ES2160289T3 - Sistema catalizador soportado, un procedimiento para su obtencion y su empleo para la polimerizacion de olefinas. - Google Patents
Sistema catalizador soportado, un procedimiento para su obtencion y su empleo para la polimerizacion de olefinas.Info
- Publication number
- ES2160289T3 ES2160289T3 ES97113406T ES97113406T ES2160289T3 ES 2160289 T3 ES2160289 T3 ES 2160289T3 ES 97113406 T ES97113406 T ES 97113406T ES 97113406 T ES97113406 T ES 97113406T ES 2160289 T3 ES2160289 T3 ES 2160289T3
- Authority
- ES
- Spain
- Prior art keywords
- halo
- group
- tri
- compound
- procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerization Catalysts (AREA)
Abstract
LA PRESENTE INVENCION SE REFIERE A UN SISTEMA CATALIZADOR SUBSTRATO, A UN PROCEDIMIENTO PARA SU PRODUCCION Y A SU USO PARA LA POLIMERIZACION DE OLEFINAS. EL SISTEMA CATALIZADOR SUBSTRATO CONTIENE AL MENOS UN COMPUESTO DE UN METAL DE TRANSICION DE LOS GRUPO ADYACENTES III, IV, V O VI DEL SISTEMA PERIODICO DE LOS ELEMENTOS, AL MENOS UN COCATALIZADOR DE FORMULA GENERAL (II) DONDE R SUP,6} O X SON CADA UNO DE ELLOS INDEPENDIENTEMENTE EL MISMO O DISTINTO ATOMO DE HALOGENO (EXCLUIDO PARA X) O UN GRUPO QUE CONTIENE CARBONO C SUP,1} INDEPENDIENTEMENTE IGUAL O DISTINTOS Y REPRESENTAN UN ELEMENTO DEL GRUPO IIA, IIIA, IV O VA DEL SISTEMA PERIODICO DE LOS ELEMENTOS, A ES UN NUMERO ENTERO ENTRE 0 Y 1, B ES UN NUMERO ENTERO ENTRE 0 Y 10, C ES UN NUMERO ENTERO ENTRE 0 Y 10 Y A =B C, N ES IGUAL A 0 O 1, M ES IGUAL A 0 O 1, L ES IGUAL A 0 O 1, G ES UN NUMERO ENTERO ENTRE 0 Y 10, H ES UN NUMERO ENTERO ENTRE 0 Y 10, P ES UN NUMERO ENTERO ENTRE 0 Y 10, I ES UN NUMERO ENTERO ENTRE 0 Y 1000, J ES UN NUMERO ENTERO ENTRE 1 Y 6, A ES UN CATION DEL GRUPO IA, IIA, IIIA DEL SISTEMA PERIODICO DE LOS ELEMENTOS, UN CATION DE CARBENIO, OXONIO O SULFONIO O UN COMPUESTO DE AMONIO CUATERNARIO.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1996132557 DE19632557A1 (de) | 1996-08-13 | 1996-08-13 | Chemische Verbindung |
DE19634703 | 1996-08-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2160289T3 true ES2160289T3 (es) | 2001-11-01 |
Family
ID=26028353
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES97113406T Expired - Lifetime ES2160289T3 (es) | 1996-08-13 | 1997-08-04 | Sistema catalizador soportado, un procedimiento para su obtencion y su empleo para la polimerizacion de olefinas. |
Country Status (9)
Country | Link |
---|---|
US (1) | US6124231A (es) |
EP (1) | EP0824113B2 (es) |
JP (1) | JP4105783B2 (es) |
KR (1) | KR19980018627A (es) |
CN (1) | CN1174205A (es) |
AT (1) | ATE202365T1 (es) |
BR (1) | BR9704310A (es) |
DE (1) | DE59703850D1 (es) |
ES (1) | ES2160289T3 (es) |
Families Citing this family (55)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19622207A1 (de) * | 1996-06-03 | 1997-12-04 | Hoechst Ag | Chemische Verbindung |
JP2001512127A (ja) * | 1997-08-01 | 2001-08-21 | ザ ダウ ケミカル カンパニー | 触媒活性剤 |
TR200002404T2 (tr) * | 1998-02-20 | 2001-01-22 | The Dow Chemical Company | Genişletilmiş anyonlar ihtiva eden katalizör etkinleştiriciler |
US6716786B1 (en) | 1998-02-20 | 2004-04-06 | The Dow Chemical Company | Supported catalyst comprising expanded anions |
DE19808253A1 (de) * | 1998-02-27 | 1999-09-02 | Aventis Res & Tech Gmbh & Co | Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
CN1133660C (zh) | 1998-03-04 | 2004-01-07 | 埃克森美孚化学专利公司 | 烯烃的高温聚合方法 |
US6486088B1 (en) | 1998-10-23 | 2002-11-26 | Exxonmobil Chemical Patents Inc. | High activity carbenium-activated polymerization catalysts |
