ATE259675T1 - Katalysatorsystem - Google Patents

Katalysatorsystem

Info

Publication number
ATE259675T1
ATE259675T1 AT00926878T AT00926878T ATE259675T1 AT E259675 T1 ATE259675 T1 AT E259675T1 AT 00926878 T AT00926878 T AT 00926878T AT 00926878 T AT00926878 T AT 00926878T AT E259675 T1 ATE259675 T1 AT E259675T1
Authority
AT
Austria
Prior art keywords
catalyst system
cocatalyst
aluminoxanes
methylaluminoxane
mao
Prior art date
Application number
AT00926878T
Other languages
German (de)
English (en)
Inventor
Joerg Schottek
Patricia Becker
Original Assignee
Basell Polyolefine Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine Gmbh filed Critical Basell Polyolefine Gmbh
Application granted granted Critical
Publication of ATE259675T1 publication Critical patent/ATE259675T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
AT00926878T 1999-04-21 2000-04-12 Katalysatorsystem ATE259675T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19917985A DE19917985A1 (de) 1999-04-21 1999-04-21 Katalysatorsystem
PCT/EP2000/003263 WO2000062928A1 (de) 1999-04-21 2000-04-12 Katalysatorsystem

Publications (1)

Publication Number Publication Date
ATE259675T1 true ATE259675T1 (de) 2004-03-15

Family

ID=7905294

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00926878T ATE259675T1 (de) 1999-04-21 2000-04-12 Katalysatorsystem

Country Status (12)

Country Link
US (1) US6949614B1 (https=)
EP (1) EP1175262B1 (https=)
JP (1) JP2002542342A (https=)
KR (1) KR20020010609A (https=)
CN (1) CN1137148C (https=)
AT (1) ATE259675T1 (https=)
AU (1) AU4547800A (https=)
BR (1) BR0009871B1 (https=)
DE (2) DE19917985A1 (https=)
ES (1) ES2215651T3 (https=)
WO (1) WO2000062928A1 (https=)
ZA (1) ZA200108611B (https=)

