ES2007367A6 - Un procedimiento mejorado de hidroformiliacion no acuosa para producir aldehidos - Google Patents

Un procedimiento mejorado de hidroformiliacion no acuosa para producir aldehidos

Info

Publication number
ES2007367A6
ES2007367A6 ES8702037A ES8702037A ES2007367A6 ES 2007367 A6 ES2007367 A6 ES 2007367A6 ES 8702037 A ES8702037 A ES 8702037A ES 8702037 A ES8702037 A ES 8702037A ES 2007367 A6 ES2007367 A6 ES 2007367A6
Authority
ES
Spain
Prior art keywords
hydroformylation
low volatile
organic soluble
phosphine ligands
soluble phosphine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES8702037A
Other languages
English (en)
Inventor
Anthony George Abatjoblu
David Robert Bryant
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of ES2007367A6 publication Critical patent/ES2007367A6/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5004—Acyclic saturated phosphines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

UN PROCEDIMIENTO MEJORADO DE HIDROFORMILACION NO ACUOSA PARA PRODUCIR ALDEHIDOS, EN EL QUE SE HACE REACCIONAR UN COMPUESTO ORGANICO OLEFINICAMENTE INSATURADO CON MONOXIDO DE CARBONO E HIDROGENO, EN UN MEDIO NO ACUOSO QUE CONTIENE UN LIGANDO DE FOSFORO LIBRE Y UN CATALIZADOR COMPLEJO DE METAL DE TRANSICION LIGANDO DE FOSFORO, CONSISTIENDO AMBOS LIGANDOS EN UNA SAL DE FOSFINA TERCIARIA MONOSULFONADA DE FORMULA:DONDE R ES ALQUILO, ARILO, ALCARILO, ARALQUILO O CICLOALQUILO Y M ES UN CATION AMINICO DE FORMULA:DONDE R1 ES HIDROGENO, ALQUILO, ARILO, ALCARILO, ARALQUILO O CICLOALQUILO Y CADA RY-R4 ES ALQUILO, ARILO, ALCARILO, ARALQUILO O CICLOHEXILO. LA TEMPERATURA DE REACCION ES DE 45-200GC, LA PRESION ES MENOR DE 105 KG/CMY ABSOLUTOS Y LA RELACION MOLAR DE HIDROGENO A MONOXIDO DE CARBONO ES DE 1:10-100:1. EL INVENTO ES UTIL PARA HIDROFORMILAR OLEFINAS DE ALTO PESO MOLECULAR.
ES8702037A 1986-07-10 1987-07-10 Un procedimiento mejorado de hidroformiliacion no acuosa para producir aldehidos Expired ES2007367A6 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/884,197 US4716250A (en) 1986-07-10 1986-07-10 Hydroformylation using low volatile/organic soluble phosphine ligands

Publications (1)

Publication Number Publication Date
ES2007367A6 true ES2007367A6 (es) 1989-06-16

Family

ID=25384155

Family Applications (1)

Application Number Title Priority Date Filing Date
ES8702037A Expired ES2007367A6 (es) 1986-07-10 1987-07-10 Un procedimiento mejorado de hidroformiliacion no acuosa para producir aldehidos

Country Status (29)

Country Link
US (1) US4716250A (es)
EP (1) EP0254937B1 (es)
JP (1) JPS6388150A (es)
KR (1) KR910008369B1 (es)
CN (1) CN1020720C (es)
AR (1) AR243490A1 (es)
AT (1) ATE74120T1 (es)
AU (1) AU605773B2 (es)
BE (1) BE1001190A5 (es)
BR (1) BR8703510A (es)
CA (1) CA1307006C (es)
CS (1) CS271475B2 (es)
DE (2) DE3777714D1 (es)
DK (1) DK359987A (es)
ES (1) ES2007367A6 (es)
FI (1) FI89351C (es)
FR (1) FR2603579B1 (es)
GB (1) GB2193494B (es)
HU (1) HU202468B (es)
IN (1) IN169702B (es)
IT (1) IT1221979B (es)
MX (1) MX166891B (es)
NL (1) NL8701626A (es)
NO (1) NO165877C (es)
PL (1) PL151795B1 (es)
SE (1) SE8702822L (es)
SU (1) SU1715202A3 (es)
YU (1) YU46424B (es)
ZA (1) ZA875058B (es)

