EP1784294A1 - Article moule par injection decore, pellicule de transfert et procede de fabrication d'un tel article - Google Patents

Article moule par injection decore, pellicule de transfert et procede de fabrication d'un tel article

Info

Publication number
EP1784294A1
EP1784294A1 EP05782855A EP05782855A EP1784294A1 EP 1784294 A1 EP1784294 A1 EP 1784294A1 EP 05782855 A EP05782855 A EP 05782855A EP 05782855 A EP05782855 A EP 05782855A EP 1784294 A1 EP1784294 A1 EP 1784294A1
Authority
EP
European Patent Office
Prior art keywords
layer
injection
plastic material
decorative
molded article
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP05782855A
Other languages
German (de)
English (en)
Inventor
Andreas Hirschfelder
Klaus HÖNG
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Leonhard Kurz Stiftung and Co KG
Original Assignee
Leonhard Kurz GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Leonhard Kurz GmbH and Co KG filed Critical Leonhard Kurz GmbH and Co KG
Publication of EP1784294A1 publication Critical patent/EP1784294A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14778—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the article consisting of a material with particular properties, e.g. porous, brittle
    • B29C45/14811—Multilayered articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14827—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles using a transfer foil detachable from the insert
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/08—Biaxial stretching during blow-moulding
    • B29C49/10—Biaxial stretching during blow-moulding using mechanical means for prestretching
    • B29C49/14—Clamps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C2045/1486—Details, accessories and auxiliary operations
    • B29C2045/14901—Coating a sheet-like insert smaller than the dimensions of the adjacent mould wall
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24843—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] with heat sealable or heat releasable adhesive layer

Definitions

  • the invention relates to a decorated injection molded article, which is formed from at least one molded plastic material and at least one mechanically fixedly connected decorative element, wherein the decorative element has one or more layers and a decor and / or a protective layer for the
  • Injection molded article provides, wherein the injection molded article has at least one spray seam, which is formed in the injection molding in the closing region of an injection mold or in the transition region between at least two individual parts of the injection mold on the molded plastic material.
  • the invention further relates to a transfer film for producing such a decorated injection molded article, wherein the transfer film has at least one carrier film, a release layer arranged on the carrier film and a transfer layer arranged on the side of the release layer facing away from the carrier film as decorative element, wherein the decorative element has one or more layer layers and provides a decor and / or a protective layer for the injection molded article, wherein the transfer layer adjacent to the release layer at least one protective lacquer layer and / or at least one decorative layer and at least one adhesive layer adjacent to the protective lacquer or decorative layer on the side facing away from the carrier film of the transfer film which softens at a spray temperature and combines with a plastic injection molding compound to form the injection molded article.
  • the invention furthermore relates to a method for producing a decorated injection-molded article using a transfer film which has at least one carrier film, a release layer arranged on the carrier film and a transfer layer arranged on the side of the release layer facing away from the carrier film as decorative element, wherein the decorative element has one or more Having layer layers and a decor and / or a protective layer for the injection molding article provides, wherein the transfer layer adjacent to the release layer at least one protective lacquer layer and / or at least one decorative layer and adjacent to the protective lacquer or decorative layer on the side facing away from the carrier film of the transfer film at least one Priming layer, wherein the transfer film is placed in a, at least two items comprising, open injection mold, the injection mold is closed and filled with plastic injection molding compound, wherein the Gr undulating layer softens at a spray temperature and combines with the plastic injection molding compound and wherein the injection molded article at least one spray seam is formed in the
  • DE 102 21 482 C1 discloses a device for producing a molded part from a thermosetting injection molding material, which is decorated by in-mold spraying with an embossing foil having a carrier foil and a decorative layer.
  • the embossing film is thereby inserted into the opened injection mold, wherein the decorative layer of the embossing film faces a top mold.
  • the injection mold is closed and liquid injection molding material is injected through an injection channel in the injection mold cavity, wherein the stamping foil conforms to the visible side of the molded part.
