ES2806598T3 - Derivados tetracíclicos activos como plaguicidas con sustituyentes que contienen azufre - Google Patents
Derivados tetracíclicos activos como plaguicidas con sustituyentes que contienen azufre Download PDFInfo
- Publication number
- ES2806598T3 ES2806598T3 ES15804527T ES15804527T ES2806598T3 ES 2806598 T3 ES2806598 T3 ES 2806598T3 ES 15804527 T ES15804527 T ES 15804527T ES 15804527 T ES15804527 T ES 15804527T ES 2806598 T3 ES2806598 T3 ES 2806598T3
- Authority
- ES
- Spain
- Prior art keywords
- spp
- alkyl
- methyl
- formula
- halogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 0 *c1cnc(*C(I)=N2)c2c1 Chemical compound *c1cnc(*C(I)=N2)c2c1 0.000 description 6
- ATIOJZCDSUIDLS-UHFFFAOYSA-N CC(C(C1CCCCC1)=C)(NC1CCCCC1)OI Chemical compound CC(C(C1CCCCC1)=C)(NC1CCCCC1)OI ATIOJZCDSUIDLS-UHFFFAOYSA-N 0.000 description 1
- OUYPVCPPHIMRRO-UHFFFAOYSA-N CCOC(c1nc2ccccc2cc1SCC)=O Chemical compound CCOC(c1nc2ccccc2cc1SCC)=O OUYPVCPPHIMRRO-UHFFFAOYSA-N 0.000 description 1
- BJVZNVHQAAJXBO-UHFFFAOYSA-N CCS(c(cc(c(N)c1)N)c1-c1nc(cc(C(F)(F)F)nc2)c2[n]1C)(=O)=O Chemical compound CCS(c(cc(c(N)c1)N)c1-c1nc(cc(C(F)(F)F)nc2)c2[n]1C)(=O)=O BJVZNVHQAAJXBO-UHFFFAOYSA-N 0.000 description 1
- VQJMMBKQRFVMNP-UHFFFAOYSA-N CCS(c(cc(c(N)c1)NC=O)c1-c1nc2cc(C(F)(F)F)ncc2[n]1C)(=O)=O Chemical compound CCS(c(cc(c(N)c1)NC=O)c1-c1nc2cc(C(F)(F)F)ncc2[n]1C)(=O)=O VQJMMBKQRFVMNP-UHFFFAOYSA-N 0.000 description 1
- DNSHCPNUPQTYFF-UHFFFAOYSA-N CCS(c(cc1nc(-c2ccccc2)[nH]c1c1)c1-c1nc2cc(C(F)(F)F)ncc2[n]1C)(=O)=O Chemical compound CCS(c(cc1nc(-c2ccccc2)[nH]c1c1)c1-c1nc2cc(C(F)(F)F)ncc2[n]1C)(=O)=O DNSHCPNUPQTYFF-UHFFFAOYSA-N 0.000 description 1
- MRSVMBANQQEDEP-UHFFFAOYSA-O CCSc(c(C(O)=O)c1)cc(NC)c1[N+](O)=O Chemical compound CCSc(c(C(O)=O)c1)cc(NC)c1[N+](O)=O MRSVMBANQQEDEP-UHFFFAOYSA-O 0.000 description 1
- XWPRQXGDKYDEKA-UHFFFAOYSA-N CCSc1cc2ccccc2nc1C(O)=O Chemical compound CCSc1cc2ccccc2nc1C(O)=O XWPRQXGDKYDEKA-UHFFFAOYSA-N 0.000 description 1
- DACBKVWIMZHOOR-UHFFFAOYSA-N Cc(nc1)cc(NI)c1N Chemical compound Cc(nc1)cc(NI)c1N DACBKVWIMZHOOR-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/04—Ortho-condensed systems
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
- A01N43/52—1,3-Diazoles; Hydrogenated 1,3-diazoles condensed with carbocyclic rings, e.g. benzimidazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
- C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
- C07D491/04—Ortho-condensed systems
- C07D491/044—Ortho-condensed systems with only one oxygen atom as ring hetero atom in the oxygen-containing ring
- C07D491/048—Ortho-condensed systems with only one oxygen atom as ring hetero atom in the oxygen-containing ring the oxygen-containing ring being five-membered
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Catching Or Destruction (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14197275 | 2014-12-11 | ||
| EP15179050 | 2015-07-30 | ||
| PCT/EP2015/078609 WO2016091731A1 (en) | 2014-12-11 | 2015-12-04 | Pesticidally active tetracyclic derivatives with sulfur containing substituents |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2806598T3 true ES2806598T3 (es) | 2021-02-18 |