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US5180854A (en) * 1988-07-14 1993-01-19 Union Carbide Chemicals & Plastics Technology Corporation Process for catalyst aldehyde product separation
US5113022A (en) * 1988-08-05 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Ionic phosphites used in homogeneous transition metal catalyzed processes
US5059710A (en) * 1988-08-05 1991-10-22 Union Carbide Chemicals And Plastics Technology Corporation Ionic phosphites and their use in homogeneous transition metal catalyzed processes
US4935550A (en) * 1988-08-12 1990-06-19 Union Carbide Chemicals And Plastics Company Inc. Catalytic metal recovery from non-polar organic solutions
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US4861918A (en) * 1988-08-12 1989-08-29 Union Carbide Corporation Reactivation of hydroformylation catalysts
DE3942954A1 (de) * 1989-12-23 1991-06-27 Hoechst Ag Verfahren zur herstellung von aldehyden
JPH06503808A (ja) * 1990-08-31 1994-04-28 ザ　ガヴァナーズ　オヴ　ザ　ユニヴァーシティ　オヴ　アルバータ 新規の遷移金属触媒先駆物質を用いるメタノールのカルボニル化
US5087763A (en) * 1990-11-09 1992-02-11 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
US5288818A (en) * 1991-08-20 1994-02-22 Exxon Chemical Patents Inc. Method for separating a water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction
US5215667A (en) * 1991-08-20 1993-06-01 Exxon Chemical Patents Inc. Method for separating water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction
CN1036388C (zh) * 1992-12-29 1997-11-12 中国石化兰州炼油化工总厂 烯烃氢甲酰化合成醛的方法
EP0823282B1 (de) * 1996-05-15 2001-11-14 Celanese Chemicals Europe GmbH Verfahren zur Herstellung von Aldehyden
DE19619528A1 (de) * 1996-05-15 1997-11-20 Hoechst Ag Substituierte Diphosphine und ein Verfahren zu ihrer Herstellung
ID21537A (id) * 1997-12-22 1999-06-24 Celanese Gmbh Proses pembuatan aldehid
DE19756945C2 (de) * 1997-12-22 2000-08-03 Celanese Chem Europe Gmbh Nichtwäßrige ionogene Ligandflüssigkeiten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatorbestandteil
JP3921853B2 (ja) * 1998-12-10 2007-05-30 三菱化学株式会社 アルデヒド類及びアルコール類の製造方法
FR2813305B1 (fr) * 2000-08-23 2004-02-13 Inst Francais Du Petrole Procede ameliore d'hydroformylation mettant en oeuvre un catalyseur a base de cobalt et/ou de rhodium dans un solvant ionique non aqueux
SG93931A1 (en) * 2001-04-13 2003-01-21 Kuraray Co Phosphonium salts and processes for production of and uses for the same, and phosphines deriving the same and processes for production of the phosphines
DE502004007631D1 (de) * 2003-10-21 2008-08-28 Basf Se Verfahren zur kontinuierlichen herstellung von aldehyden
CN102826974B (zh) * 2011-06-17 2015-11-25 中国石油化工股份有限公司 一种丙烯氢甲酰化反应制备丁醛的方法
WO2013048701A1 (en) * 2011-09-30 2013-04-04 Dow Technology Investments Llc Purification process
CN104045532B (zh) 2013-03-15 2018-05-25 陶氏技术投资有限责任公司 加氢甲酰化方法
JP6232417B2 (ja) * 2013-03-27 2017-11-15 株式会社クラレ ビス（６−メチル−３−スルホフェニル）フェニルホスフィンおよびそのアンモニウム塩並びにそれらの製造方法
SG11201507899YA (en) 2013-03-27 2015-11-27 Kuraray Co Bis(6-methyl-3-sulphophenyl)(2-methylphenyl)phosphine, ammonium salt thereof, and method for producing same
US9315433B2 (en) 2013-03-27 2016-04-19 Kuraray Co., Ltd. Method for producing 2,7-octadien-1-OL
CN104248860A (zh) 2013-06-27 2014-12-31 陶氏技术投资有限责任公司 热管理方法
WO2015065610A1 (en) 2013-10-28 2015-05-07 Rohm And Haas Company Process for separating methacrolein
MX2019013522A (es) 2017-05-25 2020-02-13 Rohm & Haas Proceso para preparar metacroleina.
WO2018217964A1 (en) 2017-05-25 2018-11-29 Rohm And Haas Company Process for preparing methacrolein
WO2020057878A1 (en) * 2018-09-17 2020-03-26 Exxonmobil Chemical Patents Inc. Transfer hydroformylation for the production of oxygenates
US20240400494A1 (en) 2021-10-08 2024-12-05 Rohm And Haas Company Process for alkyl methacrylate production
JP2024536183A (ja) 2021-10-08 2024-10-04 ローム アンド ハース カンパニー 酸化的エステル化反応器のための方法
EP4412975A1 (en) 2021-10-08 2024-08-14 Dow Global Technologies LLC Process for methacrylic acid production
CA3233792A1 (en) 2021-10-08 2023-04-13 Kirk W. Limbach Process for methyl methacrylate production
US20240391863A1 (en) 2021-10-08 2024-11-28 Dow Global Technologies Llc Process for low byproduct formation from an oxidative esterification reactor with base addition
CN118076578A (zh) 2021-10-08 2024-05-24 罗门哈斯公司 用于由氧化酯化反应器以副产物较低的方式形成甲基丙烯酸甲酯的方法
EP4412982A1 (en) 2021-10-08 2024-08-14 Rohm and Haas Company Process for methyl methacrylate production from ethanol
CN118076575A (zh) 2021-10-08 2024-05-24 罗门哈斯公司 用于产生甲基丙烯酸甲酯的方法
KR20250119549A (ko) 2022-12-08 2025-08-07 롬 앤드 하스 캄파니 메틸 메타크릴레이트 및 메타크릴산의 동시 제조를 위한 방법
KR20250116032A (ko) 2022-12-08 2025-07-31 다우 글로벌 테크놀로지스 엘엘씨 알킬 메타크릴레이트를 제조하는 방법
GB202307175D0 (en) 2023-05-15 2023-06-28 Johnson Matthey Davy Technologies Ltd Process for hydrogenating a substrate
GB202404300D0 (en) 2024-03-26 2024-05-08 Johnson Matthey Davy Technologies Ltd Process for the production of 2-alkylalkanol

