ES2215651T3 - Sistema catalizador. - Google Patents
Sistema catalizador.Info
- Publication number
- ES2215651T3 ES2215651T3 ES00926878T ES00926878T ES2215651T3 ES 2215651 T3 ES2215651 T3 ES 2215651T3 ES 00926878 T ES00926878 T ES 00926878T ES 00926878 T ES00926878 T ES 00926878T ES 2215651 T3 ES2215651 T3 ES 2215651T3
- Authority
- ES
- Spain
- Prior art keywords
- methyl
- zirconium
- indenyl
- dichloride
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 56
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 34
- 150000001336 alkenes Chemical class 0.000 claims abstract description 23
- 150000002902 organometallic compounds Chemical class 0.000 claims abstract description 14
- 125000004432 carbon atom Chemical group C* 0.000 claims description 128
- 125000004429 atom Chemical group 0.000 claims description 43
- 229910052799 carbon Inorganic materials 0.000 claims description 40
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 38
- 125000003118 aryl group Chemical group 0.000 claims description 34
- 125000000217 alkyl group Chemical group 0.000 claims description 33
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 23
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 21
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 14
- 229910052796 boron Inorganic materials 0.000 claims description 14
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 14
- 230000000737 periodic effect Effects 0.000 claims description 13
- 125000003545 alkoxy group Chemical group 0.000 claims description 12
- 229910052782 aluminium Inorganic materials 0.000 claims description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 125000004104 aryloxy group Chemical group 0.000 claims description 8
- 125000005843 halogen group Chemical group 0.000 claims description 8
- 229920000098 polyolefin Polymers 0.000 claims description 8
- 239000002879 Lewis base Substances 0.000 claims description 7
- 150000007527 lewis bases Chemical class 0.000 claims description 7
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 150000002894 organic compounds Chemical class 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 20
- 230000000694 effects Effects 0.000 abstract description 9
- 229920000642 polymer Polymers 0.000 abstract description 8
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 abstract description 5
- -1 Lewis acid cation Chemical class 0.000 description 201
- 229910052726 zirconium Inorganic materials 0.000 description 100
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 97
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 60
- 150000001875 compounds Chemical class 0.000 description 46
- DLZBYCXOUIHLLE-UHFFFAOYSA-N CC(C=C12)=CC1=CC(C=[Si](C)C)N2C1=CC=CC=C1.Cl.Cl Chemical compound CC(C=C12)=CC1=CC(C=[Si](C)C)N2C1=CC=CC=C1.Cl.Cl DLZBYCXOUIHLLE-UHFFFAOYSA-N 0.000 description 31
- GQSCEJKPOMCHIB-UHFFFAOYSA-N Cl.Cl.C[Si](=CC1=CC2=CC=NC2=C1)C Chemical compound Cl.Cl.C[Si](=CC1=CC2=CC=NC2=C1)C GQSCEJKPOMCHIB-UHFFFAOYSA-N 0.000 description 30
- UXOXZLJDEBFVCE-UHFFFAOYSA-N CC1=CC2=CC(C=[Si](C)C)=NC2=C1.Cl.Cl Chemical compound CC1=CC2=CC(C=[Si](C)C)=NC2=C1.Cl.Cl UXOXZLJDEBFVCE-UHFFFAOYSA-N 0.000 description 29
- 239000000243 solution Substances 0.000 description 29
