AU2003238849B2 - Polymerization catalyst activators, method of preparing and their use in polymerization processes - Google Patents
Polymerization catalyst activators, method of preparing and their use in polymerization processes Download PDFInfo
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- AU2003238849B2 AU2003238849B2 AU2003238849A AU2003238849A AU2003238849B2 AU 2003238849 B2 AU2003238849 B2 AU 2003238849B2 AU 2003238849 A AU2003238849 A AU 2003238849A AU 2003238849 A AU2003238849 A AU 2003238849A AU 2003238849 B2 AU2003238849 B2 AU 2003238849B2
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- toluene
- silica
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- 239000012190 activator Substances 0.000 title claims abstract description 81
- 238000000034 method Methods 0.000 title claims abstract description 69
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 39
- 239000002685 polymerization catalyst Substances 0.000 title abstract description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 336
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 153
- 239000003054 catalyst Substances 0.000 claims abstract description 126
- 239000000463 material Substances 0.000 claims abstract description 46
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 30
- 150000002391 heterocyclic compounds Chemical class 0.000 claims abstract description 27
- 239000002002 slurry Substances 0.000 claims description 162
- -1 alkylaluminum compound Chemical class 0.000 claims description 139
- 125000005842 heteroatom Chemical group 0.000 claims description 46
- 229920000642 polymer Polymers 0.000 claims description 46
- 230000008569 process Effects 0.000 claims description 46
- 125000000217 alkyl group Chemical group 0.000 claims description 42
- 125000004429 atom Chemical group 0.000 claims description 39
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- 125000001424 substituent group Chemical group 0.000 claims description 31
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- 150000002367 halogens Chemical class 0.000 claims description 28
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 22
- 239000011737 fluorine Substances 0.000 claims description 22
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Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
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- Chemical & Material Sciences (AREA)
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Toxicology (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
- Tires In General (AREA)
- Disintegrating Or Milling (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
- Indole Compounds (AREA)
- Polyethers (AREA)
Applications Claiming Priority (3)
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| US10/186,361 | 2002-06-28 | ||
| US10/186,361 US6703338B2 (en) | 2002-06-28 | 2002-06-28 | Polymerization catalyst activators, method of preparing, and their use in polymerization processes |
| PCT/US2003/017165 WO2004003031A2 (en) | 2002-06-28 | 2003-05-29 | Polymerization catalyst activators, method of preparing and their use in polymerization processes |
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| AU2003238849A1 AU2003238849A1 (en) | 2004-01-19 |
| AU2003238849B2 true AU2003238849B2 (en) | 2007-02-15 |
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| AU2003280428A Abandoned AU2003280428A1 (en) | 2002-06-28 | 2003-06-26 | Heterocyclic nitrogen-containing activators and catalyst systems for olefin polymerization |
| AU2003280424A Abandoned AU2003280424A1 (en) | 2002-06-28 | 2003-06-26 | Halogen substituted catalyst system for olefin polymerization |
