JP2003519281A5 - - Google Patents
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- JP2003519281A5 JP2003519281A5 JP2001550446A JP2001550446A JP2003519281A5 JP 2003519281 A5 JP2003519281 A5 JP 2003519281A5 JP 2001550446 A JP2001550446 A JP 2001550446A JP 2001550446 A JP2001550446 A JP 2001550446A JP 2003519281 A5 JP2003519281 A5 JP 2003519281A5
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- Japan
- Prior art keywords
- cation
- anion
- repellent
- acidity
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 150000001768 cations Chemical class 0.000 description 18
- 150000001450 anions Chemical class 0.000 description 16
- 239000000203 mixture Substances 0.000 description 13
- 239000002184 metal Substances 0.000 description 9
- 239000005871 repellent Substances 0.000 description 9
- 230000002940 repellent Effects 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N sulfonic acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- JOXIMZWYDAKGHI-UHFFFAOYSA-N P-Toluenesulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N precursor Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
Description
【特許請求の範囲】
【請求項１】 撥水撥油性帯電防止組成物であって、（ａ）（ｉ）一価金属カチオン、二価金属カチオン、及び有機オニウムカチオンからなる群から選択された少なくとも１つのカチオン及び（ｉｉ）少なくとも１つの弱配位アニオンであって、前記アニオンの共役酸が炭化水素スルホン酸の酸度以上の酸度を有するが、ただし、前記カチオンが金属である時に、有機系またはフルオロ有機系である弱配位アニオン、からなる少なくとも１つのイオン性非重合塩と、（ｂ）少なくとも１つのフルオロケミカル撥剤と、（ｃ）少なくとも１つの絶縁材と、を含む、撥水撥油性帯電防止組成物。
【請求項２】 （ａ）（ｉ）少なくとも１つの窒素オニウムまたはリンオニウムカチオン及び（ｉｉ）少なくとも１つの弱配位アニオンであって、前記アニオンの共役酸がメタンスルホン酸またはｐ−トルエンスルホン酸の酸度以上の酸度を有する弱配位アニオン、からなる少なくとも１つのイオン性非重合塩と、（ｂ）溶融添加剤として使用するのに適している少なくとも１つのフルオロケミカル撥剤と、（ｃ）少なくとも１つの熱可塑性ポリマーと、を含み、成分（ａ）、（ｂ）、及び（ｃ）の溶融ブレンドを形成することによって調製される、撥水撥油性帯電防止組成物。
【請求項３】 請求項１または２に記載の組成物を含む繊維。
【請求項４】 請求項３に記載の繊維を含む布。
【請求項５】 請求項１または２に記載の組成物を含むフィルム。
【請求項６】 請求項１または２に記載の組成物を含む成形またはブローン物品。
【請求項７】 請求項１または２に記載の組成物を含むコーティング。
【請求項８】 請求項１に記載の撥水撥油性帯電防止組成物の調製方法であって、（ａ）（ｉ）少なくとも１つのカチオン及び少なくとも１つのアニオンからなる少なくとも１つのイオン性非重合塩であって、前記カチオンが一価金属カチオン、二価金属カチオン、及び有機オニウムカチオンからなる群から選択され、前記アニオンが弱配位アニオンであり、前記アニオンの共役酸が炭化水素スルホン酸の酸度以上の酸度を有するが、ただし、前記カチオンが金属である時に前記アニオンが有機系またはフルオロ有機系である、イオン性非重合塩と、（ｉｉ）少なくとも１つのフルオロケミカル撥剤と、（ｉｉｉ）少なくとも１つの熱可塑性ポリマーと、を配合する工程と、（ｂ）得られた配合物を溶融加工する工程と、を含む、撥水撥油性帯電防止組成物の調製方法。
【請求項９】 請求項１に記載の撥水撥油性帯電防止組成物の調製方法であって、（ａ）（ｉ）少なくとも１つのカチオン及び少なくとも１つのアニオンからなる少なくとも１つのイオン性非重合塩であって、前記カチオンが一価金属カチオン、二価金属カチオン、及び有機オニウムカチオンからなる群から選択され、前記アニオンが弱配位アニオンであり、前記アニオンの共役酸が炭化水素スルホン酸の酸度以上の酸度を有するが、ただし、前記カチオンが金属である時に前記アニオンが有機系またはフルオロ有機系である、イオン性非重合塩と、（ｉｉ）少なくとも１つのフルオロケミカル撥剤と、（ｉｉｉ）少なくとも１つの熱硬化性ポリマーまたはセラマーもしくは前記ポリマーまたはセラマーの反応性前駆物質と、を配合する工程と、（ｂ）得られた配合物を硬化させる工程と、を含む、撥水撥油性帯電防止組成物の調製方法。
【請求項１】 撥水撥油性帯電防止組成物であって、（ａ）（ｉ）一価金属カチオン、二価金属カチオン、及び有機オニウムカチオンからなる群から選択された少なくとも１つのカチオン及び（ｉｉ）少なくとも１つの弱配位アニオンであって、前記アニオンの共役酸が炭化水素スルホン酸の酸度以上の酸度を有するが、ただし、前記カチオンが金属である時に、有機系またはフルオロ有機系である弱配位アニオン、からなる少なくとも１つのイオン性非重合塩と、（ｂ）少なくとも１つのフルオロケミカル撥剤と、（ｃ）少なくとも１つの絶縁材と、を含む、撥水撥油性帯電防止組成物。
【請求項２】 （ａ）（ｉ）少なくとも１つの窒素オニウムまたはリンオニウムカチオン及び（ｉｉ）少なくとも１つの弱配位アニオンであって、前記アニオンの共役酸がメタンスルホン酸またはｐ−トルエンスルホン酸の酸度以上の酸度を有する弱配位アニオン、からなる少なくとも１つのイオン性非重合塩と、（ｂ）溶融添加剤として使用するのに適している少なくとも１つのフルオロケミカル撥剤と、（ｃ）少なくとも１つの熱可塑性ポリマーと、を含み、成分（ａ）、（ｂ）、及び（ｃ）の溶融ブレンドを形成することによって調製される、撥水撥油性帯電防止組成物。
