HRP980418A2 - Catalysts for dehydrogenating ethylbenzene to styrene - Google Patents

Catalysts for dehydrogenating ethylbenzene to styrene Download PDF

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Publication number
HRP980418A2
HRP980418A2 HRMI97A001860A HRP980418A HRP980418A2 HR P980418 A2 HRP980418 A2 HR P980418A2 HR MI97A001860 A HRMI97A001860 A HR MI97A001860A HR P980418 A HRP980418 A HR P980418A HR P980418 A2 HRP980418 A2 HR P980418A2
Authority
HR
Croatia
Prior art keywords
oxide
catalysts
potassium
ethylbenzene
catalysts according
Prior art date
Application number
HRMI97A001860A
Other languages
English (en)
Croatian (hr)
Inventor
Esterino Conca
Original Assignee
Sued Chemie Mt Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sued Chemie Mt Srl filed Critical Sued Chemie Mt Srl
Publication of HRP980418A2 publication Critical patent/HRP980418A2/hr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8871—Rare earth metals or actinides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
HRMI97A001860A 1997-08-01 1998-07-29 Catalysts for dehydrogenating ethylbenzene to styrene HRP980418A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT97MI001860A IT1293531B1 (it) 1997-08-01 1997-08-01 Catalizzatori per la deidrogenazione dell'etilbenzene a stirene
US09/314,704 US6184174B1 (en) 1997-08-01 1999-05-19 Catalysts for dehydrogenating ethylbenzene to styrene

Publications (1)

Publication Number Publication Date
HRP980418A2 true HRP980418A2 (en) 1999-06-30

Family

ID=26331532

Family Applications (1)

Application Number Title Priority Date Filing Date
HRMI97A001860A HRP980418A2 (en) 1997-08-01 1998-07-29 Catalysts for dehydrogenating ethylbenzene to styrene

Country Status (19)

