IE913410A1

IE913410A1 - Polyhydroxy fatty acid amide surfactants to enhance enzyme¹performance

Polyhydroxy fatty acid amide surfactants to enhance enzyme¹performance

Info

Publication number: IE913410A1
Authority: IE; Ireland
Prior art keywords: fatty acid; composition according; alkyl; polyhydroxy fatty; acid amide
Prior art date: 1990-09-28

Application number

IE341091A

Other languages

English (en)

Original Assignee

Procter & Gamble

Priority date

1990-09-28

Filing date

1991-09-27

Publication date

1992-04-08

1991-09-27 Application filed by Procter & Gamble filed Critical Procter & Gamble

1992-04-08 Publication of IE913410A1 publication Critical patent/IE913410A1/en

Links

235000014113 dietary fatty acids Nutrition 0.000 title claims abstract description 138
239000000194 fatty acid Substances 0.000 title claims abstract description 138
229930195729 fatty acid Natural products 0.000 title claims abstract description 138
150000004665 fatty acids Chemical class 0.000 title claims abstract description 131
239000004094 surface-active agent Substances 0.000 title claims description 92
239000000203 mixture Substances 0.000 claims abstract description 317
239000003599 detergent Substances 0.000 claims abstract description 163
-1 2-hydroxy propyl Chemical group 0.000 claims abstract description 150
102000004190 Enzymes Human genes 0.000 claims abstract description 96
108090000790 Enzymes Proteins 0.000 claims abstract description 96
239000000463 material Substances 0.000 claims abstract description 73
239000003945 anionic surfactant Substances 0.000 claims abstract description 47
239000002736 nonionic surfactant Substances 0.000 claims abstract description 21
125000001183 hydrocarbyl group Chemical group 0.000 claims abstract description 17
125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 14
125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims abstract description 7
230000006872 improvement Effects 0.000 claims abstract description 3
229940088598 enzyme Drugs 0.000 claims description 94
125000000217 alkyl group Chemical group 0.000 claims description 92
238000000034 method Methods 0.000 claims description 48
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 44
239000007788 liquid Substances 0.000 claims description 43
102000004882 Lipase Human genes 0.000 claims description 40
108090001060 Lipase Proteins 0.000 claims description 40
239000004367 Lipase Substances 0.000 claims description 39
235000019421 lipase Nutrition 0.000 claims description 39
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 37
150000001875 compounds Chemical class 0.000 claims description 35
108091005804 Peptidases Proteins 0.000 claims description 32
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 25
239000004365 Protease Substances 0.000 claims description 25
229910052739 hydrogen Inorganic materials 0.000 claims description 24
239000001257 hydrogen Substances 0.000 claims description 23
229940040461 lipase Drugs 0.000 claims description 23
235000000346 sugar Nutrition 0.000 claims description 23
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 22
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 21
239000008103 glucose Substances 0.000 claims description 21
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 20
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 20
150000001768 cations Chemical group 0.000 claims description 18
OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 17
GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 17
239000007859 condensation product Substances 0.000 claims description 16
125000002768 hydroxyalkyl group Chemical group 0.000 claims description 16
150000008051 alkyl sulfates Chemical class 0.000 claims description 15
108010084185 Cellulases Proteins 0.000 claims description 14
102000005575 Cellulases Human genes 0.000 claims description 14
150000001720 carbohydrates Chemical class 0.000 claims description 14
GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 claims description 13
108010065511 Amylases Proteins 0.000 claims description 12
102000013142 Amylases Human genes 0.000 claims description 12
102000035195 Peptidases Human genes 0.000 claims description 11
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
102000003992 Peroxidases Human genes 0.000 claims description 10
235000019418 amylase Nutrition 0.000 claims description 10
108010059892 Cellulase Proteins 0.000 claims description 9
125000003342 alkenyl group Chemical group 0.000 claims description 9
230000002708 enhancing effect Effects 0.000 claims description 8
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
229940025131 amylases Drugs 0.000 claims description 7
229940106157 cellulase Drugs 0.000 claims description 7
GHPCICSQWQDZLM-UHFFFAOYSA-N 1-(4-chlorophenyl)sulfonyl-1-methyl-3-propylurea Chemical compound CCCNC(=O)N(C)S(=O)(=O)C1=CC=C(Cl)C=C1 GHPCICSQWQDZLM-UHFFFAOYSA-N 0.000 claims description 6
CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 claims description 6
RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 claims description 6
150000002016 disaccharides Chemical class 0.000 claims description 6
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 6
108700020962 Peroxidase Proteins 0.000 claims description 5
241000223258 Thermomyces lanuginosus Species 0.000 claims description 5
238000010348 incorporation Methods 0.000 claims description 5
150000002772 monosaccharides Chemical class 0.000 claims description 5
229920001282 polysaccharide Polymers 0.000 claims description 5
239000005017 polysaccharide Substances 0.000 claims description 5
239000012736 aqueous medium Substances 0.000 claims description 4
150000004676 glycans Chemical class 0.000 claims description 3
125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims description 3
108091005658 Basic proteases Proteins 0.000 claims 2
HEVUDNOESBVZAL-UHFFFAOYSA-M sodium;2,3-dihydroxybutanedioic acid;4-hydroxy-4-oxobutanoate Chemical compound [Na+].OC(=O)CCC([O-])=O.OC(=O)C(O)C(O)C(O)=O HEVUDNOESBVZAL-UHFFFAOYSA-M 0.000 claims 1
239000003795 chemical substances by application Substances 0.000 description 84
239000002689 soil Substances 0.000 description 67
