CN1137148C - 催化剂体系 - Google Patents

催化剂体系 Download PDF

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Publication number
CN1137148C
CN1137148C CNB008064636A CN00806463A CN1137148C CN 1137148 C CN1137148 C CN 1137148C CN B008064636 A CNB008064636 A CN B008064636A CN 00806463 A CN00806463 A CN 00806463A CN 1137148 C CN1137148 C CN 1137148C
Authority
CN
China
Prior art keywords
methyl
indenyl
zirconium dichloride
phenyl
dimethylsilanediyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB008064636A
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English (en)
Chinese (zh)
Other versions
CN1347343A (zh
Inventor
J��̩��
J·舒泰克
P·拜克尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novolen Technology Holdings CV
Original Assignee
Basell Polyolefine GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine GmbH filed Critical Basell Polyolefine GmbH
Publication of CN1347343A publication Critical patent/CN1347343A/zh
Application granted granted Critical
Publication of CN1137148C publication Critical patent/CN1137148C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
CNB008064636A 1999-04-21 2000-04-12 催化剂体系 Expired - Fee Related CN1137148C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19917985.9 1999-04-21
DE19917985A DE19917985A1 (de) 1999-04-21 1999-04-21 Katalysatorsystem

Publications (2)

Publication Number Publication Date
CN1347343A CN1347343A (zh) 2002-05-01
CN1137148C true CN1137148C (zh) 2004-02-04

Family

ID=7905294

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB008064636A Expired - Fee Related CN1137148C (zh) 1999-04-21 2000-04-12 催化剂体系

Country Status (12)

Country Link
US (1) US6949614B1 (https=)
EP (1) EP1175262B1 (https=)
JP (1) JP2002542342A (https=)
KR (1) KR20020010609A (https=)
CN (1) CN1137148C (https=)
AT (1) ATE259675T1 (https=)
AU (1) AU4547800A (https=)
BR (1) BR0009871B1 (https=)
DE (2) DE19917985A1 (https=)
ES (1) ES2215651T3 (https=)
WO (1) WO2000062928A1 (https=)
ZA (1) ZA200108611B (https=)

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ATE353343T1 (de) 2001-11-12 2007-02-15 Basell Polyolefine Gmbh Verfahren zur polymerisation von 1-buten und 1- buten polymeren
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US7414005B2 (en) 2002-11-04 2008-08-19 Basell Polyolefine Gmbh Preparation of catalyst compositions having improved activity
DE60329523D1 (de) 2002-12-04 2009-11-12 Basell Polyolefine Gmbh 1-Buten-Copolymere und Herstellungsverfahren dafür
US7589160B2 (en) 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
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CN100390207C (zh) * 2004-04-26 2008-05-28 中国科学院化学研究所 一种聚烯烃复合材料的制备方法
CN100471881C (zh) * 2004-04-26 2009-03-25 中国科学院化学研究所 一种负载型茂金属催化剂的制备方法
PL1805231T3 (pl) 2004-10-18 2010-08-31 Basell Poliolefine Italia Srl (Ko)polimery butenu-1 o niskiej izotaktyczności
EP1802669B1 (en) 2004-10-21 2011-03-09 Basell Polyolefine GmbH 1-butene polymer and process for the preparation thereof
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ATE515533T1 (de) 2005-05-11 2011-07-15 Basell Poliolefine Srl Polymerisationsverfahren zur herstellung von polyolefinblends
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RU2463788C2 (ru) * 2007-05-23 2012-10-20 Базелль Полиолефине Гмбх Инсектицидная композиция и изделия, полученные из нее
ATE485318T1 (de) * 2007-06-25 2010-11-15 Basell Polyolefine Gmbh 1-butenethylencopolymere
KR100905544B1 (ko) * 2007-08-13 2009-07-01 금호석유화학 주식회사 이형원자가 배위된 단분자 알루미늄과 코발트가 함유된촉매와 이를 이용한 폴리부타디엔의 제조방법
ATE543870T1 (de) * 2008-03-20 2012-02-15 Basell Poliolefine Srl Zusammensetzungen aus polymeren auf 1-buten-basis
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BRPI0910453A2 (pt) * 2008-04-22 2018-03-27 Basell Poliolefine Italia S.R.L terpolímeros de 1-buteno
BRPI0918979B1 (pt) * 2008-09-24 2019-05-07 Basell Poliolefine Italia S.R.L. Composições de poliolefina com boa resistência ao branqueamento
US9006341B2 (en) * 2008-12-19 2015-04-14 Basell Poliolefine Italia S.R.L. Polyolefin fibres
WO2011061151A1 (en) 2009-11-17 2011-05-26 Basell Polyolefine Gmbh Ethylene copolymers
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US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
US9458260B2 (en) 2013-07-17 2016-10-04 Exxonmobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
WO2015009472A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemcal Patents Inc. Metallocenes and catalyst compositions derived therefrom
US9458254B2 (en) 2013-07-17 2016-10-04 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
US10570219B2 (en) 2015-06-05 2020-02-25 Exxonmobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
US10723821B2 (en) 2015-06-05 2020-07-28 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
US10759886B2 (en) 2015-06-05 2020-09-01 Exxonmobil Chemical Patents Inc. Single reactor production of polymers in gas or slurry phase
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Also Published As

Publication number Publication date
AU4547800A (en) 2000-11-02
ATE259675T1 (de) 2004-03-15
JP2002542342A (ja) 2002-12-10
EP1175262B1 (de) 2004-02-18
US6949614B1 (en) 2005-09-27
DE19917985A1 (de) 2000-10-26
KR20020010609A (ko) 2002-02-04
BR0009871A (pt) 2002-01-08
ES2215651T3 (es) 2004-10-16
BR0009871B1 (pt) 2010-10-05
CN1347343A (zh) 2002-05-01
ZA200108611B (en) 2002-10-21
WO2000062928A1 (de) 2000-10-26
EP1175262A1 (de) 2002-01-30
DE50005332D1 (de) 2004-03-25

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Owner name: NOVOLUV TECHNOLOGY STOCK CO.,LTD.

Free format text: FORMER OWNER: BASSER POLYOLEFINE GMBH

Effective date: 20070209

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Patentee after: Novolen Technology Holdings C.

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Patentee before: Basser Polyolefin GmbH

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Termination date: 20120412