ES2164774T3 - Composicion catalitica ionica soportada. - Google Patents
Composicion catalitica ionica soportada.Info
- Publication number
- ES2164774T3 ES2164774T3 ES95928193T ES95928193T ES2164774T3 ES 2164774 T3 ES2164774 T3 ES 2164774T3 ES 95928193 T ES95928193 T ES 95928193T ES 95928193 T ES95928193 T ES 95928193T ES 2164774 T3 ES2164774 T3 ES 2164774T3
- Authority
- ES
- Spain
- Prior art keywords
- pct
- sec
- reacting
- date
- ionic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Abstract
LA INVENCION SE REFIERE A UNA COMPOSICION CATALIZADORA, ADECUADA PARA REACCIONES DE ADICION DE MONOMEROS ETILENICAMENTE Y ACETILENICAMENTE INSATURADOS, LA CUAL COMPRENDE UN SOPORTE DE OXIDO METALICO QUE PRESENTA, UNIDO COVALENTEMENTE A SU SUPERFICIE, DIRECTAMENTE A TRAVES DEL ATOMO DE OXIGENO DEL OXIDO METALICO, UN ANION ACTIVADOR QUE ESTA UNIDO TAMBIEN IONICAMENTE A UN COMPUESTO CATIONICO DE UN METAL DE TRANSICION, CATALITICAMENTE ACTIVO. LA INVENCION INCLUYE UN PROCEDIMIENTO DE PREPARACION DE LA COMPOSICION CATALIZADORA DE LA INVENCION, EJEMPLIFICADO MEDIANTE UNA REACCION DE UNA BASE DE LEWIS, COMO BORO DE TRISPERFLUOROFENILO CON GRUPOS RESIDUALES DE SILANOL DE UN SOPORTE DE SILICE, Y A CONTINUACION HACER REACCIONAR PREFERIBLEMENTE UNA BASE DE LEWIS, COMO LA DIETILANILINA, PARA PREPARAR UN ACTIVADOR ANIONICO UNIDO A SILICE, QUE, CUANDO SE COMBINA CON UN COMPUESTO DE UN METAL DE TRANSICION ADECUADO, LO PROTONA, PARA FORMAR EL SISTEMA CATALIZADOR IONICO. SE EJEMPLIFICA ASIMISMO LA UTILIZACION DEL CATALIZADOR DE LA INVENCION PARA LA POLIMERIZACION DE ALFA-OLEFINAS.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US28538094A | 1994-08-03 | 1994-08-03 | |
US08/474,948 US5643847A (en) | 1994-08-03 | 1995-06-07 | Supported ionic catalyst composition |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2164774T3 true ES2164774T3 (es) | 2002-03-01 |
Family
ID=26963166
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES95928193T Expired - Lifetime ES2164774T3 (es) | 1994-08-03 | 1995-07-28 | Composicion catalitica ionica soportada. |
Country Status (14)
Country | Link |
---|---|
US (1) | US5972823A (es) |
EP (1) | EP0775164B1 (es) |
JP (1) | JP3121838B2 (es) |
CN (1) | CN1095848C (es) |
AT (1) | ATE208404T1 (es) |
AU (1) | AU687231B2 (es) |
BR (1) | BR9508487A (es) |
CA (1) | CA2195879C (es) |
CZ (1) | CZ28597A3 (es) |
DE (1) | DE69523764T2 (es) |
ES (1) | ES2164774T3 (es) |
NO (1) | NO970409L (es) |
PL (1) | PL318432A1 (es) |
WO (1) | WO1996004319A1 (es) |
Families Citing this family (62)
Publication number | Priority date | Publication date | Assignee | Title |
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US6013727A (en) * | 1988-05-27 | 2000-01-11 | Exxon Chemical Patents, Inc. | Thermoplastic blend containing engineering resin |
US6143686A (en) * | 1994-08-03 | 2000-11-07 | Exxon Chemical Patents, Inc. | Supported ionic catalyst compositions |
US5939347A (en) * | 1995-01-25 | 1999-08-17 | W.R. Grace & Co. -Conn. | Supported catalytic activator |
US5885924A (en) * | 1995-06-07 | 1999-03-23 | W. R. Grace & Co.-Conn. | Halogenated supports and supported activators |
AU710813B2 (en) * | 1995-11-27 | 1999-09-30 | Dow Chemical Company, The | Supported catalyst containing tethered cation forming activator |
DE19622207A1 (de) | 1996-06-03 | 1997-12-04 | Hoechst Ag | Chemische Verbindung |
US5811379A (en) * | 1996-06-17 | 1998-09-22 | Exxon Chemical Patents Inc. | Polymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such polymers and additives and use thereof (PT-1267) |
IT1284097B1 (it) * | 1996-07-02 | 1998-05-08 | Montell Tecnology Company Bv | Processo in sospensione per la preparazione di copolimeri elastomerici dell'etilene |
DE59703850D1 (de) * | 1996-08-13 | 2001-07-26 | Basell Polyolefine Gmbh | Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
EP0824112B1 (de) * | 1996-08-13 | 2006-05-10 | Basell Polyolefine GmbH | Geträgerte chemische Verbindung |
US5783512A (en) * | 1996-12-18 | 1998-07-21 | The Dow Chemical Company | Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same |
DE19703478A1 (de) * | 1997-01-31 | 1998-08-06 | Hoechst Ag | Verfahren zur Herstellung eines Matallocen-Katalysatorsystems |
US6660809B1 (en) | 1997-02-07 | 2003-12-09 | Exxonmobil Chemical Patents Inc. | Propylene polymers incorporating polyethylene macromers |