Family
ID=54780333
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES15804527T Active ES2806598T3 (es) | 2014-12-11 | 2015-12-04 | Derivados tetracíclicos activos como plaguicidas con sustituyentes que contienen azufre |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US10308650B2 (enExample) |
| EP (1) | EP3230284B1 (enExample) |
| JP (1) | JP6695879B2 (enExample) |
| CN (1) | CN107001364B (enExample) |
| BR (1) | BR112017012232B1 (enExample) |
| ES (1) | ES2806598T3 (enExample) |
| WO (1) | WO2016091731A1 (enExample) |
Families Citing this family (67)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| UY36547A (es) | 2015-02-05 | 2016-06-01 | Bayer Cropscience Ag | Derivados heterocíclicos condensados bicíclicos sustituidos por 2-(het)arilo como pesticidas |
| JP6774955B2 (ja) * | 2015-03-12 | 2020-10-28 | シンジェンタ パーティシペーションズ アーゲー | 硫黄含有置換基を有する殺有害生物的に活性な四環式誘導体 |
| WO2017026384A1 (ja) * | 2015-08-07 | 2017-02-16 | 日本農薬株式会社 | インダゾール化合物又はその塩類及び該化合物を含有する農園芸用殺虫剤並びにその使用方法 |
| US10550116B2 (en) | 2015-10-26 | 2020-02-04 | Bayer Cropscience Aktiengesellschaft | Fused bicyclic heterocycle derivatives as pesticides |
| CN108349970B (zh) | 2015-11-05 | 2021-03-05 | 住友化学株式会社 | 稠合杂环化合物 |
| WO2017093180A1 (de) | 2015-12-01 | 2017-06-08 | Bayer Cropscience Aktiengesellschaft | Kondensierte bicyclische heterocyclen-derivate als schädlingsbekämpfungsmittel |
| WO2017146220A1 (ja) * | 2016-02-26 | 2017-08-31 | 日本農薬株式会社 | 縮合複素環が結合したキノリン化合物、ｎ‐オキシド又はその塩類及び該化合物を含有する農園芸用殺虫剤並びにその使用方法 |
| EA036621B1 (ru) | 2016-03-10 | 2020-12-01 | Ниссан Кемикал Корпорейшн | Конденсированные гетероциклические соединения и пестициды |
| WO2017174414A1 (de) | 2016-04-05 | 2017-10-12 | Bayer Cropscience Aktiengesellschaft | Naphthalin-derivate als schädlingsbekämpfungsmittel |
| JP6630828B2 (ja) * | 2016-07-01 | 2020-01-15 | 日本農薬株式会社 | Ｎ‐アルキルスルホニル縮合複素環化合物又はその塩類及び該化合物を含有する殺虫剤並びにその使用方法 |
| MX2019000793A (es) | 2016-07-19 | 2019-06-20 | Bayer Cropscience Ag | Derivados de heterociclos biciclicos condensados como pesticidas. |
| EP3497102B1 (de) * | 2016-08-15 | 2022-12-07 | Bayer CropScience Aktiengesellschaft | Kondensierte bicyclische heterocyclen-derivate als schädlingsbekämpfungsmittel |
| JP2019206478A (ja) * | 2016-08-31 | 2019-12-05 | 日本農薬株式会社 | ３ｈ‐ピロロピリジン化合物及びｎ‐オキサイド、又はそれらの塩類及び該化合物を含有する農園芸用殺虫剤並びにその使用方法 |
| EP3515921B1 (de) | 2016-09-19 | 2021-10-27 | Bayer CropScience Aktiengesellschaft | Pyrazolo[1,5-a]pyridin- derivative und ihre verwendung als schädlingsbekämpfungsmittel |
| WO2018065288A1 (de) | 2016-10-07 | 2018-04-12 | Bayer Cropscience Aktiengesellschaft | 2-[2-phenyl-1-(sulfonylmethyl)vinyl]-imidazo[4,5-b]pyridin-derivate und verwandte verbindungen als schädlingsbekämpfungsmittel im pflanzenschutz |
| BR112019006354B1 (pt) * | 2016-10-13 | 2023-12-26 | Nihon Nohyaku Co., Ltd | Composto heterocíclico condensado 1h-pirrolo e seu uso, método para uso de um inseticida agrícola e hortícola, método para controle de pragas agrícolas e hortícolas, composição para controle de ectoparasita e seu uso |
