ES2135771T3 - Sistemas cataliticos de polimerizacion, su produccion y su uso. - Google Patents

Sistemas cataliticos de polimerizacion, su produccion y su uso.

Info

Publication number
ES2135771T3
ES2135771T3 ES95935277T ES95935277T ES2135771T3 ES 2135771 T3 ES2135771 T3 ES 2135771T3 ES 95935277 T ES95935277 T ES 95935277T ES 95935277 T ES95935277 T ES 95935277T ES 2135771 T3 ES2135771 T3 ES 2135771T3
Authority
ES
Spain
Prior art keywords
production
catalytic polymerization
polymerization systems
catalyst
supported
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95935277T
Other languages
English (en)
Inventor
Agapios Kyriacos Agapiou
Chi-I Kuo
Michael Elroy Muhle
Anthony Nicholas Speca
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/501,897 external-priority patent/US6140432A/en
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of ES2135771T3 publication Critical patent/ES2135771T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/02—Anti-static agent incorporated into the catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

ESTA INVENCION ESTA DIRIGIDA GENERALMENTE HACIA UN SISTEMA CATALIZADOR SOPORTADO UTIL PARA POLIMERIZAR OLEFINAS. EL METODO PARA SOPORTAR EL CATALIZADOR DE LA INVENCION PROPORCIONA UN CATALIZADOR DE METALOCENO SOPORTADO QUE CUANDO SE UTILIZA EN UN PROCEDIMIENTO DE POLIMERIZACION REDUCE SUSTANCIALMENTE LA SUCIEDAD Y COBERTURA DEL REACTOR EN UN PROCEDIMIENTO DE POLIMERIZACION DE GAS O PASTA AGUADA, MEDIANTE LA UTILIZACION DE UN MODIFICADOR DE SUPERFICIE.
ES95935277T 1994-10-13 1995-10-12 Sistemas cataliticos de polimerizacion, su produccion y su uso. Expired - Lifetime ES2135771T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US32267594A 1994-10-13 1994-10-13
US08/501,897 US6140432A (en) 1995-07-13 1995-07-13 Polymerization catalyst systems, their production and use

Publications (1)

Publication Number Publication Date
ES2135771T3 true ES2135771T3 (es) 1999-11-01

Family

ID=26983547

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95935277T Expired - Lifetime ES2135771T3 (es) 1994-10-13 1995-10-12 Sistemas cataliticos de polimerizacion, su produccion y su uso.

Country Status (7)

