FI67791B - Kontinuerligt foerfarande foer framstaellning av zeolit a med konstant och homogen kvalitet - Google Patents
Kontinuerligt foerfarande foer framstaellning av zeolit a med konstant och homogen kvalitet Download PDFInfo
- Publication number
- FI67791B FI67791B FI782358A FI782358A FI67791B FI 67791 B FI67791 B FI 67791B FI 782358 A FI782358 A FI 782358A FI 782358 A FI782358 A FI 782358A FI 67791 B FI67791 B FI 67791B
- Authority
- FI
- Finland
- Prior art keywords
- sodium
- zeolite
- alumina
- process according
- sodium oxide
- Prior art date
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 43
- 239000007788 liquid Substances 0.000 claims description 37
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 36
- 239000010457 zeolite Substances 0.000 claims description 36
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 34
- 229910021536 Zeolite Inorganic materials 0.000 claims description 33
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 26
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 22
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 18
- 239000011734 sodium Substances 0.000 claims description 16
- 239000000377 silicon dioxide Substances 0.000 claims description 15
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 14
- 239000004115 Sodium Silicate Substances 0.000 claims description 14
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 14
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 14
- 238000002425 crystallisation Methods 0.000 claims description 13
- 230000008025 crystallization Effects 0.000 claims description 13
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 9
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 238000010924 continuous production Methods 0.000 claims description 4
- 238000009826 distribution Methods 0.000 claims description 4
- 239000012452 mother liquor Substances 0.000 claims description 4
- 239000000741 silica gel Substances 0.000 claims description 4
- 229910002027 silica gel Inorganic materials 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000002699 waste material Substances 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 3
- 230000008020 evaporation Effects 0.000 claims description 3
- 150000004645 aluminates Chemical class 0.000 claims description 2
- 229910001570 bauxite Inorganic materials 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 239000004576 sand Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 description 19
- 239000000047 product Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 229910052681 coesite Inorganic materials 0.000 description 8
- 229910052906 cristobalite Inorganic materials 0.000 description 8
- 229910052682 stishovite Inorganic materials 0.000 description 8
- 229910052905 tridymite Inorganic materials 0.000 description 8
- 239000011575 calcium Substances 0.000 description 7
- 238000001556 precipitation Methods 0.000 description 7
- 239000002994 raw material Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000008187 granular material Substances 0.000 description 5
- 238000005342 ion exchange Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 description 1
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 1
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- JCCZVLHHCNQSNM-UHFFFAOYSA-N [Na][Si] Chemical compound [Na][Si] JCCZVLHHCNQSNM-UHFFFAOYSA-N 0.000 description 1
- WIUHYQBOXHNHLG-UHFFFAOYSA-N acetic acid hydrofluoride Chemical compound F.C(C)(=O)O WIUHYQBOXHNHLG-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000011549 crystallization solution Substances 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910001679 gibbsite Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- -1 silicate aluminate Chemical class 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2815—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of type A (UNION CARBIDE trade name; corresponds to GRACE's types Z-12 or Z-12L)
- C01B33/2823—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of type A (UNION CARBIDE trade name; corresponds to GRACE's types Z-12 or Z-12L) from aqueous solutions of an alkali metal aluminate and an alkali metal silicate excluding any other source of alumina or silica
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/24—LTA, e.g. A, alpha, ZK-4, ZK-21, ZK-22
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Claims (8)
1. Kontinuerligt förfarande för framställning av zeolit-A med konstant och homogen kvalitet, väri minst 90 % av produkten har en granulometrisk fördelning mellan 1-5 ,um, genom kontinuerlig blandning vid en temperatur av 40-90 C av en natriumsilikatlös-ning, som innehäller ett litet överskott av natriumoxid och väri molförhällandet SiC>2/Na20 är större än eller lika med 2,8, inne-hällande ca 45-105 g/1 NaOH och ca 120-350 g/1 Si02, och en nat-riumaluminatlösning, som innehäller ett överskott av natriumoxid, dvs. ca 80-110 g/1 NaOH och ca 50-65 g/1 A^O^, varefter den ut-fällda zeoliten och den erhällna vätskan förs kontinuerligt tili kristallisationsbäcken, kännetecknat av att blandningen av reagenserna utförs mycket snabbt genom att införa dessa i en blandningszon som alstras av en turbin som roterar mellan dess skivor, varvid skivornas konkava sida är vänd mot turbinen och omröringen fortsätts tills kristallisationen är fullständig och i kristallisationsvätskan upprätthälls en koncentration av ca 26-135 g/1 NaOH och ca 2-10 g/1 Al203, varefter zeoliten-A av-skiljs ur moderluten.