| BR112019008952A2 (pt) | 2016-11-01 | 2019-07-09 | Nihon Nohyaku Co Ltd | composto de indolina n-alquilsulfonia, inseticida agrícola e hortícola compreendendo o composto e método para usar o inseticida |
| MX2019004906A (es) | 2016-11-01 | 2019-06-20 | Nihon Nohyaku Co Ltd | Compuesto de quinolina que contiene un grupo oxima, n-oxido del mismo o su sal, insecticida agricola y horticola que comprende el compuesto, y metodo para utilizar el insecticida. |
| KR20190084310A (ko) | 2016-11-23 | 2019-07-16 | 바이엘 크롭사이언스 악티엔게젤샤프트 | 살충제로서의 2-[3-(알킬술포닐)-2H-인다졸-2-일]-3H-이미다조[4,5-b]피리딘 유도체 및 유사한 화합물 |
| DK3548466T3 (da) | 2016-12-01 | 2022-04-19 | Syngenta Participations Ag | Fremgangsmåde til fremstilling af et mellemprodukt af pesticidaktive heterocykliske derivater med svovlindeholdende substituenter |
| WO2018105632A1 (ja) * | 2016-12-07 | 2018-06-14 | 日本農薬株式会社 | カーバメート基を有するキノリン化合物、又はその塩類及び該化合物を含有する農園芸用殺虫剤並びにその使用方法 |
| BR112019012127A2 (pt) | 2016-12-15 | 2019-11-05 | Syngenta Participations Ag | derivados heterocíclicos ativos em termos pesticidas com substituintes contendo enxofre |
| UA123249C2 (uk) * | 2016-12-27 | 2021-03-03 | Ніхон Нохіяку Ко., Лтд. | Сполука 4н-піролопіридину або її сіль, сільськогосподарський і садівницький інсектицид, який включає зазначену сполуку або її сіль, і спосіб застосування інсектициду |
| AU2018208422B2 (en) | 2017-01-10 | 2021-11-11 | Bayer Aktiengesellschaft | Heterocyclene derivatives as pest control agents |
| UY37556A (es) | 2017-01-10 | 2018-07-31 | Bayer Ag | Derivados heterocíclicos como pesticidas |
| WO2018138050A1 (de) * | 2017-01-26 | 2018-08-02 | Bayer Aktiengesellschaft | Kondensierte bicyclische heterocyclen-derivate als schädlingsbekämpfungsmittel |
| US20200216441A1 (en) * | 2017-04-25 | 2020-07-09 | Syngenta Participations Ag | Pesticidally active heterocyclic derivatives with sulfur containing substituents |
| ES2951425T3 (es) | 2017-04-27 | 2023-10-20 | Nihon Nohyaku Co Ltd | Compuesto heterocíclico condensado o sal del mismo, insecticida agrícola y hortícola que comprende el compuesto o la sal, y método para usar el insecticida |
| WO2018215304A1 (en) * | 2017-05-22 | 2018-11-29 | Syngenta Participations Ag | Tetracyclic pyridazine sulphur containing compounds and their use as pesticides |
| US11399542B2 (en) | 2017-07-05 | 2022-08-02 | Syngenta Participations Ag | Pesticidally active heterocyclic derivatives with sulfur containing substituents |
| WO2019038195A1 (de) | 2017-08-22 | 2019-02-28 | Bayer Aktiengesellschaft | Heterocyclen-derivate als schädlingsbekämpfungsmittel |
| JP7337810B2 (ja) | 2018-01-15 | 2023-09-04 | シンジェンタ パーティシペーションズ アーゲー | 硫黄含有置換基を有する殺有害生物的に活性な複素環式誘導体 |
| EP3305786A3 (de) | 2018-01-22 | 2018-07-25 | Bayer CropScience Aktiengesellschaft | Kondensierte bicyclische heterocyclen-derivate als schädlingsbekämpfungsmittel |
| CN111741958A (zh) | 2018-02-21 | 2020-10-02 | 拜耳公司 | 作为害虫防治剂的稠合双环杂环衍生物 |