- ZQISBCHURHITMZ-UHFFFAOYSA-N CC1=CC2=CC(C=[Si](C)C)OC2=C1.Cl.Cl Chemical compound CC1=CC2=CC(C=[Si](C)C)OC2=C1.Cl.Cl ZQISBCHURHITMZ-UHFFFAOYSA-N 0.000 description 28
- GEJFBLUJSIHYQR-UHFFFAOYSA-N C[Si](C)=CC(C=C12)=CC1=CCN2C1=CC=CC=C1.Cl.Cl Chemical compound C[Si](C)=CC(C=C12)=CC1=CCN2C1=CC=CC=C1.Cl.Cl GEJFBLUJSIHYQR-UHFFFAOYSA-N 0.000 description 28
- MVMROCNZSAQJFO-UHFFFAOYSA-N C[Si](C)=CC1=CC2=CCSC2=C1.Cl.Cl Chemical compound C[Si](C)=CC1=CC2=CCSC2=C1.Cl.Cl MVMROCNZSAQJFO-UHFFFAOYSA-N 0.000 description 28
- LYSPDWQBNFDNAH-UHFFFAOYSA-N Cl.Cl.C[Si](=CC1=CC2=CCOC2=C1)C Chemical compound Cl.Cl.C[Si](=CC1=CC2=CCOC2=C1)C LYSPDWQBNFDNAH-UHFFFAOYSA-N 0.000 description 28
- AHMZSLUWTLJNAT-UHFFFAOYSA-N Cl.Cl.C[Si](=CC1C=C2C=C(C=C2S1)C)C Chemical compound Cl.Cl.C[Si](=CC1C=C2C=C(C=C2S1)C)C AHMZSLUWTLJNAT-UHFFFAOYSA-N 0.000 description 28
- 239000007983 Tris buffer Substances 0.000 description 21
- 239000002904 solvent Substances 0.000 description 18
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 17
- QFHLJFLPBBLMKV-UHFFFAOYSA-N C[Si](C)=CC1=CC2=CN=CC2=C1.Cl.Cl Chemical compound C[Si](C)=CC1=CC2=CN=CC2=C1.Cl.Cl QFHLJFLPBBLMKV-UHFFFAOYSA-N 0.000 description 15
- JWEZRUZSQYYRGH-UHFFFAOYSA-N C[Si](C)=CC1=CC2=COCC2=C1.Cl.Cl Chemical compound C[Si](C)=CC1=CC2=COCC2=C1.Cl.Cl JWEZRUZSQYYRGH-UHFFFAOYSA-N 0.000 description 14
- YTALVOIDLUNAOV-UHFFFAOYSA-N Cl.Cl.C[Si](=CC1=CC2=CN(CC2=C1)C1=CC=CC=C1)C Chemical compound Cl.Cl.C[Si](=CC1=CC2=CN(CC2=C1)C1=CC=CC=C1)C YTALVOIDLUNAOV-UHFFFAOYSA-N 0.000 description 14
- MHVWIHLCDFDLCF-UHFFFAOYSA-N Cl.Cl.C[Si](=CC1=CC2=CSCC2=C1)C Chemical compound Cl.Cl.C[Si](=CC1=CC2=CSCC2=C1)C MHVWIHLCDFDLCF-UHFFFAOYSA-N 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 10
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 10
- 238000003786 synthesis reaction Methods 0.000 description 10
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 10
- 238000001035 drying Methods 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 9
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 239000000725 suspension Substances 0.000 description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 238000004293 19F NMR spectroscopy Methods 0.000 description 6
- 238000005160 1H NMR spectroscopy Methods 0.000 description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 6
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 5
- 238000006297 dehydration reaction Methods 0.000 description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
- 230000035484 reaction time Effects 0.000 description 5
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 5
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 4
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000004913 activation Effects 0.000 description 4
- 125000003342 alkenyl group Chemical group 0.000 description 4
- 239000004305 biphenyl Chemical group 0.000 description 4
- 235000010290 biphenyl Nutrition 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- 230000018044 dehydration Effects 0.000 description 4
- QKIUAMUSENSFQQ-UHFFFAOYSA-N dimethylazanide Chemical compound C[N-]C QKIUAMUSENSFQQ-UHFFFAOYSA-N 0.000 description 4
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 4