2. Förfarande enligt patentkravet 1,kännetecknat av att den ur kristallisationen erhällna moderluten med lag hait av aluminiumoxid, returneras tili cirkulationen efter koncentre-ring genom indunstning och tillsats av sädana mängder natriumoxid och aluminiumoxid däri, att de kompenserar den vid bild-ningen av zeolit-A utfällda natriumoxiden och aluminiumoxiden. 1 Förfarande enligt patentkravet 1, kännetecknat av att aluminatlösningen tages frän en fabrik för framställning av aluminiumoxid och returneras dit efter användningen.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7723373 | 1977-07-29 | ||
| FR7723373A FR2398698A1 (fr) | 1977-07-29 | 1977-07-29 | Procede industriel de fabrication en continu de zeolithe a |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI782358A FI782358A (fi) | 1979-01-30 |
| FI67791B true FI67791B (fi) | 1985-02-28 |
| FI67791C FI67791C (fi) | 1985-06-10 |
Family
ID=9193981
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI782358A FI67791C (fi) | 1977-07-29 | 1978-07-28 | Kontinuerligt foerfarande foer framstaellning av zeoli a med konstant och homogen kvalitet |
Country Status (24)
| Country | Link |
|---|---|
| US (1) | US4314979A (sv) |
| JP (1) | JPS5426298A (sv) |
| BE (1) | BE869156A (sv) |
| BR (1) | BR7804900A (sv) |
| CA (1) | CA1122190A (sv) |
| CH (1) | CH634282A5 (sv) |
| CS (1) | CS225107B2 (sv) |
| DE (1) | DE2832947B2 (sv) |
| DK (1) | DK336478A (sv) |
| ES (1) | ES472183A1 (sv) |
| FI (1) | FI67791C (sv) |
| FR (1) | FR2398698A1 (sv) |
| GB (1) | GB2001614B (sv) |
| GR (1) | GR62684B (sv) |
| HU (1) | HU184163B (sv) |
| IE (1) | IE47036B1 (sv) |
| IT (1) | IT1160560B (sv) |
| LU (1) | LU80045A1 (sv) |
| NO (1) | NO782606L (sv) |
| PL (1) | PL117556B1 (sv) |
| PT (1) | PT68245A (sv) |
| RO (1) | RO75844A (sv) |
| SE (1) | SE7808201L (sv) |
| YU (1) | YU183478A (sv) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4576986A (en) * | 1978-01-31 | 1986-03-18 | J. M. Huber Corporation | Rubber compositions containing small particle size zeolites and mixtures |
| US4612342A (en) * | 1978-12-20 | 1986-09-16 | J. M. Huber Corporation | Rubber compositions containing small particle size zeolites |
| US4888378A (en) * | 1978-12-20 | 1989-12-19 | J. M. Huber Corporation | Plastic compositions containing small particle size zeolites and mixtures |
| DE2910152A1 (de) * | 1979-03-15 | 1980-10-16 | Degussa | Verfahren zur herstellung von amorphen natriumaluminiumsilikaten |
| FR2454997A1 (fr) * | 1979-04-24 | 1980-11-21 | Ugine Kuhlmann | Cristallisation de la zeolithe a lors des procedes industriels de fabrication |
| DE2941636A1 (de) * | 1979-10-13 | 1981-05-07 | Degussa Ag, 6000 Frankfurt | Verfahren zur kontinuierlichen herstellung feinstteiliger zeolithischer natriumaluminiumsilikate |
| JPS6049130B2 (ja) * | 1980-12-27 | 1985-10-31 | 日本化学工業株式会社 | Ａ型ゼオライトの製造法 |
| FR2526780A1 (fr) * | 1982-05-11 | 1983-11-18 | Rhone Poulenc Spec Chim | Procede de fabrication de zeolites |
| JPS6121911A (ja) * | 1984-07-11 | 1986-01-30 | Toyo Soda Mfg Co Ltd | フオ−ジヤサイト型ゼオライトの製造方法 |
| US5474753A (en) * | 1990-11-09 | 1995-12-12 | Laviosa Rhone-Poulenc | Preparation of crystalline 4A zeolites |
| GB9322529D0 (en) * | 1993-11-02 | 1993-12-22 | Unilever Plc | Aluminosilicates |
