JP2000351813A - エチレン・α−オレフィン共重合体およびその製造方法ならびにその用途 - Google Patents

エチレン・α−オレフィン共重合体およびその製造方法ならびにその用途

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Publication number
JP2000351813A
JP2000351813A JP2000105406A JP2000105406A JP2000351813A JP 2000351813 A JP2000351813 A JP 2000351813A JP 2000105406 A JP2000105406 A JP 2000105406A JP 2000105406 A JP2000105406 A JP 2000105406A JP 2000351813 A JP2000351813 A JP 2000351813A
Authority
JP
Japan
Prior art keywords
group
ethylene
olefin
containing group
olefin copolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000105406A
Other languages
English (en)
Japanese (ja)
Other versions
JP2000351813A5 (enExample
Inventor
Hideki Hirano
野 英 樹 平
Terunori Fujita
田 照 典 藤
Junji Saito
藤 純 治 斎
Makoto Mitani
谷 誠 三
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Inc
Original Assignee
Mitsui Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Chemicals Inc filed Critical Mitsui Chemicals Inc
Priority to JP2000105406A priority Critical patent/JP2000351813A/ja
Priority to KR1020000018283A priority patent/KR20000071607A/ko
Priority to US09/545,672 priority patent/US6459005B1/en
Priority to SG200002006A priority patent/SG88774A1/en
Priority to MYPI20001478A priority patent/MY122619A/en
Priority to EP00302999A priority patent/EP1043341B1/en
Priority to DE60040360T priority patent/DE60040360D1/de
Priority to CNB001064762A priority patent/CN1172972C/zh
Priority to EP07020125A priority patent/EP1876189B1/en
Publication of JP2000351813A publication Critical patent/JP2000351813A/ja
Publication of JP2000351813A5 publication Critical patent/JP2000351813A5/ja
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M143/00Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/02Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/60003Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/60006Bidentate ligand
    • C08F4/6001Neutral ligand
    • C08F4/60017NO
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/08Epoxidation
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/14Esterification
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/30Introducing nitrogen atoms or nitrogen-containing groups
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
    • C10M107/04Polyethene
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M143/00Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/0206Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/022Ethene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/022Ethene
    • C10M2205/0225Ethene used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01Physico-chemical properties

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)
  • Lubricants (AREA)
JP2000105406A 1999-04-09 2000-04-03 エチレン・α−オレフィン共重合体およびその製造方法ならびにその用途 Pending JP2000351813A (ja)

Priority Applications (9)

Application Number Priority Date Filing Date Title
JP2000105406A JP2000351813A (ja) 1999-04-09 2000-04-03 エチレン・α−オレフィン共重合体およびその製造方法ならびにその用途
KR1020000018283A KR20000071607A (ko) 1999-04-09 2000-04-07 에틸렌/α-올레핀 공중합체, 그 제조 방법 및 그 용도
US09/545,672 US6459005B1 (en) 1999-04-09 2000-04-07 Ethylene/α-olefin copolymer, method for producing the same, and use thereof
SG200002006A SG88774A1 (en) 1999-04-09 2000-04-07 Ethylene/alpha-olefin copolymer, method for producing the same, and use thereof
MYPI20001478A MY122619A (en) 1999-04-09 2000-04-08 Ethylene/a-olefin copolymer, method for producing the same, and use thereof
EP00302999A EP1043341B1 (en) 1999-04-09 2000-04-10 Use of an Ethylene/alpha-olefin Copolymer as a Base Oil in a Lubricant Composition
DE60040360T DE60040360D1 (de) 1999-04-09 2000-04-10 Verwendung eines Ethylen/Alpha-Olefin Copolymeren als Basisöl in einer Schmierstoffzusammensetzung
CNB001064762A CN1172972C (zh) 1999-04-09 2000-04-10 乙烯/α-烯烃共聚物、其制备方法和用途
EP07020125A EP1876189B1 (en) 1999-04-09 2000-04-10 Use of a Modified Ethylene/alpha-olefin Copolymer as Resin Modifier

