HUP0204185A2 - Eljárás halogénezett 4-amino-pikolinsavak szelektív elektrokémiai redukálására - Google Patents

Eljárás halogénezett 4-amino-pikolinsavak szelektív elektrokémiai redukálására

Info

Publication number
HUP0204185A2
HUP0204185A2 HU0204185A HUP0204185A HUP0204185A2 HU P0204185 A2 HUP0204185 A2 HU P0204185A2 HU 0204185 A HU0204185 A HU 0204185A HU P0204185 A HUP0204185 A HU P0204185A HU P0204185 A2 HUP0204185 A2 HU P0204185A2
Authority
HU
Hungary
Prior art keywords
chlorine
halogenated
bromine
electrochemical reduction
amino
Prior art date
Application number
HU0204185A
Other languages
English (en)
Inventor
Craig Joseph Bott
Michael Frederick Gullo
John Wesley Hull
Karl Leopold Krumel
Carey Lee Scortichini
Original Assignee
Dow Agrosciences Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Agrosciences Llc filed Critical Dow Agrosciences Llc
Publication of HUP0204185A2 publication Critical patent/HUP0204185A2/hu
Publication of HUP0204185A3 publication Critical patent/HUP0204185A3/hu
Publication of HU225146B1 publication Critical patent/HU225146B1/hu

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/79—Acids; Esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/79—Acids; Esters
    • C07D213/803—Processes of preparation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/61—Halogen atoms or nitro radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
    • C07D213/74—Amino or imino radicals substituted by hydrocarbon or substituted hydrocarbon radicals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Pyridine Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

A találmány tárgya eljárás (I) általános képletű 4-amino-3-halogénpikolinsav előállítására - ahol X jelentése klór- vagybrómatom; Y jelentése hidrogén-, fluor-, klór-, brómatom vagy 1-4szénatomos alkilcsoport; és R jelentése hidrogénatom vagy 1-4szénatomos alkilcsoport - mely eljárás során közvetlen vagy váltakozóelektromos áramot engednek egy anódból egy katódhoz (II) általánosképletű 4-amino-3,5-dihalogén-pikolinsav oldaton keresztül, ahol X, Yés R jelentése a fenti, és ahol mindkét X klór- vagy brómatom, -0,4-től -1,7 voltig terjedő katódpotenciálnál Ag/AgCI referenciaelektródához viszonyítva (3,0 mól Cl-), és a terméket kinyerik. Ó
HU0204185A 2000-01-14 2001-01-12 Selective electrochemical reduction of halogenated 4-aminopicolinic acids HU225146B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US17671900P 2000-01-14 2000-01-14
PCT/US2001/001185 WO2001051684A1 (en) 2000-01-14 2001-01-12 Selective electrochemical reduction of halogenated 4-aminopicolinic acids

Publications (3)

Publication Number Publication Date
HUP0204185A2 true HUP0204185A2 (hu) 2003-03-28
HUP0204185A3 HUP0204185A3 (en) 2003-04-28
HU225146B1 HU225146B1 (en) 2006-07-28

Family

ID=22645552

Family Applications (1)

Application Number Title Priority Date Filing Date
HU0204185A HU225146B1 (en) 2000-01-14 2001-01-12 Selective electrochemical reduction of halogenated 4-aminopicolinic acids

Country Status (23)