| IL108272A (en) * | 1994-01-05 | 1998-02-22 | Super Industry Ltd | Process for production of zeolites |
| US6773694B1 (en) | 1999-12-22 | 2004-08-10 | Uop Llc | Process for synthesizing molecular sieves |
| US6432380B1 (en) | 2000-09-08 | 2002-08-13 | Albemarle Corporation | Synthesis of aluminosilicates via cofeeding an alkali metal aluminate and sodium silicate and cofeeding apparatus therefor |
| US7112316B1 (en) | 2005-08-08 | 2006-09-26 | Uop Llc | Process for preparing molecular sieves via continuous addition of nutrients |
| US8986253B2 (en) | 2008-01-25 | 2015-03-24 | Tandem Diabetes Care, Inc. | Two chamber pumps and related methods |
| EP2401587A2 (en) | 2009-02-27 | 2012-01-04 | Tandem Diabetes Care, Inc. | Methods and devices for determination of flow reservoir volume |
| US9250106B2 (en) | 2009-02-27 | 2016-02-02 | Tandem Diabetes Care, Inc. | Methods and devices for determination of flow reservoir volume |
| WO2010128342A1 (en) | 2009-05-06 | 2010-11-11 | Barchem Llc | Zeolite 4a with new morphological properties, its synthesis and use |
| US20110152770A1 (en) * | 2009-07-30 | 2011-06-23 | Tandem Diabetes Care, Inc. | Infusion pump system with disposable cartridge having pressure venting and pressure feedback |
| US9180242B2 (en) | 2012-05-17 | 2015-11-10 | Tandem Diabetes Care, Inc. | Methods and devices for multiple fluid transfer |
| US9555186B2 (en) | 2012-06-05 | 2017-01-31 | Tandem Diabetes Care, Inc. | Infusion pump system with disposable cartridge having pressure venting and pressure feedback |
| US9173998B2 (en) | 2013-03-14 | 2015-11-03 | Tandem Diabetes Care, Inc. | System and method for detecting occlusions in an infusion pump |
| US9180243B2 (en) | 2013-03-15 | 2015-11-10 | Tandem Diabetes Care, Inc. | Detection of infusion pump conditions |
| FR3063996B1 (fr) | 2017-03-17 | 2022-01-14 | Arkema France | Procede de synthese de cristaux de zeolithe avec agent d'ensemencement |
| FR3063993B1 (fr) * | 2017-03-17 | 2022-02-04 | Arkema France | Procede de synthese en continu de cristaux de zeolithe |
| FR3076828A1 (fr) | 2018-01-15 | 2019-07-19 | Arkema France | Procede de preparation de zeolithes en continu au moyen d'ultrasons |
| CN111170331A (zh) * | 2020-02-27 | 2020-05-19 | 中国日用化学研究院有限公司 | 一种连续化制备超细4a沸石的工艺及装置 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2882243A (en) * | 1953-12-24 | 1959-04-14 | Union Carbide Corp | Molecular sieve adsorbents |
| US3055841A (en) * | 1956-06-29 | 1962-09-25 | Exxon Research Engineering Co | Process for preparing attrition resistant adsorbents |
| US2841471A (en) | 1956-10-23 | 1958-07-01 | Texas Co | Synthesis of selective mineral sorbents |
| US2847280A (en) | 1956-10-23 | 1958-08-12 | Texas Co | Production of selective mineral sorbents |
| US2904607A (en) * | 1957-01-29 | 1959-09-15 | Exxon Research Engineering Co | Alkylation of aromatics |
| US3058805A (en) * | 1958-10-03 | 1962-10-16 | Bayer Ag | Process for the production of sodium zeolite a |
| US3071434A (en) * | 1960-01-20 | 1963-01-01 | Socony Mobil Oil Co Inc | Process for makling crystalline zeolites |
| US3425800A (en) * | 1967-10-05 | 1969-02-04 | Aluminum Co Of America | Production of crystalline zeolites |
