ES2207520T3 - Procedimiento para producir un sulfuro de litio y un metal de transicion. - Google Patents
Procedimiento para producir un sulfuro de litio y un metal de transicion.Info
- Publication number
- ES2207520T3 ES2207520T3 ES00937049T ES00937049T ES2207520T3 ES 2207520 T3 ES2207520 T3 ES 2207520T3 ES 00937049 T ES00937049 T ES 00937049T ES 00937049 T ES00937049 T ES 00937049T ES 2207520 T3 ES2207520 T3 ES 2207520T3
- Authority
- ES
- Spain
- Prior art keywords
- lithium
- sulfide
- transition metal
- procedure
- iron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 24
- GLNWILHOFOBOFD-UHFFFAOYSA-N lithium sulfide Chemical compound [Li+].[Li+].[S-2] GLNWILHOFOBOFD-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 229910052723 transition metal Inorganic materials 0.000 title claims abstract description 14
- 150000003624 transition metals Chemical class 0.000 title claims abstract description 8
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 23
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 19
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002904 solvent Substances 0.000 claims abstract description 12
- -1 Lithium transition metal sulphides Chemical class 0.000 claims abstract description 11
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000004519 manufacturing process Methods 0.000 claims abstract description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 18
- 229910052717 sulfur Inorganic materials 0.000 claims description 15
- 239000011593 sulfur Substances 0.000 claims description 15
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 229910052742 iron Inorganic materials 0.000 claims description 8
- 238000009834 vaporization Methods 0.000 claims description 3
- 230000008016 vaporization Effects 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- LWRYTNDOEJYQME-UHFFFAOYSA-N lithium;sulfanylideneiron Chemical compound [Li].[Fe]=S LWRYTNDOEJYQME-UHFFFAOYSA-N 0.000 abstract description 5
- 239000005864 Sulphur Substances 0.000 abstract 1
- 150000004763 sulfides Chemical class 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- 230000007704 transition Effects 0.000 description 6
- 239000010406 cathode material Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
- NFMAZVUSKIJEIH-UHFFFAOYSA-N bis(sulfanylidene)iron Chemical compound S=[Fe]=S NFMAZVUSKIJEIH-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 229910000339 iron disulfide Inorganic materials 0.000 description 3
- 229910001416 lithium ion Inorganic materials 0.000 description 3
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 3
- 229910001947 lithium oxide Inorganic materials 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Chemical compound [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 2
- 229910052960 marcasite Inorganic materials 0.000 description 2
- 229910052976 metal sulfide Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 2
- 229910052683 pyrite Inorganic materials 0.000 description 2
- 150000003346 selenoethers Chemical class 0.000 description 2
- 238000003746 solid phase reaction Methods 0.000 description 2
- 238000010671 solid-state reaction Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- 229910018091 Li 2 S Inorganic materials 0.000 description 1
- 229910013063 LiBF 4 Inorganic materials 0.000 description 1
- 229910032387 LiCoO2 Inorganic materials 0.000 description 1
- 229910002993 LiMnO2 Inorganic materials 0.000 description 1
- 229910003005 LiNiO2 Inorganic materials 0.000 description 1
- 229910013870 LiPF 6 Inorganic materials 0.000 description 1
- 229910003092 TiS2 Inorganic materials 0.000 description 1
- JQGOBMZVGJZVEJ-UHFFFAOYSA-M [Se-2].[Se-2].[SeH-].[Nb+5] Chemical compound [Se-2].[Se-2].[SeH-].[Nb+5] JQGOBMZVGJZVEJ-UHFFFAOYSA-M 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical group S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 229910052806 inorganic carbonate Inorganic materials 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 229910002102 lithium manganese oxide Inorganic materials 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 description 1
- VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical compound [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 description 1