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP10284599 1999-04-09
JP11-102845 1999-04-09
JP2000105406A JP2000351813A (ja) 1999-04-09 2000-04-03 エチレン・α−オレフィン共重合体およびその製造方法ならびにその用途

Publications (2)

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JP2000351813A true JP2000351813A (ja) 2000-12-19
JP2000351813A5 JP2000351813A5 (enExample) 2006-05-25

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Country Status (8)

Country Link
US (1) US6459005B1 (enExample)
EP (2) EP1043341B1 (enExample)
JP (1) JP2000351813A (enExample)
KR (1) KR20000071607A (enExample)
CN (1) CN1172972C (enExample)
DE (1) DE60040360D1 (enExample)
MY (1) MY122619A (enExample)
SG (1) SG88774A1 (enExample)

Cited By (33)

* Cited by examiner, † Cited by third party
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WO2001058968A1 (en) * 2000-02-09 2001-08-16 Idemitsu Petrochemical Co., Ltd. Ethylene-base copolymers, process for producing the same and lubricating oil compositions containing the same
JP2002363587A (ja) * 2001-05-31 2002-12-18 Mitsui Chemicals Inc 潤滑油用粘度指数向上剤および潤滑油組成物
JP2006502259A (ja) * 2002-10-02 2006-01-19 ダウ グローバル テクノロジーズ インコーポレイティド 液状およびゲル状の低分子量エチレンポリマー類
WO2006022355A1 (ja) 2004-08-27 2006-03-02 Mitsui Chemicals, Inc. オレフィン重合用触媒、オレフィン重合体の製造方法、オレフィン共重合体、新規な遷移金属化合物および遷移金属化合物の製造方法
JPWO2004044108A1 (ja) * 2002-11-12 2006-03-09 三井化学株式会社 潤滑油組成物および内燃機関用潤滑油
JP2006219537A (ja) * 2005-02-08 2006-08-24 Mitsui Chemicals Inc 末端官能基含有ポリオレフィンの製造方法
WO2008013085A1 (en) 2006-07-25 2008-01-31 Nippon Paper Chemicals Co., Ltd. Modified polyolefin resin and uses thereof
JP2008543977A (ja) * 2005-03-17 2008-12-04 ダウ グローバル テクノロジーズ インコーポレイティド 潤滑剤基油としての低分子量エチレン/α−オレフィン共重合体
WO2009004917A1 (ja) * 2007-07-02 2009-01-08 Mitsui Chemicals, Inc. 極性基含有ポリオレフィン重合体及びその製造方法、並びに、水分散体及び離型剤組成物
JP2010095692A (ja) * 2008-10-20 2010-04-30 Cosmo Oil Lubricants Co Ltd 省電力ギヤ油組成物
JP2010095691A (ja) * 2008-10-20 2010-04-30 Cosmo Oil Lubricants Co Ltd 省電力ギヤ油組成物
WO2010074233A1 (ja) 2008-12-26 2010-07-01 出光興産株式会社 α-オレフィン重合体の製造方法、α-オレフィン重合体、および潤滑油組成物
JP2011057726A (ja) * 2009-09-04 2011-03-24 Mitsui Chemicals Inc 極性基含有ポリオレフィン重合体、離型剤、樹脂組成物、及び樹脂成形体
JP2011099117A (ja) * 2004-06-08 2011-05-19 Mitsui Chemicals Inc 新規な重合体及びその用途
WO2011093295A1 (ja) 2010-01-26 2011-08-04 出光興産株式会社 α-オレフィン(共)重合体、水添α-オレフィン(共)重合体及びそれを含有する潤滑油組成物
JP2011524461A (ja) * 2008-06-20 2011-09-01 エクソンモービル・ケミカル・パテンツ・インク 官能化された、高割合のビニル末端基を有するプロピレンベースオリゴマー
WO2012157531A1 (ja) 2011-05-19 2012-11-22 出光興産株式会社 1-オクテン・1-デセン・1-ドデセン三元共重合体及びそれを含有する潤滑油組成物
WO2013015176A1 (ja) 2011-07-25 2013-01-31 出光興産株式会社 1-デセン・1-ドデセン共重合体及びそれを含有する潤滑油組成物
WO2013015175A1 (ja) 2011-07-25 2013-01-31 出光興産株式会社 1-オクテン・1-デセン共重合体及びそれを含有する潤滑油組成物
WO2015005226A1 (ja) * 2013-07-11 2015-01-15 三井化学株式会社 制振材および重合体組成物
WO2016039295A1 (ja) * 2014-09-10 2016-03-17 三井化学株式会社 潤滑油組成物
JP2016069409A (ja) * 2014-09-26 2016-05-09 三井化学株式会社 グリース組成物
JP2016069404A (ja) * 2014-09-26 2016-05-09 三井化学株式会社 潤滑油組成物
JP2016069405A (ja) * 2014-09-26 2016-05-09 三井化学株式会社 潤滑油組成物
JP2016069408A (ja) * 2014-09-26 2016-05-09 三井化学株式会社 作動油用潤滑油組成物
JP2016069407A (ja) * 2014-09-26 2016-05-09 三井化学株式会社 圧縮機油用潤滑油組成物
JP2016069406A (ja) * 2014-09-26 2016-05-09 三井化学株式会社 工業ギア用潤滑油組成物
JP2016088965A (ja) * 2014-10-30 2016-05-23 三井化学株式会社 潤滑油組成物およびその用途
JP2016098342A (ja) * 2014-11-25 2016-05-30 三井化学株式会社 潤滑油組成物
JP2016098341A (ja) * 2014-11-25 2016-05-30 三井化学株式会社 潤滑油組成物
JP2017511396A (ja) * 2014-03-28 2017-04-20 三井化学株式会社 潤滑油用粘度調整剤、潤滑油用添加剤組成物、および潤滑油組成物
KR20190077086A (ko) * 2017-01-16 2019-07-02 미쓰이 가가쿠 가부시키가이샤 자동차 기어용 윤활유 조성물
JPWO2023002947A1 (enExample) * 2021-07-20 2023-01-26