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 57
238000006243 chemical reaction Methods 0.000 description 45
150000003839 salts Chemical class 0.000 description 42
125000004432 carbon atom Chemical group C* 0.000 description 40
239000000047 product Substances 0.000 description 35
239000007844 bleaching agent Substances 0.000 description 32
239000000243 solution Substances 0.000 description 29
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 28
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 28
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 26
239000011734 sodium Substances 0.000 description 26
229910052708 sodium Inorganic materials 0.000 description 26
229920005646 polycarboxylate Polymers 0.000 description 25
239000002253 acid Substances 0.000 description 24
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 23
239000003054 catalyst Substances 0.000 description 22
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 21
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 21
238000009472 formulation Methods 0.000 description 21
235000001727 glucose Nutrition 0.000 description 21
235000020357 syrup Nutrition 0.000 description 21
239000006188 syrup Substances 0.000 description 21
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 20
BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 20
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 20
229910021536 Zeolite Inorganic materials 0.000 description 20
150000001412 amines Chemical class 0.000 description 20
238000004140 cleaning Methods 0.000 description 20
239000010457 zeolite Substances 0.000 description 20
125000000129 anionic group Chemical group 0.000 description 19
238000005406 washing Methods 0.000 description 19
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 18
240000008042 Zea mays Species 0.000 description 18
235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 18
235000002017 Zea mays subsp mays Nutrition 0.000 description 18
235000005822 corn Nutrition 0.000 description 18
229910052700 potassium Inorganic materials 0.000 description 18
229920003171 Poly (ethylene oxide) Polymers 0.000 description 17
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 17
229920000642 polymer Polymers 0.000 description 17
229920001296 polysiloxane Polymers 0.000 description 17
239000011591 potassium Substances 0.000 description 17
229910052783 alkali metal Inorganic materials 0.000 description 16
239000004615 ingredient Substances 0.000 description 16
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
230000008569 process Effects 0.000 description 15
229910000323 aluminium silicate Inorganic materials 0.000 description 14
229920001577 copolymer Polymers 0.000 description 14
239000008187 granular material Substances 0.000 description 14
230000002209 hydrophobic effect Effects 0.000 description 14
229910000029 sodium carbonate Inorganic materials 0.000 description 13
235000017550 sodium carbonate Nutrition 0.000 description 13
239000003760 tallow Substances 0.000 description 13
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
150000001340 alkali metals Chemical class 0.000 description 12
150000003863 ammonium salts Chemical class 0.000 description 12
230000008021 deposition Effects 0.000 description 12
229960002160 maltose Drugs 0.000 description 12
238000004519 manufacturing process Methods 0.000 description 12
239000011541 reaction mixture Substances 0.000 description 12
239000002904 solvent Substances 0.000 description 12
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 11
239000007864 aqueous solution Substances 0.000 description 11
150000002148 esters Chemical class 0.000 description 11
239000004744 fabric Substances 0.000 description 11
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 11
239000002245 particle Substances 0.000 description 11
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 10
150000007513 acids Chemical class 0.000 description 10
125000002947 alkylene group Chemical group 0.000 description 10
230000015572 biosynthetic process Effects 0.000 description 10
239000002738 chelating agent Substances 0.000 description 10
239000002270 dispersing agent Substances 0.000 description 10
239000000835 fiber Substances 0.000 description 10
229930195733 hydrocarbon Natural products 0.000 description 10
229960004063 propylene glycol Drugs 0.000 description 10
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 10
239000007787 solid Substances 0.000 description 10
239000000758 substrate Substances 0.000 description 10
238000012360 testing method Methods 0.000 description 10
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
MBBZMMPHUWSWHV-BDVNFPICSA-N N-methylglucamine Chemical compound CNC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO MBBZMMPHUWSWHV-BDVNFPICSA-N 0.000 description 9
150000001298 alcohols Chemical class 0.000 description 9
150000002430 hydrocarbons Chemical group 0.000 description 9
229920000728 polyester Polymers 0.000 description 9
238000002360 preparation method Methods 0.000 description 9
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 9
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 8
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 8
WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 8
239000012190 activator Substances 0.000 description 8
238000004061 bleaching Methods 0.000 description 8
WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 8
238000002156 mixing Methods 0.000 description 8
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239000002304 perfume Substances 0.000 description 8
239000000376 reactant Substances 0.000 description 8
239000000523 sample Substances 0.000 description 8
239000000126 substance Substances 0.000 description 8
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 7
229920002594 Polyethylene Glycol 8000 Polymers 0.000 description 7
150000001408 amides Chemical class 0.000 description 7
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
150000007942 carboxylates Chemical class 0.000 description 7
239000003093 cationic surfactant Substances 0.000 description 7
239000007795 chemical reaction product Substances 0.000 description 7