- 229910052735 hafnium Inorganic materials 0.000 description 4
- 239000003446 ligand Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 3
- NOXLGCOSAFGMDV-UHFFFAOYSA-N 2,3,4,5,6-pentafluoroaniline Chemical compound NC1=C(F)C(F)=C(F)C(F)=C1F NOXLGCOSAFGMDV-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 239000003426 co-catalyst Substances 0.000 description 3
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 3
- 229910052809 inorganic oxide Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000037048 polymerization activity Effects 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 3
- ODYJFRXBTXXNNM-UHFFFAOYSA-N (5-methyl-2H-cyclopenta[b]furan-2-yl)methylidene-diphenylsilane Chemical compound C1(=CC=CC=C1)[Si](=CC1OC2=CC(=CC2=C1)C)C1=CC=CC=C1 ODYJFRXBTXXNNM-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- XBNGYFFABRKICK-UHFFFAOYSA-N 2,3,4,5,6-pentafluorophenol Chemical compound OC1=C(F)C(F)=C(F)C(F)=C1F XBNGYFFABRKICK-UHFFFAOYSA-N 0.000 description 2
- DIOYAVUHUXAUPX-ZHACJKMWSA-N 2-[methyl-[(e)-octadec-9-enoyl]amino]acetic acid Chemical class CCCCCCCC\C=C\CCCCCCCC(=O)N(C)CC(O)=O DIOYAVUHUXAUPX-ZHACJKMWSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- FLFNHHSXSLXYQB-UHFFFAOYSA-L CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr](Cl)(Cl)(=[Si](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 Chemical compound CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr](Cl)(Cl)(=[Si](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 FLFNHHSXSLXYQB-UHFFFAOYSA-L 0.000 description 2
- XIZJWPPQILWRBR-UHFFFAOYSA-L C[Si](=CC1=CC2=CC=NC2=C1)C.[Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+2] Chemical compound C[Si](=CC1=CC2=CC=NC2=C1)C.[Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+2] XIZJWPPQILWRBR-UHFFFAOYSA-L 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000002841 Lewis acid Substances 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- IZUGOOYQOPXHBA-UHFFFAOYSA-L [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+2].C[Si](=CC1=CC2=CCN(C2=C1)C1=CC=CC=C1)C Chemical compound [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+2].C[Si](=CC1=CC2=CCN(C2=C1)C1=CC=CC=C1)C IZUGOOYQOPXHBA-UHFFFAOYSA-L 0.000 description 2
- UPMMFHJQODKNRE-UHFFFAOYSA-L [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+2].C[Si](=CC1=CC2=CCSC2=C1)C Chemical compound [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+2].C[Si](=CC1=CC2=CCSC2=C1)C UPMMFHJQODKNRE-UHFFFAOYSA-L 0.000 description 2
- RBXUTPCHOIIPIL-UHFFFAOYSA-L [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+2].C[Si](=CC1=CC2=NC=CC2=C1)C Chemical compound [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+2].C[Si](=CC1=CC2=NC=CC2=C1)C RBXUTPCHOIIPIL-UHFFFAOYSA-L 0.000 description 2
- GCZFNFDDULYHIJ-UHFFFAOYSA-L [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+2].C[Si](=CC1=NC2=CC(=CC2=C1)C)C Chemical compound [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+2].C[Si](=CC1=NC2=CC(=CC2=C1)C)C GCZFNFDDULYHIJ-UHFFFAOYSA-L 0.000 description 2
- QLBSZWMIJXMMDQ-UHFFFAOYSA-L [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+2].C[Si](=CC1C=C2C=C(C=C2N1C1=CC=CC=C1)C)C Chemical compound [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+2].C[Si](=CC1C=C2C=C(C=C2N1C1=CC=CC=C1)C)C QLBSZWMIJXMMDQ-UHFFFAOYSA-L 0.000 description 2