| WO2019219689A1 (en) | 2018-05-18 | 2019-11-21 | Syngenta Participations Ag | Pesticidally active heterocyclic derivatives with sulfoximine containing substituents |
| AR115495A1 (es) | 2018-06-06 | 2021-01-27 | Syngenta Crop Protection Ag | Derivados heterocíclicos con sustituyentes que contienen azufre activos como plaguicidas |
| BR122023022434A2 (pt) | 2018-06-26 | 2024-02-20 | Bayer Aktiengesellschaft | Derivados de heterocicleno como agentes de controle de pragas |
| CN109860704B (zh) * | 2018-11-13 | 2020-10-23 | 东莞东阳光科研发有限公司 | 正极成膜添加剂、包含其的电解液及锂离子电池 |
| WO2020141135A1 (en) | 2018-12-31 | 2020-07-09 | Syngenta Crop Protection Ag | Pesticidally active heterocyclic derivatives with sulfur containing substituents |
| CN113710669A (zh) | 2019-02-26 | 2021-11-26 | 拜耳公司 | 作为农药的稠合双环杂环衍生物 |
| JP7535532B2 (ja) | 2019-02-26 | 2024-08-16 | バイエル・アクチエンゲゼルシヤフト | 有害生物防除剤としての縮合二環式複素環式誘導体 |
| WO2020182577A1 (en) | 2019-03-08 | 2020-09-17 | Syngenta Crop Protection Ag | Pesticidally active heterocyclic derivatives with sulfur containing substituents |
| AR119140A1 (es) | 2019-06-13 | 2021-11-24 | Pi Industries Ltd | Compuestos heterocíclicos fusionados y su uso como agentes de control de plagas |
| WO2020254530A1 (en) | 2019-06-18 | 2020-12-24 | Syngenta Crop Protection Ag | 7-sulfonyl-n-(1,3,4-thiadiazol-2-yl)-quinoxaline-6-carboxamide derivatives and the respective -benzimidazole-5-, -imidazo[4,5-b]pyridine-5-, -3h-furo[3,2b]pyridine-5-, -quinoline-2-, and -naphthalene-2-carboxamide derivatives as pesticides |
| US20230120895A1 (en) | 2019-12-31 | 2023-04-20 | Syngenta Crop Protection Ag | Pesticidally active heterocyclic derivatives with sulfur containing substituents |
| WO2021213929A1 (en) | 2020-04-20 | 2021-10-28 | Syngenta Crop Protection Ag | Pesticidally active substituted 1,3-dihydro-2h-imidazo[4,5-c]pyridin-2-one derivatives with sulfur containing substituents |
| WO2021224409A1 (en) | 2020-05-06 | 2021-11-11 | Syngenta Crop Protection Ag | Pesticidally active heterocyclic derivatives with sulfur containing substituents |
| US20230247994A1 (en) | 2020-07-02 | 2023-08-10 | Bayer Aktiengesellschaft | Heterocyclene derivatives as pest control agents |
| PY2175398A (es) | 2020-09-01 | 2022-05-06 | Syngenta Crop Protection Ag | Derivados de isoindolin-1-ona o 7h-pirrolo[3,4-b]piridin-5-ona activos como plaguicidas con sustituyentes que contienen azufre |
| US20240043431A1 (en) | 2020-12-14 | 2024-02-08 | Basf Se | Sulfoximine Pesticides |
| PY2203251A (es) | 2021-01-21 | 2023-01-18 | Syngenta Crop Protection Ag | Derivados heterocíclicos activos como plaguicidas con sustituyentes que contienen azufre |
| CN113582776B (zh) * | 2021-08-06 | 2022-05-31 | 安徽省司尔特肥业股份有限公司 | 一种大蒜硫包衣复混肥及其制备方法 |
| AR126700A1 (es) | 2021-08-10 | 2023-11-01 | Syngenta Crop Protection Ag | Derivados heterocíclicos activos como plaguicidas con sustituyentes que contienen azufre |
| UY39992A (es) | 2021-10-25 | 2023-05-15 | Syngenta Crop Protection Ag | Derivados heterocíclicos activos como plaguicidas con sustituyentes que contienen azufre |
