DE60336812D1 - Npolymerisation - Google Patents

Npolymerisation

Info

Publication number
DE60336812D1
DE60336812D1 DE60336812T DE60336812T DE60336812D1 DE 60336812 D1 DE60336812 D1 DE 60336812D1 DE 60336812 T DE60336812 T DE 60336812T DE 60336812 T DE60336812 T DE 60336812T DE 60336812 D1 DE60336812 D1 DE 60336812D1
Authority
DE
Germany
Prior art keywords
aluminoxane
disclosed
support material
activators
heterocyclic compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60336812T
Other languages
German (de)
English (en)
Inventor
Matthew W Holtcamp
David A Cano
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Application granted granted Critical
Publication of DE60336812D1 publication Critical patent/DE60336812D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642Component covered by group C08F4/64 with an organo-aluminium compound
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06Aluminium compounds
    • C07F5/061Aluminium compounds with C-aluminium linkage
    • C07F5/066Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Tires In General (AREA)
  • Disintegrating Or Milling (AREA)
  • Superconductors And Manufacturing Methods Therefor (AREA)
  • Indole Compounds (AREA)
  • Polyethers (AREA)
DE60336812T 2002-06-28 2003-06-26 Npolymerisation Expired - Lifetime DE60336812D1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/186,361 US6703338B2 (en) 2002-06-28 2002-06-28 Polymerization catalyst activators, method of preparing, and their use in polymerization processes
PCT/US2003/020199 WO2004003037A1 (en) 2002-06-28 2003-06-26 Halogen substituted catalyst system for olefin polymerization

Publications (1)

Publication Number Publication Date
DE60336812D1 true DE60336812D1 (en) 2011-06-01

Family

ID=29999290

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60336812T Expired - Lifetime DE60336812D1 (en) 2002-06-28 2003-06-26 Npolymerisation

Country Status (20)

Country Link
US (2) US6703338B2 (enExample)
EP (3) EP1517930B1 (enExample)
JP (3) JP4361862B2 (enExample)
KR (1) KR100713748B1 (enExample)
CN (4) CN1659193B (enExample)
AT (1) ATE506381T1 (enExample)
AU (3) AU2003238849B2 (enExample)
BR (3) BR0305256A (enExample)
CA (3) CA2488052C (enExample)
CZ (1) CZ20041151A3 (enExample)
DE (1) DE60336812D1 (enExample)
MX (1) MXPA05000067A (enExample)
MY (1) MY137541A (enExample)
NO (1) NO20040872L (enExample)
PL (1) PL373380A1 (enExample)
RU (1) RU2293088C2 (enExample)
SG (1) SG173215A1 (enExample)
TW (1) TWI280252B (enExample)
WO (3) WO2004003031A2 (enExample)
ZA (1) ZA200409750B (enExample)

