HRP20120705T1 - Spiroheterociklički derivati pirolidin diona koji su korisni kao pesticidi - Google Patents

Spiroheterociklički derivati pirolidin diona koji su korisni kao pesticidi Download PDF

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HRP20120705T1
HRP20120705T1 HRP20120705AT HRP20120705T HRP20120705T1 HR P20120705 T1 HRP20120705 T1 HR P20120705T1 HR P20120705A T HRP20120705A T HR P20120705AT HR P20120705 T HRP20120705 T HR P20120705T HR P20120705 T1 HRP20120705 T1 HR P20120705T1
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c5alkyl
halogen
cyano
nitro
c3alkyl
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Zambach Werner
Franz Hueter Ottmar
Wenger Jean
Goeghova Marcela
Pitterna Thomas
Maienfisch Peter
Muehlebach Michel
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Syngenta Participations Ag
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P33/00—Antiparasitic agents
    • A61P33/14—Ectoparasiticides, e.g. scabicides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
    • C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
    • C07D471/10—Spiro-condensed systems

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
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  • Pest Control & Pesticides (AREA)
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  • Medicinal Chemistry (AREA)
  • Animal Behavior & Ethology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Pharmacology & Pharmacy (AREA)
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  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Indole Compounds (AREA)
  • Pyrrole Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)

Abstract

Spojevi sa formulom I naznačeni time daX , Y i Z, nezavisno jedan od drugoga su C1-4alkil, C3-6cikloalkil, C1-4haloalkil, C1-4alkoksi, halogen, fenil ili fenil supstituiran sa C1-4alkilom ili halogenom, C1-4haloalkil, halogen ili cijano, m i n, nezavisno jedan od drugoga su 0, 1, 2 ili 3, gdje m+n je 0, 1, 2 ili 3, G je vodik, metal, amonijak, sulfonij ili latentna skupina koja je odabrana iz skupina C1-C8alkil, C2-C8haloalkil, fenilC1-C8alkil (pri čemu fenil proizvoljno mo·e biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano ili sa nitro), heteroarilC1-C8alkil (pri čemu heteroaril proizvoljno mo·e biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom,

Claims (14)