| AT335035B (de) * | 1974-10-10 | 1977-02-25 | Henkel & Cie Gmbh | Stabile suspensionen wasserunloslicher, zum binden von calciumionen befahigter silikate und deren verwendung zur herstellung von wasch- und reinigungsmitteln |
| DE2517218B2 (de) | 1975-04-18 | 1977-05-05 | Henkel & Cie GmbH, 4000 Düsseldorf; Deutsche Gold- und Silber-Scheideanstalt vormals Roessler, 6000 Frankfurt | Kristallines zeolithpulver des typs a |
| US4041135A (en) * | 1975-07-25 | 1977-08-09 | J. M. Huber Corporation | Production of high capacity inorganic crystalline base exchange materials |
| DE2533614C2 (de) * | 1975-07-26 | 1985-10-31 | Degussa Ag, 6000 Frankfurt | Verfahren zur Herstellung von zeolithischen Alkalialuminiumsilikaten |
-
1977
- 1977-07-29 FR FR7723373A patent/FR2398698A1/fr active Granted
-
1978
- 1978-06-20 GR GR56548A patent/GR62684B/el unknown
- 1978-06-30 PT PT68245A patent/PT68245A/pt unknown
- 1978-07-20 BE BE189402A patent/BE869156A/xx not_active IP Right Cessation
- 1978-07-25 RO RO7894774A patent/RO75844A/ro unknown
- 1978-07-25 IE IE1492/78A patent/IE47036B1/en unknown
- 1978-07-27 LU LU80045A patent/LU80045A1/fr unknown
- 1978-07-27 CS CS784988A patent/CS225107B2/cs unknown
- 1978-07-27 SE SE7808201A patent/SE7808201L/sv unknown
- 1978-07-27 DE DE2832947A patent/DE2832947B2/de not_active Ceased
- 1978-07-27 CA CA000308291A patent/CA1122190A/fr not_active Expired
- 1978-07-28 BR BR7804900A patent/BR7804900A/pt unknown
- 1978-07-28 FI FI782358A patent/FI67791C/fi not_active IP Right Cessation
- 1978-07-28 ES ES472183A patent/ES472183A1/es not_active Expired
- 1978-07-28 PL PL1978208703A patent/PL117556B1/pl unknown
- 1978-07-28 JP JP9164878A patent/JPS5426298A/ja active Pending
- 1978-07-28 IT IT68811/78A patent/IT1160560B/it active
- 1978-07-28 DK DK336478A patent/DK336478A/da not_active Application Discontinuation
- 1978-07-28 YU YU01834/78A patent/YU183478A/xx unknown
- 1978-07-28 HU HU78KU534A patent/HU184163B/hu unknown
- 1978-07-28 NO NO782606A patent/NO782606L/no unknown
- 1978-07-28 GB GB787831453A patent/GB2001614B/en not_active Expired
- 1978-07-28 CH CH815578A patent/CH634282A5/fr not_active IP Right Cessation
-
1979
- 1979-12-19 US US06/105,273 patent/US4314979A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| IE781492L (en) | 1979-01-29 |
| CS225107B2 (en) | 1984-02-13 |
| DK336478A (da) | 1979-01-30 |
| US4314979A (en) | 1982-02-09 |
| IT1160560B (it) | 1987-03-11 |
| FI782358A (fi) | 1979-01-30 |
| RO75844A (ro) | 1981-02-28 |
| CH634282A5 (fr) | 1983-01-31 |
| PL208703A1 (pl) | 1979-03-12 |
| GR62684B (en) | 1979-05-22 |
| BR7804900A (pt) | 1979-04-24 |
| JPS5426298A (en) | 1979-02-27 |
| FR2398698A1 (fr) | 1979-02-23 |
| HU184163B (en) | 1984-07-30 |
| LU80045A1 (fr) | 1980-02-14 |
| FR2398698B1 (sv) | 1981-06-19 |
| GB2001614A (en) | 1979-02-07 |
| ES472183A1 (es) | 1979-10-01 |
| DE2832947A1 (de) | 1979-02-01 |
| BE869156A (fr) | 1979-01-22 |
| FI67791C (fi) | 1985-06-10 |
| IE47036B1 (en) | 1983-11-30 |
| IT7868811A0 (it) | 1978-07-28 |
| CA1122190A (fr) | 1982-04-20 |
| SE7808201L (sv) | 1979-01-30 |
| DE2832947B2 (de) | 1980-01-24 |
| GB2001614B (en) | 1982-02-10 |
| PL117556B1 (en) | 1981-08-31 |
| PT68245A (fr) | 1978-07-01 |
| YU183478A (en) | 1982-10-31 |
| NO782606L (no) | 1979-01-30 |
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Owner name: PRODUITS CHIMIQUES UGINE KUHLMANN |