HRP20140471T1 - Spiroheterocikliäśki n-oksipiperidini kao pesticidi - Google Patents

Spiroheterocikliäśki n-oksipiperidini kao pesticidi Download PDF

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HRP20140471T1
HRP20140471T1 HRP20140471AT HRP20140471T HRP20140471T1 HR P20140471 T1 HRP20140471 T1 HR P20140471T1 HR P20140471A T HRP20140471A T HR P20140471AT HR P20140471 T HRP20140471 T HR P20140471T HR P20140471 T1 HRP20140471 T1 HR P20140471T1
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Croatia
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c5alkyl
halogen
nitro
cyano
c3alkoxy
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HRP20140471AT
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Michel Muehlebach
Thomas Pitterna
Jérôme Yves CASSAYRE
Andrew Edmunds
Camilia Corsi
Myriem El Quacemi
Roger Graham Hall
André Jeanguenat
André Stoller
Christopher Richard Godfrey
Jürgen Harry SCHAETZER
Olivier Loiseleur
Peter Maienfisch
Neil Brian Carter
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Syngenta Participations Ag
Syngenta Limited
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Priority claimed from GB0822748A external-priority patent/GB0822748D0/en
Priority claimed from GB0905237A external-priority patent/GB0905237D0/en
Application filed by Syngenta Participations Ag, Syngenta Limited filed Critical Syngenta Participations Ag
Publication of HRP20140471T1 publication Critical patent/HRP20140471T1/hr

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
    • C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
    • C07D471/10—Spiro-condensed systems
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Hydrogenated Pyridines (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (20)

1. Spojevi sa formulom I [image] naznačeni time da X , Y i Z međusobno neovisno su C1-4alkil, C3-6cikloalkil, C1-4haloalkil, C14alkoksi, halogen, fenil ili fenil supstituiran s C1-4alkil, C1-4haloalkil, halogen ili cijano; m i n, međusobno neovisno su 0, 1, 2 ili 3 i m+n je 0, 1, 2 ili 3; G je vodik, metal, amonijak, sulfonij ili latentna skupina, odabrana iz skupine koja sadrži C1-C8alkil, C2-C8haloalkil, fenilC1-C8alkil (pri čemu fenil može proizvoljno biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano ili s nitro), heteroarilC1-C8alkil (pri čemu heteroaril može proizvoljno biti supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3 alkilsulfonilom, halogenom, cijano ili s nitro), C3-C8alkenil, C3-C8haloalkenil, C3-C8alkinil, C(Xa)-Ra, C(Xb)-Xc-Rb, C(Xd)-N(Rc)-Rd, -SO2-Re,-P(Xe)(Rf)-R9 ili CH2-Xf-Rh pri čemu Xa, Xb, Xc, Xd, Xe i Xf su međusobno neovisno kisik ili sumpor; Ra je H, C1-C18alkil, C2-C18alkenil, C2-C18alkinil, C1-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C1-C10aminoalkil, C1-C5alkilaminoC1-C5alkil, C2-C8dialkilaminoC1-C5alkil, C3-C7cikloalkilC1-C5alkil, C1-C5alkoksiC1-C5alkil, C3-C5alkeniloksiC1-C5alkil, C3-C5alkinilC1-C5Oksialkil, C1-C5alkiltioC1-C5alkil, C1-C5alkilsulfinilC1-C5alkil, C1-C5alkilsulfonilC1-C5alkil, C2-C8alkilideneaminoksiC1-C5alkil, C1-C5alkilkarbonilC1-C5alkil, C1-C5alkoksikarbonilC1-C5alkil, aminokarbonilC1-C5alkil, C1-C5alkilaminokarbonilC1-C5alkil, C2-C8dialkilaminokarbonilC1-C5alkil, C1-C5alkilkarbonilaminoC1-C5alkil, N-C1-C5alkilkarbonil-N-C1-C5alkilaminoC1-C5alkil, C3-C6trialkilsililC1-C5alkil, fenilC1-C5alkil (pri čemu fenil može proizvoljno biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili s nitro), heteroarilC1-C5alkil, (pri čemu heteroaril može proizvoljno biti supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili s nitro), C2-C5haloalkenil, C3-C8cikloalkil, fenil ili fenil supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, heteroaril ili heteroaril supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, Rb je C1-C18alkil, C3-C18alkenil, C3-C18alkinil, C2-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C2-C10aminoalkil, C1-C5alkilaminoC1-C5alkil, C2-C8dialkilaminoC1-C5alkil, C3-C7cikloalkilC1-C5alkil, C1-C5alkoksiC1-C5alkil, C3-C5alkeniloksiC1-C5alkil, C3-C5alkiniloksiC1-C5alkil, C1-C5alkiltioC1-C5alkil, C1-C5alkilsulfinilC1-C5alkil, C1-C5alkilsulfonilC1-C5alkil, C2-C8alkilideneaminoksiC1-C5alkil, C1-C5alkilkarbonilC1-C5alkil, C1-C5alkoksikarbonilC1-C5alkil, aminokarbonilC1-C5alkil, C1-C5alkilaminokarbonilC1-C5alkil, C2-C8dialkilaminokarbonilC1-C5alkil, C1-C5alkilkarbonilaminoC1-C5alkil, N-C1-C5alkilkarbonil-N-C1-C5alkilaminoC1-C5alkil, C3-C6trialkilsililC1-C5alkil, fenilC1-C5alkil (pri čemu fenil može proizvoljno biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili s nitro), heteroarilC1-C5alkil, (pri čemu heteroaril može proizvoljno biti supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili s nitro), C3-C5haloalkenil, C3-C8cikloalkil, fenil ili fenil supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3halo-alkoksi, halogenom, cijano ili nitro, heteroaril ili heteroaril supstituiran s C1-C3 alkilom, C1-3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, Rc i Rd su svaki međusobno neovisno vodik, C1-C10alkil, C3-C10alkenil, C3-C10alkinil, C2-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C1-C10aminoalkil, C1-C5alkilaminoC1-C5alkil, C2-C8dialkilaminoC1-C5alkil, C3-C7cikloalkilC1-C5alkil, C1-C5alkoksiC1-C5alkil, C3-C5alkeniloksiC1-C5alkil, C3-C5alkiniloksiC1-C5alkil, C1-C5alkiltioC1-C5alkil, C1-C5alkilsulfinilC1-C5alkil, C1-C5alkilsulfonilC1-C5alkil, C2-C8alkilideneaminoksiC1-C5alkil, C1-C5alkilkarbonilC1-C5alkil, C1-C5alkoksikarbonilC1-C5alkil, aminokarbonilC1-C5alkil, C1-C5alkilaminokarbonilC1-C5alkil, C2-C8dialkilaminokarbonilC1-C5alkil, C1-C5alkilkarbonilaminoC1-C5alkil, N-C1-C5alkilkarbonil-N-C2-C5alkilaminoalkil, C3-C6trialkilsililC1-C5alkil, fenilC1-C5alkil (pri čemu fenil može proizvoljno biti supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili s nitro), heteroarilC1-C5alkil, (pri čemu heteroaril može proizvoljno biti supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili s nitro), C2-C5haloalkenil, C3-C8cikloalkil, fenil ili fenil supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, heteroaril ili heteroaril supstituiran s C1-C3alkil, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, heteroarilamino ili heteroarilamino supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, diheteroarilamino ili diheteroarilamino supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, fenilamino ili fenilamino supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili s nitro, difenilamino ili difenilamino supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili s nitro ili C3-C7cikloalkilamino, di-C3-C7cikloalkilamino ili C3-C7cikloalkoksi ili Rc i Rd se mogu spojiti tako da tvore 3-7 člani prsten, koji proizvoljno sadrži jedan heteroatom odabran od O ili S, Re je C1-C10alkil, C2-C10alkenil, C2-C10alkinil, C1-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C1-C10aminoalkil, C1-C5alkilaminoC1-C5alkil, C2-C8dialkilaminoC1-C5alkil, C3-C7cikloalkilC1-C5alkil, C1-C5alkoksiC1-C5alkil, C3-C5alkeniloksiC1-C5alkil, C3-C5alkiniloksiC1-C5alkil, C1-C5alkiltioC1-C5alkil, C1-C5alkilsulfinilC1-C5alkil, C1-C5alkilsulfonilC1-C5alkil, C2-C8alkilideneaminoksiC1-C5alkil, C1-C5alkilkarbonilC1-C5alkil, C1-C5alkoksikarbonilC1-C5alkil, aminokarbonilC1-C5alkil, C1-C5alkilaminokarbonilC1-C5alkil, C2-C8dialkilaminokarbonilC1-C5alkil, C1-C5alkilkarbonilaminoC1-C5alkil, N-C1-C5alkilkarbonil-N-C1-C5alkilaminoC1-C5alkil, C3-C6trialkilsililC1-C5alkil, fenilC1-C5alkil (pri čemu fenil može proizvoljno biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili s nitro), heteroarilC1-C5alkil (pri čemu heteroaril može proizvoljno biti supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili s nitro), C2-C5haloalkenil, C3-C8cikloalkil, fenil ili fenil supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, heteroaril ili heteroaril supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili s nitro, heteroarilamino ili heteroarilamino supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili s nitro, diheteroarilamino ili diheteroarilamino supstituiran s C1-C3alkilom, C1-C3haloalkil, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, fenilamino ili fenilamino supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, difenilamino, ili difenilamino supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, ili C3-C7cikloalkilamino, diC3-C7cikloalkilamino ili C3-C7cikloalkoksi, C1-C10alkoksi, C1-C10haloalkoksi, C1-C5alkilamino ili C2-C8dialkilamino Rf i Rg su svaki međusobno neovisno C1-C10alkil, C2-C10alkenil, C2-C10alkinil, C1-C10alkoksi, C1-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C1-C10aminoalkil, C1-C5alkilaminoC1-C5alkil, C2-C8dialkilaminoC1-C5alkil, C3-C7cikloalkilC1-C5alkil, C1-C5alkoksiC1-C5alkil, C3-C5alkeniloksiC1-C5alkil, C3-C5alkiniloksiC1-C5alkil, C1-C5alkiltioC1-C5alkil, C1-C5alkilsulfinilC1-C5alkil, C1-C5alkilsulfonilC1-C5alkil, C2-C8alkilideneaminoksiC1-C5alkil, C1-C5alkilkarbonilC1-C5alkil, C1-C5alkoksikarbonilC1-C5alkil, aminokarbonilC1-C5alkil, C1-C5alkilaminokarbonilC1-C5alkil, C2-C8dialkilaminokarbonilC1-C5alkil, C1-C5alkilkarbonilaminoC1-C5alkil, N-C1-C5alkilkarbonil-N-C2-C5alkilaminoalkil, C3-C6trialkilsililC1-C5alkil, fenilC1-C5alkil (pri čemu fenil može proizvoljno biti supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili s nitro), heteroarilC1-C5alkil (pri čemu heteroaril može proizvoljno biti supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili s nitro), C2-C5haloalkenil, C3-C8cikloalkil, fenil ili fenil supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogen, cijano ili nitro, heteroaril ili heteroaril supstituiran s C1-C3 alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili s nitro, heteroarilamino ili heteroarilamino supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili s nitro, diheteroarilamino ili diheteroarilamino supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, fenilamino ili fenilamino supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, difenilamino, ili difenilamino supstituiran s C1-C3alkilom, C1-3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, ili C3-C7cikloalkilamino, diC3-C7cikloalkilamino ili C3-C7cikloalkoksi, C1-C10haloalkoksi, C1-C5alkilamino ili C2-C8dialkilamino, benziloksi ili fenoksi, pri čemu benzil i fenil skupine mogu zauzvrat biti supstituirane sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, i Rh je C1-C10alkil, C3-C10alkenil, C3-C10alkinil, C1-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C2-C10aminoalkil, C1-C5alkilaminoC1-C5alkil, C2-C8dialkilaminoC1-C5alkil, C3-C7cikloalkilC1-C5alkil, C1-C5alkoksiC1-C5alkil, C3-C5alkeniloksiC1-C5alkil, C3-C5alkiniloksiC1-C5alkil, C1-C5alkiltioC1-C5alkil, C1-C5alkilsulfinilC1-C5alkil, C1-C5alkilsulfonilC1-C5alkil, C2-C8alkilideneaminoksiC1-C5alkil, C1-C5alkilkarbonilC1-C5alkil, C1-C5alkoksikarbonilC1-C5alkil, aminokarbonilC1-C5alkil, C1-C5alkilaminokarbonilC1-C5alkil, C2-C8dialkilaminokarbonilC1-C5alkil, C1-C5alkilkarbonilaminoC1-C5alkil, N-C1-C5alkilkarbonil-N-C1-C5alkilaminoC1-C5alkil, C3-C6trialkilsililC1-C5alkil, fenilC1-C5alkil (pri čemu fenil može proizvoljno biti supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3 alkilsulfonilom, halogenom, cijano ili s nitro), heteroarilC1-C5alkil (pri čemu heteroaril može proizvoljno biti supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3 alkilsulfonilom, halogenom, cijano ili s nitro), fenoksiC1-C5alkil (pri čemu fenil može proizvoljno biti supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3 alkilsulfonilom, halogenom, cijano ili s nitro), heteroariloksiC1-C5alkil (pri čemu heteroaril može proizvoljno biti supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3akilsulfinilom, C1-C3 alkilsulfonilom, halogenom, cijano ili s nitro), C3-C5haloalkenil, C3-C8cikloalkil, fenil ili fenil supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom ili s nitro, ili heteroaril, ili heteroaril supstituiran s C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili s nitro; R je vodik, C1-6alkil, C1-6haloalkil, C1-6cijanoalkil, benzil, C1-4alkoksi(C1-4)alkil, C1-4alkoksi(C1-4)alkoksi(C1-4)alkil ili skupina odabrana od G; i A je C1-6alkil, C1-6haloalkil, C3-6cikloalkil, C3-6cikloalkil(C1-4)alkil, ili C3-6cikloalkil(C1-4)alkil gdje je u cikloalkilnom dijelu metilenska skupina zamijenjena sa O,S ili NR0, gdje R0 je C16alkil ili C1-6alkoksi, ili A je C2-6alkenil, C2-6haloalkenil, C3-6alkinil, C1-6cijanoalkil, benzil, C14alkoksi(C1-4)alkil, C1-4alkoksi(C1-4)alkoksi(C1-4)alkil, oksetanil, tetrahidrofuranil, tetrahidropiranil, C1-6alkilkarbonil, C1-6alkoksikarbonil, C3-6cikloalkil karbonil, N-di(C16alkil)karbamoil, benzoil, C1-6alkilsulfonil, fenilsulfonil, C1-4alkiltio(C1-4)alkil, C14alkilsulfinil(C1-4)alkil ili C1-4alkilsulfonil(C1-4)alkil; ili njihova agrokemijski prihvatljiva sol ili N-oksid.
2. Spoj prema zahtjevu 1 naznačen time da G je skupina odabrana od -C(Xa)-Ra ili -C(Xb)-Xc-Rb, i značenja za Xa, Ra, Xb, Xc i Rb su kako je definirano u zahtjevu 1.
3. Spoj prema zahtjevu 1 naznačen time da R je vodik, metil, etil, trifluorometil, alil, propargil, benzil, metoksimetil, etoksimetil ili metoksietil, X je metil, etil, ciklopropil, metoksi, fluoro, bromo ili kloro, Y i Z, međusobno neovisno su metil, etil, ciklopropil, metoksi, fluoro, kloro, bromo, fenil ili fenil supstituiran s halogen ili C1-C2alkil, G je vodik i A je kako je definirano u zahtjevu 1.
4. Spoj prema bilo kojem zahtjevu 1 ili zahtjevu 3 naznačen time da R je metil, etil, alil, propargil, metoksimetil, X je metil, etil, ciklopropil, metoksi, fluoro, bromo ili kloro, Y i Z, međusobno neovisno su metil, etil, ciklopropil, metoksi, fluoro, kloro, bromo, fenil ili fenil supstituiran s halogen ili C1-C2alkil, G je vodik i A je kako je definirano u zahtjevu 1.
5. Spoj prema bilo kojem zahtjevu od 1, 3 i 4 naznačen time da R je metil, etil, metoksimetil, X je metil, etil, ciklopropil, metoksi, fluoro, bromo ili kloro, Y i Z, međusobno neovisno su metil, etil, ciklopropil, metoksi, fluoro, kloro, bromo, fenil ili fenil supstituiran s halogenom ili C1-C2alkilom, G je vodik i A je metil, etil, izopropil, trifluorometil, 2,2,2-trifluoroetil, 2,2-difluoroetil, 2-fluoroetil, ciklopropil, ciklobutil, ciklopentil, cikloheksil, ciklopropilmetil, ciklobutilmetil, ciklopentilmetil, cikloheksilmetil, oksetan-3-ilmetil, tetrahidrofuran-2-ilmetil, tetrahidropiran-2-ilmetil, tetrahidrofuran-3-ilmetil, tetrahidropiran-3-ilmetil, tetrahidropiran-4-ilmetil, alil, propargil, benzil, metoksimetil, etoksimetil, metoksietil, metoksipropil, metoksietoksimetil, metoksimetoksietil, oksetanil-3-il, tetrahidropiran-4-il ili metiltioetil.