Country Link
EP (1) EP0785955B1 (es)
JP (1) JP3830513B2 (es)
KR (1) KR100405100B1 (es)
CA (1) CA2202182C (es)
DE (1) DE69510812T2 (es)
ES (1) ES2135771T3 (es)
WO (1) WO1996011960A1 (es)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996034020A1 (en) * 1995-04-28 1996-10-31 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
CA2190678A1 (en) 1995-11-22 1997-05-23 Robert Joseph Noel Bernier Process for preparing elastomeric compounds from granular elastomers and polymers and articles manufactured therefrom
DE19615953A1 (de) * 1996-04-22 1997-10-23 Basf Ag Verfahren zur Herstellung von Polymerisaten von Alk-1-enen in Gegenwart eines geträgerten Metallocenkatalysatorsystems und eines Antistatikums
US6245868B1 (en) 1998-05-29 2001-06-12 Univation Technologies Catalyst delivery method, a catalyst feeder and their use in a polymerization process
US6894131B2 (en) 1998-08-21 2005-05-17 Univation Technologies, Llc Polymerization process using a metallocene catalyst system
GB9826874D0 (en) 1998-12-07 1999-01-27 Borealis As Process
US6201076B1 (en) 1999-04-29 2001-03-13 Equistar Chemicals, L.P. Olefin polymerization process with fatty amine additives for improved activity and reduced fouling
AU769680B2 (en) * 1999-05-07 2004-01-29 Ineos Sales (Uk) Limited Process for the gas-phase (co-)polymerisation of olefins in a fluidised bed reactor
US6476165B1 (en) 2000-03-08 2002-11-05 Equistar Chemicals, Lp Olefin polymerization process using fatty amine additives and boron-modified supported catalyst
US7220801B2 (en) 2001-06-22 2007-05-22 Exxonmobil Chemical Patents Inc. Metallocene-produced very low density polyethylenes or linear low density polyethylenes as impact modifiers
EP1426385B1 (en) 2001-07-23 2012-08-22 Shanghai Institute Of Organic Chemistry, Chinese Academy Of Sciences Catalyst for polymerization or copolymerization of olefins, preparation and use of the same
US6703338B2 (en) 2002-06-28 2004-03-09 Univation Technologies, Llc Polymerization catalyst activators, method of preparing, and their use in polymerization processes
CN100351275C (zh) 2003-03-21 2007-11-28 陶氏环球技术公司 形态控制的烯烃聚合方法
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
WO2005003184A1 (en) * 2003-06-11 2005-01-13 Exxonmobil Chemical Patents Inc. Polymerization processes using antistatic agents
US7422786B2 (en) 2003-09-24 2008-09-09 Exxonmobil Chemical Patents Inc. Collation shrink
US7632086B2 (en) 2003-10-03 2009-12-15 Exxonmobil Chemical Patents Inc. Melt fracture reduction
US7183005B2 (en) 2004-08-20 2007-02-27 Exxonmobil Chemical Patents Inc. Impact strength improvement of regrind
US7951873B2 (en) 2006-05-05 2011-05-31 Exxonmobil Chemical Patents Inc. Linear low density polymer blends and articles made therefrom
US8198373B2 (en) 2006-10-02 2012-06-12 Exxonmobil Chemical Patents Inc. Plastic toughened plastics
US7985804B2 (en) 2006-11-06 2011-07-26 Exxonmobil Chemical Patents Inc. Rubber toughened compositions, articles, films, and methods of making the same
TW200932762A (en) 2007-10-22 2009-08-01 Univation Tech Llc Polyethylene compositions having improved properties
EP2112175A1 (en) 2008-04-16 2009-10-28 ExxonMobil Chemical Patents Inc. Activator for metallocenes comprising one or more halogen substituted heterocyclic heteroatom containing ligand coordinated to an alumoxane
EP2610269A1 (en) 2011-12-28 2013-07-03 Saudi Basic Industries Corporation Catalyst composition and method for preparing the same
KR101588382B1 (ko) * 2013-04-08 2016-01-27 한화케미칼 주식회사 대전 방지제를 포함하는 메탈로센 촉매 시스템 및 이를 이용한 폴리올레핀의 제조 방법
KR102414468B1 (ko) 2014-04-02 2022-06-30 유니베이션 테크놀로지즈, 엘엘씨 촉매 조성물, 제조 방법 및 중합 공정에서의 사용
CN106536193A (zh) 2014-05-20 2017-03-22 纳幕尔杜邦公司 整理收缩膜保护结构
WO2016094281A1 (en) 2014-12-11 2016-06-16 E. I. Du Pont De Nemours And Company Stretch wrapping film
BR112017023386B1 (pt) 2015-05-08 2022-04-05 Exxonmobil Chemical Patents Inc Processo de polimerização em fase gasosa em modo condensado
WO2018063765A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063767A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063764A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018118155A1 (en) 2016-12-20 2018-06-28 Exxonmobil Chemical Patents Inc. Polymerization process
CN110573533B (zh) 2017-03-09 2022-02-18 埃克森美孚化学专利公司 生产聚乙烯聚合物的方法
CN111356869B (zh) 2017-11-17 2022-02-22 埃克森美孚化学专利公司 Pe-rt管道及其制造方法
WO2019118073A1 (en) 2017-12-13 2019-06-20 Exxonmobil Chemical Patents Inc. Deactivation methods for active components from gas phase polyolefin polymerization process
WO2019126129A1 (en) 2017-12-22 2019-06-27 E. I. Du Pont De Nemours And Company Thermoplastic adhesive composition
WO2019126189A1 (en) 2017-12-22 2019-06-27 E. I. Du Pont De Nemours And Company Thermoplastic adhesive composition
WO2019173030A1 (en) 2018-03-08 2019-09-12 Exxonmobil Chemical Patents Inc. Methods of preparing and monitoring a seed bed for polymerization reactor startup
US11447587B2 (en) 2018-05-02 2022-09-20 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
US11459408B2 (en) 2018-05-02 2022-10-04 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
KR102287064B1 (ko) * 2018-12-11 2021-08-05 한화솔루션 주식회사 올레핀 중합용 촉매의 제조방법

