IT1293531B1 - Catalizzatori per la deidrogenazione dell'etilbenzene a stirene - Google Patents

Catalizzatori per la deidrogenazione dell'etilbenzene a stirene

Info

Publication number
IT1293531B1
IT1293531B1 IT97MI001860A ITMI971860A IT1293531B1 IT 1293531 B1 IT1293531 B1 IT 1293531B1 IT 97MI001860 A IT97MI001860 A IT 97MI001860A IT MI971860 A ITMI971860 A IT MI971860A IT 1293531 B1 IT1293531 B1 IT 1293531B1
Authority
IT
Italy
Prior art keywords
ethylbenzene
dehydrogenation
catalysts
styrene
Prior art date
Application number
IT97MI001860A
Other languages
English (en)
Inventor
Carlo Rubini
Luigi Cavalli
Esterino Conca
Original Assignee
Sud Chemie Mt S R L Ex Monteca
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sud Chemie Mt S R L Ex Monteca filed Critical Sud Chemie Mt S R L Ex Monteca
Priority to IT97MI001860A priority Critical patent/IT1293531B1/it
Priority to IDP981005A priority patent/ID19866A/id
Priority to EP98113498A priority patent/EP0894528B1/en
Priority to ES98113498T priority patent/ES2193445T3/es
Priority to DK98113498T priority patent/DK0894528T3/da
Priority to PT98113498T priority patent/PT894528E/pt
Priority to DE69812789T priority patent/DE69812789T2/de
Priority to KR1019980029615A priority patent/KR19990023231A/ko
Priority to JP10208001A priority patent/JPH11104494A/ja
Priority to CZ982377A priority patent/CZ237798A3/cs
Priority to HRMI97A001860A priority patent/HRP980418A2/hr
Priority to AU78591/98A priority patent/AU736855B2/en
Priority to SK1025-98A priority patent/SK102598A3/sk
Priority to CA002244188A priority patent/CA2244188A1/en
Priority to BR9802810-3A priority patent/BR9802810A/pt
Priority to PL98327785A priority patent/PL327785A1/xx
Priority to CN98116743A priority patent/CN1207330A/zh
Priority to NO983541A priority patent/NO983541L/no
Priority to HU9801740A priority patent/HUP9801740A3/hu
Publication of ITMI971860A1 publication Critical patent/ITMI971860A1/it
Application granted granted Critical
Publication of IT1293531B1 publication Critical patent/IT1293531B1/it
Priority to US09/314,704 priority patent/US6184174B1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8871—Rare earth metals or actinides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
IT97MI001860A 1997-08-01 1997-08-01 Catalizzatori per la deidrogenazione dell'etilbenzene a stirene IT1293531B1 (it)

Priority Applications (20)

Application Number Priority Date Filing Date Title
IT97MI001860A IT1293531B1 (it) 1997-08-01 1997-08-01 Catalizzatori per la deidrogenazione dell'etilbenzene a stirene
IDP981005A ID19866A (id) 1997-08-01 1998-07-15 Katalis-katalis untuk penghidrogenasian etilbenzena menjadi stirena
EP98113498A EP0894528B1 (en) 1997-08-01 1998-07-20 Potassium ferrate-containing catalyst for dehydrogenating ethylbenzene to styrene
ES98113498T ES2193445T3 (es) 1997-08-01 1998-07-20 Catalaizadores para deshidrogenacion de etilbenceno a estireno.
DK98113498T DK0894528T3 (da) 1997-08-01 1998-07-20 Kaliumferratholdig katalysator til dehydrogenering af ethylbenzen til styren
PT98113498T PT894528E (pt) 1997-08-01 1998-07-20 Catalisador contendo ferrato de potassio para a desidrogenacao do etilbenzeno em estireno
DE69812789T DE69812789T2 (de) 1997-08-01 1998-07-20 Kaliumferrat enthaltender Katalysator zur Herstellung von Styrol durch Dehydrierung von Ethylbenzol
KR1019980029615A KR19990023231A (ko) 1997-08-01 1998-07-23 에틸벤젠을 스티렌으로 탈수소화하는 촉매
JP10208001A JPH11104494A (ja) 1997-08-01 1998-07-23 エチルベンゼンのスチレンへの脱水素化触媒
CZ982377A CZ237798A3 (cs) 1997-08-01 1998-07-28 Katalyzátor pro dehydrogenaci ethylbenzenu na styren
HRMI97A001860A HRP980418A2 (en) 1997-08-01 1998-07-29 Catalysts for dehydrogenating ethylbenzene to styrene
AU78591/98A AU736855B2 (en) 1997-08-01 1998-07-29 Catalysts for dehydrogenating ethylbenzene to styrene
SK1025-98A SK102598A3 (en) 1997-08-01 1998-07-29 Catalysts and method for the dehydrogenation of ethylbenzene to styrene
CA002244188A CA2244188A1 (en) 1997-08-01 1998-07-29 Catalysts for dehydrogenating ethylbenzene to styrene
BR9802810-3A BR9802810A (pt) 1997-08-01 1998-07-30 Catalisadores e processos para desidrogenação de etilbenzeno formando estireno.
PL98327785A PL327785A1 (en) 1997-08-01 1998-07-31 Catalyst for use in dehydrogenating ethylbenzene to styrene
CN98116743A CN1207330A (zh) 1997-08-01 1998-07-31 用于乙苯脱氢制苯乙烯的催化剂
NO983541A NO983541L (no) 1997-08-01 1998-07-31 Katalysator for dehydrogenering av etylbenzen til styren
HU9801740A HUP9801740A3 (en) 1997-08-01 1998-07-31 Catalysts for dehydrogenating ethylbenzene to styrene
US09/314,704 US6184174B1 (en) 1997-08-01 1999-05-19 Catalysts for dehydrogenating ethylbenzene to styrene