Families Citing this family (57)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG74749A1 (en) * 1998-09-09 2000-08-22 Sumitomo Chemical Co Modified aluminium oxy compound polymerization catalyst and process for producing olefin polymer and alkenyl aromatic hydrocaron polymer
SG83828A1 (en) 1999-12-27 2001-10-16 Sumitomo Chemical Co Catalyst for addition polymerization, and process for producing addition polymer with the same
EP1446429B1 (en) 2001-06-12 2009-10-07 Basell Polyolefine GmbH Process for the polymerization of 1-butene
US7459511B2 (en) 2001-06-12 2008-12-02 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
ATE353343T1 (de) 2001-11-12 2007-02-15 Basell Polyolefine Gmbh Verfahren zur polymerisation von 1-buten und 1- buten polymeren
AU2003257456A1 (en) 2002-07-15 2004-02-02 Basell Polyolefine Gmbh Preparation of supported catalyst systems
WO2004022613A1 (en) 2002-09-06 2004-03-18 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
JP2006502260A (ja) 2002-10-10 2006-01-19 バセル ポリオレフィン ジーエムビーエイチ エチレンの共重合方法
US7414005B2 (en) 2002-11-04 2008-08-19 Basell Polyolefine Gmbh Preparation of catalyst compositions having improved activity
DE60329523D1 (de) 2002-12-04 2009-11-12 Basell Polyolefine Gmbh 1-Buten-Copolymere und Herstellungsverfahren dafür
US7589160B2 (en) 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
US7390862B2 (en) 2003-05-12 2008-06-24 Basell Polyolefine Gmbh Process for polymerizing 1-butene
CN100390207C (zh) * 2004-04-26 2008-05-28 中国科学院化学研究所 一种聚烯烃复合材料的制备方法
CN100471881C (zh) * 2004-04-26 2009-03-25 中国科学院化学研究所 一种负载型茂金属催化剂的制备方法
PL1805231T3 (pl) 2004-10-18 2010-08-31 Basell Poliolefine Italia Srl (Ko)polimery butenu-1 o niskiej izotaktyczności
EP1802669B1 (en) 2004-10-21 2011-03-09 Basell Polyolefine GmbH 1-butene polymer and process for the preparation thereof
RU2410388C2 (ru) 2005-03-18 2011-01-27 Базелль Полиолефине Гмбх Металлоценовые соединения
US7803887B2 (en) 2005-03-18 2010-09-28 Basell Polyolefine Gmbh Metallocene compounds
CN101146836B (zh) 2005-03-23 2011-06-08 巴塞尔聚烯烃股份有限公司 烯烃聚合方法
US7799880B2 (en) 2005-03-23 2010-09-21 Basell Polyolefine Gmbh Process for the polymerization of olefins
WO2006117285A1 (en) 2005-05-03 2006-11-09 Basell Polyolefine Gmbh Process for the polymerization of alpha olefins
ATE515533T1 (de) 2005-05-11 2011-07-15 Basell Poliolefine Srl Polymerisationsverfahren zur herstellung von polyolefinblends
US7232869B2 (en) 2005-05-17 2007-06-19 Novolen Technology Holdings, C.V. Catalyst composition for olefin polymerization
US8051611B2 (en) * 2005-06-24 2011-11-08 Dryvit Systems, Inc. Exterior insulation and finish system and method and tool for installing same
WO2007003528A2 (en) * 2005-06-30 2007-01-11 Basell Polyolefine Gmbh Metallocene compounds
EP2041188B1 (en) * 2006-07-17 2017-06-14 Albemarle Corporation Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
WO2008076632A2 (en) * 2006-12-14 2008-06-26 Albemarle Corporation Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
WO2008141928A1 (en) * 2007-05-23 2008-11-27 Basell Polyolefine Gmbh Insecticidal composition and articles obtained thereof
RU2463788C2 (ru) * 2007-05-23 2012-10-20 Базелль Полиолефине Гмбх Инсектицидная композиция и изделия, полученные из нее
ATE485318T1 (de) * 2007-06-25 2010-11-15 Basell Polyolefine Gmbh 1-butenethylencopolymere
KR100905544B1 (ko) * 2007-08-13 2009-07-01 금호석유화학 주식회사 이형원자가 배위된 단분자 알루미늄과 코발트가 함유된촉매와 이를 이용한 폴리부타디엔의 제조방법
ATE543870T1 (de) * 2008-03-20 2012-02-15 Basell Poliolefine Srl Zusammensetzungen aus polymeren auf 1-buten-basis
JP2011515517A (ja) * 2008-03-20 2011-05-19 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ １−ブテンコポリマー
EP2254918A1 (en) * 2008-03-20 2010-12-01 Basell Poliolefine Italia S.R.L. 1-butene terpolymers
EP2254917A1 (en) * 2008-03-20 2010-12-01 Basell Poliolefine Italia S.R.L. 1-butene copolymers
BRPI0910453A2 (pt) * 2008-04-22 2018-03-27 Basell Poliolefine Italia S.R.L terpolímeros de 1-buteno
BRPI0918979B1 (pt) * 2008-09-24 2019-05-07 Basell Poliolefine Italia S.R.L. Composições de poliolefina com boa resistência ao branqueamento
US9006341B2 (en) * 2008-12-19 2015-04-14 Basell Poliolefine Italia S.R.L. Polyolefin fibres
WO2011061151A1 (en) 2009-11-17 2011-05-26 Basell Polyolefine Gmbh Ethylene copolymers
EP3539993A1 (en) 2013-07-17 2019-09-18 ExxonMobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
EP3022235B1 (en) 2013-07-17 2020-04-08 ExxonMobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
US9458260B2 (en) 2013-07-17 2016-10-04 Exxonmobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
WO2015009472A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemcal Patents Inc. Metallocenes and catalyst compositions derived therefrom
US9458254B2 (en) 2013-07-17 2016-10-04 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
US10570219B2 (en) 2015-06-05 2020-02-25 Exxonmobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
US10723821B2 (en) 2015-06-05 2020-07-28 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
US10759886B2 (en) 2015-06-05 2020-09-01 Exxonmobil Chemical Patents Inc. Single reactor production of polymers in gas or slurry phase
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US11059918B2 (en) 2016-05-27 2021-07-13 Exxonmobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
KR20200056283A (ko) * 2018-11-14 2020-05-22 롯데케미칼 주식회사 올레핀 중합용 담지 촉매 및 이를 이용하는 폴리올레핀의 제조방법
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
US20250059362A1 (en) 2021-12-23 2025-02-20 Basell Poliolefine Italia S.R.L. Soft polyolefin composition

