ATE259675T1 - CATALYST SYSTEM - Google Patents

CATALYST SYSTEM

Info

Publication number
ATE259675T1
ATE259675T1 AT00926878T AT00926878T ATE259675T1 AT E259675 T1 ATE259675 T1 AT E259675T1 AT 00926878 T AT00926878 T AT 00926878T AT 00926878 T AT00926878 T AT 00926878T AT E259675 T1 ATE259675 T1 AT E259675T1
Authority
AT
Austria
Prior art keywords
catalyst system
cocatalyst
aluminoxanes
methylaluminoxane
mao
Prior art date
Application number
AT00926878T
Other languages
German (de)
Inventor
Joerg Schottek
Patricia Becker
Original Assignee
Basell Polyolefine Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine Gmbh filed Critical Basell Polyolefine Gmbh
Application granted granted Critical
Publication of ATE259675T1 publication Critical patent/ATE259675T1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Abstract

A catalyst system comprising a metallocene, a cocatalyst, a support material and optionally a further organometallic compound is described. The catalyst system can advantageously be used for the polymerization of olefins. Here, the use of aluminoxanes such as methylaluminoxane (MAO) as cocatalyst is dispensed with and a high catalyst activity and good polymer morphology are nevertheless achieved.
AT00926878T 1999-04-21 2000-04-12 CATALYST SYSTEM ATE259675T1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19917985A DE19917985A1 (en) 1999-04-21 1999-04-21 Metallocene catalyst system, useful for the production of polyolefins, comprises an organoboron or organoaluminum compound covalently bonded to a support.
PCT/EP2000/003263 WO2000062928A1 (en) 1999-04-21 2000-04-12 Catalyst system

Publications (1)

Publication Number Publication Date
ATE259675T1 true ATE259675T1 (en) 2004-03-15

Family

ID=7905294

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00926878T ATE259675T1 (en) 1999-04-21 2000-04-12 CATALYST SYSTEM

Country Status (12)

Country Link
US (1) US6949614B1 (en)
EP (1) EP1175262B1 (en)
JP (1) JP2002542342A (en)
KR (1) KR20020010609A (en)
CN (1) CN1137148C (en)
AT (1) ATE259675T1 (en)
AU (1) AU4547800A (en)
BR (1) BR0009871B1 (en)
DE (2) DE19917985A1 (en)
ES (1) ES2215651T3 (en)
WO (1) WO2000062928A1 (en)
ZA (1) ZA200108611B (en)

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US7074864B2 (en) 2001-06-12 2006-07-11 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
ATE519789T1 (en) 2001-06-12 2011-08-15 Basell Polyolefine Gmbh METHOD FOR POLYMERIZING BUTENE-1
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CN101959415B (en) * 2007-05-23 2014-07-09 巴塞尔聚烯烃股份有限公司 Insecticidal composition and articles obtained thereof
PL2158235T3 (en) * 2007-06-25 2011-04-29 Basell Polyolefine Gmbh 1-butene ethylene copolymers
KR100905544B1 (en) * 2007-08-13 2009-07-01 금호석유화학 주식회사 Catalyst consisting of heteroleptic aluminum and cobalt compounds and preparation method of polybutadiene using it
JP2011515518A (en) * 2008-03-20 2011-05-19 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ Compositions of 1-butene polymers
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CN105377904B (en) 2013-07-17 2018-07-10 埃克森美孚化学专利公司 Metallocene and by its derivative carbon monoxide-olefin polymeric
EP3022236B1 (en) 2013-07-17 2017-11-15 ExxonMobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
CN107690441A (en) 2015-06-05 2018-02-13 埃克森美孚化学专利公司 It is prepared by single reactor of the polymer in gas phase or slurry phase
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
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US11059918B2 (en) 2016-05-27 2021-07-13 Exxonmobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
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Also Published As

Publication number Publication date
ES2215651T3 (en) 2004-10-16
EP1175262B1 (en) 2004-02-18
DE50005332D1 (en) 2004-03-25
WO2000062928A1 (en) 2000-10-26
ZA200108611B (en) 2002-10-21
JP2002542342A (en) 2002-12-10
BR0009871B1 (en) 2010-10-05
US6949614B1 (en) 2005-09-27
DE19917985A1 (en) 2000-10-26
AU4547800A (en) 2000-11-02
CN1347343A (en) 2002-05-01
CN1137148C (en) 2004-02-04
BR0009871A (en) 2002-01-08
EP1175262A1 (en) 2002-01-30
KR20020010609A (en) 2002-02-04

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