JP2005530907A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2005530907A5 JP2005530907A5 JP2004517894A JP2004517894A JP2005530907A5 JP 2005530907 A5 JP2005530907 A5 JP 2005530907A5 JP 2004517894 A JP2004517894 A JP 2004517894A JP 2004517894 A JP2004517894 A JP 2004517894A JP 2005530907 A5 JP2005530907 A5 JP 2005530907A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst system
- group
- formula
- hydrogen
- atom
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000003054 catalyst Substances 0.000 claims 14
- 239000001257 hydrogen Substances 0.000 claims 9
- 229910052739 hydrogen Inorganic materials 0.000 claims 9
- 125000004429 atom Chemical group 0.000 claims 6
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 5
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 5
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 5
- 229910052794 bromium Inorganic materials 0.000 claims 5
- 229910052801 chlorine Inorganic materials 0.000 claims 5
- 239000000460 chlorine Substances 0.000 claims 5
- 229910052731 fluorine Inorganic materials 0.000 claims 5
- 239000011737 fluorine Substances 0.000 claims 5
- 229910052740 iodine Inorganic materials 0.000 claims 5
- 239000011630 iodine Substances 0.000 claims 5
- 150000002431 hydrogen Chemical class 0.000 claims 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 3
- 239000012190 activator Substances 0.000 claims 3
- 229910052782 aluminium Inorganic materials 0.000 claims 3
- 239000003446 ligand Substances 0.000 claims 3
- 239000000463 material Substances 0.000 claims 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 230000003796 beauty Effects 0.000 claims 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- -1 phenoxide transition metal Chemical class 0.000 claims 2
- 229920000642 polymer Polymers 0.000 claims 2
- 239000002685 polymerization catalyst Substances 0.000 claims 2
- 238000006116 polymerization reaction Methods 0.000 claims 2
- 125000001424 substituent group Chemical group 0.000 claims 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- 229910013504 M-O-M Inorganic materials 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 150000003949 imides Chemical class 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 229910052723 transition metal Inorganic materials 0.000 claims 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/186,361 US6703338B2 (en) | 2002-06-28 | 2002-06-28 | Polymerization catalyst activators, method of preparing, and their use in polymerization processes |
| PCT/US2003/020199 WO2004003037A1 (en) | 2002-06-28 | 2003-06-26 | Halogen substituted catalyst system for olefin polymerization |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2005530907A JP2005530907A (ja) | 2005-10-13 |
| JP2005530907A5 true JP2005530907A5 (enExample) | 2008-07-24 |
Family
ID=29999290
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004517607A Expired - Fee Related JP4361862B2 (ja) | 2002-06-28 | 2003-05-29 | 重合用触媒の活性剤、その製造方法及び重合プロセスにおけるその使用 |
| JP2004517894A Withdrawn JP2005530907A (ja) | 2002-06-28 | 2003-06-26 | オレフィン重合用のハロゲン置換触媒系 |
| JP2004517963A Withdrawn JP2005531670A (ja) | 2002-06-28 | 2003-06-26 | 複素環窒素含有活性化剤及びオレフィン重合用触媒系 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004517607A Expired - Fee Related JP4361862B2 (ja) | 2002-06-28 | 2003-05-29 | 重合用触媒の活性剤、その製造方法及び重合プロセスにおけるその使用 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004517963A Withdrawn JP2005531670A (ja) | 2002-06-28 | 2003-06-26 | 複素環窒素含有活性化剤及びオレフィン重合用触媒系 |
