ES2464528T1 - Agentes espumantes y composiciones que contienen olefinas sustiuidas con flúor, y métodos de espumación - Google Patents
Agentes espumantes y composiciones que contienen olefinas sustiuidas con flúor, y métodos de espumación Download PDFInfo
- Publication number
- ES2464528T1 ES2464528T1 ES13166417.9T ES13166417T ES2464528T1 ES 2464528 T1 ES2464528 T1 ES 2464528T1 ES 13166417 T ES13166417 T ES 13166417T ES 2464528 T1 ES2464528 T1 ES 2464528T1
- Authority
- ES
- Spain
- Prior art keywords
- foam
- blowing agent
- composition
- forming
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims 17
- 238000000034 method Methods 0.000 title claims 5
- 238000005187 foaming Methods 0.000 title claims 2
- 150000001336 alkenes Chemical class 0.000 title 1
- 239000004088 foaming agent Substances 0.000 title 1
- 239000004604 Blowing Agent Substances 0.000 claims abstract 22
- 150000001875 compounds Chemical class 0.000 claims abstract 6
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 4
- 229910052801 chlorine Inorganic materials 0.000 claims abstract 3
- 229910052731 fluorine Inorganic materials 0.000 claims abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052794 bromium Inorganic materials 0.000 claims abstract 2
- 239000001257 hydrogen Substances 0.000 claims abstract 2
- 229910052740 iodine Inorganic materials 0.000 claims abstract 2
- 239000006260 foam Substances 0.000 claims 29
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 5
- 229920005862 polyol Polymers 0.000 claims 5
- 150000003077 polyols Chemical class 0.000 claims 5
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims 4
- 229920000582 polyisocyanurate Polymers 0.000 claims 4
- 239000011495 polyisocyanurate Substances 0.000 claims 4
- 229920001187 thermosetting polymer Polymers 0.000 claims 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims 3
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 claims 3
- 229920002635 polyurethane Polymers 0.000 claims 3
- 239000004814 polyurethane Substances 0.000 claims 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 229920005830 Polyurethane Foam Polymers 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 239000000460 chlorine Substances 0.000 claims 2
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims 2
- 150000002170 ethers Chemical class 0.000 claims 2
- 239000003063 flame retardant Substances 0.000 claims 2
- 150000002367 halogens Chemical group 0.000 claims 2
- 229930195733 hydrocarbon Natural products 0.000 claims 2
- 150000002430 hydrocarbons Chemical class 0.000 claims 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims 2
- 239000012948 isocyanate Substances 0.000 claims 2
- 150000002513 isocyanates Chemical class 0.000 claims 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 2
- 239000011496 polyurethane foam Substances 0.000 claims 2
- 239000004094 surface-active agent Substances 0.000 claims 2
- 229920001169 thermoplastic Polymers 0.000 claims 2
- 239000004416 thermosoftening plastic Substances 0.000 claims 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 150000001299 aldehydes Chemical class 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 claims 1
- 239000001273 butane Substances 0.000 claims 1
- 239000003086 colorant Substances 0.000 claims 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims 1
- 150000005690 diesters Chemical class 0.000 claims 1
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 claims 1
- KLKFAASOGCDTDT-UHFFFAOYSA-N ethoxymethoxyethane Chemical compound CCOCOCC KLKFAASOGCDTDT-UHFFFAOYSA-N 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 238000011065 in-situ storage Methods 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 239000001282 iso-butane Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims 1
- 150000003254 radicals Chemical class 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/228—Forming foamed products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/12—Organic compounds only containing carbon, hydrogen and oxygen atoms, e.g. ketone or alcohol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/16—Unsaturated hydrocarbons