US6300433B1 (en) | 1998-10-23 | 2001-10-09 | Exxonmobil Chemical Patents Inc. | Olefin copolymerization process with bridged hafnocenes |
JP5255740B2 (ja) * | 1998-10-23 | 2013-08-07 | エクソンモービル・ケミカル・パテンツ・インク | 架橋されたハフノセンを用いるオレフィン共重合法 |
DE19908938A1 (de) * | 1999-03-02 | 2000-09-07 | Targor Gmbh | Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
DE19917985A1 (de) | 1999-04-21 | 2000-10-26 | Targor Gmbh | Katalysatorsystem |
AU6525500A (en) * | 1999-09-27 | 2001-04-30 | Dow Chemical Company, The | Supported catalyst comprising expanded anions |
EP1548037A3 (de) | 1999-12-23 | 2007-09-12 | Basell Polyolefine GmbH | Random-Propylen-Ethylencopolymere |
DE19962814A1 (de) | 1999-12-23 | 2001-06-28 | Targor Gmbh | Neues Katalysatorsystem und dessen Verwendung |
EP1146376A1 (en) * | 2000-04-12 | 2001-10-17 | Triple-O Microscopy GmbH | Method and apparatus for the controlled conditioning of scanning probes |
US7105690B2 (en) | 2000-05-31 | 2006-09-12 | Basell Polyolefine Gmbh | Method for producing transition metal compounds and their use for the polymerization of olefins |
BR0115159A (pt) * | 2000-11-06 | 2003-08-19 | Exxonmobil Chem Patents Inc | Ativadores de co-catalisadores zwitteriÈnicos fluorados para polimerização de olefinas |
JP2002145932A (ja) * | 2000-11-13 | 2002-05-22 | Basell Technology Co Bv | 低アイソタクティックかつ比較的高融点のポリプロピレン |
DE10057009A1 (de) | 2000-11-17 | 2002-05-29 | Celanese Ventures Gmbh | Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen |
US7459511B2 (en) * | 2001-06-12 | 2008-12-02 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
DE10130229A1 (de) | 2001-06-22 | 2003-01-02 | Celanese Ventures Gmbh | Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen |
WO2003049856A1 (en) | 2001-12-05 | 2003-06-19 | Exxonmobil Chemical Patents Inc. | Bulky borate activators |
US6806328B2 (en) * | 2002-01-28 | 2004-10-19 | Univation Technologies, Llc | Polymerization catalyst activator complexes and their use in a polymerization process |
DE10208252A1 (de) | 2002-02-26 | 2003-09-04 | Celanese Ventures Gmbh | Konvalent fixierte Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen |
KR100460451B1 (ko) * | 2002-07-24 | 2004-12-08 | 한국화학연구원 | 쯔비터이온 화합물 촉매를 이용한 다중 고리 올레핀의반응사출성형방법 |
US7319125B2 (en) * | 2002-09-20 | 2008-01-15 | Exxonmobil Chemical Patents Inc. | Supercritical polymerization process and polymers produced therefrom |
US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
WO2004046214A2 (en) | 2002-10-15 | 2004-06-03 | Exxonmobil Chemical Patents Inc. | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US7589160B2 (en) * | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
DE60329523D1 (de) * | 2002-12-04 | 2009-11-12 | Basell Polyolefine Gmbh | 1-Buten-Copolymere und Herstellungsverfahren dafür |
US7285608B2 (en) | 2004-04-21 | 2007-10-23 | Novolen Technology Holdings C.V. | Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins |
US8034886B2 (en) * | 2005-11-04 | 2011-10-11 | Ticona Gmbh | Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts |
US7598329B2 (en) * | 2005-11-04 | 2009-10-06 | Ticona Gmbh | Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts |
US7550544B2 (en) * | 2005-12-14 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Halogen substituted metallocene compounds for olefin polymerization |
EP1847555A1 (en) * | 2006-04-18 | 2007-10-24 | Borealis Technology Oy | Multi-branched Polypropylene |
US8143352B2 (en) * | 2006-12-20 | 2012-03-27 | Exxonmobil Research And Engineering Company | Process for fluid phase in-line blending of polymers |