Country Status (20)
| Country | Link |
|---|---|
| US (2) | US6703338B2 (enExample) |
| EP (3) | EP1517930B1 (enExample) |
| JP (3) | JP4361862B2 (enExample) |
| KR (1) | KR100713748B1 (enExample) |
| CN (4) | CN1659193B (enExample) |
| AT (1) | ATE506381T1 (enExample) |
| AU (3) | AU2003238849B2 (enExample) |
| BR (3) | BR0305256A (enExample) |
| CA (3) | CA2488052C (enExample) |
| CZ (1) | CZ20041151A3 (enExample) |
| DE (1) | DE60336812D1 (enExample) |
| MX (1) | MXPA05000067A (enExample) |
| MY (1) | MY137541A (enExample) |
| NO (1) | NO20040872L (enExample) |
| PL (1) | PL373380A1 (enExample) |
| RU (1) | RU2293088C2 (enExample) |
| SG (1) | SG173215A1 (enExample) |
| TW (1) | TWI280252B (enExample) |
| WO (3) | WO2004003031A2 (enExample) |
| ZA (1) | ZA200409750B (enExample) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6274684B1 (en) * | 1999-10-22 | 2001-08-14 | Univation Technologies, Llc | Catalyst composition, method of polymerization, and polymer therefrom |
| US6841504B2 (en) * | 2002-01-28 | 2005-01-11 | Univation Technologies, Llc | Polymerization catalyst activator and its use in a polymerization process |
| US6559251B1 (en) * | 2002-08-02 | 2003-05-06 | Equistar Chemicals, Lp | Process for making low-density polyolefins |
| US7220695B2 (en) * | 2004-01-07 | 2007-05-22 | Exxonmobil Chemical Patents Inc. | Supported activator |
| US7741417B2 (en) * | 2004-01-07 | 2010-06-22 | Exxonmobil Chemical Patents Inc. | Preparation of polymerization catalyst activators utilizing indole-modified silica supports |
| EP2217627A1 (en) * | 2007-11-08 | 2010-08-18 | ExxonMobil Chemical Patents Inc. | Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes |
| US8022005B2 (en) * | 2007-11-08 | 2011-09-20 | Exxonmobil Chemical Patents Inc. | Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes |
| US8524846B1 (en) | 2009-07-02 | 2013-09-03 | The University Of Toledo | Trianionic ligand precursor compounds and uses thereof in constrained geometry catalysts |
| EP2882810B1 (en) | 2012-08-03 | 2018-01-17 | ExxonMobil Chemical Patents Inc. | Catalysts comprising salan ligands |
| EP2880097B1 (en) | 2012-08-03 | 2023-10-18 | ExxonMobil Chemical Patents Inc. | Process to prepare a vinyl terminated polyethylene with long chain branching |
| US9382349B2 (en) | 2012-08-03 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Polyalphaolefins prepared using modified Salan catalyst compounds |
| EP2880096B1 (en) | 2012-08-03 | 2018-01-03 | ExxonMobil Chemical Patents Inc. | Process for preparing polyalphaolefins using modified salan catalyst compounds and polyalphaolefins prepared therewith |
| US8952114B2 (en) | 2012-08-03 | 2015-02-10 | Exxonmobil Chemical Patents Inc. | Halogenated catalysts comprising Salan ligands |
| WO2014022010A2 (en) | 2012-08-03 | 2014-02-06 | Exxonmobil Chemical Patents Inc. | Non-symmetric catalysts comprising salan ligands |
| US9120879B2 (en) | 2012-11-02 | 2015-09-01 | Exxonmobil Chemical Patents Inc. | Supported Salan catalysts |
| SG11201506868UA (en) | 2013-03-13 | 2015-09-29 | Exxonmobil Chem Patents Inc | Diphenylamine salan catalyst |
| CN105992774B (zh) | 2013-06-20 | 2018-08-24 | 埃克森美孚化学专利公司 | Salenol催化剂 |
| CN105392776B (zh) * | 2013-06-20 | 2019-02-12 | 埃克森美孚化学专利公司 | 硫代-Salalen催化剂 |
| US9200100B2 (en) | 2013-06-20 | 2015-12-01 | Exxonmobil Chemical Patents Inc. | Long-bridged salen catalyst |