  • the embossing film combines with the injection molding material, which is removed from the injection mold after curing. After removing the carrier film from the decorative layer, the decorated molded part is completed.
  • Such decorated injection molded articles will be especially in automotive interior parts such as door strips, strips in instrument panels, gear lever covers, center console covers and automotive exterior parts such Schorammschutzmannn, covers on A-, B- and C-pillars and in the audio and video field used in trim strips on the housing of radios and televisions.
  • the carrier foil is removed after the decorative element has been applied to the injection-molded body.
  • the decorative element comprises a release layer, a resist layer, a structural layer having a spatial structure, an intermediate layer, a reflective layer, and an adhesive layer.
  • the release layer serves to detach the decorative element from the carrier and may for example consist of a waxy material.
  • IMD films are usually fed via a film feed device between a fixed and a movable part of the injection mold.
  • the IMD film is also positioned on the IMD film in the correct position to the injection mold via sensors and position markings before the injection mold is closed and the IMD film is back-injected with the hot plastic injection molding compound.
  • Injection molded articles decorated with an ornamental element in an in-mold process have hitherto produced a complete covering of a surface area delimited by a spray seam extending annularly on the plastic material with the decorative element. As a rule, such a surface area also predominantly forms the visible surface of the injection-molded article, so that a full-surface decoration of the entire visible surface takes place. The visual appearance of the injection molded article is thus far dependent on the decorative element used. It is an object of the invention to provide injection molded articles decorated with decorative elements having a novel optical appearance and improved further processibility. A further object of the present invention is to provide a transfer film suitable for forming such decorated injection-molded articles and a suitable method for producing such decorated injection-molded articles.
  • the object is for the decorated injection molded article, which is formed from at least one molded plastic material and at least one mechanically fixedly connected decorative element, wherein the decorative element has one or more layer layers and provides a decor and / or a protective layer for the injection molded article, wherein the injection molded article at least a spray seam, which is formed in the injection molding in the closing region of an injection mold or in the transition region between at least two individual parts of the injection mold on the injection-molded plastic material, achieved in that the at least one decorative element, one of a ring on the plastic material extending spray surface limited surface area of the plastic material only partially covered and that the decorative element at least one protective lacquer layer and / or at least one decorative layer and adjacent to the protective lacquer or decorative layer at least one Gru annealing layer, which softens at an injection molding temperature for the plastic material, wherein the primer layer is bonded to the plastic material.
  • the injection-molded article according to the invention has only a partial coating with the decorative element in a surface region delimited by a ring-shaped spray seam on the plastic material, so that regions with hardened plastic injection molding compound are also present in the field of vision next to the region (s) of the injection-molded article decorated with the decorative element present without covering with a decorative element.
  • This opens up a multitude of new possibilities for providing a visually appealing, decorated injection molded article. If, in addition, an appealing color design of the plastic injection molding compound is taken into account, further new optical effects result.
  • injection molding articles for the automotive sector can be provided which have an intarsia decor. Here are the inlaid or the intarsia effect generated by partially arranged decorative elements.
  • a further processing of the injection molded article is enormously simplified by the exposed areas of the hardened plastic injection molding compound, as will be described later.
  • the at least one decorative element superimposes a spatial surface structuring of the plastic material.
  • the spatial structure can be visible only through the decorative element, but also haptically detectable in the region of the decorative element. It can be generated by this particularly interesting optical effects.
  • the at least one decorative element is at least partially over-injected with a second plastic material on its side facing away from the first plastic material.
  • further optical effects to achieve an optical depth such as lens effects, can be generated.
  • an overmolding of the decorative element alone to protect it against mechanical and / or corrosive stress has been proven.
  • the second plastic material is at least partially covered with at least one further decorative element on its side facing away from the at least one decorative element.
  • the decorative elements can overlap optically, so that, for example, special depth effects or color effects are achieved.