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
ATE120768T1 (de) 1989-10-30 1995-04-15 Fina Technology Herstellung von metallocenkatalysatoren für olefinpolymerisation.
EP0474391B1 (en) 1990-08-21 1995-10-25 Nippon Oil Co. Ltd. Polyolefins
JPH04323204A (ja) 1991-04-22 1992-11-12 Kansai Paint Co Ltd リビング重合体の製造方法
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5348299A (en) 1992-05-06 1994-09-20 Ltb Game Enterprises Electronic gaming apparatus
DE69403928T2 (de) * 1993-04-09 1997-12-18 Tosoh Corp Katalysator und Verfahren zur Olefin-Polymerisation
JP3264338B2 (ja) * 1993-05-20 2002-03-11 出光興産株式会社 特定のアルミニウム化合物を含有する重合用触媒
BE1007698A3 (fr) 1993-11-04 1995-10-03 Solvay Systeme catalytique utilisable pour la polymerisation des alpha-olefines et procede pour cette polymerisation.
ES2142426T3 (es) 1994-06-13 2000-04-16 Targor Gmbh Compuestos de metales de transicion.
DE4420456A1 (de) 1994-06-13 1995-12-14 Hoechst Ag Übergangsmetallverbindung
EP0775164B1 (en) * 1994-08-03 2001-11-07 ExxonMobil Chemical Patents Inc. Supported ionic catalyst composition
JPH08113604A (ja) * 1994-10-17 1996-05-07 Showa Denko Kk 新規担体、その製造方法および重合触媒
US5939347A (en) * 1995-01-25 1999-08-17 W.R. Grace & Co. -Conn. Supported catalytic activator
DE59600760D1 (de) 1995-06-12 1998-12-10 Targor Gmbh Übergangsmetallverbindung
US5908903A (en) * 1995-12-27 1999-06-01 Basf Aktiengesellschaft Metallocene catalyst systems containing lewis bases
DE19622207A1 (de) 1996-06-03 1997-12-04 Hoechst Ag Chemische Verbindung
ES2160289T3 (es) 1996-08-13 2001-11-01 Basell Polyolefine Gmbh Sistema catalizador soportado, un procedimiento para su obtencion y su empleo para la polimerizacion de olefinas.
JP3761670B2 (ja) * 1997-05-20 2006-03-29 住友化学株式会社 アルミニウム化合物、オレフィン重合用触媒およびオレフィン重合体の製造方法
DE19733017A1 (de) * 1997-07-31 1999-02-04 Hoechst Ag Chemische Verbindung
FR2769245B1 (fr) 1997-10-02 1999-10-29 Atochem Elf Sa Support solide activateur des catalyseurs metallocenes en polymerisation des olefines, son procede de preparation, systeme catalytique et procede de polymerisation correspondants
DE19757540A1 (de) * 1997-12-23 1999-06-24 Hoechst Ag Geträgertes Katalysatorsystem zur Polymerisation von Olefinen
DE19804970A1 (de) * 1998-02-07 1999-08-12 Aventis Res & Tech Gmbh & Co Katalysatorsystem
JP4440355B2 (ja) * 1998-03-25 2010-03-24 住友化学株式会社 改質された粒子、それよりなる担体、それよりなるオレフィン重合用触媒成分、それを用いてなるオレフィン重合用触媒、およびオレフィン重合体の製造方法
CA2235175A1 (en) 1998-04-17 1999-10-17 Bayer Inc. Olefin polymerization process and catalyst system therfor
DE59910526D1 (de) * 1998-04-21 2004-10-21 Basell Polyolefine Gmbh Katalysatorsystem mit metallocenen mit fluorhaltigen substituenten
EP1082353B1 (de) * 1998-05-23 2006-02-22 Basell Polyolefine GmbH Katalysatorsystem und seine verwendung zur polymerisation von propylen
DE19828271A1 (de) * 1998-06-25 1999-12-30 Elenac Gmbh Verfahren zur Herstellung eines geträgerten Katalysatorsystems

