FI108042B - Beläggningskomposition - Google Patents
Beläggningskomposition Download PDFInfo
- Publication number
- FI108042B FI108042B FI955588A FI955588A FI108042B FI 108042 B FI108042 B FI 108042B FI 955588 A FI955588 A FI 955588A FI 955588 A FI955588 A FI 955588A FI 108042 B FI108042 B FI 108042B
- Authority
- FI
- Finland
- Prior art keywords
- group
- monomer
- coating composition
- months
- examples
- Prior art date
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- 239000008199 coating composition Substances 0.000 title claims description 34
- -1 acryloyloxy group Chemical group 0.000 claims description 51
- 239000000178 monomer Substances 0.000 claims description 50
- 239000011248 coating agent Substances 0.000 claims description 25
- 238000000576 coating method Methods 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 15
- 229920002554 vinyl polymer Polymers 0.000 claims description 15
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 10
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 125000006165 cyclic alkyl group Chemical group 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 239000000470 constituent Substances 0.000 claims 1
- 230000002401 inhibitory effect Effects 0.000 claims 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 claims 1
- 230000003373 anti-fouling effect Effects 0.000 description 35
- 238000012360 testing method Methods 0.000 description 27
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 24
- 239000003973 paint Substances 0.000 description 18
- 229920000642 polymer Polymers 0.000 description 17
- 239000011347 resin Substances 0.000 description 14
- 229920005989 resin Polymers 0.000 description 14
- 239000000243 solution Substances 0.000 description 14
- 230000003628 erosive effect Effects 0.000 description 13
- 239000013535 sea water Substances 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 12
- 241000894007 species Species 0.000 description 11
- 125000004432 carbon atom Chemical group C* 0.000 description 10
- 238000005336 cracking Methods 0.000 description 10
- 239000000463 material Substances 0.000 description 9
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 9
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 9
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- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 8
- 239000008096 xylene Substances 0.000 description 8
- OVGRCEFMXPHEBL-UHFFFAOYSA-N 1-ethenoxypropane Chemical compound CCCOC=C OVGRCEFMXPHEBL-UHFFFAOYSA-N 0.000 description 6
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- 229940121375 antifungal agent Drugs 0.000 description 6
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
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- 238000000034 method Methods 0.000 description 5
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- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical class CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
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- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(i) oxide Chemical compound [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 4
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- 125000005396 acrylic acid ester group Chemical group 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 description 3
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
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- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
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- DQNSRQYYCSXZDF-UHFFFAOYSA-N 1,4-bis(ethenoxymethyl)cyclohexane Chemical compound C=COCC1CCC(COC=C)CC1 DQNSRQYYCSXZDF-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000005749 Copper compound Substances 0.000 description 2
- 239000001692 EU approved anti-caking agent Substances 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
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- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
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- 125000000753 cycloalkyl group Chemical group 0.000 description 2
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- YKSNLCVSTHTHJA-UHFFFAOYSA-L maneb Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S YKSNLCVSTHTHJA-UHFFFAOYSA-L 0.000 description 2
