JP2000109854A5 - - Google Patents
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- Publication number
- JP2000109854A5 JP2000109854A5 JP1998282894A JP28289498A JP2000109854A5 JP 2000109854 A5 JP2000109854 A5 JP 2000109854A5 JP 1998282894 A JP1998282894 A JP 1998282894A JP 28289498 A JP28289498 A JP 28289498A JP 2000109854 A5 JP2000109854 A5 JP 2000109854A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- hydrogenation zone
- weight
- moo
- alumina
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 claims description 47
- 238000005984 hydrogenation reaction Methods 0.000 claims description 44
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 21
- 229910052750 molybdenum Inorganic materials 0.000 claims description 16
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 15
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 15
- 239000011733 molybdenum Substances 0.000 claims description 15
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 13
- 229910017052 cobalt Inorganic materials 0.000 claims description 13
- 239000010941 cobalt Substances 0.000 claims description 13
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 13
- 239000011593 sulfur Substances 0.000 claims description 13
- 229910052717 sulfur Inorganic materials 0.000 claims description 13
- 229910052759 nickel Inorganic materials 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 7
- 229910052700 potassium Inorganic materials 0.000 claims description 7
- 239000011591 potassium Substances 0.000 claims description 7
- 229910015621 MoO Inorganic materials 0.000 claims 1
- 238000006477 desulfuration reaction Methods 0.000 description 19
- 230000023556 desulfurization Effects 0.000 description 19
- 239000007789 gas Substances 0.000 description 12
- IYYZUPMFVPLQIF-UHFFFAOYSA-N dibenzothiophene Chemical compound C1=CC=C2C3=CC=CC=C3SC2=C1 IYYZUPMFVPLQIF-UHFFFAOYSA-N 0.000 description 11
- 150000003573 thiols Chemical class 0.000 description 11
- 150000003568 thioethers Chemical class 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 239000000306 component Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- DGUACJDPTAAFMP-UHFFFAOYSA-N 1,9-dimethyldibenzo[2,1-b:1',2'-d]thiophene Natural products S1C2=CC=CC(C)=C2C2=C1C=CC=C2C DGUACJDPTAAFMP-UHFFFAOYSA-N 0.000 description 3
- BLZKSRBAQDZAIX-UHFFFAOYSA-N 2-methyl-1-benzothiophene Chemical compound C1=CC=C2SC(C)=CC2=C1 BLZKSRBAQDZAIX-UHFFFAOYSA-N 0.000 description 3
- MYAQZIAVOLKEGW-UHFFFAOYSA-N 4,6-dimethyldibenzothiophene Chemical compound S1C2=C(C)C=CC=C2C2=C1C(C)=CC=C2 MYAQZIAVOLKEGW-UHFFFAOYSA-N 0.000 description 3
- 229910018871 CoO 2 Inorganic materials 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- SEBRPHZZSLCDRQ-UHFFFAOYSA-N 3-methyl-1-benzothiophene Chemical compound C1=CC=C2C(C)=CSC2=C1 SEBRPHZZSLCDRQ-UHFFFAOYSA-N 0.000 description 2
- NICUQYHIOMMFGV-UHFFFAOYSA-N 4-Methyldibenzothiophene Chemical compound S1C2=CC=CC=C2C2=C1C(C)=CC=C2 NICUQYHIOMMFGV-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000002283 diesel fuel Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- BVDZFPDJCHLKBJ-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=C[CH]C2=C=CSC2=C1 BVDZFPDJCHLKBJ-UHFFFAOYSA-N 0.000 description 1
