JP2005531670A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2005531670A5 JP2005531670A5 JP2004517963A JP2004517963A JP2005531670A5 JP 2005531670 A5 JP2005531670 A5 JP 2005531670A5 JP 2004517963 A JP2004517963 A JP 2004517963A JP 2004517963 A JP2004517963 A JP 2004517963A JP 2005531670 A5 JP2005531670 A5 JP 2005531670A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- catalyst system
- atom
- formula
- heterocyclic nitrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000003054 catalyst Substances 0.000 claims 10
- 125000004429 atom Chemical group 0.000 claims 6
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 claims 4
- -1 heterocyclic nitrogen-containing compound Chemical class 0.000 claims 4
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims 3
- 239000012190 activator Substances 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims 3
- 239000003446 ligand Substances 0.000 claims 3
- 239000002685 polymerization catalyst Substances 0.000 claims 3
- PAPNRQCYSFBWDI-UHFFFAOYSA-N 2,5-Dimethyl-1H-pyrrole Chemical compound CC1=CC=C(C)N1 PAPNRQCYSFBWDI-UHFFFAOYSA-N 0.000 claims 2
- KDCGOANMDULRCW-UHFFFAOYSA-N 7H-purine Chemical compound N1=CNC2=NC=NC2=C1 KDCGOANMDULRCW-UHFFFAOYSA-N 0.000 claims 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 claims 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims 2
- 229910052782 aluminium Inorganic materials 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 2
- 125000001424 substituent group Chemical group 0.000 claims 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-O 1H-indol-1-ium Chemical compound C1=CC=C2[NH2+]C=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-O 0.000 claims 1
- KLLLJCACIRKBDT-UHFFFAOYSA-N 2-phenyl-1H-indole Chemical compound N1C2=CC=CC=C2C=C1C1=CC=CC=C1 KLLLJCACIRKBDT-UHFFFAOYSA-N 0.000 claims 1
- RSEBUVRVKCANEP-UHFFFAOYSA-N 2-pyrroline Chemical compound C1CC=CN1 RSEBUVRVKCANEP-UHFFFAOYSA-N 0.000 claims 1
- BMJOPWQYDZAFDZ-UHFFFAOYSA-N 3,4-difluoro-1h-pyrrole Chemical compound FC1=CNC=C1F BMJOPWQYDZAFDZ-UHFFFAOYSA-N 0.000 claims 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- 229910013504 M-O-M Inorganic materials 0.000 claims 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 150000002391 heterocyclic compounds Chemical group 0.000 claims 1
- 150000003949 imides Chemical class 0.000 claims 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 claims 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 claims 1
- 125000001041 indolyl group Chemical group 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- ZVJHJDDKYZXRJI-UHFFFAOYSA-N pyrroline Natural products C1CC=NC1 ZVJHJDDKYZXRJI-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/186,361 US6703338B2 (en) | 2002-06-28 | 2002-06-28 | Polymerization catalyst activators, method of preparing, and their use in polymerization processes |
| PCT/US2003/020320 WO2004003032A2 (en) | 2002-06-28 | 2003-06-26 | Heterocyclic nitrogen-containing activators and catalyst systems for olefin polymerization |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2005531670A JP2005531670A (ja) | 2005-10-20 |
| JP2005531670A5 true JP2005531670A5 (enExample) | 2008-07-24 |
Family
ID=29999290
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004517607A Expired - Fee Related JP4361862B2 (ja) | 2002-06-28 | 2003-05-29 | 重合用触媒の活性剤、その製造方法及び重合プロセスにおけるその使用 |
| JP2004517894A Withdrawn JP2005530907A (ja) | 2002-06-28 | 2003-06-26 | オレフィン重合用のハロゲン置換触媒系 |
| JP2004517963A Withdrawn JP2005531670A (ja) | 2002-06-28 | 2003-06-26 | 複素環窒素含有活性化剤及びオレフィン重合用触媒系 |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004517607A Expired - Fee Related JP4361862B2 (ja) | 2002-06-28 | 2003-05-29 | 重合用触媒の活性剤、その製造方法及び重合プロセスにおけるその使用 |
| JP2004517894A Withdrawn JP2005530907A (ja) | 2002-06-28 | 2003-06-26 | オレフィン重合用のハロゲン置換触媒系 |