KR100532265B1 (ko) * | 1997-06-05 | 2005-11-29 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 올레핀 중합용 중합체 지지 촉매 |
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US6117962A (en) * | 1997-12-10 | 2000-09-12 | Exxon Chemical Patents Inc. | Vinyl-containing stereospecific polypropylene macromers |
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US6177375B1 (en) * | 1998-03-09 | 2001-01-23 | Pq Corporation | High activity olefin polymerization catalysts |
JP2002517571A (ja) | 1998-06-12 | 2002-06-18 | ユニベーション・テクノロジーズ・エルエルシー | 活性化されたルイス酸−塩基錯体を使用するオレフィン重合方法 |
WO2000004058A1 (en) * | 1998-07-16 | 2000-01-27 | Univation Technologies Llc | Aluminum-based lewis acid cocatalysts for olefin polymerization |
ES2197649T3 (es) | 1998-08-26 | 2004-01-01 | Exxonmobil Chemical Patents Inc. | Composiciones cataliticas soportadas altamente activas. |
EP1115761B1 (en) | 1998-08-26 | 2013-09-18 | ExxonMobil Chemical Patents Inc. | Branched polypropylene compositions |
WO2000018808A1 (en) | 1998-09-30 | 2000-04-06 | Exxon Chemical Patents Inc. | Cationic group 3 catalyst system |
US6184171B1 (en) | 1998-10-05 | 2001-02-06 | W.R. Grace & Co. -Conn | Supported bidentate and tridentate catalyst compositions and olefin polymerization using same |
DE19917985A1 (de) * | 1999-04-21 | 2000-10-26 | Targor Gmbh | Katalysatorsystem |
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US6395847B2 (en) | 1999-11-19 | 2002-05-28 | Exxonmobil Chemical Patents Inc. | Supported organometallic catalysts and their use in olefin polymerization |
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US7220804B1 (en) * | 2000-10-13 | 2007-05-22 | Univation Technologies, Llc | Method for preparing a catalyst system and its use in a polymerization process |
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KR100460451B1 (ko) * | 2002-07-24 | 2004-12-08 | 한국화학연구원 | 쯔비터이온 화합물 촉매를 이용한 다중 고리 올레핀의반응사출성형방법 |
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KR101271055B1 (ko) * | 2008-03-28 | 2013-06-04 | 에스케이종합화학 주식회사 | 메탈로센 담지촉매 조성물 및 이를 이용한 폴리올레핀의제조방법 |
CN107586353A (zh) | 2009-12-24 | 2018-01-16 | 埃克森美孚化学专利公司 | 用于生产新型合成基础油料的方法 |
GB201714756D0 (en) | 2017-09-13 | 2017-10-25 | Lucite Int Uk Ltd | A catalyst and a process for the production of ethylenicallly unsaturated carboxylic acids or esters |
JP2019156896A (ja) * | 2018-03-08 | 2019-09-19 | 日本ポリエチレン株式会社 | オレフィン重合触媒及びオレフィン重合体の製造方法 |
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CN110190234B (zh) * | 2019-06-13 | 2021-10-22 | 重庆恩捷纽米科技股份有限公司 | 锂电池隔膜陶瓷涂覆浆料及陶瓷涂覆隔膜 |
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-
1995
- 1995-07-28 US US08/776,738 patent/US5972823A/en not_active Expired - Lifetime
- 1995-07-28 AU AU32046/95A patent/AU687231B2/en not_active Ceased
- 1995-07-28 CN CN95195034A patent/CN1095848C/zh not_active Expired - Fee Related
- 1995-07-28 JP JP08506645A patent/JP3121838B2/ja not_active Expired - Fee Related
- 1995-07-28 ES ES95928193T patent/ES2164774T3/es not_active Expired - Lifetime
- 1995-07-28 AT AT95928193T patent/ATE208404T1/de not_active IP Right Cessation
- 1995-07-28 PL PL95318432A patent/PL318432A1/xx unknown
- 1995-07-28 BR BR9508487-8A patent/BR9508487A/pt not_active IP Right Cessation
- 1995-07-28 DE DE69523764T patent/DE69523764T2/de not_active Expired - Fee Related
- 1995-07-28 EP EP95928193A patent/EP0775164B1/en not_active Expired - Lifetime
- 1995-07-28 CA CA002195879A patent/CA2195879C/en not_active Expired - Fee Related
- 1995-07-28 CZ CZ97285A patent/CZ28597A3/cs unknown
- 1995-07-28 WO PCT/US1995/009578 patent/WO1996004319A1/en active IP Right Grant
-
1997
- 1997-01-30 NO NO970409A patent/NO970409L/no unknown
Also Published As
Publication number | Publication date |
---|---|
EP0775164B1 (en) | 2001-11-07 |
EP0775164A1 (en) | 1997-05-28 |
CA2195879A1 (en) | 1996-02-15 |
DE69523764D1 (de) | 2001-12-13 |
AU3204695A (en) | 1996-03-04 |
NO970409L (no) | 1997-03-19 |
WO1996004319A1 (en) | 1996-02-15 |
CZ28597A3 (en) | 1997-07-16 |
JPH10503798A (ja) | 1998-04-07 |
CN1095848C (zh) | 2002-12-11 |
MX9700799A (es) | 1997-11-29 |
AU687231B2 (en) | 1998-02-19 |
ATE208404T1 (de) | 2001-11-15 |
CN1157623A (zh) | 1997-08-20 |
CA2195879C (en) | 2001-01-09 |
PL318432A1 (en) | 1997-06-09 |
DE69523764T2 (de) | 2002-08-01 |
JP3121838B2 (ja) | 2001-01-09 |
BR9508487A (pt) | 1997-12-30 |
NO970409D0 (no) | 1997-01-30 |
US5972823A (en) | 1999-10-26 |
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