- JGHVGXQGKURBSJ-UHFFFAOYSA-L [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+2].C[Si](=CC1SC2=CC(=CC2=C1)C)C Chemical compound [Cl-].[Cl-].C1(C=CC2=CC=CC=C12)[Zr+2].C[Si](=CC1SC2=CC(=CC2=C1)C)C JGHVGXQGKURBSJ-UHFFFAOYSA-L 0.000 description 2
- QPTFKVRTGRGJQA-UHFFFAOYSA-L [Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+2].C[Si](=CC1=NC2=CC(=CC2=C1)C)C Chemical compound [Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+2].C[Si](=CC1=NC2=CC(=CC2=C1)C)C QPTFKVRTGRGJQA-UHFFFAOYSA-L 0.000 description 2
- YZEQRDUSXRUUTA-UHFFFAOYSA-L [Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+2].C[Si](=CC1C=C2C=C(C=C2N1C1=CC=CC=C1)C)C Chemical compound [Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+2].C[Si](=CC1C=C2C=C(C=C2N1C1=CC=CC=C1)C)C YZEQRDUSXRUUTA-UHFFFAOYSA-L 0.000 description 2
- KLDILJQYUFNGSM-UHFFFAOYSA-L [Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+2].C[Si](=CC1C=C2C=C(C=C2O1)C)C Chemical compound [Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Zr+2].C[Si](=CC1C=C2C=C(C=C2O1)C)C KLDILJQYUFNGSM-UHFFFAOYSA-L 0.000 description 2
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- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- NRQNMMBQPIGPTB-UHFFFAOYSA-N methylaluminum Chemical compound [CH3].[Al] NRQNMMBQPIGPTB-UHFFFAOYSA-N 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- JZBZLRKFJWQZHU-UHFFFAOYSA-N n,n,2,4,6-pentamethylaniline Chemical compound CN(C)C1=C(C)C=C(C)C=C1C JZBZLRKFJWQZHU-UHFFFAOYSA-N 0.000 description 1
- JBGNFLUETJDDBA-UHFFFAOYSA-N n,n-bis(trifluoromethyl)aniline Chemical compound FC(F)(F)N(C(F)(F)F)C1=CC=CC=C1 JBGNFLUETJDDBA-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Chemical class 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229920006395 saturated elastomer Chemical group 0.000 description 1
- 229930195734 saturated hydrocarbon Chemical group 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Chemical group 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- XBFJAVXCNXDMBH-UHFFFAOYSA-N tetracyclo[6.2.1.1(3,6).0(2,7)]dodec-4-ene Chemical compound C1C(C23)C=CC1C3C1CC2CC1 XBFJAVXCNXDMBH-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 125000005147 toluenesulfonyl group Chemical group C=1(C(=CC=CC1)S(=O)(=O)*)C 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical compound CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 description 1
- 125000004044 trifluoroacetyl group Chemical group FC(C(=O)*)(F)F 0.000 description 1
- 125000001889 triflyl group Chemical group FC(F)(F)S(*)(=O)=O 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 1
- GIIXTFIYICRGMZ-UHFFFAOYSA-N tris(2,3-dimethylphenyl)phosphane Chemical compound CC1=CC=CC(P(C=2C(=C(C)C=CC=2)C)C=2C(=C(C)C=CC=2)C)=C1C GIIXTFIYICRGMZ-UHFFFAOYSA-N 0.000 description 1
- COIOYMYWGDAQPM-UHFFFAOYSA-N tris(2-methylphenyl)phosphane Chemical compound CC1=CC=CC=C1P(C=1C(=CC=CC=1)C)C1=CC=CC=C1C COIOYMYWGDAQPM-UHFFFAOYSA-N 0.000 description 1
- 229930195735 unsaturated hydrocarbon Chemical group 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19917985 | 1999-04-21 | ||