- C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/18—Binary blends of expanding agents
- C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/20—Ternary blends of expanding agents
- C08J2203/202—Ternary blends of expanding agents of physical blowing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2361/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Molding Of Porous Articles (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US69385305P | 2005-06-24 | 2005-06-24 | |
| US693853P | 2005-06-24 | ||
| US78473106P | 2006-03-21 | 2006-03-21 | |
| US784731P | 2006-03-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2464528T1 true ES2464528T1 (es) | 2014-06-03 |
Family
ID=37595995
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES13166417.9T Pending ES2464528T1 (es) | 2005-06-24 | 2006-06-26 | Agentes espumantes y composiciones que contienen olefinas sustiuidas con flúor, y métodos de espumación |
| ES09173778T Active ES2338519T7 (es) | 2005-06-24 | 2006-06-26 | Espuma de aislamiento térmico que comprende HFO-1233zd como agente de soplado |
| ES13166420.3T Active ES2438525T3 (es) | 2005-06-24 | 2006-06-26 | Espuma termoestable que comprende HFCO-1233zd como agente de expansión |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES09173778T Active ES2338519T7 (es) | 2005-06-24 | 2006-06-26 | Espuma de aislamiento térmico que comprende HFO-1233zd como agente de soplado |
| ES13166420.3T Active ES2438525T3 (es) | 2005-06-24 | 2006-06-26 | Espuma termoestable que comprende HFCO-1233zd como agente de expansión |
Country Status (15)
| Country | Link |
|---|---|
| EP (3) | EP2154223B3 (enExample) |
| JP (12) | JP2008546892A (enExample) |
| KR (9) | KR20160018846A (enExample) |
| CN (1) | CN103497351B (enExample) |
| CA (1) | CA2613090C (enExample) |
| DE (3) | DE13166417T1 (enExample) |
| DK (2) | DK2154223T6 (enExample) |
| ES (3) | ES2464528T1 (enExample) |
| HK (1) | HK1243109A1 (enExample) |
| MX (4) | MX359510B (enExample) |
| MY (3) | MY155122A (enExample) |
| PL (1) | PL2154223T6 (enExample) |
| PT (1) | PT2154223E (enExample) |
| TW (5) | TWI626262B (enExample) |
| WO (1) | WO2007002703A2 (enExample) |
Families Citing this family (83)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2779979B2 (ja) | 1990-10-05 | 1998-07-23 | 内山工業株式会社 | 密封シールの製造方法 |
| US20090253820A1 (en) * | 2006-03-21 | 2009-10-08 | Honeywell International Inc. | Foaming agents and compositions containing fluorine sustituted olefins and methods of foaming |
| US20110037016A1 (en) * | 2003-10-27 | 2011-02-17 | Honeywell International Inc. | Fluoropropene compounds and compositions and methods using same |
| US9499729B2 (en) * | 2006-06-26 | 2016-11-22 | Honeywell International Inc. | Compositions and methods containing fluorine substituted olefins |
| US8008244B2 (en) | 2004-04-29 | 2011-08-30 | Honeywell International Inc. | Compositions of tetrafluoropropene and hydrocarbons |
| TWI708756B (zh) * | 2005-06-24 | 2020-11-01 | 美商哈尼威爾國際公司 | 含有經氟取代之烯烴之組合物 |
| CN101356217A (zh) * | 2005-11-01 | 2009-01-28 | 纳幕尔杜邦公司 | 用于形成泡沫的包含不饱和氟碳化合物的发泡剂 |
| US9695267B2 (en) | 2009-08-11 | 2017-07-04 | Honeywell International Inc. | Foams and foamable compositions containing halogenated olefin blowing agents |
| US9000061B2 (en) * | 2006-03-21 | 2015-04-07 | Honeywell International Inc. | Foams and articles made from foams containing 1-chloro-3,3,3-trifluoropropene (HFCO-1233zd) |
| GB2441006A (en) * | 2006-08-17 | 2008-02-20 | Ineos Fluor Holdings Ltd | Fluid Composition |
| CN101646724B (zh) * | 2007-03-27 | 2012-06-20 | 陶氏环球技术公司 | 包含氟化链烯烃发泡剂的链烯基芳族聚合物泡沫体 |
| US9234070B2 (en) | 2007-03-29 | 2016-01-12 | Arkema Inc. | Blowing agent composition of hydrochlorofluoroolefin |
| CN104962070B (zh) | 2007-03-29 | 2018-06-01 | 阿科玛股份有限公司 | 氢氯氟烯烃以及氢氟烯烃的发泡剂组合物 |
| US11208536B2 (en) | 2007-03-29 | 2021-12-28 | Arkema Inc. | Blowing agent compositions of hydrofluoroolefins and hydrochlorofluoroolefins |
| US11091602B2 (en) | 2007-03-29 | 2021-08-17 | Arkema Inc. | Blowing agent compositions of carbon dioxide and hydrochlorofluoroolefins |
| CN101652414B (zh) * | 2007-03-29 | 2012-06-27 | 阿科玛股份有限公司 | 用于热塑性塑料的氢氟丙烯发泡剂 |
