KR100713748B1 - 중합 촉매 활성제, 그 제조 방법 및 중합 공정에서의 용도 - Google Patents

중합 촉매 활성제, 그 제조 방법 및 중합 공정에서의 용도 Download PDF

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Publication number
KR100713748B1
KR100713748B1 KR1020047019815A KR20047019815A KR100713748B1 KR 100713748 B1 KR100713748 B1 KR 100713748B1 KR 1020047019815 A KR1020047019815 A KR 1020047019815A KR 20047019815 A KR20047019815 A KR 20047019815A KR 100713748 B1 KR100713748 B1 KR 100713748B1
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South Korea
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group
toluene
slurry
silica
flask
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Korean (ko)
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KR20050008796A (ko
Inventor
매튜 더블류. 홀트캠프
데이비드 에이. 캐노
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다우 글로벌 테크놀로지스 인크.
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Tires In General (AREA)
  • Disintegrating Or Milling (AREA)
  • Superconductors And Manufacturing Methods Therefor (AREA)
  • Indole Compounds (AREA)
  • Polyethers (AREA)
KR1020047019815A 2002-06-28 2003-05-29 중합 촉매 활성제, 그 제조 방법 및 중합 공정에서의 용도 Expired - Fee Related KR100713748B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/186,361 2002-06-28
US10/186,361 US6703338B2 (en) 2002-06-28 2002-06-28 Polymerization catalyst activators, method of preparing, and their use in polymerization processes
PCT/US2003/017165 WO2004003031A2 (en) 2002-06-28 2003-05-29 Polymerization catalyst activators, method of preparing and their use in polymerization processes

Publications (2)

Publication Number Publication Date
KR20050008796A KR20050008796A (ko) 2005-01-21
KR100713748B1 true KR100713748B1 (ko) 2007-05-04

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KR1020047019815A Expired - Fee Related KR100713748B1 (ko) 2002-06-28 2003-05-29 중합 촉매 활성제, 그 제조 방법 및 중합 공정에서의 용도

Country Status (20)

Country Link
US (2) US6703338B2 (enExample)
EP (3) EP1517930B1 (enExample)
JP (3) JP4361862B2 (enExample)
KR (1) KR100713748B1 (enExample)
CN (4) CN1659193B (enExample)
AT (1) ATE506381T1 (enExample)
AU (3) AU2003238849B2 (enExample)
BR (3) BR0305256A (enExample)
CA (3) CA2488052C (enExample)
CZ (1) CZ20041151A3 (enExample)
DE (1) DE60336812D1 (enExample)
MX (1) MXPA05000067A (enExample)
MY (1) MY137541A (enExample)
NO (1) NO20040872L (enExample)
PL (1) PL373380A1 (enExample)
RU (1) RU2293088C2 (enExample)
SG (1) SG173215A1 (enExample)
TW (1) TWI280252B (enExample)
WO (3) WO2004003031A2 (enExample)
ZA (1) ZA200409750B (enExample)

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US8524846B1 (en) 2009-07-02 2013-09-03 The University Of Toledo Trianionic ligand precursor compounds and uses thereof in constrained geometry catalysts
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US8952114B2 (en) 2012-08-03 2015-02-10 Exxonmobil Chemical Patents Inc. Halogenated catalysts comprising Salan ligands
WO2014022010A2 (en) 2012-08-03 2014-02-06 Exxonmobil Chemical Patents Inc. Non-symmetric catalysts comprising salan ligands
US9120879B2 (en) 2012-11-02 2015-09-01 Exxonmobil Chemical Patents Inc. Supported Salan catalysts
SG11201506868UA (en) 2013-03-13 2015-09-29 Exxonmobil Chem Patents Inc Diphenylamine salan catalyst
CN105992774B (zh) 2013-06-20 2018-08-24 埃克森美孚化学专利公司 Salenol催化剂
CN105392776B (zh) * 2013-06-20 2019-02-12 埃克森美孚化学专利公司 硫代-Salalen催化剂
US9200100B2 (en) 2013-06-20 2015-12-01 Exxonmobil Chemical Patents Inc. Long-bridged salen catalyst
US9290589B2 (en) 2013-12-13 2016-03-22 Exxonmobil Chemical Patents Inc. Cyclopentadienyl-substituted salan catalysts
CN106132924B (zh) 2014-03-31 2019-03-19 埃克森美孚化学专利公司 亚苯基桥连的salalen催化剂
US10351647B2 (en) 2015-05-29 2019-07-16 Exxonmobil Chemical Patents Inc. Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports
ES2784359T5 (es) 2015-07-31 2024-04-04 Cargill Inc Método para preparar fibras de cítricos con características de unión de agua optimizadas

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DE60336812D1 (en) 2011-06-01
CN101054388B (zh) 2012-09-26
PL373380A1 (en) 2005-08-22
US20040167016A1 (en) 2004-08-26
BR0312210A (pt) 2007-05-29
BR0312263A (pt) 2005-04-26
CA2488052C (en) 2010-08-03
CA2489240A1 (en) 2004-01-08
WO2004003037A1 (en) 2004-01-08
EP1517932A2 (en) 2005-03-30
CN1659193B (zh) 2012-06-20
WO2004003031A2 (en) 2004-01-08
ZA200409750B (en) 2005-09-29
JP2005530907A (ja) 2005-10-13
CN100339403C (zh) 2007-09-26
RU2293088C2 (ru) 2007-02-10
AU2003238849A1 (en) 2004-01-19
BR0305256A (pt) 2004-10-05
TWI280252B (en) 2007-05-01
CA2489240C (en) 2009-09-22
CN101054388A (zh) 2007-10-17
RU2005102068A (ru) 2005-10-27
SG173215A1 (en) 2011-08-29
CA2488043A1 (en) 2004-01-08
JP2005527695A (ja) 2005-09-15
CA2488052A1 (en) 2004-01-08
JP4361862B2 (ja) 2009-11-11
AU2003280428A8 (en) 2004-01-19
EP1517930B1 (en) 2016-11-02
CZ20041151A3 (cs) 2005-08-17
ATE506381T1 (de) 2011-05-15
US6858689B2 (en) 2005-02-22
CN1659193A (zh) 2005-08-24
MY137541A (en) 2009-02-27
AU2003280424A1 (en) 2004-01-19
CN1665850A (zh) 2005-09-07
NO20040872L (no) 2004-04-27
EP1517930A2 (en) 2005-03-30
WO2004003031A3 (en) 2004-07-08
US6703338B2 (en) 2004-03-09
EP1517931B1 (en) 2011-04-20
CA2488043C (en) 2009-12-08
CN1665849A (zh) 2005-09-07
JP2005531670A (ja) 2005-10-20
TW200403264A (en) 2004-03-01
EP1517931A1 (en) 2005-03-30
WO2004003032A3 (en) 2004-07-29
WO2004003032A2 (en) 2004-01-08
AU2003280428A1 (en) 2004-01-19
CN1302029C (zh) 2007-02-28
MXPA05000067A (es) 2005-04-08
KR20050008796A (ko) 2005-01-21
US20040005983A1 (en) 2004-01-08
AU2003238849B2 (en) 2007-02-15

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