CA2375195C - Process for producing a lithium transition metal sulphide - Google Patents

Process for producing a lithium transition metal sulphide Download PDF

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Publication number
CA2375195C
CA2375195C CA002375195A CA2375195A CA2375195C CA 2375195 C CA2375195 C CA 2375195C CA 002375195 A CA002375195 A CA 002375195A CA 2375195 A CA2375195 A CA 2375195A CA 2375195 C CA2375195 C CA 2375195C
Authority
CA
Canada
Prior art keywords
lithium
sulphide
transition metal
sulphur
solvent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002375195A
Other languages
English (en)
French (fr)
Other versions
CA2375195A1 (en
Inventor
Andrew Grahame Ritchie
Peter George Bowles
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qinetiq Ltd
Original Assignee
Qinetiq Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qinetiq Ltd filed Critical Qinetiq Ltd
Publication of CA2375195A1 publication Critical patent/CA2375195A1/en
Application granted granted Critical
Publication of CA2375195C publication Critical patent/CA2375195C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H01M4/5815—Sulfides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/002—Compounds containing titanium, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G33/00—Compounds of niobium
    • C01G33/006—Compounds containing niobium, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G39/00—Compounds of molybdenum
    • C01G39/006—Compounds containing molybdenum, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/009—Compounds containing iron, with or without oxygen or hydrogen, and containing two or more other elements
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Compounds Of Iron (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Saccharide Compounds (AREA)
  • Catalysts (AREA)
CA002375195A 1999-06-17 2000-06-05 Process for producing a lithium transition metal sulphide Expired - Fee Related CA2375195C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB9914041A GB2351075A (en) 1999-06-17 1999-06-17 Producing lithiated transition metal sulphides
GB9914041.0 1999-06-17
PCT/GB2000/002179 WO2000078673A1 (en) 1999-06-17 2000-06-05 Process for producing a lithium transition metal sulphide

Publications (2)

Publication Number Publication Date
CA2375195A1 CA2375195A1 (en) 2000-12-28
CA2375195C true CA2375195C (en) 2009-08-11

Family

ID=10855484

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002375195A Expired - Fee Related CA2375195C (en) 1999-06-17 2000-06-05 Process for producing a lithium transition metal sulphide

Country Status (10)

Country Link
US (1) US6740301B1 (https=)
EP (1) EP1187790B1 (https=)
JP (1) JP4744755B2 (https=)
AT (1) ATE253017T1 (https=)
AU (1) AU5234300A (https=)
CA (1) CA2375195C (https=)
DE (1) DE60006236T2 (https=)
ES (1) ES2207520T3 (https=)
GB (2) GB2351075A (https=)
WO (1) WO2000078673A1 (https=)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0029958D0 (en) 2000-12-08 2001-01-24 Secr Defence Synthesis of lithium transition metal sulphides
EP2146931B1 (de) 2007-04-16 2014-09-24 Basf Se Verfahren zur herstellung von lithiumreichen metalloxiden
GB2464455B (en) * 2008-10-14 2010-09-15 Iti Scotland Ltd Lithium-containing transition metal sulfide compounds
JP5271035B2 (ja) * 2008-10-23 2013-08-21 日本化学工業株式会社 硫化リチウム鉄の製造方法及び硫化リチウム遷移金属の製造方法
JP5403632B2 (ja) * 2009-01-22 2014-01-29 独立行政法人産業技術総合研究所 硫化鉄リチウム複合体の製造方法
CN102797031B (zh) * 2012-08-22 2015-07-08 兰州大学 一种黄铁矿型二硫化亚铁纳米单晶半导体材料的制备方法
JP6011989B2 (ja) * 2013-03-18 2016-10-25 国立研究開発法人産業技術総合研究所 リチウムチタン硫化物、リチウムニオブ硫化物及びリチウムチタンニオブ硫化物
JP6254413B2 (ja) * 2013-10-07 2017-12-27 古河機械金属株式会社 硫化リチウムの製造方法
DE102014211421A1 (de) 2014-06-13 2015-12-17 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren zur Herstellung von Alkalimetallsulfid-Nanopartikeln, Alkalimetallsulfid-Nanopartikel, Verwendung der Alkalimetallsulfid-Nanopartikel sowie Alkalimetall-Schwefel-Batterie
KR102350807B1 (ko) * 2014-11-18 2022-01-14 내셔날 인스티튜트 오브 어드밴스드 인더스트리얼 사이언스 앤드 테크놀로지 리튬-철-인-황-탄소 복합체 및 그 제조 방법
CN106129380A (zh) * 2016-08-31 2016-11-16 四川剑兴锂电池有限公司 一种正极极片及含有该正极片的无定形碳锂电池
CN112670559A (zh) 2019-10-15 2021-04-16 通用汽车环球科技运作有限责任公司 固态电解质和制备其的方法
DE102020125123B4 (de) 2020-09-25 2022-06-30 GM Global Technology Operations LLC Verfahren zur Herstellung eines Festkörperelektrolyten
CN112678865A (zh) * 2021-01-13 2021-04-20 福建工程学院 一种基于过渡金属硫化物的光限幅材料
CN121546045A (zh) * 2026-01-20 2026-02-17 浙江工业大学 一种双功能网络结构硫化锂复合正极材料及其制备方法和应用

