980-09-26 1982-06-08 E. I. Du Pont De Nemours And Company Dialkyl perfluoro-ω-fluoroformyl diesters and monomers and polymers therefrom
US4414159A (en) 1980-09-26 1983-11-08 E. I. Du Pont De Nemours & Co. Vinyl ether monomers and polymers therefrom
ZA818207B (en) 1980-11-27 1982-10-27 Ici Australia Ltd Permselective membranes
US4391844A (en) * 1981-06-26 1983-07-05 Diamond Shamrock Corporation Method for making linings and coatings from soluble cross-linkable perfluorocarbon copolymers
US4454247A (en) 1981-12-14 1984-06-12 E. I. Du Pont De Nemours & Company Ion exchange membranes
US4440917A (en) 1981-12-14 1984-04-03 E. I. Du Pont De Nemours & Company Vinyl ethers monomers and polymers therefrom
WO1986000624A1 (fr) 1984-07-13 1986-01-30 Societe Atochem Nouveau polymere fluore ionique, son procede de preparation et les membranes d'electrolyse formees a partir de ce polymere
JPH0641494B2 (ja) * 1984-08-31 1994-06-01 旭化成工業株式会社 架橋可能な含フツ素共重合体
JPS61164630A (ja) 1985-01-16 1986-07-25 Kinki Kokakoola Botoringu Kk 炭酸水の製造装置
US4686024A (en) 1985-02-01 1987-08-11 The Green Cross Corporation Novel perfluoro chemicals and polyfluorinated compounds and process for production of the same
US4743419A (en) 1985-03-04 1988-05-10 The Dow Chemical Company On-line film fluorination method
US4755567A (en) 1985-11-08 1988-07-05 Exfluor Research Corporation Perfluorination of ethers in the presence of hydrogen fluoride scavengers
US5693748A (en) 1989-02-01 1997-12-02 Asahi Kasei Kogyo Kabushiki Kaisha High molecular weight polyimidoylamidine and a polytriazine derived therefrom
JP2750594B2 (ja) 1989-02-01 1998-05-13 旭化成工業株式会社 高分子量ポリイミドイルアミジンとその製造法および用途
US5986012A (en) 1989-04-24 1999-11-16 E. I. Du Pont De Nemours And Company Fluorination of radiation crosslinked perfluoroelastomers
US5260351A (en) * 1989-04-24 1993-11-09 E. I. Du Pont De Nemours And Company Radiation curing of perfluoroelastomers
IT1235545B (it) 1989-07-10 1992-09-09 Ausimont Srl Fluoroelastomeri dotati di migliore processabilita' e procedimento di preparazione
US5852148A (en) * 1991-07-10 1998-12-22 Minnesota Mining & Manufacturing Company Perfluoroalkyl halides and derivatives
US6048952A (en) * 1991-07-10 2000-04-11 3M Innovative Properties Company Perfluoroalkyl halides and derivatives
JP3101085B2 (ja) 1992-05-11 2000-10-23 日東電工株式会社 電池用セパレータの製造法
US5264508A (en) 1992-06-25 1993-11-23 The Dow Chemical Company Polymers of haloperfluoro and perfluoro ethers
US5595676A (en) 1992-07-30 1997-01-21 Imperial Chemical Industries Plc Fluorinated polymers
US5330626A (en) 1993-02-16 1994-07-19 E. I. Du Pont De Nemours And Company Irradiation of polymeric ion exchange membranes to increase water absorption
WO1995010541A1 (en) 1993-10-12 1995-04-20 Asahi Kasei Kogyo Kabushiki Kaisha Perfluorocarbon copolymer having functional groups and process for producing the same