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT97MI001860A IT1293531B1 (it) 1997-08-01 1997-08-01 Catalizzatori per la deidrogenazione dell'etilbenzene a stirene
US09/314,704 US6184174B1 (en) 1997-08-01 1999-05-19 Catalysts for dehydrogenating ethylbenzene to styrene

Publications (2)

Publication Number Publication Date
ITMI971860A1 ITMI971860A1 (it) 1999-02-01
IT1293531B1 true IT1293531B1 (it) 1999-03-01

Family

ID=26331532

Family Applications (1)

Application Number Title Priority Date Filing Date
IT97MI001860A IT1293531B1 (it) 1997-08-01 1997-08-01 Catalizzatori per la deidrogenazione dell'etilbenzene a stirene

Country Status (19)

Country Link
US (1) US6184174B1 (it)
EP (1) EP0894528B1 (it)
JP (1) JPH11104494A (it)
CN (1) CN1207330A (it)
AU (1) AU736855B2 (it)
BR (1) BR9802810A (it)
CA (1) CA2244188A1 (it)
CZ (1) CZ237798A3 (it)
DE (1) DE69812789T2 (it)
DK (1) DK0894528T3 (it)
ES (1) ES2193445T3 (it)
HR (1) HRP980418A2 (it)
HU (1) HUP9801740A3 (it)
ID (1) ID19866A (it)
IT (1) IT1293531B1 (it)
NO (1) NO983541L (it)
PL (1) PL327785A1 (it)
PT (1) PT894528E (it)
SK (1) SK102598A3 (it)