Country Status (20)
| Country | Link |
|---|---|
| US (2) | US6703338B2 (enExample) |
| EP (3) | EP1517930B1 (enExample) |
| JP (3) | JP4361862B2 (enExample) |
| KR (1) | KR100713748B1 (enExample) |
| CN (4) | CN1659193B (enExample) |
| AT (1) | ATE506381T1 (enExample) |
| AU (3) | AU2003238849B2 (enExample) |
| BR (3) | BR0305256A (enExample) |
| CA (3) | CA2488052C (enExample) |
| CZ (1) | CZ20041151A3 (enExample) |
| DE (1) | DE60336812D1 (enExample) |
| MX (1) | MXPA05000067A (enExample) |
| MY (1) | MY137541A (enExample) |
| NO (1) | NO20040872L (enExample) |
| PL (1) | PL373380A1 (enExample) |
| RU (1) | RU2293088C2 (enExample) |
| SG (1) | SG173215A1 (enExample) |
| TW (1) | TWI280252B (enExample) |
| WO (3) | WO2004003031A2 (enExample) |
| ZA (1) | ZA200409750B (enExample) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6274684B1 (en) | 1999-10-22 | 2001-08-14 | Univation Technologies, Llc | Catalyst composition, method of polymerization, and polymer therefrom |
| US6841504B2 (en) * | 2002-01-28 | 2005-01-11 | Univation Technologies, Llc | Polymerization catalyst activator and its use in a polymerization process |
| US6559251B1 (en) * | 2002-08-02 | 2003-05-06 | Equistar Chemicals, Lp | Process for making low-density polyolefins |
| US7220695B2 (en) * | 2004-01-07 | 2007-05-22 | Exxonmobil Chemical Patents Inc. | Supported activator |
| US7741417B2 (en) * | 2004-01-07 | 2010-06-22 | Exxonmobil Chemical Patents Inc. | Preparation of polymerization catalyst activators utilizing indole-modified silica supports |
| WO2009061678A1 (en) * | 2007-11-08 | 2009-05-14 | Exxonmobil Chemicals Patents Inc. | Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes |
| US8022005B2 (en) * | 2007-11-08 | 2011-09-20 | Exxonmobil Chemical Patents Inc. | Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes |
| US8524846B1 (en) | 2009-07-02 | 2013-09-03 | The University Of Toledo | Trianionic ligand precursor compounds and uses thereof in constrained geometry catalysts |
| WO2014022012A1 (en) | 2012-08-03 | 2014-02-06 | Exxonmobil Chemical Patents Inc. | Vinyl terminated polyethylene with long chain branching |
| EP2882810B1 (en) | 2012-08-03 | 2018-01-17 | ExxonMobil Chemical Patents Inc. | Catalysts comprising salan ligands |
| WO2014022011A1 (en) | 2012-08-03 | 2014-02-06 | Exxonmobil Chemical Patents Inc. | Halogenated catalysts comprising salan ligands |
| EP2880006B1 (en) | 2012-08-03 | 2017-12-20 | ExxonMobil Chemical Patents Inc. | Non-symmetric catalysts comprising salan ligands |
| US9365661B2 (en) | 2012-08-03 | 2016-06-14 | Exxonmobil Chemical Patents Inc. | Polyalphaolefins prepared using modified salan catalyst compounds |
| US9382349B2 (en) | 2012-08-03 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Polyalphaolefins prepared using modified Salan catalyst compounds |
| CN104428324B (zh) | 2012-11-02 | 2018-08-17 | 埃克森美孚化学专利公司 | 负载型Salan催化剂 |
| US8937137B2 (en) | 2013-03-13 | 2015-01-20 | Exxonmobil Chemical Patents Inc. | Diphenylamine salan catalyst |
| US9150676B2 (en) | 2013-06-20 | 2015-10-06 | Exxonmobil Chemical Patents Inc. | Thio-salalen catalyst |
| WO2014204681A1 (en) | 2013-06-20 | 2014-12-24 | Exxonmobil Chemical Patents Inc. | Long-bridged salen catalyst |
| CN105992774B (zh) | 2013-06-20 | 2018-08-24 | 埃克森美孚化学专利公司 | Salenol催化剂 |
| US9290589B2 (en) | 2013-12-13 | 2016-03-22 | Exxonmobil Chemical Patents Inc. | Cyclopentadienyl-substituted salan catalysts |
| EP3126325B1 (en) | 2014-03-31 | 2019-04-24 | ExxonMobil Chemical Patents Inc. | Phenylene-bridged salalen catalysts |
| US10351647B2 (en) | 2015-05-29 | 2019-07-16 | Exxonmobil Chemical Patents Inc. | Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports |
| US11812775B2 (en) | 2015-07-31 | 2023-11-14 | Cargill, Incorporated | Citrus fibers with optimized water binding characteristics |
Family Cites Families (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL125095C (enExample) * | 1961-05-02 | |||
| JPS5421391B1 (enExample) * | 1969-07-10 | 1979-07-30 | ||
| US4224181A (en) * | 1979-03-07 | 1980-09-23 | Exxon Research & Engineering Co. | Ziegler type catalyst system |
| US4271060A (en) | 1979-09-17 | 1981-06-02 | Phillips Petroleum Company | Solution polymerization process |
| US4434313A (en) * | 1981-12-14 | 1984-02-28 | Exxon Research And Engineering Co. | Preparation of linear olefin products |
| IT1178466B (it) * | 1984-03-20 | 1987-09-09 | Montedison Spa | Catalizzatori per la omo e copolimerizzazione dell'etilene e polimeri ottenuti |
| US5001205A (en) | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
| US5236998A (en) | 1991-03-07 | 1993-08-17 | Occidental Chemical Corporation | Process for the manufacture of linear polyethylene containing α-alkene commonomers |
| IT1251462B (it) * | 1991-07-12 | 1995-05-15 | Enichem Polimeri | Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene e delle alfa olefine. |
| US5589555A (en) | 1991-10-03 | 1996-12-31 | Novacor Chemicals (International) S.A. | Control of a solution process for polymerization of ethylene |
| US5221761A (en) * | 1992-04-29 | 1993-06-22 | Instituto Guido Donegani | Melt transesterification process for the production of polycarbonates |
| US5317036A (en) | 1992-10-16 | 1994-05-31 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization reactions utilizing soluble unsupported catalysts |
| ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
| US5804678A (en) | 1993-07-13 | 1998-09-08 | Mitsui Petrochemical Industries, Ltd. | Process for gas phase polymerization of olefin |
| EP0649992B1 (de) | 1993-10-23 | 1997-07-30 | WABCO GmbH | Betätigungseinrichtung für eine Scheibenbremse |
| US5763543A (en) | 1994-09-14 | 1998-06-09 | Exxon Chemical Patents Inc. | Olefin polymerization process with little or no scavenger present |
| DE69510812T2 (de) | 1994-10-13 | 2000-04-20 | Exxon Chemical Patents, Inc. | Verfahren zur herstellung von polymerisationskatalysatorsystemen und ihre verwendung |
| CN1171794A (zh) * | 1994-10-31 | 1998-01-28 | Dsm有限公司 | 用于烯烃聚合的催化剂组合物及方法 |
| US5677375A (en) | 1995-07-21 | 1997-10-14 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing an in situ polyethylene blend |
| GB9522859D0 (en) * | 1995-11-08 | 1996-01-10 | Borealis As | Compounds |
| US5665818A (en) | 1996-03-05 | 1997-09-09 | Union Carbide Chemicals & Plastics Technology Corporation | High activity staged reactor process |
| US5627242A (en) | 1996-03-28 | 1997-05-06 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling gas phase fluidized bed polymerization reactor |
| US5693727A (en) | 1996-06-06 | 1997-12-02 | Union Carbide Chemicals & Plastics Technology Corporation | Method for feeding a liquid catalyst to a fluidized bed polymerization reactor |
| JP2000035973A (ja) * | 1996-06-11 | 2000-02-02 | Masanobu Kujirada | 遠隔匂い発生システム |
| JP3889881B2 (ja) * | 1997-07-10 | 2007-03-07 | 三井化学株式会社 | オレフィン重合用触媒成分、オレフィン重合用触媒およびオレフィンの重合方法 |
| KR100520588B1 (ko) | 1997-12-23 | 2005-10-10 | 다우 글로벌 테크놀로지스 인크. | 올레핀의 용액 중합 방법에서 중합체 함량을 증가시키기위한 마무리처리 공정 디자인 |
| ID25653A (id) * | 1998-02-20 | 2000-10-19 | Dow Chemical Co | Aktifator katalis terdiri dari pengembangan anion |
| WO1999064476A1 (en) * | 1998-06-12 | 1999-12-16 | Univation Technologies Llc | Olefin polymerization process using activated lewis acid-base complexes |
| US7354880B2 (en) | 1998-07-10 | 2008-04-08 | Univation Technologies, Llc | Catalyst composition and methods for its preparation and use in a polymerization process |