US5466930A (en) 1994-02-23 1995-11-14 Florida State University Solid scintillators for detecting radioactive ions in solution
US5447993A (en) 1994-04-19 1995-09-05 E. I. Du Pont De Nemours And Company Perfluoroelastomer curing
JP3298321B2 (ja) 1994-08-31 2002-07-02 ダイキン工業株式会社 ビニリデンフルオライド系共重合体水性分散液、ビニリデンフルオライド系シード重合体水性分散液およびそれらの製法
JPH08104789A (ja) * 1994-10-04 1996-04-23 Nippon Mektron Ltd 含フッ素エラストマー組成物
USRE37701E1 (en) * 1994-11-14 2002-05-14 W. L. Gore & Associates, Inc. Integral composite membrane
US5547551A (en) * 1995-03-15 1996-08-20 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
USRE37307E1 (en) * 1994-11-14 2001-08-07 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
JPH08239494A (ja) 1995-03-02 1996-09-17 Mitsubishi Chem Corp ポリオレフィン系陽イオン交換膜の製造法
US5955556A (en) 1995-11-06 1999-09-21 Alliedsignal Inc. Method of manufacturing fluoropolymers
US5795496A (en) * 1995-11-22 1998-08-18 California Institute Of Technology Polymer material for electrolytic membranes in fuel cells
DE19622337C1 (de) * 1996-06-04 1998-03-12 Dlr Deutsche Forschungsanstalt Vernetzung von modifizierten Engineering Thermoplasten
US5798417A (en) 1996-10-15 1998-08-25 E. I. Du Pont De Nemours And Company (Fluorovinyl ether)-grafted high-surface-area polyolefins and preparation thereof
US5747546A (en) 1996-12-31 1998-05-05 The Dow Chemical Company Ion-exchange polymers having an expanded microstructure
CN1154633C (zh) * 1997-03-31 2004-06-23 大金工业株式会社 卤代乙烯醚类磺酸衍生物的制法
CA2266660C (fr) * 1997-07-25 2012-07-17 Acep Inc. Composes ioniques perfluorovinyliques, leurs utilisations comme composants de conducteurs ioniques du type polymere, de membranes selectives, de catalyseurs
US6248469B1 (en) * 1997-08-29 2001-06-19 Foster-Miller, Inc. Composite solid polymer electrolyte membranes
JPH11111310A (ja) 1997-09-30 1999-04-23 Aisin Seiki Co Ltd 燃料電池用の固体高分子電解質膜およびその製造方法
DE19854728B4 (de) * 1997-11-27 2006-04-27 Aisin Seiki K.K., Kariya Polymerelektrolyt-Brennstoffzelle
US6462228B1 (en) * 1997-12-22 2002-10-08 3M Innovative Properties Company Process for preparation of fluorinated sulfinates
JPH11204121A (ja) 1998-01-19 1999-07-30 Aisin Seiki Co Ltd 固体高分子電解質型燃料電池
JP4477149B2 (ja) 1998-01-30 2010-06-09 ハイドロ−ケベック 架橋したスルホン化ポリマーおよびその製造法
AU2978199A (en) * 1998-03-03 1999-09-20 E.I. Du Pont De Nemours And Company Substantially fluorinated ionomers
JP4150867B2 (ja) 1998-05-13 2008-09-17 ダイキン工業株式会社 燃料電池に使用するのに適した固体高分子電解質用材料
US6090895A (en) 1998-05-22 2000-07-18 3M Innovative Properties Co., Crosslinked ion conductive membranes
EA003457B1 (ru) * 1998-05-29 2003-06-26 Е.И.Дюпон Де Немур Энд Компани Окрашиваемые фторполимерные волокна
HUP0104331A3 (en) 1998-09-15 2003-05-28 Regenesys Technologies Ltd Swi Grafting of an unsaturated monomer to a polymer in water
JP2000119420A (ja) 1998-10-19 2000-04-25 Nissan Motor Co Ltd イオン交換膜およびその製造方法
ATE284418T1 (de) 1999-03-02 2004-12-15 Du Pont Radikalische polymerisationsmethode für fluorierte copolymere