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- QEQBMZQFDDDTPN-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy benzenecarboperoxoate Chemical compound CC(C)(C)OOOC(=O)C1=CC=CC=C1 QEQBMZQFDDDTPN-UHFFFAOYSA-N 0.000 description 1
- KDGNCLDCOVTOCS-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy propan-2-yl carbonate Chemical compound CC(C)OC(=O)OOC(C)(C)C KDGNCLDCOVTOCS-UHFFFAOYSA-N 0.000 description 1
- ADDAJJNRBDCPFR-UHFFFAOYSA-N (5-thiocyanatothiophen-2-yl) thiocyanate Chemical compound N#CSC1=CC=C(SC#N)S1 ADDAJJNRBDCPFR-UHFFFAOYSA-N 0.000 description 1
- QCEMLEAFICYLBX-CCEZHUSRSA-N (E)-4-[[tert-butyl(diphenyl)silyl]methoxy]-4-oxobut-2-enoic acid Chemical compound C=1C=CC=CC=1[Si](COC(=O)\C=C\C(O)=O)(C(C)(C)C)C1=CC=CC=C1 QCEMLEAFICYLBX-CCEZHUSRSA-N 0.000 description 1
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- KKMMAMLLJKUXNI-SEYXRHQNSA-N (Z)-4-oxo-4-(4-tributylsilylbutoxy)but-2-enoic acid Chemical compound CCCC[Si](CCCC)(CCCC)CCCCOC(=O)\C=C/C(O)=O KKMMAMLLJKUXNI-SEYXRHQNSA-N 0.000 description 1
- SKYXLDSRLNRAPS-UHFFFAOYSA-N 1,2,4-trifluoro-5-methoxybenzene Chemical compound COC1=CC(F)=C(F)C=C1F SKYXLDSRLNRAPS-UHFFFAOYSA-N 0.000 description 1
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- HFOCAQPWSXBFFN-UHFFFAOYSA-N 2-methylsulfonylbenzaldehyde Chemical compound CS(=O)(=O)C1=CC=CC=C1C=O HFOCAQPWSXBFFN-UHFFFAOYSA-N 0.000 description 1
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- GIHRSJHMOYLKNF-UHFFFAOYSA-N 3-(benzylideneamino)-1,3-thiazolidine-2,4-dione Chemical compound O=C1CSC(=O)N1N=CC1=CC=CC=C1 GIHRSJHMOYLKNF-UHFFFAOYSA-N 0.000 description 1
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- GTSOGRNBGAMGHJ-UHFFFAOYSA-N 3-[(2-hydroxyphenyl)methylideneamino]-1,3-thiazolidine-2,4-dione Chemical compound Oc1ccccc1C=NN1C(=O)CSC1=O GTSOGRNBGAMGHJ-UHFFFAOYSA-N 0.000 description 1
- PORQOHRXAJJKGK-UHFFFAOYSA-N 4,5-dichloro-2-n-octyl-3(2H)-isothiazolone Chemical compound CCCCCCCCN1SC(Cl)=C(Cl)C1=O PORQOHRXAJJKGK-UHFFFAOYSA-N 0.000 description 1
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- RHOJHZRROLYFKX-UHFFFAOYSA-N azane 2-carbamothioylsulfanylethyl carbamodithioate Chemical compound N.NC(=S)SCCSC(N)=S RHOJHZRROLYFKX-UHFFFAOYSA-N 0.000 description 1
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- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Inorganic materials [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 description 1
- UTOVMEACOLCUCK-PLNGDYQASA-N butyl maleate Chemical compound CCCCOC(=O)\C=C/C(O)=O UTOVMEACOLCUCK-PLNGDYQASA-N 0.000 description 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 125000000068 chlorophenyl group Chemical group 0.000 description 1
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 229940116318 copper carbonate Drugs 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- 229940120693 copper naphthenate Drugs 0.000 description 1
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 1
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 description 1
- LCGITQAMTPXTBS-UHFFFAOYSA-N copper;copper(1+) Chemical compound [Cu+].[Cu+2] LCGITQAMTPXTBS-UHFFFAOYSA-N 0.000 description 1
- BQVVSSAWECGTRN-UHFFFAOYSA-L copper;dithiocyanate Chemical compound [Cu+2].[S-]C#N.[S-]C#N BQVVSSAWECGTRN-UHFFFAOYSA-L 0.000 description 1
- QYBZRRUECLSRCO-UHFFFAOYSA-N copper;ethane-1,2-diamine Chemical compound [Cu].NCCN.NCCN QYBZRRUECLSRCO-UHFFFAOYSA-N 0.000 description 1
- IURRXCRWRKQLGC-UHFFFAOYSA-N copper;quinolin-8-ol Chemical compound [Cu].C1=CN=C2C(O)=CC=CC2=C1.C1=CN=C2C(O)=CC=CC2=C1 IURRXCRWRKQLGC-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical class C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- LDCRTTXIJACKKU-ONEGZZNKSA-N dimethyl fumarate Chemical compound COC(=O)\C=C\C(=O)OC LDCRTTXIJACKKU-ONEGZZNKSA-N 0.000 description 1
- 229960004419 dimethyl fumarate Drugs 0.000 description 1
- REQPQFUJGGOFQL-UHFFFAOYSA-N dimethylcarbamothioyl n,n-dimethylcarbamodithioate Chemical compound CN(C)C(=S)SC(=S)N(C)C REQPQFUJGGOFQL-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000003966 growth inhibitor Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 201000006747 infectious mononucleosis Diseases 0.000 description 1