6. Spoj prema bilo kojem zahtjevu od 1 i 3 do 5 naznačen time da R je metil, etil, metoksimetil, X je metil, etil, ciklopropil, metoksi, fluoro, bromo ili kloro, Y i Z, međusobno neovisno su metil, etil, ciklopropil, metoksi, fluoro, kloro, bromo, fenil ili fenil supstituiran s halogenom ili C1-C2alkilom, G je vodik i A je metil, etil, izopropil, trifluorometil, 2,2,2-trifluoroetil, 2,2-difluoroetil, 2-fluoroetil, ciklopropil, cikloheksil, ciklopropilmetil, alil, propargil, benzil, metoksimetil, etoksimetil, metoksietil, metoksietoksimetil, metoksimetoksietil, oksetanilil.
7. Postupak za pripravu spojeva sa formulom I prema bilo kojem zahtjevu od 1 do 6, naznačen time da G je vodik, koji se sastoji od ciklizacije spoja sa formulom IV [image] pri čemu X, Y, Z, m, n, R i A imaju značenja koja su im dodijeljena u bilo kojem od patentnih zahtjeva 1 do 6, i R14 je C1-6alkil, pod bazičnim uvjetima.
8. Pesticidni pripravak naznačen time da sadrži pesticidno učinkovitu količinu barem jednog spoja sa formulom I prema bilo kojem zahtjevu od 1 do 6.
9. Pesticidni pripravak prema zahtjevu 8, naznačen time da pored toga što sadrži spoj sa formulom I, sadrži pomoćna sredstva za formulaciju.
10. Pesticidni pripravak prema zahtjevu 9, naznačen time da pomoćno sredstvo za formulaciju je ulje biljnog ili životinjskog podrijetla, mineralno ulje, alkil esteri takvih ulja ili smjese takvih ulja i derivati ulja, ili je gnojivo ili amonijeva ili fosfonijeva sol, proizvoljno u smjesi s gore navedenim uljima i derivatima ulja.
11. Pesticidni pripravak prema zahtjevu 8, naznačen time da pored toga što sadrži spoj sa formulom I, sadrži barem jedan dodatni insekticid, akaricid, nematicid ili moluskicid.
12. Pesticidni pripravak prema zahtjevu 8, naznačen time da pored toga što sadrži spoj sa formulom I, sadrži barem jedan dodatni fungicid, herbicid, zaštitnu tvar ili regulator rasta biljke.
13. Postupak suzbijanja i kontrole štetočina, koji obuhvaća primjenu na štetočine, na lokus štetočina, ili na biljku osjetljivu na napad štetočina pesticidno učinkovite količine spoja sa formulom I kako je definirano u bilo kojem zahtjevu od 1 do 6, s izuzetkom postupka liječenja ljudskog ili životinjskog tijela kirurškim zahvatom ili liječenja i dijagnostičkih postupaka koji se primjenjuju na ljudskom ili životinjskom tijelu.
14. Postupak suzbijanja i kontrole štetočina, koji obuhvaća primjenu na štetočine, na lokus štetočina, ili na biljku osjetljivu na napad štetočina pesticidnog pripravka prema zahtjevu 8, s izuzetkom postupka liječenja ljudskog ili životinjskog tijela kirurškim zahvatom ili liječenja i dijagnostičkih postupaka koji se primjenjuju na ljudskom ili životinjskom tijelu.
15. Spojevi sa formulom IV [image] ili njihove soli, naznačeni time da X, Y, Z, m, n, R i A imaju značenja koja su im dodijeljena u bilo kojem od patentnih zahtjeva 1 do 6, i R14 je C1-6alkil.
16. Spojevi sa formulom V [image] ili njihove soli, naznačeni time da R i A imaju značenja koja su im dodijeljena u bilo kojem od patentnih zahtjeva 1 do 6, i R14 je C1-6alkil.
17. Spojevi sa formulom VIII [image] ili njihove soli, naznačeni time da R i A imaju značenja koja su im dodijeljena u bilo kojem od patentnih zahtjeva 1 do 6.
18. Spojevi sa formulom XI [image] ili njihove soli, naznačeni time da X, Y, Z, m, n, R i A imaju značenja koja su im dodijeljena u bilo kojem od patentnih zahtjeva 1 do 6.
19. Spojevi sa formulom VII [image] ili njihove soli, naznačeni time da R i A imaju značenja koja su im dodijeljena u bilo kojem od patentnih zahtjeva 1 do 6.
20. Spojevi sa formulom XIV [image] ili njihove soli, naznačeni time da X, Y, Z, m, n, R i A imaju značenja koja su im dodijeljena u bilo kojem od patentnih zahtjeva 1 do 6, i T je vodik, C1-4alkoksi, di(C1-4alkoksi), nitro ili kloro.
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