| US9290589B2 (en) | 2013-12-13 | 2016-03-22 | Exxonmobil Chemical Patents Inc. | Cyclopentadienyl-substituted salan catalysts |
| CN106132924B (zh) | 2014-03-31 | 2019-03-19 | 埃克森美孚化学专利公司 | 亚苯基桥连的salalen催化剂 |
| US10351647B2 (en) | 2015-05-29 | 2019-07-16 | Exxonmobil Chemical Patents Inc. | Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports |
| ES2784359T5 (es) | 2015-07-31 | 2024-04-04 | Cargill Inc | Método para preparar fibras de cítricos con características de unión de agua optimizadas |
Family Cites Families (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL277898A (enExample) * | 1961-05-02 | |||
| JPS5421391B1 (enExample) * | 1969-07-10 | 1979-07-30 | ||
| US4224181A (en) * | 1979-03-07 | 1980-09-23 | Exxon Research & Engineering Co. | Ziegler type catalyst system |
| US4271060A (en) | 1979-09-17 | 1981-06-02 | Phillips Petroleum Company | Solution polymerization process |
| US4434313A (en) * | 1981-12-14 | 1984-02-28 | Exxon Research And Engineering Co. | Preparation of linear olefin products |
| IT1178466B (it) * | 1984-03-20 | 1987-09-09 | Montedison Spa | Catalizzatori per la omo e copolimerizzazione dell'etilene e polimeri ottenuti |
| US5001205A (en) | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
| US5236998A (en) | 1991-03-07 | 1993-08-17 | Occidental Chemical Corporation | Process for the manufacture of linear polyethylene containing α-alkene commonomers |
| IT1251462B (it) * | 1991-07-12 | 1995-05-15 | Enichem Polimeri | Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene e delle alfa olefine. |
| US5589555A (en) | 1991-10-03 | 1996-12-31 | Novacor Chemicals (International) S.A. | Control of a solution process for polymerization of ethylene |
| US5221761A (en) * | 1992-04-29 | 1993-06-22 | Instituto Guido Donegani | Melt transesterification process for the production of polycarbonates |
| US5317036A (en) | 1992-10-16 | 1994-05-31 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization reactions utilizing soluble unsupported catalysts |
| ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
| US5804678A (en) | 1993-07-13 | 1998-09-08 | Mitsui Petrochemical Industries, Ltd. | Process for gas phase polymerization of olefin |
| EP0649992B1 (de) | 1993-10-23 | 1997-07-30 | WABCO GmbH | Betätigungseinrichtung für eine Scheibenbremse |
| US5763543A (en) | 1994-09-14 | 1998-06-09 | Exxon Chemical Patents Inc. | Olefin polymerization process with little or no scavenger present |
| ES2135771T3 (es) | 1994-10-13 | 1999-11-01 | Exxon Chemical Patents Inc | Sistemas cataliticos de polimerizacion, su produccion y su uso. |
| ES2116776T3 (es) * | 1994-10-31 | 1998-07-16 | Dsm Nv | Composicion catalitica y procedimiento para la polimerizacion de una olefina. |
| US5677375A (en) | 1995-07-21 | 1997-10-14 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing an in situ polyethylene blend |
| GB9522859D0 (en) * | 1995-11-08 | 1996-01-10 | Borealis As | Compounds |
| US5665818A (en) | 1996-03-05 | 1997-09-09 | Union Carbide Chemicals & Plastics Technology Corporation | High activity staged reactor process |
| US5627242A (en) | 1996-03-28 | 1997-05-06 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling gas phase fluidized bed polymerization reactor |
| US5693727A (en) | 1996-06-06 | 1997-12-02 | Union Carbide Chemicals & Plastics Technology Corporation | Method for feeding a liquid catalyst to a fluidized bed polymerization reactor |
| JP2000035973A (ja) * | 1996-06-11 | 2000-02-02 | Masanobu Kujirada | 遠隔匂い発生システム |