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
FR2656315B1 (fr) * 1989-12-22 1992-04-17 Bp Chemicals Snc Procede de preparation d'un catalyseur a base de zirconium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
CA2162565C (en) * 1993-05-13 2006-01-24 Main Chang Polymerization catalyst systems, their production and use
US5539069A (en) * 1993-08-10 1996-07-23 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalysts and methods of olefin polymerization

Also Published As

Publication number Publication date
DE69510812D1 (de) 1999-08-19
KR970706316A (ko) 1997-11-03
JPH10507471A (ja) 1998-07-21
CA2202182A1 (en) 1996-04-25
KR100405100B1 (ko) 2004-02-05
DE69510812T2 (de) 2000-04-20
JP3830513B2 (ja) 2006-10-04
EP0785955B1 (en) 1999-07-14
EP0785955A1 (en) 1997-07-30
CA2202182C (en) 2008-03-18
WO1996011960A1 (en) 1996-04-25

Similar Documents

Publication Publication Date Title
ES2135771T3 (es) Sistemas cataliticos de polimerizacion, su produccion y su uso.
ES2132744T3 (es) Sistemas cataliticos de polimerizacion, su produccion y uso.
ES2194924T3 (es) Sistemas cataliticos de polimerizacion, su produccion y uso.
ES2171184T3 (es) Sistemas cataliticos de polimerizacion, su produccion y uso.
ES2165425T3 (es) Sistemas cataliticos de polimerizacion, su produccion y uso.
ES2048871T3 (es) Catalizadores para la polimerizacion de olefinas.
AR025163A1 (es) Un procedimiento para preparar olefinas, un sistema catalizador soportado, el uso de un compuesto catalizador del grupo 15 que contiene hafnio y el uso deun sistema catalizador que comprende un compuesto catalizador
ES2126269T3 (es) Catalizadores de acidos de lewis soportados para reacciones de conversion de hidrocarburos.
BR9814410A (pt) Sistema catalisador suportado, uso do mesmo, e, processos para preparar um polìmero de olefina e, um sistema catalisador suportado.
MY115571A (en) Conversion of oxygenates to hydrocarbons with monolith supported non-zeolitic molecular sieve catalysts
BR9810154A (pt) Processos para a preparação de um polìmero olefìnico e para a preparação de um catalisador suportado, polìmero olefìnico, catalisador suportado, e, usos de um catalisador, ativador de catalisador ou precursor de catalisador
MX9206587A (es) Proceso para la preparacion de un catalizador prepolimerizado.
BR9806251A (pt) Composição catalìtica para a produção de polìmeros olefìnicos.
ES2135966T3 (es) Polimerizacion de olefinas.
ES2139094T3 (es) Componentes cataliticos puenteados de amido-siladiilo, metodo de fabricacion y uso.
ZA981912B (en) Supported catalyst system, process for its preparation and its use for the polymerization or olefins.
MX9201835A (es) Sistema de reactor catalitico.
ES2160634T3 (es) Sistemas catalizadores de polimerizacion, su produccion y uso.
ES2142458T3 (es) Procedimiento mejorado de polimerizacion de olefinas de lecho fluidizado con la ayuda de un flujo tangencial que consiste en gas o gas/solido.
ES2133888T3 (es) Solido catalitico para la (co)polimerizacion de etileno, procedimiento para su preparacion, sistema catalitico para la (co)polimerizacion de etileno y procedimiento de (co)polimerizacion de etileno.
AR002292A1 (es) Espuma de poliuretano flexible, proceso para su preparacion y sistema de reaccion.
IT9019162A0 (it) Sistema catalitico e procedimento per la produzione di gas di sintesi mediante reazione di reforming di idrocarubri leggeri con co2
ES2068419T3 (es) Catalizador y procedimiento de deshidrogenacion y deshidrociclacion.
MX9302991A (es) Soportes catalizadores, catalizadores soportados, metodos para prepararlos y usarlos.
ES2160182T3 (es) Sistemas catalizadores de polimerizacion, su produccion y uso.

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 785955

Country of ref document: ES