- MCVFFRWZNYZUIJ-UHFFFAOYSA-M lithium;trifluoromethanesulfonate Chemical compound [Li+].[O-]S(=O)(=O)C(F)(F)F MCVFFRWZNYZUIJ-UHFFFAOYSA-M 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- CXHHBNMLPJOKQD-UHFFFAOYSA-M methyl carbonate Chemical compound COC([O-])=O CXHHBNMLPJOKQD-UHFFFAOYSA-M 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 238000013341 scale-up Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- PTISTKLWEJDJID-UHFFFAOYSA-N sulfanylidenemolybdenum Chemical compound [Mo]=S PTISTKLWEJDJID-UHFFFAOYSA-N 0.000 description 1
- NYPFJVOIAWPAAV-UHFFFAOYSA-N sulfanylideneniobium Chemical compound [Nb]=S NYPFJVOIAWPAAV-UHFFFAOYSA-N 0.000 description 1
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 1
- CFJRPNFOLVDFMJ-UHFFFAOYSA-N titanium disulfide Chemical compound S=[Ti]=S CFJRPNFOLVDFMJ-UHFFFAOYSA-N 0.000 description 1
- OCDVSJMWGCXRKO-UHFFFAOYSA-N titanium(4+);disulfide Chemical compound [S-2].[S-2].[Ti+4] OCDVSJMWGCXRKO-UHFFFAOYSA-N 0.000 description 1
- 150000008648 triflates Chemical class 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/581—Chalcogenides or intercalation compounds thereof
- H01M4/5815—Sulfides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/002—Compounds containing titanium, with or without oxygen or hydrogen, and containing two or more other elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G33/00—Compounds of niobium
- C01G33/006—Compounds containing niobium, with or without oxygen or hydrogen, and containing two or more other elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G39/00—Compounds of molybdenum
- C01G39/006—Compounds containing molybdenum, with or without oxygen or hydrogen, and containing two or more other elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/009—Compounds containing iron, with or without oxygen or hydrogen, and containing two or more other elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/581—Chalcogenides or intercalation compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Compounds Of Iron (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Saccharide Compounds (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9914041 | 1999-06-17 | ||
| GB9914041A GB2351075A (en) | 1999-06-17 | 1999-06-17 | Producing lithiated transition metal sulphides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2207520T3 true ES2207520T3 (es) | 2004-06-01 |
Family
ID=10855484
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES00937049T Expired - Lifetime ES2207520T3 (es) | 1999-06-17 | 2000-06-05 | Procedimiento para producir un sulfuro de litio y un metal de transicion. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6740301B1 (https=) |
| EP (1) | EP1187790B1 (https=) |
| JP (1) | JP4744755B2 (https=) |
| AT (1) | ATE253017T1 (https=) |
| AU (1) | AU5234300A (https=) |
| CA (1) | CA2375195C (https=) |
| DE (1) | DE60006236T2 (https=) |
| ES (1) | ES2207520T3 (https=) |
| GB (2) | GB2351075A (https=) |
| WO (1) | WO2000078673A1 (https=) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0029958D0 (en) | 2000-12-08 | 2001-01-24 | Secr Defence | Synthesis of lithium transition metal sulphides |
| EP2146931B1 (de) | 2007-04-16 | 2014-09-24 | Basf Se | Verfahren zur herstellung von lithiumreichen metalloxiden |
| GB2464455B (en) * | 2008-10-14 | 2010-09-15 | Iti Scotland Ltd | Lithium-containing transition metal sulfide compounds |
| JP5271035B2 (ja) * | 2008-10-23 | 2013-08-21 | 日本化学工業株式会社 | 硫化リチウム鉄の製造方法及び硫化リチウム遷移金属の製造方法 |
| JP5403632B2 (ja) * | 2009-01-22 | 2014-01-29 | 独立行政法人産業技術総合研究所 | 硫化鉄リチウム複合体の製造方法 |
| CN102797031B (zh) * | 2012-08-22 | 2015-07-08 | 兰州大学 | 一种黄铁矿型二硫化亚铁纳米单晶半导体材料的制备方法 |
| JP6011989B2 (ja) * | 2013-03-18 | 2016-10-25 | 国立研究開発法人産業技術総合研究所 | リチウムチタン硫化物、リチウムニオブ硫化物及びリチウムチタンニオブ硫化物 |
| JP6254413B2 (ja) * | 2013-10-07 | 2017-12-27 | 古河機械金属株式会社 | 硫化リチウムの製造方法 |
| DE102014211421A1 (de) | 2014-06-13 | 2015-12-17 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Herstellung von Alkalimetallsulfid-Nanopartikeln, Alkalimetallsulfid-Nanopartikel, Verwendung der Alkalimetallsulfid-Nanopartikel sowie Alkalimetall-Schwefel-Batterie |
| KR102350807B1 (ko) * | 2014-11-18 | 2022-01-14 | 내셔날 인스티튜트 오브 어드밴스드 인더스트리얼 사이언스 앤드 테크놀로지 | 리튬-철-인-황-탄소 복합체 및 그 제조 방법 |
| CN106129380A (zh) * | 2016-08-31 | 2016-11-16 | 四川剑兴锂电池有限公司 | 一种正极极片及含有该正极片的无定形碳锂电池 |
| CN112670559A (zh) | 2019-10-15 | 2021-04-16 | 通用汽车环球科技运作有限责任公司 | 固态电解质和制备其的方法 |
| DE102020125123B4 (de) | 2020-09-25 | 2022-06-30 | GM Global Technology Operations LLC | Verfahren zur Herstellung eines Festkörperelektrolyten |