  • the object is for a transfer film for producing such a decorated injection molded article, wherein the transfer film has at least one carrier film, a release layer arranged on the carrier film and a transfer layer arranged on the side of the release layer facing away from the carrier film as decorative element, wherein the decorative element has one or more layer layers and provides a decor and / or a protective layer for the injection molded article, wherein the transfer layer adjacent to the release layer at least one protective lacquer layer and / or at least one decorative layer and at least one primer layer adjacent to the protective lacquer or decorative layer on the side facing away from the carrier film having, which softens at a spray temperature and combines with the plastic material for forming the injection molded article, achieved in that a) a masking layer only partially covers the primer layer on its side facing away from the carrier film, wherein the masking layer is formed such that it does not coincide with under spray conditions connects the plastic material, or b) the primer layer is arranged only in some areas and adjacent to the primer layer protective lacquer or decorative layer is
  • injection-molded articles can be decorated in a simple and cost-effective manner on the surface.
  • Suitable layers which prevent sticking or a connection with the plastic injection molding compound preferably have a softening temperature which is significantly above the processing temperature in the injection molding tool.
  • the masking layer in case b) the protective lacquer or decorative layer adjoining the primer layer, and in case c) the release layer withstand a spray temperature of the plastic material without softening. As a result, a connection with the sprayed plastic material is greatly impeded.
  • the masking layer in case b) the protective lacquer or decorative layer adjacent to the undercoat layer and in case c) the release layer to the plastic material is chemically incompatible, so that it already at the molecular level to a repulsion comes, which prevents a connection with the injected plastic material.
  • layers of the transfer film which are intended to mechanically bond firmly to the plastic material preferably at least partially soften under the processing temperatures in the injection mold and have at least a minor compatibility with the molten plastic material.
  • the masking layer in case b) the protective lacquer or decorative layer adjoining the primer layer and in case c) the peel layer is a lacquer layer highly crosslinked by radiation curing, isocyanate curing or acid hardening, has proven to be useful.
  • radiation curing, isocyanate curing or acid curing highly crosslinked paint layers do not combine with a hot plastic injection molding compound and therefore allow easy and defined separation from the injection molded body.
  • acid-cured melamine resin paints, 2-component polyurethanes or radiation-cured paints have proven to be suitable as masking layers.
  • the release effect of such a layer can be further enhanced if, for example, paints are used which have a very uniform layer thickness in the range of 0.1-20 ⁇ m, preferably 0.3-2.5 ⁇ m and a smooth surface with a surface roughness. in order to prevent a mechanical gearing with the plastic injection compound as possible.
  • these paint layers have a low surface tension.
  • suitable additives preferably based on wax, fluorohydrocarbon or silicone, the surface tension of the masking layer can be lowered further, so that its separation effect is further enhanced.
  • Suitable here are in particular - hydroxy-functional polyether-modified polysiloxanes, dispersions of polyethylene waxes having a melting range below 130 0 C and functionalized fluoroethylene copolymers (Hydroxiowski: 55 mg KOH / g).
  • the object is for the method for producing a decorated injection molded article using a transfer film having at least one carrier film, a release layer arranged on the carrier film and a transfer layer arranged on the side of the release layer facing away from the carrier film as decorative element, wherein the decorative element has one or more Having layer layers and a decor and / or a protective layer for the injection molding article provides, wherein the transfer layer adjacent to the release layer at least one protective lacquer layer and / or at least one decorative layer and adjacent to the protective lacquer or decorative layer on the side facing away from the carrier film of the transfer film at least one Priming layer, wherein the transfer film is placed in a, at least two items comprising, open injection mold, the injection mold is closed and filled with plastic injection molding compound, wherein the primer softens at a spray temperature and combines with the plastic injection molding compound
  • Closing portion of the injection mold or in the transition region between the at least two individual parts of the injection mold is formed, and that the plastic injection molding compound is cured to a first plastic material, achieved in that the at least one decorative element so limited to a, extending from an annular on the plastic material spray seam
  • a transfer film according to the invention which is arranged in the injection mold in such a way that the carrier film bears directly against the injection mold.