【請求項３】 請求項１または２に記載の組成物を含む繊維。
【請求項４】 請求項３に記載の繊維を含む布。
【請求項５】 請求項１または２に記載の組成物を含むフィルム。
【請求項６】 請求項１または２に記載の組成物を含む成形またはブローン物品。
【請求項７】 請求項１または２に記載の組成物を含むコーティング。
【請求項８】 請求項１に記載の撥水撥油性帯電防止組成物の調製方法であって、（ａ）（ｉ）少なくとも１つのカチオン及び少なくとも１つのアニオンからなる少なくとも１つのイオン性非重合塩であって、前記カチオンが一価金属カチオン、二価金属カチオン、及び有機オニウムカチオンからなる群から選択され、前記アニオンが弱配位アニオンであり、前記アニオンの共役酸が炭化水素スルホン酸の酸度以上の酸度を有するが、ただし、前記カチオンが金属である時に前記アニオンが有機系またはフルオロ有機系である、イオン性非重合塩と、（ｉｉ）少なくとも１つのフルオロケミカル撥剤と、（ｉｉｉ）少なくとも１つの熱可塑性ポリマーと、を配合する工程と、（ｂ）得られた配合物を溶融加工する工程と、を含む、撥水撥油性帯電防止組成物の調製方法。
【請求項９】 請求項１に記載の撥水撥油性帯電防止組成物の調製方法であって、（ａ）（ｉ）少なくとも１つのカチオン及び少なくとも１つのアニオンからなる少なくとも１つのイオン性非重合塩であって、前記カチオンが一価金属カチオン、二価金属カチオン、及び有機オニウムカチオンからなる群から選択され、前記アニオンが弱配位アニオンであり、前記アニオンの共役酸が炭化水素スルホン酸の酸度以上の酸度を有するが、ただし、前記カチオンが金属である時に前記アニオンが有機系またはフルオロ有機系である、イオン性非重合塩と、（ｉｉ）少なくとも１つのフルオロケミカル撥剤と、（ｉｉｉ）少なくとも１つの熱硬化性ポリマーまたはセラマーもしくは前記ポリマーまたはセラマーの反応性前駆物質と、を配合する工程と、（ｂ）得られた配合物を硬化させる工程と、を含む、撥水撥油性帯電防止組成物の調製方法。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/474,711 | 1999-12-29 | ||
| US09/474,711 US6592988B1 (en) | 1999-12-29 | 1999-12-29 | Water-and oil-repellent, antistatic composition |
| PCT/US2000/025097 WO2001049925A1 (en) | 1999-12-29 | 2000-09-13 | Water- and oil-repellent, antistatic composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2003519281A JP2003519281A (ja) | 2003-06-17 |
| JP2003519281A5 true JP2003519281A5 (ja) | 2007-11-08 |
Family
ID=23884651
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001550446A Pending JP2003519281A (ja) | 1999-12-29 | 2000-09-13 | 撥水撥油性帯電防止組成物 |
Country Status (10)
| Country | Link |
|---|---|
| US (3) | US6592988B1 (ja) |
| EP (1) | EP1242670B1 (ja) |
| JP (1) | JP2003519281A (ja) |
| KR (1) | KR100702927B1 (ja) |
| AT (1) | ATE396297T1 (ja) |
| AU (1) | AU7483200A (ja) |
| CA (1) | CA2394724C (ja) |
| DE (1) | DE60038978D1 (ja) |
| TW (1) | TWI254727B (ja) |
| WO (1) | WO2001049925A1 (ja) |
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- 2000-09-13 JP JP2001550446A patent/JP2003519281A/ja active Pending
- 2000-09-13 EP EP00963416A patent/EP1242670B1/en not_active Expired - Lifetime
- 2000-09-13 AT AT00963416T patent/ATE396297T1/de not_active IP Right Cessation
- 2000-09-13 KR KR20027008548A patent/KR100702927B1/ko not_active IP Right Cessation
- 2000-09-13 WO PCT/US2000/025097 patent/WO2001049925A1/en active Application Filing
- 2000-09-13 CA CA002394724A patent/CA2394724C/en not_active Expired - Fee Related
- 2000-09-13 DE DE60038978T patent/DE60038978D1/de not_active Expired - Lifetime
- 2000-12-26 TW TW089127881A patent/TWI254727B/zh not_active IP Right Cessation
-
2003
- 2003-06-11 US US10/458,971 patent/US6784237B2/en not_active Expired - Lifetime
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2004
- 2004-02-24 US US10/785,332 patent/US7361706B2/en not_active Expired - Fee Related
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