1. Spojevi sa formulom I [image] naznačeni time da X , Y i Z, nezavisno jedan od drugoga su C1-4alkil, C3-6cikloalkil, C1-4haloalkil, C1-4alkoksi, halogen, fenil ili fenil supstituiran sa C1-4alkilom ili halogenom, C1-4haloalkil, halogen ili cijano, m i n, nezavisno jedan od drugoga su 0, 1, 2 ili 3, gdje m+n je 0, 1, 2 ili 3, G je vodik, metal, amonijak, sulfonij ili latentna skupina koja je odabrana iz skupina C1-C8alkil, C2-C8haloalkil, fenilC1-C8alkil (pri čemu fenil proizvoljno može biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano ili sa nitro), heteroarilC1-C8alkil (pri čemu heteroaril proizvoljno može biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3 alkilsulfonilom, halogenom, cijano ili sa nitro), C3-C8alkenil, C3-C8haloalkenil, C3-C8alkinil, C(Xa)-Ra, C(Xb)-Xc-Rb, C(Xd)-N(Rc)-Rd, -SO2-Re, -P(Xe)(Rf)-Rg ili CH2-Xf-Rh pri čemu Xa, Xb, Xc, Xd, Xe i Xf su nezavisno jedan od drugoga kisik ili sumpor; Ra je H, C1-C18alkil, C2-C18alkenil, C2-C18alkinil, C1-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C1-C10aminoalkil, C1-C5alkilaminoC1-C5alkil, C2-C8dialkilaminoC1-C5alkil, C3-C7cikloalkilC1-C5alkil, C1-C5alkoksiC1-C5alkil, C3-C5alkeniloksiC1-C5alkil, C3-C5alkinilC1-C5oksialkil, C1-C5alkiltioC1-C5alkil, C1-C5alkilsulfinilC1-C5alkil, C1-C5alkilsuflonilC1-C5alkil, C2-C8alkilidenaminoksiC1-C5alkil, C1-C5alkilkarbonilC1-C5alkil, C1-C5alkoksikarbonilC1-C5alkil, aminokarbonilC1-C5alkil, C1-C5alkilaminokarbonilC1-C5alkil, C2-C8dialkilaminokarbonilC1-C5alkil, C1-C5alkilkarbonilaminoCiC5alkil, N-C1-C5alkilkarbonil-N-C1-C5alkilaminoC1-C5alkil, C3-C6trialkilsililC1-C5alkil, fenilC1-C5alkil (pri čemu fenil proizvoljno može biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano ili sa nitro), heteroarilC1-C5alkil, (pri čemu heteroaril proizvoljno može biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano ili sa nitro), C2-C5haloalkenil, C3-C8cikloalkil, fenil ili fenil supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, heteroaril ili heteroaril supstituiran sa C1-C3 alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, Rb je C1-C18alkil, C3-C18alkenil, C3-C18alkinil, C2-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C2-C10aminoalkil, C1-C5alkilaminoC1-C5alkil, C2-C8dialkilaminoC1-C5alkil, C3-C7cikloalkilC1-C5alkil, C1-C5alkoksiC1-C5alkil, C3-C5alkeniloksiC1-C5alkil, C3-C5alkiniloksiC1-C5alkil, C1-C5alkiltioC1-C5alkil, C1-C5alkilsulfinilC1-C5alkil, C1-C5alkilsuflonilC1-C5alkil, C2-C8alkilidenaminoksiC1-C5alkil, C1-C5alkilkarbonilC1-C5alkil, C1-C5alkoksikarbonilC1-C5alkil, aminokarbonilC1-C5alkil, C1-C5alkilaminokarbonilC1-C5alkil, C2-C8dialkilaminokarbonilC1-C5alkil, C1-C5alkilkarbonilaminoC1-C5alkil, N-C1-C5alkilkarbonil-N-C1-C5alkilaminoC1-C5alkil, C3-C6trialkilsililC1-C5alkil, fenilC1-C5alkil (pri čemu fenil proizvoljno može biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano ili sa nitro), heteroarilC1-C5alkil, (pri čemu heteroaril proizvoljno može biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano ili sa nitro), C3-C5haloalkenil, C3-C8cikloalkil, fenil ili fenil supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, heteroaril ili heteroaril supstituiran sa C1-C3 alkilom, C1-3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, Rc i Rd nezavisno jedan od drugoga su vodik, C1-C10alkil, C3-C10alkenil, C3-C10alkinil, C2-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C1-C10aminoalkil, C1-C5alkilaminoC1-C5alkil, C2-C8dialkilaminoC1-C5alkil, C3-C7cikloalkilC1-C5alkil, C1-C5alkoksiC1-C5alkil, C3-C5alkeniloksiC1-C5alkil, C3-C5alkiniloksiC1-C5alkil, C1-C5alkiltioC1-C5alkil, C1-C5alkilsulfinilC1-C5alkil, C1-C5alkilsuflonilC1-C5alkil, C2-C8alkilidenaminoksiC1-C5alkil, C1-C5alkilkarbonilC1-C5alkil, C1-C5alkoksikarbonilC1-C5alkil, aminokarbonilC1-C5alkil, C1-C5alkilaminokarbonilC1-C5alkil, C2-C8dialkilaminokarbonilC1-C5alkil, C1-C5alkilkarbonilaminoC1-C5alkil, N-C1-C5alkilkarbonil-N-C2-C5alkilaminoalkil, C3-C6trialkilsililC1-C5alkil, fenilC1-C5alkil (pri čemu fenil proizvoljno može biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsuflonilom, halogenom, cijano ili sa nitro), heteroarilC1-C5alkil, (pri čemu heteroaril proizvoljno može biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano ili sa nitro), C2-C5haloalkenil, C3-C8cikloalkil, fenil ili fenil supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, heteroaril ili heteroaril supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, heteroarilamino ili heteroarilamino supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, diheteroarilamino ili diheteroarilamino supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, fenilamino ili fenilamino supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili sa nitro, difenilamino ili difenilamino supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili sa nitro ili C3-C7cikloalkilamino, di-C3-C7cikloalkilamino ili C3-C7cikloalkoksi ili Rc i Rd mogu se spajati zajedno da se formira 3-7 člani prsten, koji proizvoljno sadrži jedan heteroatom koji je odabran od O ili S, Re je C1-C10alkil, C2-C10alkenil, C2-C10alkinil, C1-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C1-C10aminoalkil, C1-C5alkilaminoC1-C5alkil, C2-C8dialkilaminoC1-C5alkil, C3-C7cikloalkilC1-C5alkil, C1-C5alkoksiC1-C5alkil, C3-C5alkeniloksiC1-C5alkil, C3-C5alkiniloksiC1-C5alkil, C1-C5alkiltioC1-C5alkil, C1-C5alkilsulfinilC1-C5alkil, C1-C5alkilsulfonilC1-C5alkil, C2-C8alkilidenaminoksiC1-C5alkil, C1-C5alkilkarbonilC1-C5alkil, C1-C5alkoksikarbonilC1-C5alkil, aminokarbonilC1-C5alkil, C1-C5alkilaminokarbonilC1-C5alkil, C2-C8dialkilaminokarbonilC1-C5alkil, C1-C5alkilkarbonilaminoC1-C5alkil, N-C1-C5alkilkarbonil-N-C1-C5alkilaminoC1-C5alkil, C3-C6trialkilsililC1-C5alkil, fenilC1-C5alkil (pri čemu fenil proizvoljno može biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano ili sa nitro), heteroarilC1-C5alkil (pri čemu heteroaril proizvoljno može biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano ili sa nitro), C2-C5haloalkenil, C3-C8cikloalkil, fenil ili fenil supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, heteroaril ili heteroaril supstituiran sa C1-C3 alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili sa nitro, heteroarilamino ili heteroarilamino supstituiran sa C1-C3 alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili sa nitro, diheteroarilamino ili diheteroarilamino supstituiran sa C1-C3 alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, fenilamino ili fenilamino supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, difenilamino, ili difenilamino supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, ili C3-C7cikloalkilamino, diC3-C7cikloalkilamino ili C3-C7cikloalkoksi, C1-C10alkoksi, C1-C1ohaloalkoksi, C1-C5alkilamino ili C2-C8dialkilamino Rf i Rg nezavisno jedan od drugoga su C1-C10alkil, C2-C10alkenil, C2-C10alkinil, C1-C10alkoksi, C1-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C1-C10aminoalkil, C1-C5alkilaminoC1-C5alkil, C2-C8dialkilaminoC1-C5alkil, C3-C7cikloalkilC1-C5alkil, C1-C5alkoksiC1-C5alkil, C3-C5alkeniloksiC1-5alkil, C3-C5alkiniloksiC1-C5alkil, C1-C5alkiltioC1-C5alkil, C1-C5alkilsulfinilC1-C5alkil, C1-C5alkilsulfonilC1-C5alkil, C2-C8alkilidenaminoksiC1-C5alkil, C1-C5alkilkarbonilC1-C5alkil, C1-C5alkoksikarbonilC1-C5alkil, aminokarbonilC1-C5alkil, C1-C5alkilaminokarbonilC1-C5alkil, C2-C8dialkilaminokarbonilC1-C5alkil, C1-C5alkilkarbonilaminoC1-C5alkil, N-C1-C5alkilkarbonil-N-C2-Calkilaminoalkil, C3-C6trialkilsililC1-C5alkil, fenilC1-C5alkil (pri čemu fenil proizvoljno može biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano ili sa nitro), heteroarilC1-C5alkil (pri čemu heteroaril proizvoljno može biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano ili sa nitro), C2-C5haloalkenil, C3-C8cikloalkil, fenil ili fenil supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, heteroaril ili heteroaril supstituiran sa C1-C3 alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili sa nitro, heteroarilamino ili heteroarilamino supstituiran sa C1-C3 alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili sa nitro, diheteroarilamino ili diheteroarilamino supstituiran sa C1-C3 alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, fenilamino ili fenilamino supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, difenilamino, ili difenilamino supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom cijano ili nitro, ili C3-C7cikloalkilamino, diC3-C7cikloalkilamino ili C3-C7cikloalkoksi, C1-C10haloalkoksi, C1-C5alkilamino ili C2-C8dialkilamino, benziloksi ili fenoksi, pri čemu benzil i fenil skupine mogu