SG173215A1 - Polymerization catalyst activators, method of preparing, and their use in polymerization processes - Google Patents

Polymerization catalyst activators, method of preparing, and their use in polymerization processes Download PDF

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Publication number
SG173215A1
SG173215A1 SG2006090062A SG2006090062A SG173215A1 SG 173215 A1 SG173215 A1 SG 173215A1 SG 2006090062 A SG2006090062 A SG 2006090062A SG 2006090062 A SG2006090062 A SG 2006090062A SG 173215 A1 SG173215 A1 SG 173215A1
Authority
SG
Singapore
Prior art keywords
group
toluene
silica
catalyst system
slurry
Prior art date
Application number
SG2006090062A
Other languages
English (en)
Inventor
Matthew W Holtcamp
David A Cano
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Publication of SG173215A1 publication Critical patent/SG173215A1/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Tires In General (AREA)
  • Disintegrating Or Milling (AREA)
  • Superconductors And Manufacturing Methods Therefor (AREA)
  • Indole Compounds (AREA)
  • Polyethers (AREA)
SG2006090062A 2002-06-28 2003-05-29 Polymerization catalyst activators, method of preparing, and their use in polymerization processes SG173215A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/186,361 US6703338B2 (en) 2002-06-28 2002-06-28 Polymerization catalyst activators, method of preparing, and their use in polymerization processes

Publications (1)

Publication Number Publication Date
SG173215A1 true SG173215A1 (en) 2011-08-29

Family

ID=29999290

Family Applications (1)

Application Number Title Priority Date Filing Date
SG2006090062A SG173215A1 (en) 2002-06-28 2003-05-29 Polymerization catalyst activators, method of preparing, and their use in polymerization processes

Country Status (20)

Country Link
US (2) US6703338B2 (enExample)
EP (3) EP1517930B1 (enExample)
JP (3) JP4361862B2 (enExample)
KR (1) KR100713748B1 (enExample)
CN (4) CN1659193B (enExample)
AT (1) ATE506381T1 (enExample)
AU (3) AU2003238849B2 (enExample)
BR (3) BR0305256A (enExample)
CA (3) CA2488052C (enExample)
CZ (1) CZ20041151A3 (enExample)
DE (1) DE60336812D1 (enExample)
MX (1) MXPA05000067A (enExample)
MY (1) MY137541A (enExample)
NO (1) NO20040872L (enExample)
PL (1) PL373380A1 (enExample)
RU (1) RU2293088C2 (enExample)
SG (1) SG173215A1 (enExample)
TW (1) TWI280252B (enExample)
WO (3) WO2004003031A2 (enExample)
ZA (1) ZA200409750B (enExample)

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US6274684B1 (en) * 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6841504B2 (en) * 2002-01-28 2005-01-11 Univation Technologies, Llc Polymerization catalyst activator and its use in a polymerization process
US6559251B1 (en) * 2002-08-02 2003-05-06 Equistar Chemicals, Lp Process for making low-density polyolefins
US7220695B2 (en) * 2004-01-07 2007-05-22 Exxonmobil Chemical Patents Inc. Supported activator
US7741417B2 (en) * 2004-01-07 2010-06-22 Exxonmobil Chemical Patents Inc. Preparation of polymerization catalyst activators utilizing indole-modified silica supports
EP2217627A1 (en) * 2007-11-08 2010-08-18 ExxonMobil Chemical Patents Inc. Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
US8022005B2 (en) * 2007-11-08 2011-09-20 Exxonmobil Chemical Patents Inc. Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
US8524846B1 (en) 2009-07-02 2013-09-03 The University Of Toledo Trianionic ligand precursor compounds and uses thereof in constrained geometry catalysts
EP2882810B1 (en) 2012-08-03 2018-01-17 ExxonMobil Chemical Patents Inc. Catalysts comprising salan ligands
EP2880097B1 (en) 2012-08-03 2023-10-18 ExxonMobil Chemical Patents Inc. Process to prepare a vinyl terminated polyethylene with long chain branching
US9382349B2 (en) 2012-08-03 2016-07-05 Exxonmobil Chemical Patents Inc. Polyalphaolefins prepared using modified Salan catalyst compounds
EP2880096B1 (en) 2012-08-03 2018-01-03 ExxonMobil Chemical Patents Inc. Process for preparing polyalphaolefins using modified salan catalyst compounds and polyalphaolefins prepared therewith
US8952114B2 (en) 2012-08-03 2015-02-10 Exxonmobil Chemical Patents Inc. Halogenated catalysts comprising Salan ligands
WO2014022010A2 (en) 2012-08-03 2014-02-06 Exxonmobil Chemical Patents Inc. Non-symmetric catalysts comprising salan ligands
US9120879B2 (en) 2012-11-02 2015-09-01 Exxonmobil Chemical Patents Inc. Supported Salan catalysts
SG11201506868UA (en) 2013-03-13 2015-09-29 Exxonmobil Chem Patents Inc Diphenylamine salan catalyst
CN105992774B (zh) 2013-06-20 2018-08-24 埃克森美孚化学专利公司 Salenol催化剂
CN105392776B (zh) * 2013-06-20 2019-02-12 埃克森美孚化学专利公司 硫代-Salalen催化剂
US9200100B2 (en) 2013-06-20 2015-12-01 Exxonmobil Chemical Patents Inc. Long-bridged salen catalyst
US9290589B2 (en) 2013-12-13 2016-03-22 Exxonmobil Chemical Patents Inc. Cyclopentadienyl-substituted salan catalysts
CN106132924B (zh) 2014-03-31 2019-03-19 埃克森美孚化学专利公司 亚苯基桥连的salalen催化剂
US10351647B2 (en) 2015-05-29 2019-07-16 Exxonmobil Chemical Patents Inc. Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports
ES2784359T5 (es) 2015-07-31 2024-04-04 Cargill Inc Método para preparar fibras de cítricos con características de unión de agua optimizadas