| US6500949B2 (en) * | 1998-10-08 | 2002-12-31 | Dow Global Technologies Inc. | Bridged metal complexes |
| KR100628614B1 (ko) * | 1998-10-08 | 2006-09-26 | 더 다우 케미칼 캄파니 | 가교된 금속 착체 |
| US6147173A (en) | 1998-11-13 | 2000-11-14 | Univation Technologies, Llc | Nitrogen-containing group 13 anionic complexes for olefin polymerization |
| EP1054914B1 (de) * | 1998-12-12 | 2004-03-03 | Basell Polyolefine GmbH | Zwitterionische, neutrale übergansmetallverbindung |
| KR100656109B1 (ko) * | 1999-07-29 | 2006-12-12 | 다우 글로벌 테크놀로지스 인크. | 개선된 실란 관능화 올레핀 인터폴리머 및 이의 유도체 |
| EP1228109B1 (en) * | 1999-09-27 | 2006-02-01 | Dow Global Technologies Inc. | Supported catalyst comprising expanded anions |
| BR0015901A (pt) * | 1999-11-26 | 2002-10-22 | Sasol Tech Pty Ltd | Processos de oligomerização de olefina para converter olefinas em hidrocarbonetos de cadeia mais longa, e de trimerização para a trimerização de olefinas, e, lubrificante de polialfaolefina |
| ATE268779T1 (de) | 2000-02-24 | 2004-06-15 | Basell Polyolefine Gmbh | Organometallische verbindung die als cokatalysator bei der polymerisation von olefinen verwendbar ist |
| AU2001263526A1 (en) * | 2000-05-04 | 2001-11-12 | Sasol Technology (Pty) Ltd. | A halopyrrole ligand for use in a catalyst system |
| WO2002008303A1 (en) * | 2000-07-20 | 2002-01-31 | The Dow Chemical Company | Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom |
| WO2002074779A1 (en) * | 2001-03-19 | 2002-09-26 | Dow Global Technologies Inc. | Metal complexes containing acetylenic ligands, polymerization catalysts and addition polymerization process |
| JP4173803B2 (ja) * | 2001-05-21 | 2008-10-29 | バーゼル・ポリオレフィン・ゲーエムベーハー | オレフィンの重合用触媒系 |
| DE60224671T2 (de) * | 2001-06-15 | 2009-01-08 | Dow Global Technologies, Inc., Midland | Verzweigte polymere auf alpha-olefin basis |
| US6841504B2 (en) * | 2002-01-28 | 2005-01-11 | Univation Technologies, Llc | Polymerization catalyst activator and its use in a polymerization process |
-
2002
- 2002-06-28 US US10/186,361 patent/US6703338B2/en not_active Expired - Fee Related
-
2003
- 2003-05-29 PL PL03373380A patent/PL373380A1/xx unknown
- 2003-05-29 JP JP2004517607A patent/JP4361862B2/ja not_active Expired - Fee Related
- 2003-05-29 KR KR1020047019815A patent/KR100713748B1/ko not_active Expired - Fee Related
- 2003-05-29 BR BR0305256-7A patent/BR0305256A/pt not_active Application Discontinuation
- 2003-05-29 CZ CZ20041151A patent/CZ20041151A3/cs unknown
- 2003-05-29 SG SG2006090062A patent/SG173215A1/en unknown
- 2003-05-29 CA CA2488052A patent/CA2488052C/en not_active Expired - Fee Related
- 2003-05-29 CN CN038126850A patent/CN1659193B/zh not_active Expired - Fee Related
- 2003-05-29 WO PCT/US2003/017165 patent/WO2004003031A2/en not_active Ceased
- 2003-05-29 AU AU2003238849A patent/AU2003238849B2/en not_active Ceased
- 2003-05-29 EP EP03734308.4A patent/EP1517930B1/en not_active Expired - Lifetime
- 2003-05-29 RU RU2005102068/04A patent/RU2293088C2/ru not_active IP Right Cessation
- 2003-05-29 MX MXPA05000067A patent/MXPA05000067A/es active IP Right Grant
- 2003-06-23 TW TW092117000A patent/TWI280252B/zh not_active IP Right Cessation
- 2003-06-26 CN CNB038151561A patent/CN1302029C/zh not_active Expired - Fee Related
- 2003-06-26 DE DE60336812T patent/DE60336812D1/de not_active Expired - Lifetime
- 2003-06-26 JP JP2004517894A patent/JP2005530907A/ja not_active Withdrawn
- 2003-06-26 CN CNB038151197A patent/CN100339403C/zh not_active Expired - Fee Related
- 2003-06-26 EP EP03742270A patent/EP1517932A2/en not_active Withdrawn
- 2003-06-26 EP EP03742245A patent/EP1517931B1/en not_active Expired - Lifetime
- 2003-06-26 CA CA002488043A patent/CA2488043C/en not_active Expired - Fee Related
- 2003-06-26 WO PCT/US2003/020320 patent/WO2004003032A2/en not_active Ceased