Also Published As

Publication number Publication date
AU4547800A (en) 2000-11-02
JP2002542342A (ja) 2002-12-10
EP1175262B1 (de) 2004-02-18
US6949614B1 (en) 2005-09-27
DE19917985A1 (de) 2000-10-26
CN1137148C (zh) 2004-02-04
KR20020010609A (ko) 2002-02-04
BR0009871A (pt) 2002-01-08
ES2215651T3 (es) 2004-10-16
BR0009871B1 (pt) 2010-10-05
CN1347343A (zh) 2002-05-01
ZA200108611B (en) 2002-10-21
WO2000062928A1 (de) 2000-10-26
EP1175262A1 (de) 2002-01-30
DE50005332D1 (de) 2004-03-25

Similar Documents

Publication Publication Date Title
ATE259675T1 (de) Katalysatorsystem
AU2009101A (en) Novel catalyst system and the use thereof
BR9914227A (pt) Sistema catalisador, processo para preparar uma poliolefina, e, uso de um sistema catalisador
ES2144146T3 (es) Procedimiento para producir polimeros y copolimeros de etileno de distribucion de peso molecular bimodal.
AU2972892A (en) Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts
CA2570874A1 (en) Acidic activator-supports and catalysts for olefin polymerization
SG158099A1 (en) Metallocene catalysts, their synthesis and their use for the polymerization of olefins
DE59712813D1 (de) Metallocene
NO985694L (no) Fremstilling av stereoregulµre polymerer
DE60226010D1 (de) Mehrkerniger metallocenkatalysator
RU92004438A (ru) Металлоцены с бензоконденсированными производными инденила, способ их получения, способ получения олефинового полимера, катализатор полимеризации олефинов
WO2009054889A3 (en) Metallocene catalysts and their use in polymerization processes
AU2003266352A1 (en) Process to prepare a particulated metallocene catalyste with a modified aluminoxane and use in polymerization of olefins
FR2659337B1 (fr) Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
ATE399800T1 (de) Stickstoffsubstituierte phosphiniminligand
AU7540700A (en) Modified supported catalysts for the polymerization of olefins
MXPA02005494A (es) Compuestos de metaloceno unidos con puente, proceso para su preparacion y su uso como catalizadores para la polimerizacion de olefinas.
ATE260945T1 (de) Zwitterionische, neutrale übergansmetallverbindung
BR9910675A (pt) Sistema de catalisador, processo para preparar uma poliolefina, e, uso de um sistema de catalisador
EP0791607A3 (en) Substituted metallocene catalyst for the (co)polymerization of olefins
NO953017L (no) Katalysatorsystem og fremgangsmåte for polymerisasjon av olefiner
AU2001226937A1 (en) Metallocene catalysts comprising monocyclic siloxy substituted cyclopentadienyl group(s) for the polymerisation of olefins
DE69914012D1 (de) Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen
ATE296319T1 (de) Geträgerter ziegler - metallocene polymerisationskatalysator und dessen benutzung für die polymerisation von olefinen
WO2002024769A3 (en) Process for the preparation of ethylene polymers with a bis-amido titanium compound

Legal Events

Date Code Title Description
REN Ceased due to non-payment of the annual fee