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Also Published As

Publication number Publication date
SE8702822D0 (sv) 1987-07-09
FI89351C (fi) 1993-09-27
DE3722928A1 (de) 1988-01-21
NO872887D0 (no) 1987-07-10
FI873054L (fi) 1988-01-11
DK359987D0 (da) 1987-07-10
GB2193494B (en) 1991-01-02
NO165877B (no) 1991-01-14
EP0254937A3 (en) 1989-04-19
PL151795B1 (en) 1990-10-31
FR2603579B1 (fr) 1990-05-25
ZA875058B (en) 1988-03-30
AU605773B2 (en) 1991-01-24
KR910008369B1 (ko) 1991-10-12
GB2193494A (en) 1988-02-10
HUT48193A (en) 1989-05-29
YU46424B (sh) 1993-10-20
SU1715202A3 (ru) 1992-02-23
EP0254937B1 (en) 1992-03-25
CA1307006C (en) 1992-09-01
NL8701626A (nl) 1988-02-01
IT8721213A0 (it) 1987-07-08
PL266758A1 (en) 1988-09-01
ATE74120T1 (de) 1992-04-15
HU202468B (en) 1991-03-28
JPH0548214B2 (es) 1993-07-20
MX166891B (es) 1993-02-11
DE3777714D1 (de) 1992-04-30
FR2603579A1 (fr) 1988-03-11
DK359987A (da) 1988-01-11
YU129787A (en) 1988-04-30
CS271475B2 (en) 1990-10-12
CN1020720C (zh) 1993-05-19
SE8702822L (sv) 1988-01-11
AU7553187A (en) 1988-01-14
AR243490A1 (es) 1993-08-31
BR8703510A (pt) 1988-03-22
EP0254937A2 (en) 1988-02-03
KR880001557A (ko) 1988-04-25
BE1001190A5 (fr) 1989-08-16
CS527687A2 (en) 1990-02-12
US4716250A (en) 1987-12-29
IN169702B (es) 1991-12-14
NO872887L (no) 1988-01-11
FI89351B (fi) 1993-06-15
FI873054A0 (fi) 1987-07-10
JPS6388150A (ja) 1988-04-19
NO165877C (no) 1991-04-24
CN87105466A (zh) 1988-02-03
IT1221979B (it) 1990-08-31
GB8716161D0 (en) 1987-08-12

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Effective date: 20000202