  • the transfer film is pressed against the inner wall of the injection mold.
  • the layers arranged on the carrier film which preferably have a thickness in the range from 19 to 100 ⁇ m, are preferably produced in gravure printing, screen printing or, in particular, the decorative layers, also in digital, flexographic or offset printing.
  • the hot plastic injection molding compound comes into contact with the masking layer as well as with exposed areas of the undercoating layer.
  • the plastic injection molding compound mechanically bonds firmly to the priming layer, the priming layer at least melting or completely melting.
  • the direct contact area between the masking layer and the plastic injection molding compound there is no connection, since the masking layer does not combine with the plastic material, preferably by not softening or only above the spray temperature and also receives no chemical reaction with the plastic injection molding compound in the spray temperature.
  • the injection mold is opened and the carrier film removed. Only the areas of the decorative element that are mechanically firmly connected to the plastic material via the priming layer remain on the hardened plastic injection molding compound.
  • a decorated injection-molded article according to the invention is obtained.
  • the use of a transfer film according to case a) is particularly cost-effective, since a conventional, IMD-capable transfer film can be used, which is provided only with a masking layer in the desired pattern or decor. As a result, a pattern change is easy, inexpensive and fast to carry out.
  • the masking layer has a thickness in the range of 1 to 4 ⁇ m. In such a layer thickness particularly sharp edges and good transmission results for the partially transferred decorative elements are achieved.
  • the masking layer at least one Opening with a diameter of at least 0.15 mm. Smaller diameters lead to an incomplete transfer of Obviouslyslage- areas with unclean, randomly changing edges, since the hot plastic injection molding compound can not or only limited penetrate through the opening and can connect to the primer layer.
  • the hot plastic injection molding compound comes into contact with the partially disposed primer layer and with the areas of a protective lacquer or decorative layer which are not covered by the primer layer.
  • the hot plastic injection molding compound mechanically bonds firmly to the priming layer, with the priming layer at least melting or completely melting.
  • the protective lacquer or decorative layer does not combine with the plastic material, preferably by not softening or only above the spraying temperature and no chemical reaction in the spraying temperature received with the plastic injection molding compound.
  • the materials which are also suitable for the masking layer according to case a), for example UV paints based on polyacrylate or 2-component polyurethane paint, can be used for the protective lacquer layer or decorative layer adjacent to the primer layer.
  • the injection mold is opened and the carrier film removed. Only the areas of the decorative element that are mechanically firmly connected to the plastic material via the priming layer remain on the hardened plastic injection molding compound.
  • Decorative layer (s) uncovered by the primer layer are removed together with the carrier film, so that a decorated injection molded article according to the invention is obtained.
  • the use of a transfer film according to case b) is also inexpensive, since a conventional, IMD-capable transfer film can be used, which is provided only with a primer layer in the desired pattern or decor. As a result, a pattern change is also simple, inexpensive and fast to carry out here. If a transfer film according to case c) is used, the hot plastic injection molding compound comes into contact with the primer layer of the partially arranged transfer layer as well as with the exposed areas of a release layer, which may also be provided over a surface of a carrier film of suitable material.
  • the hot plastic injection molding compound mechanically bonds firmly to the priming layer, with the priming layer at least melting or completely melting.
  • the direct contact area between the release layer and the plastic injection molding compound there is no connection, preferably in that the release layer does not soften or only above the spray temperature and does not enter into any chemical reaction with the plastic injection compound in the area of the spray temperature.
  • the materials which are also suitable for the masking layer according to case a) can be used for the release layer, for example acid-cured melamine resin paints, 2-component polyurethanes or radiation-cured paints.
  • the masking layer in case b) the primer layer and in case c) the transfer layer is pattern-shaped, so that a pattern-shaped decoration of the injection molded article results.