Country Link
US (1) US6352635B2 (hu)
EP (1) EP1248867B1 (hu)
JP (1) JP4615809B2 (hu)
KR (1) KR100727279B1 (hu)
CN (1) CN1238565C (hu)
AT (1) ATE247726T1 (hu)
AU (1) AU2001229457A1 (hu)
CA (1) CA2396253C (hu)
CZ (1) CZ296504B6 (hu)
DE (1) DE60100620T2 (hu)
DK (1) DK1248867T3 (hu)
ES (1) ES2204866T3 (hu)
HU (1) HU225146B1 (hu)
IL (1) IL150703A (hu)
MX (1) MXPA02006890A (hu)
NZ (1) NZ519768A (hu)
PL (1) PL195415B1 (hu)
PT (1) PT1248867E (hu)
RU (1) RU2254401C2 (hu)
TR (1) TR200301395T4 (hu)
TW (1) TW548347B (hu)
UA (1) UA70405C2 (hu)
WO (1) WO2001051684A1 (hu)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10259362A1 (de) * 2002-12-18 2004-07-08 Siemens Ag Verfahren zum Abscheiden einer Legierung auf ein Substrat
UA82358C2 (uk) * 2003-04-02 2008-04-10 Дау Агросайенсиз Ллс 6-алкіл або алкеніл-4-амінопіколінати гербіцидна композиція, спосіб боротьби з небажаною рослинністю
UA81177C2 (uk) * 2003-08-04 2007-12-10 Дау Агросайєнсіз Ллс 6-(1,1-дифторалкіл)-4-амінопіколінати та їх використання як гербіцидів
EP1526192A1 (de) * 2003-10-24 2005-04-27 Siemens Aktiengesellschaft Elektrolytisches Verfahren zum Abscheiden einer gradierten Schicht auf ein Substrat und Bauteil
TWI406849B (zh) * 2006-10-04 2013-09-01 Dow Agrosciences Llc 鹵化４-胺基吡啶甲酸之經改良的電化學還原反應
US7666293B2 (en) * 2007-10-04 2010-02-23 Dow Agrosciences Llc Electrochemical reduction of halogenated 4-aminopicolinic acids
ITMI20081282A1 (it) * 2008-07-15 2010-01-16 Industrie De Nora Spa Processo di trattamento di reflui industriali
CN101603179B (zh) * 2009-06-29 2013-11-06 浙江工业大学 3,5,6-三氯吡啶甲酸的电解合成方法
WO2011053582A1 (en) 2009-10-27 2011-05-05 Dow Agrosciences Llc Improved silver cathode activation
TWI529163B (zh) * 2011-01-25 2016-04-11 陶氏農業科學公司 用於製備４－胺基－５－氟－３－鹵素－６－（經取代之）吡啶甲酸酯的方法
CN102358944A (zh) * 2011-08-23 2012-02-22 哈尔滨理工大学 一种氨基吡啶氯化物的制备方法
JP6167114B2 (ja) * 2012-01-31 2017-07-19 カウンシル オブ サイエンティフィック アンド インダストリアル リサーチ ナノ構造の酸化銀膜使用の水性ボルタンメトリー農薬センサおよびそのセンサの製造方法
CN104988531B (zh) * 2015-07-07 2017-11-07 浙江工业大学 一种氯代吡啶甲酸电催化选择性脱氯制备吡啶甲酸的方法
CN105803481B (zh) * 2016-03-22 2018-03-27 浙江埃森化学有限公司 一种催化电解制备4‑氨基‑3,6‑二氯吡啶‑2‑甲酸的方法
CN105887129B (zh) * 2016-05-16 2017-12-29 浙江工业大学 一种三氯甲基吡啶衍生物电化学选择性脱氯制备甲基吡啶衍生物的方法
CN105887128B (zh) * 2016-05-16 2018-01-12 浙江工业大学 一种五氯吡啶电催化选择性氢化脱氯的方法
CN105887127B (zh) * 2016-05-16 2017-12-29 浙江工业大学 一种电化学选择性脱氯制备氯甲基吡啶衍生物的方法
CN107778226B (zh) * 2016-08-26 2019-07-02 利尔化学股份有限公司 一种4-氨基-3，6-二氯吡啶-2-甲酸的纯化方法
CN108611656B (zh) * 2016-12-12 2019-07-30 利尔化学股份有限公司 一种4-氨基-3,6-二氯吡啶-2-甲酸的合成方法
CN109763138A (zh) * 2017-11-09 2019-05-17 山东润博生物科技有限公司 一种3,6-二氯水杨酸的制备方法
CN114075675B (zh) * 2021-11-18 2023-09-29 永农生物科学有限公司 电解脱氯合成4-氨基-3,6-二氯吡啶甲酸的方法及产品和应用

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US3285925A (en) * 1962-03-06 1966-11-15 Dow Chemical Co Amino-trichloropicolinic acid compounds
US3694332A (en) 1971-03-05 1972-09-26 Dow Chemical Co Electrolytic reduction of halogenated pyridines
US4242183A (en) * 1979-04-13 1980-12-30 The Dow Chemical Company Highly active silver cathode, preparation of same and use to make 2,3,5-trichloropyridine
US4217185A (en) * 1979-07-02 1980-08-12 The Dow Chemical Company Electrolytic production of certain trichloropicolinic acids and/or 3,6-dichloropicolinic acid
JPH0670277B2 (ja) * 1984-06-14 1994-09-07 ザ・ダウ・ケミカル・カンパニー ポリクロロピコリネートアニオンの電解還元用エキスパンデッドメタル銀電極
JPS6227582A (ja) * 1985-07-22 1987-02-05 ザ　ダウ　ケミカル　カンパニ− ステンレススチ−ル陽極よりなる電解セル及びポリクロロピコリン酸塩アニオンの製造方法
DE4333697A1 (de) * 1993-10-02 1995-04-06 Merck Patent Gmbh Verfahren zur Herstellung von 3-Aminopyridinen aus 3-Nitropyridinen
US6297197B1 (en) * 2000-01-14 2001-10-02 Dow Agrosciences Llc 4-aminopicolinates and their use as herbicides

Also Published As

Publication number Publication date
CA2396253A1 (en) 2001-07-19
DE60100620T2 (de) 2004-03-11
EP1248867A1 (en) 2002-10-16
KR20020063624A (ko) 2002-08-03
TW548347B (en) 2003-08-21
NZ519768A (en) 2002-11-26
JP4615809B2 (ja) 2011-01-19
UA70405C2 (uk) 2004-10-15
RU2254401C2 (ru) 2005-06-20
RU2002121773A (ru) 2004-01-10
PL195415B1 (pl) 2007-09-28
JP2003519726A (ja) 2003-06-24
US6352635B2 (en) 2002-03-05
ATE247726T1 (de) 2003-09-15
WO2001051684A1 (en) 2001-07-19
TR200301395T4 (tr) 2004-04-21
CZ296504B6 (cs) 2006-03-15
MXPA02006890A (es) 2003-01-28
EP1248867B1 (en) 2003-08-20
DK1248867T3 (da) 2003-12-08
PT1248867E (pt) 2003-12-31
AU2001229457A1 (en) 2001-07-24
PL355993A1 (en) 2004-05-31
DE60100620D1 (de) 2003-09-25
HUP0204185A3 (en) 2003-04-28
CN1394241A (zh) 2003-01-29
CA2396253C (en) 2009-05-26
KR100727279B1 (ko) 2007-06-13
ES2204866T3 (es) 2004-05-01
CN1238565C (zh) 2006-01-25
IL150703A (en) 2005-09-25
HU225146B1 (en) 2006-07-28
US20010054559A1 (en) 2001-12-27

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