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US6274684B1 (en) * 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6841504B2 (en) * 2002-01-28 2005-01-11 Univation Technologies, Llc Polymerization catalyst activator and its use in a polymerization process
US6559251B1 (en) * 2002-08-02 2003-05-06 Equistar Chemicals, Lp Process for making low-density polyolefins
US7220695B2 (en) * 2004-01-07 2007-05-22 Exxonmobil Chemical Patents Inc. Supported activator
US7741417B2 (en) * 2004-01-07 2010-06-22 Exxonmobil Chemical Patents Inc. Preparation of polymerization catalyst activators utilizing indole-modified silica supports
EP2217627A1 (en) * 2007-11-08 2010-08-18 ExxonMobil Chemical Patents Inc. Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
US8022005B2 (en) * 2007-11-08 2011-09-20 Exxonmobil Chemical Patents Inc. Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
US8524846B1 (en) 2009-07-02 2013-09-03 The University Of Toledo Trianionic ligand precursor compounds and uses thereof in constrained geometry catalysts
EP2882810B1 (en) 2012-08-03 2018-01-17 ExxonMobil Chemical Patents Inc. Catalysts comprising salan ligands
EP2880097B1 (en) 2012-08-03 2023-10-18 ExxonMobil Chemical Patents Inc. Process to prepare a vinyl terminated polyethylene with long chain branching
US9382349B2 (en) 2012-08-03 2016-07-05 Exxonmobil Chemical Patents Inc. Polyalphaolefins prepared using modified Salan catalyst compounds
EP2880096B1 (en) 2012-08-03 2018-01-03 ExxonMobil Chemical Patents Inc. Process for preparing polyalphaolefins using modified salan catalyst compounds and polyalphaolefins prepared therewith
US8952114B2 (en) 2012-08-03 2015-02-10 Exxonmobil Chemical Patents Inc. Halogenated catalysts comprising Salan ligands
WO2014022010A2 (en) 2012-08-03 2014-02-06 Exxonmobil Chemical Patents Inc. Non-symmetric catalysts comprising salan ligands
US9120879B2 (en) 2012-11-02 2015-09-01 Exxonmobil Chemical Patents Inc. Supported Salan catalysts
SG11201506868UA (en) 2013-03-13 2015-09-29 Exxonmobil Chem Patents Inc Diphenylamine salan catalyst
CN105992774B (zh) 2013-06-20 2018-08-24 埃克森美孚化学专利公司 Salenol催化剂
CN105392776B (zh) * 2013-06-20 2019-02-12 埃克森美孚化学专利公司 硫代-Salalen催化剂
US9200100B2 (en) 2013-06-20 2015-12-01 Exxonmobil Chemical Patents Inc. Long-bridged salen catalyst
US9290589B2 (en) 2013-12-13 2016-03-22 Exxonmobil Chemical Patents Inc. Cyclopentadienyl-substituted salan catalysts
CN106132924B (zh) 2014-03-31 2019-03-19 埃克森美孚化学专利公司 亚苯基桥连的salalen催化剂
US10351647B2 (en) 2015-05-29 2019-07-16 Exxonmobil Chemical Patents Inc. Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports
ES2784359T5 (es) 2015-07-31 2024-04-04 Cargill Inc Método para preparar fibras de cítricos con características de unión de agua optimizadas

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Also Published As

Publication number Publication date
CN101054388B (zh) 2012-09-26
PL373380A1 (en) 2005-08-22
KR100713748B1 (ko) 2007-05-04
US20040167016A1 (en) 2004-08-26
BR0312210A (pt) 2007-05-29
BR0312263A (pt) 2005-04-26
CA2488052C (en) 2010-08-03
CA2489240A1 (en) 2004-01-08
WO2004003037A1 (en) 2004-01-08
EP1517932A2 (en) 2005-03-30
CN1659193B (zh) 2012-06-20
WO2004003031A2 (en) 2004-01-08
ZA200409750B (en) 2005-09-29
JP2005530907A (ja) 2005-10-13
CN100339403C (zh) 2007-09-26
RU2293088C2 (ru) 2007-02-10
AU2003238849A1 (en) 2004-01-19
BR0305256A (pt) 2004-10-05
TWI280252B (en) 2007-05-01
CA2489240C (en) 2009-09-22
CN101054388A (zh) 2007-10-17
RU2005102068A (ru) 2005-10-27
SG173215A1 (en) 2011-08-29
CA2488043A1 (en) 2004-01-08
JP2005527695A (ja) 2005-09-15
CA2488052A1 (en) 2004-01-08
JP4361862B2 (ja) 2009-11-11
AU2003280428A8 (en) 2004-01-19
EP1517930B1 (en) 2016-11-02
CZ20041151A3 (cs) 2005-08-17
ATE506381T1 (de) 2011-05-15
US6858689B2 (en) 2005-02-22
CN1659193A (zh) 2005-08-24
MY137541A (en) 2009-02-27
AU2003280424A1 (en) 2004-01-19
CN1665850A (zh) 2005-09-07
NO20040872L (no) 2004-04-27
EP1517930A2 (en) 2005-03-30
WO2004003031A3 (en) 2004-07-08
US6703338B2 (en) 2004-03-09
EP1517931B1 (en) 2011-04-20
CA2488043C (en) 2009-12-08
CN1665849A (zh) 2005-09-07
JP2005531670A (ja) 2005-10-20
TW200403264A (en) 2004-03-01
EP1517931A1 (en) 2005-03-30
WO2004003032A3 (en) 2004-07-29
WO2004003032A2 (en) 2004-01-08
AU2003280428A1 (en) 2004-01-19
CN1302029C (zh) 2007-02-28
MXPA05000067A (es) 2005-04-08
KR20050008796A (ko) 2005-01-21
US20040005983A1 (en) 2004-01-08
AU2003238849B2 (en) 2007-02-15

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