US8242237B2 (en) * | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
US8080610B2 (en) | 2007-03-06 | 2011-12-20 | Exxonmobil Research And Engineering Company | Monomer recycle process for fluid phase in-line blending of polymers |
WO2008150572A1 (en) | 2007-06-04 | 2008-12-11 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization |
EP2201042B1 (en) * | 2007-09-13 | 2012-06-27 | ExxonMobil Research and Engineering Company | In-line blending of plasticizers with a base polymer |
CN101855249B (zh) * | 2007-09-13 | 2013-02-13 | 埃克森美孚研究工程公司 | 在线生产增塑聚合物和增塑聚合物共混物的方法 |
US8168556B2 (en) | 2007-10-25 | 2012-05-01 | Lummus Novolen Technology Gmbh | Racemoselective synthesis of ansa-metallocene compounds, ansa-metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers |
WO2009054833A2 (en) | 2007-10-25 | 2009-04-30 | Novolen Technology Holdings, C.V. | Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo and copolymers |
US8299287B2 (en) * | 2007-10-25 | 2012-10-30 | Lammus Novolen Technology GmbH | Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers |
US7910679B2 (en) * | 2007-12-20 | 2011-03-22 | Exxonmobil Research And Engineering Company | Bulk homogeneous polymerization process for ethylene propylene copolymers |
EP2231779B1 (en) * | 2007-12-20 | 2012-06-06 | ExxonMobil Research and Engineering Company | In-line process to produce pellet-stable polyolefins |
US8138269B2 (en) * | 2007-12-20 | 2012-03-20 | Exxonmobil Research And Engineering Company | Polypropylene ethylene-propylene copolymer blends and in-line process to produce them |
US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
JP5769711B2 (ja) * | 2009-08-18 | 2015-08-26 | エルジー・ケム・リミテッド | 新規な化合物、これを含む触媒組成物およびこれを用いた環状オレフィン系重合体の製造方法 |
JP2013520841A (ja) * | 2010-02-25 | 2013-06-06 | アプライド マテリアルズ インコーポレイテッド | プラズマ化学気相堆積による、有機官能基と共にシリコンを含有するハイブリッド前駆体を使用する超低誘電材料 |
CN104974286B (zh) * | 2014-04-14 | 2017-08-22 | 中国石油化工股份有限公司 | 用于丙烯聚合的催化剂组分及催化剂 |
CN104974285B (zh) * | 2014-04-14 | 2017-08-22 | 中国石油化工股份有限公司 | 一种聚丙烯催化剂组分制备方法及催化剂 |
KR20200141452A (ko) * | 2018-03-30 | 2020-12-18 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합을 위한 이핵의 공-촉매로서 고도 가용성 비스-보레이트 |
WO2020223488A1 (en) * | 2019-04-30 | 2020-11-05 | Dow Global Technologies Llc | Alkene functionalized activators |
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FR1393410A (fr) * | 1964-02-04 | 1965-03-26 | Normande De Matieres Plastique | Perfectionnements aux procédés de préparation de polyoléfines isotactiques |
US3578461A (en) † | 1968-12-12 | 1971-05-11 | Monsanto Co | Process for the preparation of proteinaceous materials |
DE2601082A1 (de) * | 1976-01-14 | 1977-07-21 | Bayer Ag | Katalysatoren fuer isocyanat-polyadditionsreaktionen |
US4677088A (en) * | 1986-05-30 | 1987-06-30 | Exxon Chemical Patents Inc. | High efficiency polymerization catalyst component for use in the polymerization of propylene and higher alpha-olefins |
AU643255B2 (en) † | 1990-01-02 | 1993-11-11 | Exxon Chemical Patents Inc. | Supported ionic metallocene catalysts for olefin polymerization |
EP0522581B1 (en) † | 1991-07-11 | 1997-10-15 | Idemitsu Kosan Company Limited | Process for producing olefin based polymers and olefin polymerization catalyst |
DE69222317T2 (de) * | 1991-11-25 | 1998-02-12 | Exxon Chemical Patents Inc | Polyionische, uebergangsmetall enthaltende katalysatorzusammensetzung |
EP0631589A1 (en) * | 1992-03-16 | 1995-01-04 | Exxon Chemical Patents Inc. | IONIC CATALYST FOR THE PRODUCTION OF POLY-$g(a)-OLEFINS OF CONTROLLED TACTICITY |