Country Link
US (1) US6184174B1 (de)
EP (1) EP0894528B1 (de)
JP (1) JPH11104494A (de)
CN (1) CN1207330A (de)
AU (1) AU736855B2 (de)
BR (1) BR9802810A (de)
CA (1) CA2244188A1 (de)
CZ (1) CZ237798A3 (de)
DE (1) DE69812789T2 (de)
DK (1) DK0894528T3 (de)
ES (1) ES2193445T3 (de)
HR (1) HRP980418A2 (de)
HU (1) HUP9801740A3 (de)
ID (1) ID19866A (de)
IT (1) IT1293531B1 (de)
NO (1) NO983541L (de)
PL (1) PL327785A1 (de)
PT (1) PT894528E (de)
SK (1) SK102598A3 (de)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19814080A1 (de) * 1998-03-30 1999-10-07 Basf Ag Katalysator zur Dehydrierung von Kohlenwasserstoffen, insbesondere zur Dehydrierung von Ethylbenzol zu Styrol, sowie Verfahren zu seiner Herstellung
EP1027928B1 (de) * 1999-02-10 2006-03-01 Basf Aktiengesellschaft Katalysator zur Dehydrierung von Ethylbenzol zu Styrol
KR100383221B1 (ko) * 2001-01-17 2003-05-12 한국화학연구원 알킬방향족 탄화수소의 탈수소반응용 촉매와 그 제조방법
TWI267401B (en) * 2002-01-30 2006-12-01 Shell Int Research A catalyst, its preparation and its use in a dehydrogenation process
US7271126B2 (en) * 2002-05-15 2007-09-18 Sud-Chemie Inc. Catalyst for the dehydrogenation of ethyl benzene to STYRENE prepared with a high purity iron precursor
US6936743B2 (en) * 2002-09-05 2005-08-30 Fina Technology, Inc. Method for extending catalyst life in processes for preparing vinyl aromatic hydrocarbons
CN1299822C (zh) * 2004-07-13 2007-02-14 华东理工大学 用于乙苯氧化脱氢制苯乙烯的纳米碳纤维催化剂及其成型方法
DE102004039603A1 (de) * 2004-08-13 2006-02-23 Basf Ag Katalysator enthaltend Eisenoxid(e), Alkalimetallverbindung(en) und Ceroxid(e)
CN100381362C (zh) * 2004-10-29 2008-04-16 中国石油化工股份有限公司 制备高铁酸钾的方法
CN100368083C (zh) * 2004-10-29 2008-02-13 中国石油化工股份有限公司 用于乙苯脱氢制备苯乙烯的催化剂
TW200631934A (en) * 2004-11-18 2006-09-16 Shell Int Research An improved process for the manufacture of an alkenyl aromatic compound under low steam-to-oil process conditions
US20060224029A1 (en) * 2005-03-29 2006-10-05 Fina Technology, Inc. Method of extending catalyst life in vinyl aromatic hydrocarbon formation
CN100443171C (zh) * 2005-06-22 2008-12-17 中国石油化工股份有限公司 用于乙苯脱氢制备苯乙烯的氧化物催化剂
CN1307108C (zh) * 2005-07-29 2007-03-28 大庆石油学院 一种提高高铁酸钾氧化活性的方法
CN100408174C (zh) * 2005-08-15 2008-08-06 中国石油化工股份有限公司 乙苯脱氢的催化剂
CN100408175C (zh) * 2005-08-15 2008-08-06 中国石油化工股份有限公司 制备烷烯基芳烃的脱氢催化剂
RU2302293C1 (ru) * 2006-05-06 2007-07-10 Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук Катализатор, способ его приготовления и способ дегидрирования алкилароматических углеводородов
CN101279263B (zh) * 2007-04-04 2010-07-21 中国石油化工股份有限公司 用于乙苯脱氢制苯乙烯的催化剂
CN101279267B (zh) * 2007-04-04 2011-07-13 中国石油化工股份有限公司 节能的乙苯脱氢催化剂
JP5313233B2 (ja) * 2007-05-03 2013-10-09 バスフ・コーポレイション 触媒、それの調製および使用
US9138706B2 (en) * 2008-04-22 2015-09-22 Fina Technology, Inc. Method and apparatus for addition of an alkali metal promoter to a dehydrogenation catalyst
US8648007B2 (en) * 2008-04-22 2014-02-11 Fina Technology, Inc. Vaporization and transportation of alkali metal salts
JP5628039B2 (ja) * 2008-09-22 2014-11-19 学校法人早稲田大学 レドックス能の高いアルキル芳香族化合物の脱水素触媒およびその製造方法並びにそれを使用した脱水素化方法
US20110105316A1 (en) * 2009-10-31 2011-05-05 Fina Technology, Inc. Mixed Metal Oxide Ingredients for Bulk Metal Oxide Catalysts
CN103372452B (zh) * 2012-04-24 2015-08-19 中国石油天然气股份有限公司 乙苯脱氢制备苯乙烯的催化剂及其制备方法
CN103537296B (zh) * 2012-07-12 2015-06-10 中国石油化工股份有限公司 低水比的乙苯脱氢催化剂
US10336667B2 (en) 2014-05-09 2019-07-02 Basf Se Catalyst for dehydrogenating hydrocarbons
JP6596445B2 (ja) 2014-05-09 2019-10-23 ビーエーエスエフ ソシエタス・ヨーロピア 炭化水素の脱水素化のための改良された触媒
CN105562025B (zh) * 2014-10-13 2018-05-11 中国石油化工股份有限公司 低温低水比乙苯脱氢催化剂及其制备方法和应用
CN105562024A (zh) * 2014-10-13 2016-05-11 中国石油化工股份有限公司 制对甲基苯乙烯的催化剂及其制备方法和应用
CN105562023A (zh) * 2014-10-13 2016-05-11 中国石油化工股份有限公司 制备对甲基苯乙烯的催化剂及其制备方法和应用
CN106423238B (zh) * 2015-08-12 2019-01-25 中国石油化工股份有限公司 苯乙烯催化剂及其制备方法
CN106423239B (zh) * 2015-08-12 2019-01-25 中国石油化工股份有限公司 高稳定苯乙烯催化剂
CN106423187B (zh) * 2015-08-12 2019-02-19 中国石油化工股份有限公司 苯乙烯催化剂
CN105056966B (zh) * 2015-08-25 2018-09-25 营口风光新材料股份有限公司 用于乙苯脱氢制备苯乙烯的催化剂
RU2626238C1 (ru) * 2016-06-08 2017-07-25 Федеральное государственное бюджетное образовательное учреждение высшего образования "Ярославский государственный технический университет" (ФГБОУВО "ЯГТУ") Катализатор для дегидрирования алкилароматических углеводородов
CN108722430A (zh) * 2018-04-19 2018-11-02 天津理工大学 以纳米氧化铁为铁源的乙苯脱氢催化剂及其制备方法
CN111420673A (zh) * 2020-03-19 2020-07-17 湖南城市学院 一种烷基芳烃脱氢的催化剂的制备方法
CN117920289B (zh) * 2022-10-24 2026-04-21 中国石油化工股份有限公司 脱氢催化剂及其制备方法和应用以及烯基苯的制备方法

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GB8510197D0 (en) * 1985-04-22 1985-05-30 Ici Plc Catalysts
US4758543A (en) * 1987-07-01 1988-07-19 The Dow Chemical Company Dehydrogenation catalyst
JPH04277030A (ja) * 1991-03-05 1992-10-02 Nissan Gaadoraa Shokubai Kk エチルベンゼン脱水素触媒
CA2207564C (en) * 1994-12-14 2007-05-01 Shell Internationale Research Maatschappij B.V. Iron oxide dehydrogenation catalysts and process

Also Published As

Publication number Publication date
PL327785A1 (en) 1999-02-15
JPH11104494A (ja) 1999-04-20
NO983541L (no) 1999-02-02
EP0894528A2 (de) 1999-02-03
SK102598A3 (en) 1999-04-13
HUP9801740A3 (en) 2000-02-28
ID19866A (id) 1998-08-13
BR9802810A (pt) 1999-12-21
EP0894528A3 (de) 1999-11-03
DE69812789D1 (de) 2003-05-08
ITMI971860A1 (it) 1999-02-01
DK0894528T3 (da) 2003-07-28
HU9801740D0 (en) 1998-09-28
PT894528E (pt) 2003-06-30
ES2193445T3 (es) 2003-11-01
US6184174B1 (en) 2001-02-06
CZ237798A3 (cs) 1999-02-17
CA2244188A1 (en) 1999-02-01
AU7859198A (en) 1999-02-11
HUP9801740A2 (hu) 1999-05-28
NO983541D0 (no) 1998-07-31
DE69812789T2 (de) 2004-02-12
EP0894528B1 (de) 2003-04-02
CN1207330A (zh) 1999-02-10
IT1293531B1 (it) 1999-03-01
AU736855B2 (en) 2001-08-02

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