JP2000268834A (ja) 1999-03-12 2000-09-29 Mireenu Corporation:Kk プロトン伝導型燃料電池
US6255370B1 (en) 1999-04-29 2001-07-03 Railroad-Solutions, Llc Rail spike retention and tie preservation mixture and method
JP2001029800A (ja) 1999-05-18 2001-02-06 Sumitomo Electric Ind Ltd イオン交換膜、イオン交換膜・電極接合体、及びこれらの製造方法
US6277512B1 (en) * 1999-06-18 2001-08-21 3M Innovative Properties Company Polymer electrolyte membranes from mixed dispersions
JP4539896B2 (ja) 1999-09-17 2010-09-08 独立行政法人産業技術総合研究所 プロトン伝導性膜、その製造方法及びそれを用いた燃料電池
CN1233668C (zh) 1999-10-12 2005-12-28 迈克里斯公司 具有亲水官能团的氟烃聚合物及方法
US6423784B1 (en) * 1999-12-15 2002-07-23 3M Innovative Properties Company Acid functional fluoropolymer membranes and method of manufacture
JP4714957B2 (ja) 1999-12-21 2011-07-06 旭硝子株式会社 固体高分子電解質型燃料電池
JP4352546B2 (ja) * 1999-12-22 2009-10-28 ユニマテック株式会社 フルオロエラストマー、その製造方法、架橋性組成物およびその硬化物
US6780935B2 (en) * 2000-02-15 2004-08-24 Atofina Chemicals, Inc. Fluoropolymer resins containing ionic or ionizable groups and products containing the same
DE10021104A1 (de) 2000-05-02 2001-11-08 Univ Stuttgart Organisch-anorganische Membranen
US6982303B2 (en) * 2000-05-19 2006-01-03 Jochen Kerres Covalently cross-linked polymers and polymer membranes via sulfinate alkylation
DE10024576A1 (de) 2000-05-19 2001-11-22 Univ Stuttgart Kovalent und ionisch vernetzte Polymere und Polymermembranen
JP2001354641A (ja) 2000-06-13 2001-12-25 Asahi Glass Co Ltd 新規含フッ素化合物およびその製造方法
JP2002003466A (ja) 2000-06-23 2002-01-09 Asahi Glass Co Ltd 新規含フッ素化合物およびその製造方法
IT1318593B1 (it) * 2000-06-23 2003-08-27 Ausimont Spa Ionomeri fluorurati.
IT1318669B1 (it) * 2000-08-08 2003-08-27 Ausimont Spa Ionomeri fluorurati solfonici.
CA2328433A1 (fr) 2000-12-20 2002-06-20 Hydro-Quebec Elastomeres nitriles fluorosulfones reticulables a faible tg a base de fluorure de vinylidene et ne contenant ni du tetrafluoroethylene ni de groupement siloxane
EP1359142A4 (en) 2001-02-01 2007-06-13 Asahi Chemical Ind PERFLUOROVINYL ETHER MONOMER HAVING A SULFONAMIDE GROUP
ITMI20010383A1 (it) 2001-02-26 2002-08-26 Ausimont Spa Membrane idrofiliche porose
JP2002313364A (ja) 2001-04-13 2002-10-25 Hitachi Cable Ltd 燃料電池用電解質膜及びその製造方法並びに燃料電池
US6503378B1 (en) 2001-04-23 2003-01-07 Motorola, Inc. Polymer electrolyte membrane and method of fabrication
US7045571B2 (en) 2001-05-21 2006-05-16 3M Innovative Properties Company Emulsion polymerization of fluorinated monomers
KR100403754B1 (ko) 2001-06-19 2003-10-30 송민규 연료전지용 복합 고분자 전해질 막, 이의 제조방법 및이를 포함하는 연료전지
CA2352417A1 (fr) 2001-07-05 2003-01-05 Hydro-Quebec Procede de synthese de monomeres fluorosulfones et leur copolymerisation avec des alcenes fluores
DE10209784A1 (de) 2001-09-01 2003-12-04 Univ Stuttgart Inst Fuer Chemi Sulfinatgruppen enthaltende Oligomere und Polymere und Verfahren zu ihrer Herstellung