- HDHLIWCXDDZUFH-UHFFFAOYSA-N irgarol 1051 Chemical compound CC(C)(C)NC1=NC(SC)=NC(NC2CC2)=N1 HDHLIWCXDDZUFH-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical class OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- HYVVJDQGXFXBRZ-UHFFFAOYSA-N metam Chemical compound CNC(S)=S HYVVJDQGXFXBRZ-UHFFFAOYSA-N 0.000 description 1
- 125000006626 methoxycarbonylamino group Chemical group 0.000 description 1
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000020638 mussel Nutrition 0.000 description 1
- BLCKKNLGFULNRC-UHFFFAOYSA-L n,n-dimethylcarbamodithioate;nickel(2+) Chemical compound [Ni+2].CN(C)C([S-])=S.CN(C)C([S-])=S BLCKKNLGFULNRC-UHFFFAOYSA-L 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 229940078494 nickel acetate Drugs 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- KVQYEAOOWVNEIM-UHFFFAOYSA-N oxygen(2-) titanium(4+) Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4] KVQYEAOOWVNEIM-UHFFFAOYSA-N 0.000 description 1
- LBXODIPKUUDMEU-UHFFFAOYSA-N oxygen(2-) titanium(4+) Chemical compound [O--].[O--].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4].[Ti+4] LBXODIPKUUDMEU-UHFFFAOYSA-N 0.000 description 1
- IZUPBVBPLAPZRR-UHFFFAOYSA-M pentachlorophenolate Chemical compound [O-]C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-M 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- YFMFSCRSAWIWOP-UHFFFAOYSA-N phenyl(trityl)diazene Chemical compound C1=CC=CC=C1N=NC(C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 YFMFSCRSAWIWOP-UHFFFAOYSA-N 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical compound [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 description 1
- YWVYZMVYXAVAKS-UHFFFAOYSA-N pyridin-1-ium;trifluoromethanesulfonate Chemical compound C1=CC=[NH+]C=C1.[O-]S(=O)(=O)C(F)(F)F YWVYZMVYXAVAKS-UHFFFAOYSA-N 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- NVBFHJWHLNUMCV-UHFFFAOYSA-N sulfamide Chemical compound NS(N)(=O)=O NVBFHJWHLNUMCV-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- 150000003560 thiocarbamic acids Chemical class 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- VWYNJZWPOOGWHN-UHFFFAOYSA-N titanium Chemical compound [Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti] VWYNJZWPOOGWHN-UHFFFAOYSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 125000002306 tributylsilyl group Chemical group C(CCC)[Si](CCCC)(CCCC)* 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- CWMFRHBXRUITQE-UHFFFAOYSA-N trimethylsilylacetylene Chemical compound C[Si](C)(C)C#C CWMFRHBXRUITQE-UHFFFAOYSA-N 0.000 description 1
- ZEVPGAHZONRGQP-UHFFFAOYSA-N tris(4-methylpentan-2-yloxy)silyl prop-2-enoate Chemical compound CC(C)CC(C)O[Si](OC(C)CC(C)C)(OC(C)CC(C)C)OC(=O)C=C ZEVPGAHZONRGQP-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
- NRINZBKAERVHFW-UHFFFAOYSA-L zinc;dicarbamate Chemical compound [Zn+2].NC([O-])=O.NC([O-])=O NRINZBKAERVHFW-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
Claims (6)
1. Beläggningskomposition, kännetecknad av att den innehäller som väsentliga beständsdelar ett 5 tillväxtförhindrande medel och en kopolymer, vilken framställs frän en monomerblandning omfattande monomer A, som representeras av formel (1), R1 ίο | X-Si-R2 (1) R3 15 där var och en av grupperna R1-R3, som kan vara samma eller olika grupper, är en rakkedjad, förgrenad eller cyklisk alkylgrupp eller en arylgrupp och X är en akryloyloxigrupp, en metakryloyloxigrupp, en maleinoyl-oxigrupp eller en fumaroyloxigrupp, och monomer B, som 20 representeras av formel (2), R4 Y-CH (2) ♦;·<' 25 1 OR5 där R4 är en rakkedjad eller förgrenad alkylgrupp, R5 är en rakkedjad, förgrenad eller cyklisk alkylgrupp och
30 Y är en akryloyloxigrupp, en metakryloyloxigrupp, en ♦ 4 maleinoyloxigrupp eller en fumaroyloxigrupp.
2. Beläggningskomposition enligt patentkrav 1, kännetecknad av att nämnda monomerblandning innehäller 1-95 vikt-% av monomer A och 1-95 vikt-% av monomer
35 B. ' 33 108042
3. Beläggningskomposition enligt patentkrav 1, kännetecknad av att nämnda monomerblandning inne-häller en annan vinylmonomer än monomererna A och B.
4. Beläggningskomposition enligt patentkrav 3, 5' kännetecknad av att andelen av nämnda vinylmonomer är högst 98 vikt-% av monomerblandningens totalmängd.