  • the masking layer represents the negative for the pattern
  • the primer layer and in case c) the transfer layer represent the positive for the pattern.
  • alphanumeric character representations or pictorial representations such as coats of arms, logos, nature motives or the like understood.
  • the decorative layer has an at least partially formed metal layer and / or an at least partially formed interference layer and / or an at least partially formed ink layer and / or an at least partially arranged layer with relief structures, such as macroscopic relief structures, diffractive structures or holograms, and / or a pigmented layer comprising fluorescent or phosphorescent pigments or pigments with viewing angle dependent color change effects.
  • relief structures such as macroscopic relief structures, diffractive structures or holograms, and / or a pigmented layer comprising fluorescent or phosphorescent pigments or pigments with viewing angle dependent color change effects.
  • the protective lacquer layer of the transfer film according to the invention it has proven useful if the protective lacquer layer is colorless transparent, colored transparent or at least partially opaque. This allows further optical effects to be achieved.
  • the carrier film is formed from a material which can be easily detached from the transfer layer after the injection molding process, then the carrier film has a surface which itself forms the release layer. Carrier film and release layer thus form a unit. An additional release layer on the carrier film can be dispensed with in this case.
  • the injection molded article according to the invention proves to be advantageous if it is to be overmolded with a second plastic injection molding compound in a further injection mold, for example to produce lenticular elements.
  • a good durable connection between the cured plastic material and the second plastic injection molding compound can be produced.
  • the same or different plastic materials can be used here for the cured plastic material and the second plastic injection molding compound, with the same materials also being designated those which have only a different coloring of an otherwise identical plastic.
  • the structure of the decorative film is advantageously not important.
  • such an exposed area of the hardened plastic injection molding compound in the field of view of the injection molded article can continue to be labeled uncomplicatedly, for example by means of a laser. It also results in the possibility that any arranged on the injection molded optical lens systems or contact surfaces of the plastic injection molded body electrically conductive contact structures of the decorative film remain uncovered, so that they remain directly visible and accessible or in the case of the contact surfaces, that these electrical cables or electrical components can be connected. On the decorative film itself so no consideration must be taken, so that in general a very straightforward, fast and therefore cost-effective further processing of the injection molded article according to the invention is possible.
  • FIGS. 1a to 3a are intended to illustrate the invention by way of example. So shows: FIG. 1 a shows a cross section through a transfer film according to case a),
  • FIG. 1 b shows a cross section through a transfer film according to case b
  • FIG. 1c shows a cross section through a transfer film according to case c
  • FIG. 2 a shows a cross section through a decorated injection-molded article
  • FIG. 2b shows a cross section through a decorated injection-molded article, overmolded in the field of view with a second plastic material
  • FIG. 3a shows a cross section through a further decorated injection molded article, which has a spatial structure in a surface area
  • Figure 3b shows a cross section through another decorated injection molded article, which has a spatial structure in a surface area and is over-injected with a second plastic material.
  • FIG. 1 shows a cross section through a transfer film 1a according to case a).
  • Transfer film 1a has a carrier film 2 made of PET with a film thickness of 36 microns, an arranged on the carrier film 2 release layer 3 made of a polyethylene wax melting range of 90-100 0 C and a on the side remote from the carrier film 2 side of the peel layer 3 arranged transfer layer 7 as Decorative element, wherein the decorative element has a plurality of layers.
  • the transfer layer 7 Adjacent to the release layer 3, the transfer layer 7 has a protective lacquer layer 4, a decorative layer 5 and, adjacent to the decorative layer 5 on the side of the transfer foil 1a facing away from the carrier foil 2, a primer layer 6 of polyvinyl chloride copolymers, polymethyl methacrylate (MW 60000 g / mol) , A masking layer 8 partially covers the primer layer 6 on its side facing away from the carrier film 2.
  • the masking layer 8 is a highly crosslinked lacquer layer and has pattern-like openings 9a, which partially expose the primer layer 6.