DE69331112T2 (de) † | 1992-08-05 | 2002-06-20 | Exxonmobil Chem Patents Inc | Ionische übergangsmetallkatalysatoreren auf träger für olefinpolymerisation |
US5347024A (en) * | 1993-03-19 | 1994-09-13 | The Dow Chemical Company | Preparation of addition polymerization catalysts via Lewis acid mitigated metal center oxidation |
DE69426648T3 (de) † | 1993-06-15 | 2005-02-03 | Idemitsu Kosan Co. Ltd. | Verfahren zur herstellung von olefinpolymeren und katalysator zur olefinpolymerisation |
US5502017A (en) * | 1994-03-10 | 1996-03-26 | Northwestern University | Metallocene catalyst containing bulky organic group |
US5447895A (en) * | 1994-03-10 | 1995-09-05 | Northwestern University | Sterically shielded diboron-containing metallocene olefin polymerization catalysts |
ES2164774T3 (es) * | 1994-08-03 | 2002-03-01 | Exxonmobil Chem Patents Inc | Composicion catalitica ionica soportada. |
EP0710663A1 (en) * | 1994-11-01 | 1996-05-08 | Japan Polyolefins Co., Ltd. | Boron-containing compound, its polymer, catalyst comprising the polymer and metallocene compound, and process for producing polyolefin |
GB9423606D0 (en) * | 1994-11-23 | 1995-01-11 | Piers Warren E | Method of producing base free ziegler-natta olefin polymerizaton catalysts using a new, highly electrophilic borane reagent |
US5939347A (en) * | 1995-01-25 | 1999-08-17 | W.R. Grace & Co. -Conn. | Supported catalytic activator |
WO1996028480A1 (en) * | 1995-03-10 | 1996-09-19 | The Dow Chemical Company | Supported catalyst component, supported catalyst, preparation process, polymerization process, complex compounds, and their preparation |
US5869723A (en) * | 1995-06-08 | 1999-02-09 | Showa Denko K.K. | Ionic compound and olefin polymerization catalyst containing the same |
DK0863919T3 (da) * | 1995-11-27 | 2000-12-11 | Grace W R & Co | Understøttet katalysator indeholdende en tøjret, kationdannende aktivator |
US5744417A (en) * | 1996-05-02 | 1998-04-28 | Lyondell Petrochemical Company | Supported catalyst |
DE19622207A1 (de) † | 1996-06-03 | 1997-12-04 | Hoechst Ag | Chemische Verbindung |
FR2764524B1 (fr) * | 1997-06-17 | 1999-07-16 | Inst Francais Du Petrole | Composition catalytique et procede pour l'oligomerisation de l'ethylene, en particulier en butene-1 et/ou hexene-1 |
-
1997
- 1997-08-04 ES ES97113406T patent/ES2160289T3/es not_active Expired - Lifetime
- 1997-08-04 EP EP97113406A patent/EP0824113B2/de not_active Expired - Lifetime
- 1997-08-04 DE DE59703850T patent/DE59703850D1/de not_active Expired - Lifetime
- 1997-08-04 AT AT97113406T patent/ATE202365T1/de not_active IP Right Cessation
- 1997-08-11 BR BR9704310A patent/BR9704310A/pt unknown
- 1997-08-12 US US08/909,546 patent/US6124231A/en not_active Expired - Lifetime
- 1997-08-12 CN CN97117379A patent/CN1174205A/zh active Pending
- 1997-08-13 JP JP21870797A patent/JP4105783B2/ja not_active Expired - Lifetime
- 1997-08-13 KR KR1019970038496A patent/KR19980018627A/ko not_active Application Discontinuation
Also Published As
Publication number | Publication date |
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DE59703850D1 (de) | 2001-07-26 |
EP0824113B1 (de) | 2001-06-20 |
CN1174205A (zh) | 1998-02-25 |
JPH10139806A (ja) | 1998-05-26 |
ATE202365T1 (de) | 2001-07-15 |
BR9704310A (pt) | 1999-06-15 |
KR19980018627A (ko) | 1998-06-05 |
EP0824113B2 (de) | 2012-06-27 |
US6124231A (en) | 2000-09-26 |
JP4105783B2 (ja) | 2008-06-25 |
EP0824113A1 (de) | 1998-02-18 |
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