| JP3889881B2 (ja) * | 1997-07-10 | 2007-03-07 | 三井化学株式会社 | オレフィン重合用触媒成分、オレフィン重合用触媒およびオレフィンの重合方法 |
| CA2315753C (en) | 1997-12-23 | 2009-01-27 | The Dow Chemical Company | Finishing design to increase the polymer content in an olefin solution polymerization process |
| TR200002404T2 (tr) * | 1998-02-20 | 2001-01-22 | The Dow Chemical Company | Genişletilmiş anyonlar ihtiva eden katalizör etkinleştiriciler |
| CA2330529A1 (en) * | 1998-06-12 | 1999-12-16 | Univation Technologies Llc | Olefin polymerization process using activated lewis acid-base complexes |
| US7354880B2 (en) | 1998-07-10 | 2008-04-08 | Univation Technologies, Llc | Catalyst composition and methods for its preparation and use in a polymerization process |
| PL347324A1 (en) * | 1998-10-08 | 2002-03-25 | Dow Chemical Co | Bridged metal complexes |
| US6500949B2 (en) * | 1998-10-08 | 2002-12-31 | Dow Global Technologies Inc. | Bridged metal complexes |
| US6147173A (en) | 1998-11-13 | 2000-11-14 | Univation Technologies, Llc | Nitrogen-containing group 13 anionic complexes for olefin polymerization |
| US6486277B1 (en) * | 1998-12-12 | 2002-11-26 | Targor Gmbh | Zwitterionic transition metal compound which contains boron |
| BR0013051A (pt) * | 1999-07-29 | 2002-04-02 | Dow Chemical Co | Processo para preparar interpolìmeros de olefinas funcionalizados com silano melhorados, produtos obtidos, derivados destes e seu uso |
| DE60025831T2 (de) * | 1999-09-27 | 2006-08-10 | Dow Global Technologies, Inc., Midland | Expandierte anionen enthaltende geträgertes katalysatorsystem |
| CN1409694A (zh) * | 1999-11-26 | 2003-04-09 | 沙索尔技术股份有限公司 | 烃转化方法 |
| EP1173445B1 (en) | 2000-02-24 | 2004-06-09 | Basell Polyolefine GmbH | Organometallic compound useful as cocatalyst for polymerizing olefins |
| AU2001263526A1 (en) * | 2000-05-04 | 2001-11-12 | Sasol Technology (Pty) Ltd. | A halopyrrole ligand for use in a catalyst system |
| US6627573B2 (en) * | 2000-07-20 | 2003-09-30 | The Dow Chemical Company | Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom |
| CA2440985A1 (en) * | 2001-03-19 | 2002-09-26 | Alexander Vogel | Metal complexes containing acetylenic ligands, polymerization catalysts and addition polymerization process |
| WO2002102811A1 (en) * | 2001-05-21 | 2002-12-27 | Basell Polyolefine Gmbh | Catalyst system for the polymerization of olefins |
| JP2005504853A (ja) * | 2001-06-15 | 2005-02-17 | ダウ グローバル テクノロジーズ インコーポレイティド | アルファ−オレフィンをベースとした枝分れポリマー |
| US6841504B2 (en) * | 2002-01-28 | 2005-01-11 | Univation Technologies, Llc | Polymerization catalyst activator and its use in a polymerization process |
-
2002
- 2002-06-28 US US10/186,361 patent/US6703338B2/en not_active Expired - Fee Related
-
2003
- 2003-05-29 AU AU2003238849A patent/AU2003238849B2/en not_active Ceased
- 2003-05-29 RU RU2005102068/04A patent/RU2293088C2/ru not_active IP Right Cessation
- 2003-05-29 CA CA2488052A patent/CA2488052C/en not_active Expired - Fee Related
- 2003-05-29 MX MXPA05000067A patent/MXPA05000067A/es active IP Right Grant
- 2003-05-29 SG SG2006090062A patent/SG173215A1/en unknown
- 2003-05-29 KR KR1020047019815A patent/KR100713748B1/ko not_active Expired - Fee Related
- 2003-05-29 PL PL03373380A patent/PL373380A1/xx unknown
- 2003-05-29 EP EP03734308.4A patent/EP1517930B1/en not_active Expired - Lifetime
- 2003-05-29 BR BR0305256-7A patent/BR0305256A/pt not_active Application Discontinuation