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* Cited by examiner, † Cited by third party
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DE19814080A1 (de) * 1998-03-30 1999-10-07 Basf Ag Katalysator zur Dehydrierung von Kohlenwasserstoffen, insbesondere zur Dehydrierung von Ethylbenzol zu Styrol, sowie Verfahren zu seiner Herstellung
DE50012271D1 (de) * 1999-02-10 2006-04-27 Basf Ag Katalysator zur Dehydrierung von Ethylbenzol zu Styrol
KR100383221B1 (ko) * 2001-01-17 2003-05-12 한국화학연구원 알킬방향족 탄화수소의 탈수소반응용 촉매와 그 제조방법
TWI267401B (en) 2002-01-30 2006-12-01 Shell Int Research A catalyst, its preparation and its use in a dehydrogenation process
US7271126B2 (en) * 2002-05-15 2007-09-18 Sud-Chemie Inc. Catalyst for the dehydrogenation of ethyl benzene to STYRENE prepared with a high purity iron precursor
US6936743B2 (en) * 2002-09-05 2005-08-30 Fina Technology, Inc. Method for extending catalyst life in processes for preparing vinyl aromatic hydrocarbons
CN1299822C (zh) * 2004-07-13 2007-02-14 华东理工大学 用于乙苯氧化脱氢制苯乙烯的纳米碳纤维催化剂及其成型方法
DE102004039603A1 (de) * 2004-08-13 2006-02-23 Basf Ag Katalysator enthaltend Eisenoxid(e), Alkalimetallverbindung(en) und Ceroxid(e)
CN100368083C (zh) * 2004-10-29 2008-02-13 中国石油化工股份有限公司 用于乙苯脱氢制备苯乙烯的催化剂
CN100381362C (zh) * 2004-10-29 2008-04-16 中国石油化工股份有限公司 制备高铁酸钾的方法
AU2005307751A1 (en) 2004-11-18 2006-05-26 Shell Internationale Research Maatschappij B.V. An improved process for the manufacture of an alkenyl aromatic compound under low steam-to-oil process conditions
US20060224029A1 (en) * 2005-03-29 2006-10-05 Fina Technology, Inc. Method of extending catalyst life in vinyl aromatic hydrocarbon formation
CN100443171C (zh) * 2005-06-22 2008-12-17 中国石油化工股份有限公司 用于乙苯脱氢制备苯乙烯的氧化物催化剂
CN1307108C (zh) * 2005-07-29 2007-03-28 大庆石油学院 一种提高高铁酸钾氧化活性的方法
CN100408175C (zh) * 2005-08-15 2008-08-06 中国石油化工股份有限公司 制备烷烯基芳烃的脱氢催化剂
CN100408174C (zh) * 2005-08-15 2008-08-06 中国石油化工股份有限公司 乙苯脱氢的催化剂
CN101279263B (zh) * 2007-04-04 2010-07-21 中国石油化工股份有限公司 用于乙苯脱氢制苯乙烯的催化剂
CN101279267B (zh) * 2007-04-04 2011-07-13 中国石油化工股份有限公司 节能的乙苯脱氢催化剂
US8119559B2 (en) * 2007-05-03 2012-02-21 Basf Corporation Catalyst, its preparation and use
US8648007B2 (en) * 2008-04-22 2014-02-11 Fina Technology, Inc. Vaporization and transportation of alkali metal salts
US9138706B2 (en) * 2008-04-22 2015-09-22 Fina Technology, Inc. Method and apparatus for addition of an alkali metal promoter to a dehydrogenation catalyst
WO2010032338A1 (ja) * 2008-09-22 2010-03-25 学校法人早稲田大学 レドックス能の高いアルキル芳香族化合物の脱水素触媒およびその製造方法並びにそれを使用した脱水素化方法
US20110105316A1 (en) * 2009-10-31 2011-05-05 Fina Technology, Inc. Mixed Metal Oxide Ingredients for Bulk Metal Oxide Catalysts
CN103372452B (zh) * 2012-04-24 2015-08-19 中国石油天然气股份有限公司 乙苯脱氢制备苯乙烯的催化剂及其制备方法
CN103537296B (zh) * 2012-07-12 2015-06-10 中国石油化工股份有限公司 低水比的乙苯脱氢催化剂
EP3140267B1 (de) 2014-05-09 2021-03-31 Basf Se Katalysator für die dehydrierung von kohlenwasserstoffen
PL3140039T3 (pl) 2014-05-09 2021-01-25 Basf Se Ulepszony katalizator do odwodorniania węglowodorów
CN105562024A (zh) * 2014-10-13 2016-05-11 中国石油化工股份有限公司 制对甲基苯乙烯的催化剂及其制备方法和应用
CN105562025B (zh) * 2014-10-13 2018-05-11 中国石油化工股份有限公司 低温低水比乙苯脱氢催化剂及其制备方法和应用
CN105562023A (zh) * 2014-10-13 2016-05-11 中国石油化工股份有限公司 制备对甲基苯乙烯的催化剂及其制备方法和应用
CN106423239B (zh) * 2015-08-12 2019-01-25 中国石油化工股份有限公司 高稳定苯乙烯催化剂
CN106423187B (zh) * 2015-08-12 2019-02-19 中国石油化工股份有限公司 苯乙烯催化剂
CN106423238B (zh) * 2015-08-12 2019-01-25 中国石油化工股份有限公司 苯乙烯催化剂及其制备方法
CN105056966B (zh) * 2015-08-25 2018-09-25 营口风光新材料股份有限公司 用于乙苯脱氢制备苯乙烯的催化剂
RU2626238C1 (ru) * 2016-06-08 2017-07-25 Федеральное государственное бюджетное образовательное учреждение высшего образования "Ярославский государственный технический университет" (ФГБОУВО "ЯГТУ") Катализатор для дегидрирования алкилароматических углеводородов
CN108722430A (zh) * 2018-04-19 2018-11-02 天津理工大学 以纳米氧化铁为铁源的乙苯脱氢催化剂及其制备方法
CN111420673A (zh) * 2020-03-19 2020-07-17 湖南城市学院 一种烷基芳烃脱氢的催化剂的制备方法

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US4758543A (en) * 1987-07-01 1988-07-19 The Dow Chemical Company Dehydrogenation catalyst
JPH04277030A (ja) * 1991-03-05 1992-10-02 Nissan Gaadoraa Shokubai Kk エチルベンゼン脱水素触媒
ES2222468T3 (es) * 1994-12-14 2005-02-01 Shell Internationale Research Maatschappij B.V. Proceso de preparacion de catalizadores de deshidrogenacion.

Also Published As

Publication number Publication date
DK0894528T3 (da) 2003-07-28
US6184174B1 (en) 2001-02-06
DE69812789D1 (de) 2003-05-08
PL327785A1 (en) 1999-02-15
BR9802810A (pt) 1999-12-21
SK102598A3 (en) 1999-04-13
ITMI971860A1 (it) 1999-02-01
JPH11104494A (ja) 1999-04-20
HUP9801740A2 (hu) 1999-05-28
NO983541L (no) 1999-02-02
EP0894528B1 (en) 2003-04-02
EP0894528A2 (en) 1999-02-03
DE69812789T2 (de) 2004-02-12
CN1207330A (zh) 1999-02-10
AU7859198A (en) 1999-02-11
EP0894528A3 (en) 1999-11-03
CZ237798A3 (cs) 1999-02-17
CA2244188A1 (en) 1999-02-01
HU9801740D0 (en) 1998-09-28
NO983541D0 (no) 1998-07-31
HRP980418A2 (en) 1999-06-30
ES2193445T3 (es) 2003-11-01
PT894528E (pt) 2003-06-30
AU736855B2 (en) 2001-08-02
ID19866A (id) 1998-08-13
HUP9801740A3 (en) 2000-02-28

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