- 239000007848 Bronsted acid Substances 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000003009 desulfurizing effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- FCEHBMOGCRZNNI-UHFFFAOYSA-N thianaphthalene Natural products C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP28289498A JP4233154B2 (ja) | 1998-10-05 | 1998-10-05 | 軽油の水素化脱硫方法 |
| US09/377,087 US6251262B1 (en) | 1998-10-05 | 1999-08-19 | Process for hydrodesulfurization of diesel gas oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP28289498A JP4233154B2 (ja) | 1998-10-05 | 1998-10-05 | 軽油の水素化脱硫方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2000109854A JP2000109854A (ja) | 2000-04-18 |
| JP2000109854A5 true JP2000109854A5 (https=) | 2005-02-17 |
| JP4233154B2 JP4233154B2 (ja) | 2009-03-04 |
Family
ID=17658489
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP28289498A Expired - Fee Related JP4233154B2 (ja) | 1998-10-05 | 1998-10-05 | 軽油の水素化脱硫方法 |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US6251262B1 (https=) |
| JP (1) | JP4233154B2 (https=) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002010314A1 (fr) * | 2000-07-28 | 2002-02-07 | Japan Energy Corporation | Procede de desulfuration super profonde d'une fraction d'huile legere |
| JP5016331B2 (ja) * | 2000-07-28 | 2012-09-05 | Ｊｘ日鉱日石エネルギー株式会社 | 超深度脱硫軽油の製造方法 |
| RU2221838C1 (ru) * | 2002-11-26 | 2004-01-20 | ОАО "Всероссийский научно-исследовательский институт по переработке нефти" | Способ получения дизельного топлива |
| RU2232183C1 (ru) * | 2002-11-26 | 2004-07-10 | ОАО "Всероссийский научно-исследовательский институт по переработке нефти" | Способ получения моторных топлив |
| US20060211900A1 (en) * | 2003-03-07 | 2006-09-21 | Hideshi Iki | Method of hydrotreating gas oil fraction |
| CN1294239C (zh) * | 2004-07-06 | 2007-01-10 | 中国石油化工股份有限公司 | 一种柴油两段加氢处理方法 |
| US7507327B2 (en) * | 2004-09-30 | 2009-03-24 | Exxonmobil Research And Engineering Company | Desulfurizing organosulfur heterocycles in feeds with supported sodium |
| JP4881662B2 (ja) * | 2006-06-20 | 2012-02-22 | コスモ石油株式会社 | 軽油組成物及び軽油組成物の製造方法 |
| EP2202204A4 (en) * | 2007-09-07 | 2013-11-27 | Japan Energy Corp | SOLID ACID, PROCESS FOR PREPARING THE SOLID ACID, METHOD FOR THE DEHUMIDIFICATION OF HYDROCARBON OIL, USING SOLUBLE ACIDITY AS A DEGREASING AGENT |
| JP5419672B2 (ja) * | 2009-12-14 | 2014-02-19 | Ｊｘ日鉱日石エネルギー株式会社 | 炭化水素油の水素化精製方法 |
| JP5419671B2 (ja) * | 2009-12-14 | 2014-02-19 | Ｊｘ日鉱日石エネルギー株式会社 | 炭化水素油の水素化精製方法 |
| CN102344826B (zh) * | 2010-08-05 | 2014-05-28 | 中国石油化工股份有限公司 | 一种生产催化原料与优质柴油的加氢组合方法 |
| CN103059983B (zh) * | 2011-10-21 | 2014-12-31 | 中国石油化工股份有限公司 | 一种加氢精制催化剂组合装填方法 |
| JP6801927B2 (ja) * | 2015-11-25 | 2020-12-16 | 出光興産株式会社 | 軽油基材の製造方法 |
| US12071592B2 (en) | 2017-02-12 | 2024-08-27 | Magēmā Technology LLC | Multi-stage process and device utilizing structured catalyst beds and reactive distillation for the production of a low sulfur heavy marine fuel oil |
| US12559689B2 (en) | 2017-02-12 | 2026-02-24 | Magēmā Technology LLC | Multi-stage process and device for treatment heavy marine fuel and resultant composition and the removal of detrimental solids |
| US12025435B2 (en) | 2017-02-12 | 2024-07-02 | Magēmã Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil |
| US10604709B2 (en) | 2017-02-12 | 2020-03-31 | Magēmā Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials |
| US12281266B2 (en) | 2017-02-12 | 2025-04-22 | Magẽmã Technology LLC | Heavy marine fuel oil composition |
| US11788017B2 (en) | 2017-02-12 | 2023-10-17 | Magëmã Technology LLC | Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil |
| US20180230389A1 (en) | 2017-02-12 | 2018-08-16 | Magēmā Technology, LLC | Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil |
| JP7321790B2 (ja) | 2019-06-25 | 2023-08-07 | 日揮触媒化成株式会社 | 重質油の水素化処理方法 |
| CN114425369B (zh) * | 2020-10-14 | 2023-07-28 | 中国石油化工股份有限公司 | 一种降低柴油中多环芳烃的催化剂级配工艺 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3239453A (en) * | 1962-11-19 | 1966-03-08 | Socony Mobil Oil Co Inc | Selective hydrogenation of hydrocarbons |
| US3317419A (en) * | 1964-06-01 | 1967-05-02 | Universal Oil Prod Co | Multiple-stage cascade hydrorefining of contaminated charge stocks |
| US3696027A (en) * | 1970-01-12 | 1972-10-03 | Chevron Res | Multi-stage desulfurization |
| US3876530A (en) * | 1973-08-22 | 1975-04-08 | Gulf Research Development Co | Multiple stage hydrodesulfurization with greater sulfur and metal removal in initial stage |
| US4054508A (en) * | 1975-02-21 | 1977-10-18 | Mobil Oil Corporation | Demetalation and desulfurization of residual oil utilizing hydrogen and trickle beds of catalysts in three zones |
| US4003828A (en) | 1975-07-23 | 1977-01-18 | Exxon Research And Engineering Company | Catalyst and process for removing sulfur and metal contaminants from hydrocarbon feedstocks |
| US4306964A (en) * | 1980-09-16 | 1981-12-22 | Mobil Oil Corporation | Multi-stage process for demetalation and desulfurization of petroleum oils |
| US4431525A (en) * | 1982-04-26 | 1984-02-14 | Standard Oil Company (Indiana) | Three-catalyst process for the hydrotreating of heavy hydrocarbon streams |
| US4657663A (en) * | 1985-04-24 | 1987-04-14 | Phillips Petroleum Company | Hydrotreating process employing a three-stage catalyst system wherein a titanium compound is employed in the second stage |
| US4797195A (en) * | 1988-02-26 | 1989-01-10 | Amoco Corporation | Three zone hydrocracking process |
| US4959140A (en) * | 1989-03-27 | 1990-09-25 | Amoco Corporation | Two-catalyst hydrocracking process |
| GB8910711D0 (en) * | 1989-05-10 | 1989-06-28 | Davy Mckee London | Process |
| JP2567291B2 (ja) | 1990-03-28 | 1996-12-25 | 株式会社コスモ総合研究所 | 炭化水素油の水素化処理方法 |
| JP2547115B2 (ja) * | 1990-03-30 | 1996-10-23 | 財団法人石油産業活性化センター | 炭化水素油用水素化処理触媒組成物ならびにそれを用いる水素化処理方法 |
| JP3187104B2 (ja) | 1991-07-19 | 2001-07-11 | 日石三菱株式会社 | 低硫黄ディーゼル軽油の製造方法 |
| JPH05311179A (ja) | 1992-05-11 | 1993-11-22 | Showa Shell Sekiyu Kk | 低硫黄分高性能軽油の製造方法 |
| JPH07102266A (ja) | 1993-11-17 | 1995-04-18 | Tonen Corp | 石油蒸留物の低イオウ化方法 |
| JP2921379B2 (ja) | 1993-12-30 | 1999-07-19 | 株式会社コスモ総合研究所 | 軽油の水素化脱硫方法 |
| JP3378402B2 (ja) * | 1995-04-05 | 2003-02-17 | 新日本石油株式会社 | 接触分解ガソリンの脱硫方法 |
| US5948239A (en) * | 1997-03-12 | 1999-09-07 | Abb Lummus Global Inc. | Process for obtaining distillate fuel products using a multi-bed catalytic reactor |
-
1998
- 1998-10-05 JP JP28289498A patent/JP4233154B2/ja not_active Expired - Fee Related
-
1999
- 1999-08-19 US US09/377,087 patent/US6251262B1/en not_active Expired - Lifetime
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