| CN114149291B (zh) * | 2021-12-30 | 2022-07-22 | 河北萌帮水溶肥料股份有限公司 | 一种缓释型液体氮肥、制备方法及其在果树上的应用 |
| US12593840B2 (en) | 2022-01-24 | 2026-04-07 | Optimally Balanced Corp. | Pesticidal or repellant composition and method of use |
| UY40138A (es) | 2022-02-07 | 2023-08-31 | Syngenta Crop Protection Ag | Derivados de pirazolo[3,4-c]piridin-5-il]-2-quinoxalina o 2-quinolina activos como pesticidas con su |
| UY40139A (es) | 2022-02-07 | 2023-08-31 | Syngenta Crop Protection Ag | Derivados de imidazo[1,2-a]piridin-2-il]-1-pirazolo[3,4-c]piridina activos como pesticidas con susti |
| UY40202A (es) | 2022-04-01 | 2023-10-31 | Syngenta Crop Protection Ag | Derivados de pirazolopiridina activos como pesticidas con sustituyentes que contienen azufre |
| CN115181116B (zh) * | 2022-07-29 | 2024-11-26 | 江苏中旗科技股份有限公司 | 具有含硫取代基的稠环化合物、制备方法、杀虫剂组合物及用途 |
| WO2024089023A1 (en) | 2022-10-25 | 2024-05-02 | Syngenta Crop Protection Ag | Pesticidally active heterocyclic derivatives with sulfur containing substituents |
| CN120112528A (zh) | 2022-10-31 | 2025-06-06 | 先正达农作物保护股份公司 | 具有含硫取代基的杀有害生物活性的杂环衍生物 |
| WO2024126388A1 (en) | 2022-12-12 | 2024-06-20 | Syngenta Crop Protection Ag | Pesticidally active heterocyclic derivatives with sulfur containing substituents |
| CN120584105A (zh) | 2023-01-23 | 2025-09-02 | 先正达农作物保护股份公司 | 具有含硫取代基的杀有害生物活性的杂环衍生物 |
| EP4680028A1 (en) | 2023-03-14 | 2026-01-21 | Syngenta Crop Protection AG | Control of pests resistant to insecticides |
| WO2025026738A1 (en) | 2023-07-31 | 2025-02-06 | Bayer Aktiengesellschaft | 6-[5-(ethylsulfonyl)-1-methyl-1h-imidazol-4-yl]-7-methyl-3-(pentafluoroethyl)-7h-imidazo[4,5-c]pyridazine derivatives as pesticides |
| WO2026046204A1 (zh) * | 2024-08-27 | 2026-03-05 | 青岛清原化合物有限公司 | 一种取代的杂环化合物及其制备方法、杀虫组合物和应用 |
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| DE3445299A1 (de) * | 1984-12-12 | 1986-06-19 | Dr. Karl Thomae Gmbh, 7950 Biberach | Neue imidazoderivate, diese verbindungen enthaltende arzneimittel und verfahren zu ihrer herstellung |
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-
2015
- 2015-12-04 ES ES15804527T patent/ES2806598T3/es active Active
- 2015-12-04 EP EP15804527.8A patent/EP3230284B1/en active Active
- 2015-12-04 WO PCT/EP2015/078609 patent/WO2016091731A1/en not_active Ceased
- 2015-12-04 JP JP2017531155A patent/JP6695879B2/ja active Active
- 2015-12-04 CN CN201580066999.2A patent/CN107001364B/zh active Active
- 2015-12-04 US US15/534,734 patent/US10308650B2/en active Active
- 2015-12-04 BR BR112017012232-4A patent/BR112017012232B1/pt active IP Right Grant
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|---|---|
| US10308650B2 (en) | 2019-06-04 |
| EP3230284A1 (en) | 2017-10-18 |
| WO2016091731A1 (en) | 2016-06-16 |
| CN107001364A (zh) | 2017-08-01 |
| US20170349581A1 (en) | 2017-12-07 |
| JP6695879B2 (ja) | 2020-05-20 |
| EP3230284B1 (en) | 2020-04-15 |
| CN107001364B (zh) | 2020-06-16 |
| BR112017012232B1 (pt) | 2021-08-17 |
| JP2018501226A (ja) | 2018-01-18 |
| BR112017012232A2 (pt) | 2018-05-15 |
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