5. Kompositionsbeläggning enligt patentkrav 1, kännetecknad av att nämnda kopolymers massagenom-snittliga molmassa är 1 000-150 000.
6. Beläggningskomposition enligt patentkrav 1, kännetecknad av att andelen av nämnda tillväxt-förhindrande medel är 0,1-90 vikt-% av beläggningskompo-sitionens fasta substans. ♦ 1< < \
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP31267594 | 1994-11-21 | ||
| JP31267594 | 1994-11-21 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI955588A0 FI955588A0 (sv) | 1995-11-20 |
| FI955588A FI955588A (sv) | 1996-05-22 |
| FI108042B true FI108042B (sv) | 2001-11-15 |
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ID=18032075
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI955588A FI108042B (sv) | 1994-11-21 | 1995-11-20 | Beläggningskomposition |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5767171A (sv) |
| EP (1) | EP0714957B1 (sv) |
| KR (1) | KR100189477B1 (sv) |
| CN (1) | CN1058280C (sv) |
| DE (1) | DE69501715T2 (sv) |
| DK (1) | DK0714957T3 (sv) |
| FI (1) | FI108042B (sv) |
| GR (1) | GR3026512T3 (sv) |
| HK (1) | HK1008749A1 (sv) |
| NO (1) | NO309486B1 (sv) |
| TW (1) | TW319791B (sv) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL200670B1 (pl) * | 1998-12-28 | 2009-01-30 | Chugoku Marine Paints | Kopolimer sililo(met)akrylanowy, sposób jego wytwarzania, przeciwporostowa kompozycja do malowania zawierająca kopolimer sililo(met)akrylanowy oraz jej zastosowanie |
| US6992120B2 (en) * | 2001-11-13 | 2006-01-31 | Arkema Inc. | Coating compositions |
| JP3914437B2 (ja) * | 2000-04-24 | 2007-05-16 | Ｂａｓｆコーティングスジャパン株式会社 | 防汚塗料、防汚塗膜、浸水構造体及び防汚方法 |
| JP4725941B2 (ja) * | 2001-05-23 | 2011-07-13 | 楠本化成株式会社 | 粉体塗料用平滑剤 |
| EP1288234A1 (en) * | 2001-08-27 | 2003-03-05 | Sigma Coatings B.V. | Binders with low content in hydrolysable monomer suitable for selfpolishing antifouling paints |
| KR20040035829A (ko) | 2001-09-21 | 2004-04-29 | 시그마 코팅즈 비.브이. | 유기실릴화 카르복실레이트 모노머의 제조방법 및 그것을오염방지 코팅에 사용하는 방법 |
| EP1308484A1 (en) * | 2001-10-30 | 2003-05-07 | Sigma Coatings B.V. | Use of silylesters of rosin in self-polishing antifouling paints |
| NO328137B1 (no) * | 2001-12-26 | 2009-12-14 | Nippon Paint Co Ltd | Akrylharpiks og antibegroingsbelegg |
| US6767978B2 (en) * | 2002-01-03 | 2004-07-27 | Atofina Chemicals, Inc. | Copolymers containing fluoro and silyl groups and their use in marine antifoulant composition |
| US7297727B2 (en) | 2002-05-28 | 2007-11-20 | Arkema Inc. | Triarylsilyl(meth)acryloyl-containing polymers for marine coating compositions |
| EP1475415A1 (en) * | 2003-05-07 | 2004-11-10 | SigmaKalon Services B.V. | Silyl esters, their use in binder systems and paint compositions and a process of production thereof |
| ATE345361T1 (de) | 2003-07-07 | 2006-12-15 | Akzo Nobel Coatings Int Bv | Silylestercopolymerzusammensetzungen |
| RU2357992C2 (ru) * | 2004-08-10 | 2009-06-10 | Чугоку Марин Пейнтс, Лтд. | Антикоррозийный покрывающий состав с высоким содержанием нелетучих компонентов, быстро отверждающийся антикоррозийный покрывающий состав с высоким содержанием нелетучих компонентов, способ покрытия корабля или подобной конструкции, антикоррозийная пленка с высоким содержанием нелетучих компонентов и быстро отверждающаяся антикоррозийная пленка с высоким содержанием нелетучих компонентов, получаемые при покрытии, и корабль и подводная конструкция, покрытые этими пленками |