238000001035 drying Methods 0.000 description 7
230000000694 effects Effects 0.000 description 7
150000002431 hydrogen Chemical group 0.000 description 7
229910052744 lithium Inorganic materials 0.000 description 7
229910052757 nitrogen Inorganic materials 0.000 description 7
230000003287 optical effect Effects 0.000 description 7
238000006116 polymerization reaction Methods 0.000 description 7
239000002994 raw material Substances 0.000 description 7
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 6
239000004115 Sodium Silicate Substances 0.000 description 6
229920002125 Sokalan® Polymers 0.000 description 6
238000007792 addition Methods 0.000 description 6
125000001931 aliphatic group Chemical group 0.000 description 6
125000003118 aryl group Chemical group 0.000 description 6
239000002585 base Substances 0.000 description 6
230000008901 benefit Effects 0.000 description 6
239000004927 clay Substances 0.000 description 6
ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 6
150000002194 fatty esters Chemical class 0.000 description 6
230000002538 fungal effect Effects 0.000 description 6
125000000623 heterocyclic group Chemical group 0.000 description 6
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 6
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GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 5
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VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 5
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KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical group OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
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ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 4
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IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 4
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235000015424 sodium Nutrition 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
235000019254 sodium formate Nutrition 0.000 description 1
235000019333 sodium laurylsulphate Nutrition 0.000 description 1
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229960001922 sodium perborate Drugs 0.000 description 1
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239000001488 sodium phosphate Substances 0.000 description 1
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239000001476 sodium potassium tartrate Substances 0.000 description 1
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229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
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YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
239000011343 solid material Substances 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
229940037312 stearamide Drugs 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000005480 straight-chain fatty acid group Chemical group 0.000 description 1
125000000547 substituted alkyl group Chemical group 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
239000001384 succinic acid Substances 0.000 description 1
238000000967 suction filtration Methods 0.000 description 1
DIORMHZUUKOISG-UHFFFAOYSA-N sulfoformic acid Chemical compound OC(=O)S(O)(=O)=O DIORMHZUUKOISG-UHFFFAOYSA-N 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
238000006277 sulfonation reaction Methods 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
150000003457 sulfones Chemical group 0.000 description 1
150000003462 sulfoxides Chemical class 0.000 description 1
239000000375 suspending agent Substances 0.000 description 1
229950009390 symclosene Drugs 0.000 description 1
239000000271 synthetic detergent Substances 0.000 description 1
229940042055 systemic antimycotics triazole derivative Drugs 0.000 description 1
239000003784 tall oil Substances 0.000 description 1
230000002277 temperature effect Effects 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
150000004026 tertiary sulfonium compounds Chemical class 0.000 description 1
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
MSLRPWGRFCKNIZ-UHFFFAOYSA-J tetrasodium;hydrogen peroxide;dicarbonate Chemical compound [Na+].[Na+].[Na+].[Na+].OO.OO.OO.[O-]C([O-])=O.[O-]C([O-])=O MSLRPWGRFCKNIZ-UHFFFAOYSA-J 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
229940015849 thiophene Drugs 0.000 description 1
229930192474 thiophene Natural products 0.000 description 1
QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical class N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 description 1
125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000005457 triglyceride group Chemical group 0.000 description 1
TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical compound [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 description 1
JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical class OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
235000015870 tripotassium citrate Nutrition 0.000 description 1
235000019798 tripotassium phosphate Nutrition 0.000 description 1
229910000404 tripotassium phosphate Inorganic materials 0.000 description 1
150000004043 trisaccharides Chemical class 0.000 description 1
HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
229940038773 trisodium citrate Drugs 0.000 description 1
235000019263 trisodium citrate Nutrition 0.000 description 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
235000019801 trisodium phosphate Nutrition 0.000 description 1
229910000406 trisodium phosphate Inorganic materials 0.000 description 1
WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
238000001665 trituration Methods 0.000 description 1
OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
125000001493 tyrosinyl group Chemical group [H]OC1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])(N([H])[H])C(*)=O 0.000 description 1
229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
238000005292 vacuum distillation Methods 0.000 description 1
238000001291 vacuum drying Methods 0.000 description 1
235000013311 vegetables Nutrition 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
239000011345 viscous material Substances 0.000 description 1