| DE19917985A DE19917985A1 (de) | 1999-04-21 | 1999-04-21 | Katalysatorsystem |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2215651T3 true ES2215651T3 (es) | 2004-10-16 |
Family
ID=7905294
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES00926878T Expired - Lifetime ES2215651T3 (es) | 1999-04-21 | 2000-04-12 | Sistema catalizador. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6949614B1 (https=) |
| EP (1) | EP1175262B1 (https=) |
| JP (1) | JP2002542342A (https=) |
| KR (1) | KR20020010609A (https=) |
| CN (1) | CN1137148C (https=) |
| AT (1) | ATE259675T1 (https=) |
| AU (1) | AU4547800A (https=) |
| BR (1) | BR0009871B1 (https=) |
| DE (2) | DE19917985A1 (https=) |
| ES (1) | ES2215651T3 (https=) |
| WO (1) | WO2000062928A1 (https=) |
| ZA (1) | ZA200108611B (https=) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG74749A1 (en) * | 1998-09-09 | 2000-08-22 | Sumitomo Chemical Co | Modified aluminium oxy compound polymerization catalyst and process for producing olefin polymer and alkenyl aromatic hydrocaron polymer |
| SG83828A1 (en) | 1999-12-27 | 2001-10-16 | Sumitomo Chemical Co | Catalyst for addition polymerization, and process for producing addition polymer with the same |
| EP1446429B1 (en) | 2001-06-12 | 2009-10-07 | Basell Polyolefine GmbH | Process for the polymerization of 1-butene |
| US7459511B2 (en) | 2001-06-12 | 2008-12-02 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
| ATE353343T1 (de) | 2001-11-12 | 2007-02-15 | Basell Polyolefine Gmbh | Verfahren zur polymerisation von 1-buten und 1- buten polymeren |
| AU2003257456A1 (en) | 2002-07-15 | 2004-02-02 | Basell Polyolefine Gmbh | Preparation of supported catalyst systems |
| WO2004022613A1 (en) | 2002-09-06 | 2004-03-18 | Basell Polyolefine Gmbh | Process for the copolymerization of ethylene |
| JP2006502260A (ja) | 2002-10-10 | 2006-01-19 | バセル ポリオレフィン ジーエムビーエイチ | エチレンの共重合方法 |
| US7414005B2 (en) | 2002-11-04 | 2008-08-19 | Basell Polyolefine Gmbh | Preparation of catalyst compositions having improved activity |
| DE60329523D1 (de) | 2002-12-04 | 2009-11-12 | Basell Polyolefine Gmbh | 1-Buten-Copolymere und Herstellungsverfahren dafür |
| US7589160B2 (en) | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
| US7390862B2 (en) | 2003-05-12 | 2008-06-24 | Basell Polyolefine Gmbh | Process for polymerizing 1-butene |
| CN100390207C (zh) * | 2004-04-26 | 2008-05-28 | 中国科学院化学研究所 | 一种聚烯烃复合材料的制备方法 |
| CN100471881C (zh) * | 2004-04-26 | 2009-03-25 | 中国科学院化学研究所 | 一种负载型茂金属催化剂的制备方法 |
| PL1805231T3 (pl) | 2004-10-18 | 2010-08-31 | Basell Poliolefine Italia Srl | (Ko)polimery butenu-1 o niskiej izotaktyczności |
| EP1802669B1 (en) | 2004-10-21 | 2011-03-09 | Basell Polyolefine GmbH | 1-butene polymer and process for the preparation thereof |
| RU2410388C2 (ru) | 2005-03-18 | 2011-01-27 | Базелль Полиолефине Гмбх | Металлоценовые соединения |
| US7803887B2 (en) | 2005-03-18 | 2010-09-28 | Basell Polyolefine Gmbh | Metallocene compounds |
| CN101146836B (zh) | 2005-03-23 | 2011-06-08 | 巴塞尔聚烯烃股份有限公司 | 烯烃聚合方法 |
| US7799880B2 (en) | 2005-03-23 | 2010-09-21 | Basell Polyolefine Gmbh | Process for the polymerization of olefins |
| WO2006117285A1 (en) | 2005-05-03 | 2006-11-09 | Basell Polyolefine Gmbh | Process for the polymerization of alpha olefins |