  • a suitable lacquer for forming the masking layer 8 has the following composition: Example A
  • the masking layer 8 can be used if the plastic material used is PMMA 1 ABS 1 SAN, PS 1 PC, PP or suitable compatible mixtures of these materials.
  • FIG. 1b shows a cross section through a transfer film 1b according to case b).
  • the transfer sheet 1 b has a carrier film 2 made of PET, an arranged on the carrier film 2 release layer 3 made of a polyethylene wax (melting range 80 - 100 0C) and facing away from the carrier film 2 side of the peel layer 3 arranged transfer layer as a decorative element on , wherein the decorative element has a plurality of layer layers.
  • the primer layer 6 is covered the decorative layer 5 only partially.
  • the colored decorative layer 5 was formed by means of the following composition:
  • Chlorinated polyolefin (chlorine content 30%) 33 parts
  • This decorative layer 5 can be used when used as plastic materials PP, PE, TPO.
  • FIG. 1c shows a cross section through a transfer film 1c according to case c).
  • the transfer film 1c has a carrier film 2 made of PET, a release layer 3 arranged on the carrier film 2, and a transfer layer arranged on the side of the release layer 3 facing away from the carrier film 2 as decorative element 9, the decorative element 9 having a plurality of layer layers.
  • Adjacent to the release layer 3, the decorative element 9 has a protective lacquer layer 4, a decorative layer 5 and, adjacent to the decorative layer 5, an undercoating layer 6 on the side of the transfer foil 1a facing away from the carrier foil 2.
  • the decorative element 9 covers the release layer 3 only partially, wherein the protective layer 4, the decorative layer 5 and the primer layer 6 are arranged substantially congruently one above the other.
  • the release layer 3 was formed by means of the following composition:
  • Ethanol 10 parts isopropanol 8 parts methyl ethyl ketone 8 parts toluene 8 parts hexamethylmethylmelamine 25 parts solution of hydroxy-functionalized polymer methacrylate (60%) in 29 parts by weight of xylene
  • thermoplastic polymers such as PMMA, ABS, ASA, PC, PP, PE, SAN, PVC and mixtures compatible therewith.
  • FIG. 2a shows a decorated injection-molded article 11a in cross-section.
  • colored plastic material 10 of PMMA are partially decorative elements 9.
  • the dashed line indicates the position of a spray seam, which is formed on the plastic material 10 in the seam area between the two halves of a closed, two-part injection mold.
  • FIG. 2b shows a decorated injection molded article 11b in cross section.
  • plastic material 10 made of PMMA partially decorative elements 9.
  • the dashed line indicates the position of a spray seam, which has arisen on the plastic material 10 in the seam area between the two halves of a closed, two-part injection mold.
  • the decorative elements 9 as well as the surface area of the plastic material 10 which is limited by the spray seam are overmolded with a second colorless transparent plastic material 12 made of PMMA or PC, PS, SAN, PA, so that a depth effect results.
  • FIG. 3a shows a decorated injection molded article 13a in cross section.
  • the decor elements 9 emphasize the elevations in the hardened, colored plastic material 10.
  • the dashed line indicates the position of a spray seam on the plastic material 10 in the seam area between the two Halves of a closed, two-piece injection mold has emerged.
  • FIG. 3b shows a decorated injection-molded article 13b in cross-section.
  • the decor elements 9 emphasize the elevations in the hardened, colored plastic material 10.
  • the dashed line indicates the position of a spray seam on the plastic material 10 in the seam area between the two Halves of a closed, two-piece injection mold has emerged.
  • the decorative elements 9 as well as the surface area of the plastic material 10 delimited by the spray seam are overmolded with a second, colorless, transparent plastic material 12, so that a depth effect results, the spatial structure of the hardened, colored plastic material 10 remaining visible.