| CN112678865A (zh) * | 2021-01-13 | 2021-04-20 | 福建工程学院 | 一种基于过渡金属硫化物的光限幅材料 |
| CN121546045A (zh) * | 2026-01-20 | 2026-02-17 | 浙江工业大学 | 一种双功能网络结构硫化锂复合正极材料及其制备方法和应用 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB385895A (en) * | 1931-09-05 | 1933-01-05 | Ig Farbenindustrie Ag | Improved manufacture of anhydrous alkali polysulphides |
| GB453203A (en) * | 1935-03-04 | 1936-09-04 | Werner Wilfred Duecker | Improvements in plastics |
| GB805922A (en) * | 1955-10-17 | 1958-12-17 | Texas Gulf Sulphur Co | Improvements in or relating to decomposition of sulfide minerals |
| US3925098A (en) * | 1974-11-27 | 1975-12-09 | Electric Power Res Inst | Positive electrode for electrical energy storage device |
| FR2420852A1 (fr) * | 1978-03-24 | 1979-10-19 | Comp Generale Electricite | Generateur au lithium |
| US4164069A (en) * | 1978-04-28 | 1979-08-14 | The United States Of America As Represented By The United States Department Of Energy | Method of preparing a positive electrode for an electrochemical cell |
| US4172926A (en) * | 1978-06-29 | 1979-10-30 | The United States Of America As Represented By The United States Department Of Energy | Electrochemical cell and method of assembly |
| GB2057412B (en) | 1979-08-20 | 1983-05-18 | Ihara Chemical Ind Co | Process for preparing carbonyl sulphide |
| US4731307A (en) * | 1986-06-10 | 1988-03-15 | The United States Of America As Represented By The United States Department Of Energy | Methods for achieving the equilibrium number of phases in mixtures suitable for use in battery electrodes, e.g., for lithiating FeS2 |
| US4761487A (en) * | 1986-06-10 | 1988-08-02 | The United States Of America As Represented By The United States Department Of Energy | Method for improving voltage regulation of batteries, particularly Li/FeS2 thermal batteries |
| US4917871A (en) * | 1987-04-09 | 1990-04-17 | Moli Energy Limited | Chevrel-phase syntheses and electrochemical cells |
| JPH0624983B2 (ja) * | 1987-10-16 | 1994-04-06 | 松下電器産業株式会社 | シェブレル化合物の製造法 |
| JPH0230624A (ja) * | 1988-07-20 | 1990-02-01 | Mitsui Toatsu Chem Inc | 銅モリブデン硫化物の製造方法 |
| JPH0350108A (ja) * | 1989-07-17 | 1991-03-04 | Natl Res Inst For Metals | 金属硫化物の製造方法 |
| JPH03109212A (ja) * | 1989-09-21 | 1991-05-09 | Mitsui Toatsu Chem Inc | シェブレル相硫化物の製造方法 |
| DE69516351T2 (de) * | 1994-09-21 | 2000-12-07 | Matsushita Electric Industrial Co., Ltd. | Sekundäre Lithium Feststoffbatterie |
| JP3885897B2 (ja) | 1996-04-16 | 2007-02-28 | 古河機械金属株式会社 | 硫化珪素の製造方法 |
| JP2958445B2 (ja) * | 1997-03-07 | 1999-10-06 | 科学技術庁無機材質研究所長 | Ｌｉ５Ａｇ２Ｈｆ３Ｓ８で示される立方晶系の構造を有する化合物およびその製造法 |
| JPH11297358A (ja) * | 1998-04-14 | 1999-10-29 | Matsushita Electric Ind Co Ltd | リチウム二次電池 |
| JPH11297359A (ja) * | 1998-04-15 | 1999-10-29 | Matsushita Electric Ind Co Ltd | 全固体リチウム二次電池 |
-
1999
- 1999-06-17 GB GB9914041A patent/GB2351075A/en not_active Withdrawn
-
2000
- 2000-06-05 CA CA002375195A patent/CA2375195C/en not_active Expired - Fee Related
- 2000-06-05 AT AT00937049T patent/ATE253017T1/de not_active IP Right Cessation
- 2000-06-05 WO PCT/GB2000/002179 patent/WO2000078673A1/en not_active Ceased
- 2000-06-05 ES ES00937049T patent/ES2207520T3/es not_active Expired - Lifetime
- 2000-06-05 AU AU52343/00A patent/AU5234300A/en not_active Abandoned
- 2000-06-05 JP JP2001504848A patent/JP4744755B2/ja not_active Expired - Lifetime
- 2000-06-05 EP EP00937049A patent/EP1187790B1/en not_active Expired - Lifetime
- 2000-06-05 DE DE60006236T patent/DE60006236T2/de not_active Expired - Lifetime
- 2000-06-05 GB GB0128324A patent/GB2365858B/en not_active Expired - Lifetime
- 2000-06-05 US US09/980,711 patent/US6740301B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| AU5234300A (en) | 2001-01-09 |
| EP1187790A1 (en) | 2002-03-20 |
| JP2003502265A (ja) | 2003-01-21 |
| US6740301B1 (en) | 2004-05-25 |
| GB2365858A (en) | 2002-02-27 |
| ATE253017T1 (de) | 2003-11-15 |
| JP4744755B2 (ja) | 2011-08-10 |
| CA2375195C (en) | 2009-08-11 |
| DE60006236D1 (de) | 2003-12-04 |
| WO2000078673A1 (en) | 2000-12-28 |
| GB0128324D0 (en) | 2002-01-16 |
| GB9914041D0 (en) | 1999-08-18 |
| GB2351075A (en) | 2000-12-20 |
| DE60006236T2 (de) | 2004-07-29 |
| GB2365858B (en) | 2002-12-31 |
| EP1187790B1 (en) | 2003-10-29 |
| CA2375195A1 (en) | 2000-12-28 |
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