Citations (2)

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WO2001062764A1 (en) * 2000-02-24 2001-08-30 Basell Technology Company B.V. Organometallic compound useful as cocatalyst for polymerizing olefins

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Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
WO2001023442A1 (en) * 1999-09-27 2001-04-05 The Dow Chemical Company Supported catalyst comprising expanded anions
WO2001062764A1 (en) * 2000-02-24 2001-08-30 Basell Technology Company B.V. Organometallic compound useful as cocatalyst for polymerizing olefins

Also Published As

Publication number Publication date
DE60336812D1 (en) 2011-06-01
CN101054388B (zh) 2012-09-26
PL373380A1 (en) 2005-08-22
KR100713748B1 (ko) 2007-05-04
US20040167016A1 (en) 2004-08-26
BR0312210A (pt) 2007-05-29
BR0312263A (pt) 2005-04-26
CA2488052C (en) 2010-08-03
CA2489240A1 (en) 2004-01-08
WO2004003037A1 (en) 2004-01-08
EP1517932A2 (en) 2005-03-30
CN1659193B (zh) 2012-06-20
WO2004003031A2 (en) 2004-01-08
ZA200409750B (en) 2005-09-29
JP2005530907A (ja) 2005-10-13
CN100339403C (zh) 2007-09-26
RU2293088C2 (ru) 2007-02-10
AU2003238849A1 (en) 2004-01-19
BR0305256A (pt) 2004-10-05
TWI280252B (en) 2007-05-01
CA2489240C (en) 2009-09-22
CN101054388A (zh) 2007-10-17
RU2005102068A (ru) 2005-10-27
CA2488043A1 (en) 2004-01-08
JP2005527695A (ja) 2005-09-15
CA2488052A1 (en) 2004-01-08
JP4361862B2 (ja) 2009-11-11
AU2003280428A8 (en) 2004-01-19
EP1517930B1 (en) 2016-11-02
CZ20041151A3 (cs) 2005-08-17
ATE506381T1 (de) 2011-05-15
US6858689B2 (en) 2005-02-22
CN1659193A (zh) 2005-08-24
MY137541A (en) 2009-02-27
AU2003280424A1 (en) 2004-01-19
CN1665850A (zh) 2005-09-07
NO20040872L (no) 2004-04-27
EP1517930A2 (en) 2005-03-30
WO2004003031A3 (en) 2004-07-08
US6703338B2 (en) 2004-03-09
EP1517931B1 (en) 2011-04-20
CA2488043C (en) 2009-12-08
CN1665849A (zh) 2005-09-07
JP2005531670A (ja) 2005-10-20
TW200403264A (en) 2004-03-01
EP1517931A1 (en) 2005-03-30
WO2004003032A3 (en) 2004-07-29
WO2004003032A2 (en) 2004-01-08
AU2003280428A1 (en) 2004-01-19
CN1302029C (zh) 2007-02-28
MXPA05000067A (es) 2005-04-08
KR20050008796A (ko) 2005-01-21
US20040005983A1 (en) 2004-01-08
AU2003238849B2 (en) 2007-02-15

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