- 2003-05-29 WO PCT/US2003/017165 patent/WO2004003031A2/en not_active Ceased
- 2003-05-29 CN CN038126850A patent/CN1659193B/zh not_active Expired - Fee Related
- 2003-05-29 CZ CZ20041151A patent/CZ20041151A3/cs unknown
- 2003-05-29 JP JP2004517607A patent/JP4361862B2/ja not_active Expired - Fee Related
- 2003-06-23 TW TW092117000A patent/TWI280252B/zh not_active IP Right Cessation
- 2003-06-26 CN CNB038151561A patent/CN1302029C/zh not_active Expired - Fee Related
- 2003-06-26 BR BRPI0312210-7A patent/BR0312210A/pt unknown
- 2003-06-26 AT AT03742245T patent/ATE506381T1/de not_active IP Right Cessation
- 2003-06-26 EP EP03742270A patent/EP1517932A2/en not_active Withdrawn
- 2003-06-26 CN CNB038151197A patent/CN100339403C/zh not_active Expired - Fee Related
- 2003-06-26 BR BR0312263-8A patent/BR0312263A/pt not_active IP Right Cessation
- 2003-06-26 DE DE60336812T patent/DE60336812D1/de not_active Expired - Lifetime
- 2003-06-26 CN CN200710102101XA patent/CN101054388B/zh not_active Expired - Fee Related
- 2003-06-26 CA CA002488043A patent/CA2488043C/en not_active Expired - Fee Related
- 2003-06-26 WO PCT/US2003/020320 patent/WO2004003032A2/en not_active Ceased
- 2003-06-26 MY MYPI20032414A patent/MY137541A/en unknown
- 2003-06-26 WO PCT/US2003/020199 patent/WO2004003037A1/en not_active Ceased
- 2003-06-26 AU AU2003280428A patent/AU2003280428A1/en not_active Abandoned
- 2003-06-26 EP EP03742245A patent/EP1517931B1/en not_active Expired - Lifetime
- 2003-06-26 CA CA002489240A patent/CA2489240C/en not_active Expired - Fee Related
- 2003-06-26 AU AU2003280424A patent/AU2003280424A1/en not_active Abandoned
- 2003-06-26 JP JP2004517894A patent/JP2005530907A/ja not_active Withdrawn
- 2003-06-26 JP JP2004517963A patent/JP2005531670A/ja not_active Withdrawn
- 2003-12-12 US US10/734,871 patent/US6858689B2/en not_active Expired - Fee Related
-
2004
- 2004-02-27 NO NO20040872A patent/NO20040872L/no not_active Application Discontinuation
- 2004-12-01 ZA ZA200409750A patent/ZA200409750B/en unknown
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2005530907A5 (enExample) | ||
| KR100567304B1 (ko) | 촉매 시스템 및 그의 중합 방법에서의 용도 | |
| ES2167870T5 (es) | Sistemas cataliticos de polimerizacion que comprenden ligandos ciclopentadienuro heterociclicos fusionados. | |
| EP0421659B1 (en) | Process for preparation of syndiotactic vinyl aromatic polymers | |
| CN100386331C (zh) | 聚合催化剂活化剂及其在聚合过程中的应用 | |
| JP2001527135A5 (enExample) | ||
| CA2488043A1 (en) | Halogen substituted catalyst system for olefin polymerization | |
| JP2003513116A (ja) | 担持された触媒系の製造方法及び重合方法でのその使用 | |
| JP2004537584A5 (enExample) | ||
| JPH07149781A (ja) | 担体に支持されたメタロセン組成物の製法 | |
| CN1239526C (zh) | 用于烯烃聚合的催化剂组分 | |
| JP2005531670A5 (enExample) | ||
| JP3694371B2 (ja) | メタロセン化合物の新規な合成方法 | |
| JP4165720B2 (ja) | メタロセン化合物 | |
| JP4169371B2 (ja) | 立体剛性メタロセン化合物 | |
| Clark et al. | Compounds with ruthenium-silicon and osmium-silicon bonds | |
| CN1179983C (zh) | 非茂金属聚烯烃催化剂及其制备方法 | |
| NO20055625L (no) | Katalysator for polymerisering og kopolymerisering av alfa-olenfiner | |
| JPH11255816A (ja) | α−オレフィン重合用触媒成分、触媒、及びそれを用いたα−オレフィンの重合方法 | |
| KR101623487B1 (ko) | 신규한 리간드 화합물, 이의 제조방법, 전이금속 화합물, 및 이의 제조방법 | |
| JP2001510847A5 (enExample) | ||
| JP3850048B2 (ja) | 有機遷移金属化合物およびそれを用いたポリオレフィンの製造方法 | |
| JPH06510807A (ja) | 不活性化および再活性化されたメタロセン触媒組成物 | |
| JP3743687B2 (ja) | ハロゲン化アルキルを用いるテトラキス（ペンタフルオロフェニル）ボレート誘導体の製造方法 | |
| JP2004530653A (ja) | 非メタロセン、その製造方法およびオレフィンの重合での使用 |