CN1659193B - 聚合催化剂活化剂,制备方法和它们在聚合方法中的用途 - Google Patents

聚合催化剂活化剂,制备方法和它们在聚合方法中的用途 Download PDF

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Publication number
CN1659193B
CN1659193B CN038126850A CN03812685A CN1659193B CN 1659193 B CN1659193 B CN 1659193B CN 038126850 A CN038126850 A CN 038126850A CN 03812685 A CN03812685 A CN 03812685A CN 1659193 B CN1659193 B CN 1659193B
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China
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group
toluene
silicon
catalyst system
dioxide
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Expired - Fee Related
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CN038126850A
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Chinese (zh)
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CN1659193A (zh
Inventor
M·W·霍尔特坎普
D·A·卡农
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Dow Global Technologies LLC
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Univation Technologies LLC
Dow Global Technologies LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Indole Compounds (AREA)
  • Disintegrating Or Milling (AREA)
  • Superconductors And Manufacturing Methods Therefor (AREA)
  • Tires In General (AREA)
  • Polyethers (AREA)
CN038126850A 2002-06-28 2003-05-29 聚合催化剂活化剂,制备方法和它们在聚合方法中的用途 Expired - Fee Related CN1659193B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/186,361 US6703338B2 (en) 2002-06-28 2002-06-28 Polymerization catalyst activators, method of preparing, and their use in polymerization processes
US10/186,361 2002-06-28
PCT/US2003/017165 WO2004003031A2 (en) 2002-06-28 2003-05-29 Polymerization catalyst activators, method of preparing and their use in polymerization processes

Publications (2)

Publication Number Publication Date
CN1659193A CN1659193A (zh) 2005-08-24
CN1659193B true CN1659193B (zh) 2012-06-20

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CN038126850A Expired - Fee Related CN1659193B (zh) 2002-06-28 2003-05-29 聚合催化剂活化剂,制备方法和它们在聚合方法中的用途
CNB038151197A Expired - Fee Related CN100339403C (zh) 2002-06-28 2003-06-26 用于烯烃聚合的卤代催化剂体系
CN200710102101XA Expired - Fee Related CN101054388B (zh) 2002-06-28 2003-06-26 聚合催化剂活化剂化合物、其制备方法及其应用
CNB038151561A Expired - Fee Related CN1302029C (zh) 2002-06-28 2003-06-26 含杂环氮的活化剂和用于烯烃聚合的催化剂体系

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CNB038151197A Expired - Fee Related CN100339403C (zh) 2002-06-28 2003-06-26 用于烯烃聚合的卤代催化剂体系
CN200710102101XA Expired - Fee Related CN101054388B (zh) 2002-06-28 2003-06-26 聚合催化剂活化剂化合物、其制备方法及其应用
CNB038151561A Expired - Fee Related CN1302029C (zh) 2002-06-28 2003-06-26 含杂环氮的活化剂和用于烯烃聚合的催化剂体系

Country Status (20)

Country Link
US (2) US6703338B2 (enExample)
EP (3) EP1517930B1 (enExample)
JP (3) JP4361862B2 (enExample)
KR (1) KR100713748B1 (enExample)
CN (4) CN1659193B (enExample)
AT (1) ATE506381T1 (enExample)
AU (3) AU2003238849B2 (enExample)
BR (3) BR0305256A (enExample)
CA (3) CA2488052C (enExample)
CZ (1) CZ20041151A3 (enExample)
DE (1) DE60336812D1 (enExample)
MX (1) MXPA05000067A (enExample)
MY (1) MY137541A (enExample)
NO (1) NO20040872L (enExample)
PL (1) PL373380A1 (enExample)
RU (1) RU2293088C2 (enExample)
SG (1) SG173215A1 (enExample)
TW (1) TWI280252B (enExample)
WO (3) WO2004003031A2 (enExample)
ZA (1) ZA200409750B (enExample)

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Publication number Publication date
CN101054388B (zh) 2012-09-26
WO2004003031A2 (en) 2004-01-08
CN100339403C (zh) 2007-09-26
BR0305256A (pt) 2004-10-05
US20040167016A1 (en) 2004-08-26
US20040005983A1 (en) 2004-01-08
CA2488052C (en) 2010-08-03
CA2489240A1 (en) 2004-01-08
CN1659193A (zh) 2005-08-24
EP1517930A2 (en) 2005-03-30
JP2005530907A (ja) 2005-10-13
AU2003238849B2 (en) 2007-02-15
JP4361862B2 (ja) 2009-11-11
AU2003280428A8 (en) 2004-01-19
KR20050008796A (ko) 2005-01-21
BR0312210A (pt) 2007-05-29
CZ20041151A3 (cs) 2005-08-17
AU2003280424A1 (en) 2004-01-19
DE60336812D1 (en) 2011-06-01
CN1302029C (zh) 2007-02-28
BR0312263A (pt) 2005-04-26
JP2005527695A (ja) 2005-09-15
CN1665849A (zh) 2005-09-07
RU2005102068A (ru) 2005-10-27
SG173215A1 (en) 2011-08-29
US6703338B2 (en) 2004-03-09
TWI280252B (en) 2007-05-01
KR100713748B1 (ko) 2007-05-04
CN1665850A (zh) 2005-09-07
WO2004003031A3 (en) 2004-07-08
MY137541A (en) 2009-02-27
AU2003280428A1 (en) 2004-01-19
MXPA05000067A (es) 2005-04-08
EP1517932A2 (en) 2005-03-30
ATE506381T1 (de) 2011-05-15
NO20040872L (no) 2004-04-27
CA2488043C (en) 2009-12-08
EP1517931B1 (en) 2011-04-20
JP2005531670A (ja) 2005-10-20
US6858689B2 (en) 2005-02-22
ZA200409750B (en) 2005-09-29
PL373380A1 (en) 2005-08-22
WO2004003037A1 (en) 2004-01-08
EP1517931A1 (en) 2005-03-30
CA2488052A1 (en) 2004-01-08
RU2293088C2 (ru) 2007-02-10
EP1517930B1 (en) 2016-11-02
WO2004003032A3 (en) 2004-07-29
AU2003238849A1 (en) 2004-01-19
WO2004003032A2 (en) 2004-01-08
TW200403264A (en) 2004-03-01
CA2489240C (en) 2009-09-22
CN101054388A (zh) 2007-10-17
CA2488043A1 (en) 2004-01-08

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