biti naizmjenično supstituirane sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, i Rh je C1-C10alkil, C3-C10alkenil, C3-C10alkinil, C1-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C2-C10aminoalkil, C1-C5alkilaminoC1-C5alkil, C2-C8dialkilaminoC1-C5alkil, C3-C7cikloalkilC1-C5alkil, C1-C5alkoksiC1-C5alkil, C3-C5alkeniloksiC1-C5alkil, C3-C5alkiniloksiC1-C5alkil, C1-C5alkiltioC1-C5alkil, C1-C5alkilsulfinilC1-C5alkil, C1-C5alkilsulfonilC1-C5alkil, C2-C8alkilidenaminoksiC1-C5alkil, C1-C5alkilkarbonilC1-C5alkil, C1-C5alkoksikarbonilC1-C5alkil, aminokarbonilC1-C5alkil, C1-C5alkilaminokarbonilC1-C5alkil, C2-C8dialkilaminokarbonilC1-C5alkil, C1-C5alkilkarbonilaminoC1-C5alkil, N-C1-C5alkilkarbonil-N-C1-C5alkilaminoC1-C5alkil, C3-C6trialkilsililC1-C5alkil, fenilC1-C5alkil (pri čemu fenil proizvoljno može biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3 alkilsulfonilom, halogenom, cijano ili sa nitro), heteroarilC1-C5alkil (pri čemu heteroaril proizvoljno može biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano ili sa nitro), fenoksiC1-C5alkil (pri čemu fenil proizvoljno može biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano ili sa nitro), heteroariloksiC1-C5alkil (pri čemu heteroaril proizvoljno može biti supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3akilsulfinilom, C1-C3 alkilsulfonilom, halogenom, cijano ili sa nitro), C3-C5haloalkenil, C3-C8cikloalkil, fenil ili fenil supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom ili sa nitro, ili heteroaril, ili heteroaril supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili sa nitro, R je vodik, C1-6alkil, C1-6haloalkil, C1-6cijanoalkil, benzil, C1-4alkoksi(C1-4)alkil, C1-4alkoksi(C1-4)alkoksi(C1-4)alkil ili skupine odabrana od G, te R1, R2, R3 i R4, nezavisno jedan od drugoga su vodik ili metil, ili njihova agrokemijski prihvatljiva sol ili N-oksid.
2. Postupak za dobivanje spojeva sa formulom I prema zahtjevu 1, naznačen time da G je vodik, koji se sastoji od ciklizacije spoja formule IV [image] pri čemu X, Y, Z, m, n, R, R1, R2, R3, i R4 imaju značenja dodijeljena u zahtjevu 1, i R14 je C1-4alkil, kod baznih uvjeta.
3. Pesticidni pripravak naznačen time da sadrži pesticidno učinkovitu količinu barem jednog spoja sa formulom I prema zahtjevu 1.
4. Pesticidni pripravak prema zahtjevu 3, naznačen time da pored toga što sadrži spoj sa formulom I, sadrži formulaciju adjuvanata.
5. Pesticidni pripravak prema zahtjevu 3, naznačen time da pored toga što sadrži spoj sa formulom I, sadrži barem jedan dodatni insekticid, akaricid, nematicid ili moluskicid.
6. Pesticidni pripravak prema zahtjevu 3, naznačen time da pored toga što sadrži spoj sa formulom I, sadrži barem jedan dodatni fungicid, herbicid ili regulator rasta biljke.
7. Postupak za suzbijanje i kontrolu štetnika naznačen time da se sastoji od primjene pesticidno učinkovite količine spoja sa formulom I na štetočine, na lokus štetočina, ili na biljku osjetljivu na napade štetočina.
8. Postupak za suzbijanje i kontrolu štetnika naznačen time da se sastoji od primjene pesticidnog pripravka prema zahtjevu 3n a štetočine, na lokus štetočina ili na biljku osjetljivu na napade štetočina.
9. Spojevi sa formulom IV [image] naznačeni time da X, Y, Z, m, n, R, R1, R2, R3 i R4 imaju značenja dodijeljena u zahtjevu 1, i R14 je C1-4alkil.
10. Spojevi sa formulom V [image] ili njihove soli, naznačeni time da R, R1, R2, R3 i R4 imaju značenja dodijeljena u zahtjevu 1, i R14 je C1-4alkil.
11. Spojevi sa formulom VII [image] ili njihove soli, naznačeni time da R1, R2, R3 i R4 imaju značenja dodijeljena u zahtjevu 1 i R je C1-C6alkil, C2-C6alkenil, C3-C6alkinil ili benzil.
12. Spojevi sa formulom XI [image] naznačeni time da X, Y, Z, m, n, R, R1, R2, R3, i R4 imaju značenja dodijeljena u zahtjevu 1.
13. Spojevi sa formulom VIII [image] ili njihove soli, naznačeni time da R, R1, R2, R3 i R4 imaju značenja dodijeljena u zahtjevu 1.
14. Spojevi sa formulom IX [image] naznačeni time da R1, R2, R3 i R4 imaju značenja dodijeljena u zahtjevu 1 i R je C1-C6alkil, C2-C6alkenil, C3-C6alkinil ili benzil.
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ATE478072T1 (de) * 2006-01-30 2010-09-15 Irm Llc Spiroimidazol-derivate als ppar-modulatoren

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