| US20060189708A1 (en) * | 2005-02-24 | 2006-08-24 | Michael Abrams | Benzylsilyl(meth)acryloyl-containing polymers for marine coating compositions |
| US20100183540A1 (en) * | 2007-07-06 | 2010-07-22 | Jotun A/S | Branched polymer and antifouling coating composition comprising the polymer |
| JP5043805B2 (ja) | 2007-11-19 | 2012-10-10 | キヤノン株式会社 | 画像形成装置 |
| JP5360759B2 (ja) * | 2009-06-08 | 2013-12-04 | 日東化成株式会社 | 防汚塗料組成物、該組成物を用いて形成される防汚塗膜、該塗膜を表面に有する塗装物、および該塗膜を形成する防汚処理方法 |
| CN103228744B (zh) * | 2010-10-14 | 2016-10-12 | 汉伯公司 | 高固含量防污油漆组合物 |
| GB2592921B (en) | 2020-03-09 | 2024-04-17 | Jotun As | Hull cleaning robot |
| KR20220156612A (ko) | 2020-03-27 | 2022-11-25 | 요툰 에이/에스 | 방오성 코팅 조성물 |
| GB202107159D0 (en) | 2021-03-23 | 2021-06-30 | Jotun As | Monitoring a vessel |
| BR112023018007A2 (pt) | 2021-03-23 | 2023-10-03 | Jotun As | Monitoração da limpeza de uma superfície subaquática de um objeto estacionário |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3896753A (en) * | 1966-07-26 | 1975-07-29 | Nat Patent Dev Corp | Hydrophilic polymer coating for underwater structures |
| EP0131626B1 (en) * | 1983-01-17 | 1989-05-24 | M & T Chemicals, Inc. | Erodible paints for control of marine fouling |
| DK171994B1 (da) * | 1987-06-28 | 1997-09-08 | Nippon Oils & Fats Co Ltd | Begroningshæmmende maling indeholdende et begroningshæmmende middel og en siliciumholdig organisk polymer |
| JP2987902B2 (ja) * | 1990-08-24 | 1999-12-06 | 大日本インキ化学工業株式会社 | 防汚塗料用組成物 |
| JPH04264168A (ja) * | 1991-02-18 | 1992-09-18 | Nippon Oil & Fats Co Ltd | 塗料組成物 |
| JP2790021B2 (ja) * | 1993-09-30 | 1998-08-27 | 日本油脂株式会社 | 塗料組成物 |
-
1995
- 1995-11-17 TW TW084112201A patent/TW319791B/zh active
- 1995-11-17 US US08/560,028 patent/US5767171A/en not_active Expired - Lifetime
- 1995-11-20 KR KR1019950042169A patent/KR100189477B1/ko not_active IP Right Cessation
- 1995-11-20 DE DE69501715T patent/DE69501715T2/de not_active Expired - Lifetime
- 1995-11-20 NO NO954675A patent/NO309486B1/no not_active IP Right Cessation
- 1995-11-20 DK DK95118255.9T patent/DK0714957T3/da active
- 1995-11-20 FI FI955588A patent/FI108042B/sv not_active IP Right Cessation
- 1995-11-20 EP EP95118255A patent/EP0714957B1/en not_active Expired - Lifetime
- 1995-11-21 CN CN95119618A patent/CN1058280C/zh not_active Expired - Lifetime
-
1998
- 1998-04-03 GR GR980400696T patent/GR3026512T3/el unknown
- 1998-07-28 HK HK98109467A patent/HK1008749A1/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR960017802A (ko) | 1996-06-17 |
| DE69501715D1 (de) | 1998-04-09 |
| NO954675L (no) | 1996-05-22 |
| FI955588A0 (sv) | 1995-11-20 |
| EP0714957B1 (en) | 1998-03-04 |
| TW319791B (sv) | 1997-11-11 |
| KR100189477B1 (ko) | 1999-06-01 |
| NO309486B1 (no) | 2001-02-05 |
| US5767171A (en) | 1998-06-16 |
| DE69501715T2 (de) | 1998-08-06 |
| CN1128778A (zh) | 1996-08-14 |
| EP0714957A1 (en) | 1996-06-05 |
| DK0714957T3 (da) | 1998-03-30 |
| FI955588A (sv) | 1996-05-22 |
| NO954675D0 (no) | 1995-11-20 |
| CN1058280C (zh) | 2000-11-08 |
| HK1008749A1 (en) | 1999-05-14 |
| GR3026512T3 (en) | 1998-07-31 |
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| PC | Transfer of assignment of patent |
Owner name: NITTO KASEI CO., LTD Free format text: NITTO KASEI CO., LTD Owner name: NKM COATINGS CO., LTD. Free format text: NKM COATINGS CO., LTD. |
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| MA | Patent expired |