| ATE515533T1 (de) | 2005-05-11 | 2011-07-15 | Basell Poliolefine Srl | Polymerisationsverfahren zur herstellung von polyolefinblends |
| US7232869B2 (en) | 2005-05-17 | 2007-06-19 | Novolen Technology Holdings, C.V. | Catalyst composition for olefin polymerization |
| US8051611B2 (en) * | 2005-06-24 | 2011-11-08 | Dryvit Systems, Inc. | Exterior insulation and finish system and method and tool for installing same |
| WO2007003528A2 (en) * | 2005-06-30 | 2007-01-11 | Basell Polyolefine Gmbh | Metallocene compounds |
| EP2041188B1 (en) * | 2006-07-17 | 2017-06-14 | Albemarle Corporation | Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins |
| WO2008076632A2 (en) * | 2006-12-14 | 2008-06-26 | Albemarle Corporation | Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins |
| WO2008141928A1 (en) * | 2007-05-23 | 2008-11-27 | Basell Polyolefine Gmbh | Insecticidal composition and articles obtained thereof |
| RU2463788C2 (ru) * | 2007-05-23 | 2012-10-20 | Базелль Полиолефине Гмбх | Инсектицидная композиция и изделия, полученные из нее |
| ATE485318T1 (de) * | 2007-06-25 | 2010-11-15 | Basell Polyolefine Gmbh | 1-butenethylencopolymere |
| KR100905544B1 (ko) * | 2007-08-13 | 2009-07-01 | 금호석유화학 주식회사 | 이형원자가 배위된 단분자 알루미늄과 코발트가 함유된촉매와 이를 이용한 폴리부타디엔의 제조방법 |
| ATE543870T1 (de) * | 2008-03-20 | 2012-02-15 | Basell Poliolefine Srl | Zusammensetzungen aus polymeren auf 1-buten-basis |
| JP2011515517A (ja) * | 2008-03-20 | 2011-05-19 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | １−ブテンコポリマー |
| EP2254918A1 (en) * | 2008-03-20 | 2010-12-01 | Basell Poliolefine Italia S.R.L. | 1-butene terpolymers |
| EP2254917A1 (en) * | 2008-03-20 | 2010-12-01 | Basell Poliolefine Italia S.R.L. | 1-butene copolymers |
| BRPI0910453A2 (pt) * | 2008-04-22 | 2018-03-27 | Basell Poliolefine Italia S.R.L | terpolímeros de 1-buteno |
| BRPI0918979B1 (pt) * | 2008-09-24 | 2019-05-07 | Basell Poliolefine Italia S.R.L. | Composições de poliolefina com boa resistência ao branqueamento |
| US9006341B2 (en) * | 2008-12-19 | 2015-04-14 | Basell Poliolefine Italia S.R.L. | Polyolefin fibres |
| WO2011061151A1 (en) | 2009-11-17 | 2011-05-26 | Basell Polyolefine Gmbh | Ethylene copolymers |
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| US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
| US9458260B2 (en) | 2013-07-17 | 2016-10-04 | Exxonmobil Chemical Patents Inc. | Process using substituted metallocene catalysts and products therefrom |
| WO2015009472A1 (en) | 2013-07-17 | 2015-01-22 | Exxonmobil Chemcal Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
| US9458254B2 (en) | 2013-07-17 | 2016-10-04 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
| US10294316B2 (en) | 2015-06-05 | 2019-05-21 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
| US10280233B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst systems and methods of making and using the same |
| US10570219B2 (en) | 2015-06-05 | 2020-02-25 | Exxonmobil Chemical Patents Inc. | Production of heterophasic polymers in gas or slurry phase |
| US10723821B2 (en) | 2015-06-05 | 2020-07-28 | Exxonmobil Chemical Patents Inc. | Supported metallocene catalyst systems for polymerization |
