ES2338519T1 - Espuma de aislamiento termico que comprende hfo-1233zd como agente de soplado. - Google Patents
Espuma de aislamiento termico que comprende hfo-1233zd como agente de soplado. Download PDFInfo
- Publication number
- ES2338519T1 ES2338519T1 ES09173778T ES09173778T ES2338519T1 ES 2338519 T1 ES2338519 T1 ES 2338519T1 ES 09173778 T ES09173778 T ES 09173778T ES 09173778 T ES09173778 T ES 09173778T ES 2338519 T1 ES2338519 T1 ES 2338519T1
- Authority
- ES
- Spain
- Prior art keywords
- foam
- hfco
- blowing agent
- thermal insulation
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/228—Forming foamed products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/12—Organic compounds only containing carbon, hydrogen and oxygen atoms, e.g. ketone or alcohol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/16—Unsaturated hydrocarbons
- C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/18—Binary blends of expanding agents
- C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/20—Ternary blends of expanding agents
- C08J2203/202—Ternary blends of expanding agents of physical blowing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2361/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Molding Of Porous Articles (AREA)
Abstract
Una espuma de aislamiento térmico que comprende una pluralidad de celdillas de polímero y una composición contenida en al menos una de dichas celdillas, comprendiendo dicha composición al menos un agente de soplado que comprende HFCO-1233zd (1-cloro-3,3,3-trifluoro-propeno).
Claims (14)
1. Una espuma de aislamiento térmico que
comprende una pluralidad de celdillas de polímero y una composición
contenida en al menos una de dichas celdillas, comprendiendo dicha
composición al menos un agente de soplado que comprende
HFCO-1233zd
(1-cloro-3,3,3-trifluoro-propeno).
2. La espuma de aislamiento térmico de acuerdo
con la reivindicación 1, en donde la espuma es una espuma de
celdillas cerradas.
3. La espuma de la reivindicación 1, que tiene
un factor k (BTU in/hr ft^{2}ºF) a 40ºF (4,4ºC) no mayor que
aproximadamente 0,14 (0,0202 W/m.K), preferiblemente no mayor que
0,135 (0,0194 W/m.K), preferiblemente no mayor que 0,13 (0,0187
W/m.K).
4. La espuma de la reivindicación 1, que tiene
un factor k (BTU in/hr ft^{2}ºF) a 75ºF (23,9ºC) no mayor que
aproximadamente 0,16 (0,0230 W/m.K), preferiblemente no mayor que
0,15 (0,0216 W/m.K), preferiblemente no mayor que 0,145 (0,0209
W/m.K).
5. La espuma de la reivindicación 1, en donde la
espuma es una espuma de poliuretano, una espuma de poliisocianurato
o una espuma fenólica.
6. La espuma de la reivindicación 1, en donde el
agente de soplado consiste en HFCO-1233zd.
7. La espuma de la reivindicación 1, en donde el
HFCO-1233zd está presente en el agente de soplado en
cantidades de aproximadamente 5% en peso a aproximadamente 95% en
peso del agente de soplado.
8. La espuma de la reivindicación 1, en donde el
HFCO-1233zd es
cis-HFCO-1233zd.
9. La espuma de la reivindicación 1, en donde el
HFCO-1233zd es
trans-HFCO-1233zd.
10. La espuma de la reivindicación 1, en donde
la composición comprende adicionalmente al menos un agente de
cosoplado.
11. La espuma de la reivindicación 1, en donde
el al menos un agente de cosoplado se selecciona del grupo
constituido por agua, CO_{2}, CFCs, HCCs, HCFCs, alcoholes
C1-C5, aldehídos C1-C4, cetonas
C1-C4, éteres C1-C4, y
combinaciones de dos o más de estos.
12. Una espuma de aislamiento térmico de acuerdo
con cualquiera de las reivindicaciones anteriores, en donde la
espuma es una espuma termoendurecible que exhibe conductividad
térmica mejorada con relación a las espumas fabricadas utilizando
el mismo agente de soplado en la misma cantidad pero sin
HFCO-1233zd
(1-cloro-3,3,3-trifluoropropeno).
13. Un método de proporcionar una espuma de
aislamiento térmico de acuerdo con cualquiera de las
reivindicaciones anteriores, comprendiendo dicho método (a)
proporcionar una composición de agente de soplado que comprende al
menos un agente de soplado que comprende HFCO-1233zd
(1-cloro-3,3,3-trifluoropropeno);
(b) añadir la composición de agente de soplado a una composición
susceptible de transformarse en espuma; (c) hacer reaccionar la
composición susceptible de transformarse en espuma para formar una
espuma o estructura alveolar.
14. Uso de HFCO-1233zd
(1-cloro-3,3,3-trifluoropropeno)
para mejorar la conductividad térmica de una espuma
termoendurecible de aislamiento térmico con relación a las espumas
fabricadas utilizando el mismo agente de soplado en la misma
cantidad pero sin HFCO-1233zd
(1-cloro-3,3,3-trifluoropropeno).
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US69385305P | 2005-06-24 | 2005-06-24 | |
| US693853P | 2005-06-24 | ||
| US78473106P | 2006-03-21 | 2006-03-21 | |
| US784731P | 2006-03-21 |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| ES2338519T1 true ES2338519T1 (es) | 2010-05-10 |
| ES2338519T3 ES2338519T3 (es) | 2013-04-29 |
| ES2338519T5 ES2338519T5 (es) | 2018-03-28 |
| ES2338519T7 ES2338519T7 (es) | 2020-08-21 |
Family
ID=37595995
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES13166417.9T Pending ES2464528T1 (es) | 2005-06-24 | 2006-06-26 | Agentes espumantes y composiciones que contienen olefinas sustiuidas con flúor, y métodos de espumación |
| ES13166420.3T Active ES2438525T3 (es) | 2005-06-24 | 2006-06-26 | Espuma termoestable que comprende HFCO-1233zd como agente de expansión |
| ES09173778T Active ES2338519T7 (es) | 2005-06-24 | 2006-06-26 | Espuma de aislamiento térmico que comprende HFO-1233zd como agente de soplado |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES13166417.9T Pending ES2464528T1 (es) | 2005-06-24 | 2006-06-26 | Agentes espumantes y composiciones que contienen olefinas sustiuidas con flúor, y métodos de espumación |
| ES13166420.3T Active ES2438525T3 (es) | 2005-06-24 | 2006-06-26 | Espuma termoestable que comprende HFCO-1233zd como agente de expansión |
Country Status (15)
| Country | Link |
|---|---|
| EP (3) | EP2154223B3 (es) |
| JP (11) | JP2008546892A (es) |
| KR (9) | KR20140116458A (es) |
| CN (1) | CN103497351B (es) |
| CA (1) | CA2613090C (es) |
| DE (3) | DE13166417T1 (es) |
| DK (2) | DK2660282T3 (es) |
| ES (3) | ES2464528T1 (es) |
| HK (1) | HK1243109A1 (es) |
| MX (3) | MX2007016269A (es) |
| MY (3) | MY158385A (es) |
| PL (1) | PL2154223T6 (es) |
| PT (1) | PT2154223E (es) |
| TW (5) | TW201336906A (es) |
| WO (1) | WO2007002703A2 (es) |
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| PL2129714T3 (pl) * | 2007-03-29 | 2012-04-30 | Arkema Inc | Kompozycja środka porotwórczego złożona z fluoropropenu i chlorofluoroolefiny |
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