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DE10107045A1 (de) * 2001-02-13 2002-08-14 Basf Ag Verfahren zur Polymerisation von Olefinen
EP1270603B1 (en) * 2001-06-20 2014-04-09 Mitsui Chemicals, Inc. Olefin polymerization catalyst, process for polymerizing olefins
WO2003038017A1 (fr) * 2001-11-01 2003-05-08 Mitsui Chemicals, Inc. Additif pour huile lubrifiante et composition d'huile lubrifiante
JP4708188B2 (ja) * 2003-01-23 2011-06-22 三井化学株式会社 エチレン・α−オレフィン・非共役ポリエン共重合体の製造方法およびエチレン・α−オレフィン・非共役ポリエン共重合体
CN101798363A (zh) 2004-11-19 2010-08-11 三井化学株式会社 乙烯类聚合物微粒、含有官能团的乙烯类聚合物微粒及其制造用催化剂载体
EP1875961B1 (en) 2005-04-07 2018-08-29 Mitsui Chemicals, Inc. Capsular fine particle comprising olefinic polymer
JP4852038B2 (ja) * 2005-04-28 2012-01-11 出光興産株式会社 重合触媒及び該触媒を用いるポリα−オレフィンの製造方法
WO2007011462A1 (en) 2005-07-19 2007-01-25 Exxonmobil Chemical Patents Inc. Lubricants from mixed alpha-olefin feeds
CN105061644B (zh) 2009-12-24 2017-10-27 埃克森美孚化学专利公司 用于生产新型合成基础油料的方法
EP2880097B1 (en) 2012-08-03 2023-10-18 ExxonMobil Chemical Patents Inc. Process to prepare a vinyl terminated polyethylene with long chain branching
EP2880096B1 (en) 2012-08-03 2018-01-03 ExxonMobil Chemical Patents Inc. Process for preparing polyalphaolefins using modified salan catalyst compounds and polyalphaolefins prepared therewith
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