| US10329360B2 (en) | 2015-06-05 | 2019-06-25 | Exxonmobil Chemical Patents Inc. | Catalyst system comprising supported alumoxane and unsupported alumoxane particles |
| US10759886B2 (en) | 2015-06-05 | 2020-09-01 | Exxonmobil Chemical Patents Inc. | Single reactor production of polymers in gas or slurry phase |
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| DE19733017A1 (de) * | 1997-07-31 | 1999-02-04 | Hoechst Ag | Chemische Verbindung |
| FR2769245B1 (fr) | 1997-10-02 | 1999-10-29 | Atochem Elf Sa | Support solide activateur des catalyseurs metallocenes en polymerisation des olefines, son procede de preparation, systeme catalytique et procede de polymerisation correspondants |
| DE19757540A1 (de) * | 1997-12-23 | 1999-06-24 | Hoechst Ag | Geträgertes Katalysatorsystem zur Polymerisation von Olefinen |
| DE19804970A1 (de) * | 1998-02-07 | 1999-08-12 | Aventis Res & Tech Gmbh & Co | Katalysatorsystem |
| JP4440355B2 (ja) * | 1998-03-25 | 2010-03-24 | 住友化学株式会社 | 改質された粒子、それよりなる担体、それよりなるオレフィン重合用触媒成分、それを用いてなるオレフィン重合用触媒、およびオレフィン重合体の製造方法 |
| CA2235175A1 (en) | 1998-04-17 | 1999-10-17 | Bayer Inc. | Olefin polymerization process and catalyst system therfor |
| DE59910526D1 (de) * | 1998-04-21 | 2004-10-21 | Basell Polyolefine Gmbh | Katalysatorsystem mit metallocenen mit fluorhaltigen substituenten |
| EP1082353B1 (de) * | 1998-05-23 | 2006-02-22 | Basell Polyolefine GmbH | Katalysatorsystem und seine verwendung zur polymerisation von propylen |
| DE19828271A1 (de) * | 1998-06-25 | 1999-12-30 | Elenac Gmbh | Verfahren zur Herstellung eines geträgerten Katalysatorsystems |
-
1999
- 1999-04-21 DE DE19917985A patent/DE19917985A1/de not_active Withdrawn
-
2000
- 2000-04-12 WO PCT/EP2000/003263 patent/WO2000062928A1/de not_active Ceased
- 2000-04-12 JP JP2000612058A patent/JP2002542342A/ja active Pending
- 2000-04-12 BR BRPI0009871-0A patent/BR0009871B1/pt not_active IP Right Cessation
- 2000-04-12 EP EP00926878A patent/EP1175262B1/de not_active Expired - Lifetime
- 2000-04-12 DE DE50005332T patent/DE50005332D1/de not_active Expired - Fee Related
- 2000-04-12 AT AT00926878T patent/ATE259675T1/de not_active IP Right Cessation
- 2000-04-12 KR KR1020017013418A patent/KR20020010609A/ko not_active Abandoned
- 2000-04-12 CN CNB008064636A patent/CN1137148C/zh not_active Expired - Fee Related
- 2000-04-12 US US09/980,926 patent/US6949614B1/en not_active Expired - Fee Related
- 2000-04-12 AU AU45478/00A patent/AU4547800A/en not_active Abandoned
- 2000-04-12 ES ES00926878T patent/ES2215651T3/es not_active Expired - Lifetime
-
2001
- 2001-10-19 ZA ZA200108611A patent/ZA200108611B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU4547800A (en) | 2000-11-02 |
| ATE259675T1 (de) | 2004-03-15 |
| JP2002542342A (ja) | 2002-12-10 |
| EP1175262B1 (de) | 2004-02-18 |
| US6949614B1 (en) | 2005-09-27 |
| DE19917985A1 (de) | 2000-10-26 |
| CN1137148C (zh) | 2004-02-04 |
| KR20020010609A (ko) | 2002-02-04 |
| BR0009871A (pt) | 2002-01-08 |
| BR0009871B1 (pt) | 2010-10-05 |
| CN1347343A (zh) | 2002-05-01 |
| ZA200108611B (en) | 2002-10-21 |
| WO2000062928A1 (de) | 2000-10-26 |
| EP1175262A1 (de) | 2002-01-30 |
| DE50005332D1 (de) | 2004-03-25 |
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