| US9738768B2 (en) | 2007-03-29 | 2017-08-22 | Arkema Inc. | Blowing agent composition of hydrochlorofluoroolefin |
| US8895635B2 (en) | 2007-03-29 | 2014-11-25 | Arkema Inc. | Blowing agent compositions of hydrochlorofluoroolefins |
| EP2129709B2 (en) * | 2007-03-29 | 2021-05-12 | Arkema Inc. | Process for preparing thermosetting foams |
| US9206297B2 (en) | 2007-03-29 | 2015-12-08 | Arkema Inc. | Blowing agent compositions of hydrochlorofluoroolefins |
| US8114828B2 (en) * | 2007-04-16 | 2012-02-14 | Honeywell International Inc. | Azeotrope-like compositions of tetrafluoropropene and alcohols |
| WO2009035893A1 (en) | 2007-09-13 | 2009-03-19 | Arkema Inc. | Compositions containing a combination of z and e stereoisomers of hydrofluoroolefins |
| US20090099273A1 (en) * | 2007-10-12 | 2009-04-16 | Williams David J | Non-silicone surfactants for polyurethane or polyisocyanurate foam containing halogenated olefins as blowing agents |
| US9453115B2 (en) * | 2007-10-12 | 2016-09-27 | Honeywell International Inc. | Stabilization of polyurethane foam polyol premixes containing halogenated olefin blowing agents |
| US7479238B1 (en) | 2007-11-06 | 2009-01-20 | Arkema Inc. | Azeotrope-like composition of 1,1,1-trifluoro-3-chloropropene and methyl formate |
| CN101808966A (zh) | 2008-03-07 | 2010-08-18 | 阿科玛股份有限公司 | 用氯-3,3,3-三氟丙烯配制的稳定系统 |
| US7438826B1 (en) * | 2008-03-07 | 2008-10-21 | Arkema Inc. | Azeotrope-like composition of 1,1,1-trifluoro-3-chloropropene and methyl acetate |
| CN101688107A (zh) * | 2008-03-07 | 2010-03-31 | 阿科玛股份有限公司 | 具有改进的油返回的卤代烯热传输组合物 |
| US20090270522A1 (en) * | 2008-04-25 | 2009-10-29 | Honeywell International Inc. | Blowing agents for polymeric foams |
| CA3076129C (en) | 2008-05-07 | 2022-10-18 | The Chemours Company Fc, Llc | Compositions comprising 2,3-dichloro-1,1,1-trifluoropropane, 2-chloro-1,1,1-trifluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane or 2,3,3,3-tetrafluoropropene |
| CN102066521B (zh) | 2008-06-20 | 2013-11-13 | 纳幕尔杜邦公司 | Z-1，1，1，4，4，4-六氟-2-丁烯的共沸和类共沸组合物 |
| WO2010009090A2 (en) * | 2008-07-16 | 2010-01-21 | Honeywell International Inc. | Hfo-1234ze mixed isomers with hfc-245fa as a blowing agent, aerosol, and solvent |
| US8163196B2 (en) * | 2008-10-28 | 2012-04-24 | Honeywell International Inc. | Azeotrope-like compositions comprising 1-chloro-3,3,3-trifluoropropene |
| US20100122545A1 (en) | 2008-11-19 | 2010-05-20 | E. I. Du Pont De Nemours And Company | Tetrafluoropropene compositions and uses thereof |
| US8217208B2 (en) * | 2008-12-12 | 2012-07-10 | Honeywell International, Inc. | Isomerization of 1-chloro-3,3,3-trifluoropropene |
| US9815955B2 (en) | 2009-01-29 | 2017-11-14 | Arkema Inc. | Tetrafluoropropene based blowing agent compositions |
| CN102307832A (zh) | 2009-02-11 | 2012-01-04 | 阿克马法国公司 | 三氟氯丙烯和戊烷的共沸物和类共沸物组合物 |
| DE102009028061A1 (de) | 2009-07-29 | 2011-02-10 | Evonik Goldschmidt Gmbh | Verfahren zur Herstellung von Polyurethanschaum |
| US20110144216A1 (en) * | 2009-12-16 | 2011-06-16 | Honeywell International Inc. | Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene |
| GB201002616D0 (en) * | 2010-02-16 | 2010-03-31 | Ineos Fluor Holdings Ltd | Heat transfer compositions |
| GB201002617D0 (en) * | 2010-02-16 | 2010-03-31 | Ineos Fluor Holdings Ltd | Heat transfer compositions |
| WO2011144907A2 (en) * | 2010-05-20 | 2011-11-24 | Mexichem Amanco Holding S.A. De C.V. | Heat transfer compositions |
| US20120046372A1 (en) * | 2010-08-18 | 2012-02-23 | Honeywell International Inc. | Blowing agents, foamable compositions and foams |
| FR2968009B1 (fr) | 2010-11-25 | 2012-11-16 | Arkema France | Fluides frigorigenes contenant du (e)-1,1,1,4,4,4-hexafluorobut-2-ene |
| JP5881725B2 (ja) | 2010-11-25 | 2016-03-09 | アルケマ フランス | クロロトリフルオロプロペンとヘキサフルオロブテンとの組成物 |
| FR2968310B1 (fr) | 2010-12-03 | 2012-12-07 | Arkema France | Compositions a base de 1,1,1,4,4,4-hexafluorobut-2-ene et de 3,3,4,4,4-pentafluorobut-1-ene |
| FR2977256B1 (fr) | 2011-07-01 | 2013-06-21 | Arkema France | Compositions de 2,4,4,4-tetrafluorobut-1-ene et de cis-1,1,1,4,4,4-hexafluorobut-2-ene |
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