KR20040041695A (ko) * 2001-10-15 2004-05-17 이 아이 듀폰 디 네모아 앤드 캄파니 메탄올 투과율의 감소를 위하여 폴리아민이 흡수된, 연료전지용 고체 중합체 막
US6727386B2 (en) * 2001-10-25 2004-04-27 3M Innovative Properties Company Aromatic imide and aromatic methylidynetrissulfonyl compounds and method of making
US7273537B2 (en) * 2002-09-12 2007-09-25 Teck Cominco Metals, Ltd. Method of production of metal particles through electrolysis
US6624328B1 (en) * 2002-12-17 2003-09-23 3M Innovative Properties Company Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group
US7071271B2 (en) 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
US7074841B2 (en) * 2003-11-13 2006-07-11 Yandrasits Michael A Polymer electrolyte membranes crosslinked by nitrile trimerization
US7265162B2 (en) * 2003-11-13 2007-09-04 3M Innovative Properties Company Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam
US7259208B2 (en) * 2003-11-13 2007-08-21 3M Innovative Properties Company Reinforced polymer electrolyte membrane
US7179847B2 (en) * 2003-11-13 2007-02-20 3M Innovative Properties Company Polymer electrolytes crosslinked by e-beam
US7060756B2 (en) * 2003-11-24 2006-06-13 3M Innovative Properties Company Polymer electrolyte with aromatic sulfone crosslinking
US7112614B2 (en) * 2003-12-08 2006-09-26 3M Innovative Properties Company Crosslinked polymer
US7060738B2 (en) 2003-12-11 2006-06-13 3M Innovative Properties Company Polymer electrolytes crosslinked by ultraviolet radiation
US7173067B2 (en) * 2003-12-17 2007-02-06 3M Innovative Properties Company Polymer electrolyte membranes crosslinked by direct fluorination

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5728119A (en) * 1980-06-11 1982-02-15 Dow Chemical Co Acid-functional novel polymer
US6254978B1 (en) * 1994-11-14 2001-07-03 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
WO2001096268A2 (fr) * 2000-06-13 2001-12-20 HYDRO-QUéBEC ÉLASTOMÈRES RÉTICULABLES FLUORÉS BROMOSULFONÉS À BASE DE FLUORURE DE VINYLIDÈNE PRÉSENTANT UNE FAIBLE Tg ET PROCÉDÉS POUR LEURS PRÉPARATIONS
JP2004502786A (ja) * 2000-06-13 2004-01-29 ハイドロ−ケベック 低いＴｇを示すフッ化ビニリデンを主成分とする、架橋性ブロモスルホン化フルオロエラストマー
JP2003342328A (ja) * 2002-05-30 2003-12-03 Daikin Ind Ltd 成形体及び固体高分子電解質型燃料電池

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006511919A (ja) * 2002-12-19 2006-04-06 スリーエム イノベイティブ プロパティズ カンパニー 高フッ素化主鎖ポリマー電解質膜
JP2013513667A (ja) * 2009-12-11 2013-04-22 シャンドン・フアシャ・シェンゾウ・ニュー・マテリアル・カンパニー・リミテッド パーフルオロイオン交換樹脂、その調製法および使用
JP2013513707A (ja) * 2009-12-15 2013-04-22 シャンドン・フアシャ・シェンゾウ・ニュー・マテリアル・カンパニー・リミテッド 高交換容量過フッ化イオン交換樹脂、その調製方法、及び使用
JP2014516165A (ja) * 2011-06-08 2014-07-07 スリーエム イノベイティブ プロパティズ カンパニー 湿度センサ及びそのためのセンサ素子
US9599583B2 (en) 2011-06-08 2017-03-21 3M Innovative Properties Company Humidity sensor and sensor element therefor

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US20050131097A1 (en) 2005-06-16
CN1890300A (zh) 2007-01-03
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