- 2003-06-26 WO PCT/US2003/020199 patent/WO2004003037A1/en not_active Ceased
- 2003-06-26 AT AT03742245T patent/ATE506381T1/de not_active IP Right Cessation
- 2003-06-26 CA CA002489240A patent/CA2489240C/en not_active Expired - Fee Related
- 2003-06-26 JP JP2004517963A patent/JP2005531670A/ja not_active Withdrawn
- 2003-06-26 BR BR0312263-8A patent/BR0312263A/pt not_active IP Right Cessation
- 2003-06-26 AU AU2003280424A patent/AU2003280424A1/en not_active Abandoned
- 2003-06-26 AU AU2003280428A patent/AU2003280428A1/en not_active Abandoned
- 2003-06-26 MY MYPI20032414A patent/MY137541A/en unknown
- 2003-06-26 BR BRPI0312210-7A patent/BR0312210A/pt unknown
- 2003-06-26 CN CN200710102101XA patent/CN101054388B/zh not_active Expired - Fee Related
- 2003-12-12 US US10/734,871 patent/US6858689B2/en not_active Expired - Fee Related
-
2004
- 2004-02-27 NO NO20040872A patent/NO20040872L/no not_active Application Discontinuation
- 2004-12-01 ZA ZA200409750A patent/ZA200409750B/en unknown
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2005531670A5 (enExample) | ||
| Focante et al. | Complexes of tris (pentafluorophenyl) boron with nitrogen-containing compounds: Synthesis, reactivity and metallocene activation | |
| ES2167870T5 (es) | Sistemas cataliticos de polimerizacion que comprenden ligandos ciclopentadienuro heterociclicos fusionados. | |
| TW538051B (en) | Catalyst systems and their use in a polymerization process | |
| CA2488043A1 (en) | Halogen substituted catalyst system for olefin polymerization | |
| JP2005530907A5 (enExample) | ||
| JP2003524013A (ja) | オレフィン重合用助触媒として有用な有機金属化合物 | |
| JP2003517058A (ja) | 重合方法 | |
| Ma et al. | Dinuclear Pd (II)–NHC complex derived from proline and its application toward Mizoroki–Heck reaction performed in water | |
| Gehrmann et al. | Alternative reaction pathways in domino reactions of hydrazinediidozirconium complexes with alkynes | |
| CN100402535C (zh) | 使用非共价相互作用的聚烯烃催化剂组分 | |
| Park et al. | Zinc (II), palladium (II) and cadmium (II) complexes containing 4‐methoxy‐N‐(pyridin‐2‐ylmethylene) aniline derivatives: Synthesis, characterization and methyl methacrylate polymerization | |
| Sadimenko | Organometallic compounds of pyrrole, indole, carbazole, phospholes, siloles, and boroles | |
| Noor | Coordination chemistry of bulky aminopryridinates with main group and transition metals | |
| Yang | Heteroleptic (N‐heterocyclic carbene)–Pd–pyrazole (indazole) complexes: Synthesis, characterization and catalytic activities towards C–C and C–N cross‐coupling reactions | |
| KR20010112403A (ko) | 중성의 다가 아자시클릭 리간드 함유 금속 화합물, 이들을사용한 촉매, 이들을 사용한 올레핀 중합 방법 | |
| Manßen et al. | From organic azides through titanium triazenido complexes to titanium imides | |
| Jiang et al. | Recent advances in the synthesis of 1-monosubstituted 1, 2, 3-triazoles | |
| Cravotto et al. | Novel cyclometallated Pd (II) and Pt (II) complexes with indole derivatives and their use as catalysts in Heck reaction | |
| Wang et al. | Piperazine‐and DABCO‐bridged dinuclear N‐heterocyclic carbene palladium complexes: synthesis, structure and application to Hiyama coupling reaction | |
| NO20055625L (no) | Katalysator for polymerisering og kopolymerisering av alfa-olenfiner | |
| Donkervoort et al. | Formation of mixed aryl–, alkyl–lithium aggregates in the heteroatom assisted lithiation of α, α′-dialkyl substituted 1, 3-bis [(dimethylamino) methyl] benzene | |
| Lundrigan et al. | Synthesis of heteroleptic pyrrolide/bipyridyl complexes of ruthenium (II) | |
| JP3850048B2 (ja) | 有機遷移金属化合物およびそれを用いたポリオレフィンの製造方法 | |
| Barriola et al. | Insertion of isocyanides into zirconium-alkyl bonds of di-ansa-zirconocene complexes. X-ray molecular structure of Zr {(SiMe2) 2 (η5− C5H3) 2} Cl {η2− C (i− Pr) N (2, 6-Me2C6H3) |