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| AU2003280428A Abandoned AU2003280428A1 (en) | 2002-06-28 | 2003-06-26 | Heterocyclic nitrogen-containing activators and catalyst systems for olefin polymerization |
| AU2003280424A Abandoned AU2003280424A1 (en) | 2002-06-28 | 2003-06-26 | Halogen substituted catalyst system for olefin polymerization |
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| AT (1) | ATE506381T1 (enExample) |
| AU (3) | AU2003238849B2 (enExample) |
| BR (3) | BR0305256A (enExample) |
| CA (3) | CA2488052C (enExample) |
| CZ (1) | CZ20041151A3 (enExample) |
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| PL (1) | PL373380A1 (enExample) |
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| WO (3) | WO2004003031A2 (enExample) |
| ZA (1) | ZA200409750B (enExample) |
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| US6274684B1 (en) * | 1999-10-22 | 2001-08-14 | Univation Technologies, Llc | Catalyst composition, method of polymerization, and polymer therefrom |
| US6841504B2 (en) * | 2002-01-28 | 2005-01-11 | Univation Technologies, Llc | Polymerization catalyst activator and its use in a polymerization process |
| US6559251B1 (en) * | 2002-08-02 | 2003-05-06 | Equistar Chemicals, Lp | Process for making low-density polyolefins |
| US7220695B2 (en) * | 2004-01-07 | 2007-05-22 | Exxonmobil Chemical Patents Inc. | Supported activator |
| US7741417B2 (en) * | 2004-01-07 | 2010-06-22 | Exxonmobil Chemical Patents Inc. | Preparation of polymerization catalyst activators utilizing indole-modified silica supports |
| EP2217627A1 (en) * | 2007-11-08 | 2010-08-18 | ExxonMobil Chemical Patents Inc. | Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes |
| US8022005B2 (en) * | 2007-11-08 | 2011-09-20 | Exxonmobil Chemical Patents Inc. | Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes |
| US8524846B1 (en) | 2009-07-02 | 2013-09-03 | The University Of Toledo | Trianionic ligand precursor compounds and uses thereof in constrained geometry catalysts |
| EP2882810B1 (en) | 2012-08-03 | 2018-01-17 | ExxonMobil Chemical Patents Inc. | Catalysts comprising salan ligands |
| EP2880097B1 (en) | 2012-08-03 | 2023-10-18 | ExxonMobil Chemical Patents Inc. | Process to prepare a vinyl terminated polyethylene with long chain branching |
| US9382349B2 (en) | 2012-08-03 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Polyalphaolefins prepared using modified Salan catalyst compounds |
| EP2880096B1 (en) | 2012-08-03 | 2018-01-03 | ExxonMobil Chemical Patents Inc. | Process for preparing polyalphaolefins using modified salan catalyst compounds and polyalphaolefins prepared therewith |
| US8952114B2 (en) | 2012-08-03 | 2015-02-10 | Exxonmobil Chemical Patents Inc. | Halogenated catalysts comprising Salan ligands |
| WO2014022010A2 (en) | 2012-08-03 | 2014-02-06 | Exxonmobil Chemical Patents Inc. | Non-symmetric catalysts comprising salan ligands |
| US9120879B2 (en) | 2012-11-02 | 2015-09-01 | Exxonmobil Chemical Patents Inc. | Supported Salan catalysts |
| SG11201506868UA (en) | 2013-03-13 | 2015-09-29 | Exxonmobil Chem Patents Inc | Diphenylamine salan catalyst |
| CN105992774B (zh) | 2013-06-20 | 2018-08-24 | 埃克森美孚化学专利公司 | Salenol催化剂 |
| CN105392776B (zh) * | 2013-06-20 | 2019-02-12 | 埃克森美孚化学专利公司 | 硫代-Salalen催化剂 |
| US9200100B2 (en) | 2013-06-20 | 2015-12-01 | Exxonmobil Chemical Patents Inc. | Long-bridged salen catalyst |
| US9290589B2 (en) | 2013-12-13 | 2016-03-22 | Exxonmobil Chemical Patents Inc. | Cyclopentadienyl-substituted salan catalysts |
| CN106132924B (zh) | 2014-03-31 | 2019-03-19 | 埃克森美孚化学专利公司 | 亚苯基桥连的salalen催化剂 |
| US10351647B2 (en) | 2015-05-29 | 2019-07-16 | Exxonmobil Chemical Patents Inc. | Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports |
| ES2784359T5 (es) | 2015-07-31 | 2024-04-04 | Cargill Inc | Método para preparar fibras de cítricos con características de unión de agua optimizadas |
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| US6486277B1 (en) * | 1998-12-12 | 2002-11-26 | Targor Gmbh | Zwitterionic transition metal compound which contains boron |
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-
2002
- 2002-06-28 US US10/186,361 patent/US6703338B2/en not_active Expired - Fee Related
-
2003
- 2003-05-29 AU AU2003238849A patent/AU2003238849B2/en not_active Ceased
- 2003-05-29 RU RU2005102068/04A patent/RU2293088C2/ru not_active IP Right Cessation
- 2003-05-29 CA CA2488052A patent/CA2488052C/en not_active Expired - Fee Related
- 2003-05-29 MX MXPA05000067A patent/MXPA05000067A/es active IP Right Grant
- 2003-05-29 SG SG2006090062A patent/SG173215A1/en unknown
- 2003-05-29 KR KR1020047019815A patent/KR100713748B1/ko not_active Expired - Fee Related
- 2003-05-29 PL PL03373380A patent/PL373380A1/xx unknown
- 2003-05-29 EP EP03734308.4A patent/EP1517930B1/en not_active Expired - Lifetime
- 2003-05-29 BR BR0305256-7A patent/BR0305256A/pt not_active Application Discontinuation
- 2003-05-29 WO PCT/US2003/017165 patent/WO2004003031A2/en not_active Ceased
- 2003-05-29 CN CN038126850A patent/CN1659193B/zh not_active Expired - Fee Related
- 2003-05-29 CZ CZ20041151A patent/CZ20041151A3/cs unknown
- 2003-05-29 JP JP2004517607A patent/JP4361862B2/ja not_active Expired - Fee Related
- 2003-06-23 TW TW092117000A patent/TWI280252B/zh not_active IP Right Cessation
- 2003-06-26 CN CNB038151561A patent/CN1302029C/zh not_active Expired - Fee Related
- 2003-06-26 BR BRPI0312210-7A patent/BR0312210A/pt unknown
- 2003-06-26 AT AT03742245T patent/ATE506381T1/de not_active IP Right Cessation
- 2003-06-26 EP EP03742270A patent/EP1517932A2/en not_active Withdrawn
- 2003-06-26 CN CNB038151197A patent/CN100339403C/zh not_active Expired - Fee Related
- 2003-06-26 BR BR0312263-8A patent/BR0312263A/pt not_active IP Right Cessation
- 2003-06-26 DE DE60336812T patent/DE60336812D1/de not_active Expired - Lifetime
- 2003-06-26 CN CN200710102101XA patent/CN101054388B/zh not_active Expired - Fee Related
- 2003-06-26 CA CA002488043A patent/CA2488043C/en not_active Expired - Fee Related
- 2003-06-26 WO PCT/US2003/020320 patent/WO2004003032A2/en not_active Ceased
- 2003-06-26 MY MYPI20032414A patent/MY137541A/en unknown
- 2003-06-26 WO PCT/US2003/020199 patent/WO2004003037A1/en not_active Ceased
- 2003-06-26 AU AU2003280428A patent/AU2003280428A1/en not_active Abandoned
- 2003-06-26 EP EP03742245A patent/EP1517931B1/en not_active Expired - Lifetime
- 2003-06-26 CA CA002489240A patent/CA2489240C/en not_active Expired - Fee Related
- 2003-06-26 AU AU2003280424A patent/AU2003280424A1/en not_active Abandoned
- 2003-06-26 JP JP2004517894A patent/JP2005530907A/ja not_active Withdrawn
- 2003-06-26 JP JP2004517963A patent/JP2005531670A/ja not_active Withdrawn
- 2003-12-12 US US10/734,871 patent/US6858689B2/en not_active Expired - Fee Related
-
2004
- 2004-02-27 NO NO20040872A patent/NO20040872L/no not_active Application Discontinuation
- 2004-12-01 ZA ZA200409750A patent/ZA200409750B/en unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6486277B1 (en) * | 1998-12-12 | 2002-11-26 | Targor Gmbh | Zwitterionic transition metal compound which contains boron |
| WO2001023442A1 (en) * | 1999-09-27 | 2001-04-05 | The Dow Chemical Company | Supported catalyst comprising expanded anions |
| WO2001062764A1 (en) * | 2000-02-24 | 2001-08-30 | Basell Technology Company B.V. | Organometallic compound useful as cocatalyst for polymerizing olefins |
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