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB385895A (en) * 1931-09-05 1933-01-05 Ig Farbenindustrie Ag Improved manufacture of anhydrous alkali polysulphides
GB453203A (en) * 1935-03-04 1936-09-04 Werner Wilfred Duecker Improvements in plastics
GB805922A (en) * 1955-10-17 1958-12-17 Texas Gulf Sulphur Co Improvements in or relating to decomposition of sulfide minerals
US3925098A (en) * 1974-11-27 1975-12-09 Electric Power Res Inst Positive electrode for electrical energy storage device
FR2420852A1 (fr) * 1978-03-24 1979-10-19 Comp Generale Electricite Generateur au lithium
US4164069A (en) * 1978-04-28 1979-08-14 The United States Of America As Represented By The United States Department Of Energy Method of preparing a positive electrode for an electrochemical cell
US4172926A (en) * 1978-06-29 1979-10-30 The United States Of America As Represented By The United States Department Of Energy Electrochemical cell and method of assembly
GB2057412B (en) 1979-08-20 1983-05-18 Ihara Chemical Ind Co Process for preparing carbonyl sulphide
US4731307A (en) * 1986-06-10 1988-03-15 The United States Of America As Represented By The United States Department Of Energy Methods for achieving the equilibrium number of phases in mixtures suitable for use in battery electrodes, e.g., for lithiating FeS2
US4761487A (en) * 1986-06-10 1988-08-02 The United States Of America As Represented By The United States Department Of Energy Method for improving voltage regulation of batteries, particularly Li/FeS2 thermal batteries
US4917871A (en) * 1987-04-09 1990-04-17 Moli Energy Limited Chevrel-phase syntheses and electrochemical cells
JPH0624983B2 (ja) * 1987-10-16 1994-04-06 松下電器産業株式会社 シェブレル化合物の製造法
JPH0230624A (ja) * 1988-07-20 1990-02-01 Mitsui Toatsu Chem Inc 銅モリブデン硫化物の製造方法
JPH0350108A (ja) * 1989-07-17 1991-03-04 Natl Res Inst For Metals 金属硫化物の製造方法
JPH03109212A (ja) * 1989-09-21 1991-05-09 Mitsui Toatsu Chem Inc シェブレル相硫化物の製造方法
DE69516351T2 (de) * 1994-09-21 2000-12-07 Matsushita Electric Industrial Co., Ltd. Sekundäre Lithium Feststoffbatterie
JP3885897B2 (ja) 1996-04-16 2007-02-28 古河機械金属株式会社 硫化珪素の製造方法
JP2958445B2 (ja) * 1997-03-07 1999-10-06 科学技術庁無機材質研究所長 Ｌｉ５Ａｇ２Ｈｆ３Ｓ８で示される立方晶系の構造を有する化合物およびその製造法
JPH11297358A (ja) * 1998-04-14 1999-10-29 Matsushita Electric Ind Co Ltd リチウム二次電池
JPH11297359A (ja) * 1998-04-15 1999-10-29 Matsushita Electric Ind Co Ltd 全固体リチウム二次電池

Also Published As

Publication number Publication date
AU5234300A (en) 2001-01-09
EP1187790A1 (en) 2002-03-20
JP2003502265A (ja) 2003-01-21
US6740301B1 (en) 2004-05-25
GB2365858A (en) 2002-02-27
ATE253017T1 (de) 2003-11-15
JP4744755B2 (ja) 2011-08-10
ES2207520T3 (es) 2004-06-01
DE60006236D1 (de) 2003-12-04
WO2000078673A1 (en) 2000-12-28
GB0128324D0 (en) 2002-01-16
GB9914041D0 (en) 1999-08-18
GB2351075A (en) 2000-12-20
DE60006236T2 (de) 2004-07-29
GB2365858B (en) 2002-12-31
EP1187790B1 (en) 2003-10-29
CA2375195A1 (en) 2000-12-28

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Effective date: 20140605