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Laminated Bodies (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)

Abstract

L'invention concerne un article moulé par injection décoré, composé d'au moins un matériau plastique moulé et d'au moins un élément de décoration relié fixement de façon mécanique audit matériau. L'élément de décoration présente une ou plusieurs couches et un décor et/ou une couche de protection, ainsi qu'au moins un joint de moulage formé lors du processus de moulage par injection dans la zone de fermeture du moule ou dans la zone de transition entre au moins deux éléments individuels du moule, sur le matériau plastique moulé. Le ou les éléments de décoration ne recouvrent que partiellement une zone de surface du matériau plastique, délimitée par un joint de moulage s'étendant de façon annulaire sur le matériau plastique, et l'élément de décoration comporte au moins une couche de vernis de protection (4) et/ou au moins une couche de décoration (5), ainsi qu'au moins une couche de base (6) adjacente à la couche de vernis de protection ou de décoration, ramollissant à une température de moulage par injection du matériau plastique, ladite couche de base étant par ailleurs reliée au matériau plastique. L'invention concerne également une couche de transfert dans le moule ainsi qu'un procédé de fabrication de tel article moulé par injection.
EP05782855A 2004-08-27 2005-08-23 Article moule par injection decore, pellicule de transfert et procede de fabrication d'un tel article Withdrawn EP1784294A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102004041867A DE102004041867A1 (de) 2004-08-27 2004-08-27 Dekorierter Spritzgussartikel, sowie Transferfolie und Verfahren zur Herstellung eines solchen
PCT/DE2005/001487 WO2006021200A1 (fr) 2004-08-27 2005-08-23 Article moule par injection decore, pellicule de transfert et procede de fabrication d'un tel article

Publications (1)

Publication Number Publication Date
EP1784294A1 true EP1784294A1 (fr) 2007-05-16

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EP05782855A Withdrawn EP1784294A1 (fr) 2004-08-27 2005-08-23 Article moule par injection decore, pellicule de transfert et procede de fabrication d'un tel article

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Country Link
US (1) US20080095992A1 (fr)
EP (1) EP1784294A1 (fr)
JP (1) JP4827846B2 (fr)
KR (1) KR101232418B1 (fr)
CN (1) CN101018655B (fr)
BR (1) BRPI0514700A (fr)
DE (1) DE102004041867A1 (fr)
MX (1) MX2007002152A (fr)
TW (1) TWI356762B (fr)
WO (1) WO2006021200A1 (fr)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004062477A1 (de) * 2004-12-24 2006-07-06 Bayer Materialscience Ag Verfahren zur Herstellung eines Verbundformteiles aus Kunststoff und dessen Verwendung
WO2007146034A2 (fr) * 2006-06-07 2007-12-21 Pursuit Engineering Llc Surface(s) optique(s) de réception et de réflexion à haut rendement et système de moulage pour fabriquer lesdites surfaces
DE102007020308A1 (de) * 2007-04-17 2008-10-23 Cmc Consumer Medical Care Gmbh Kraftfahrzeug-Verbandmaterialbehälter
DE102007028469B4 (de) 2007-06-18 2013-08-14 Oechsler Ag Verfahren zum Herstellen von dekorierten Spritzguß-Formteilen und Einrichtung zum Ausüben des Verfahrens
DE102007041347B4 (de) * 2007-08-30 2018-12-20 Linden Gmbh Emblem mit farbigen und silberglänzenden Flächen
JP4544372B2 (ja) * 2008-08-22 2010-09-15 コニカミノルタオプト株式会社 基板の製造方法
US20100075091A1 (en) * 2008-09-22 2010-03-25 Shih-Feng Lee Three dimension ornamental article
AT507883B1 (de) 2009-05-19 2010-09-15 Swarovski & Co Spritzgegossener dekorationsartikel
DE202009015066U1 (de) * 2009-11-05 2010-03-25 Schoeller Arca Systems Gmbh Behälter insbesondere Flaschenkasten mit Inmould-Label
TW201351239A (zh) * 2010-06-07 2013-12-16 Wintek Corp 觸控裝置及觸控顯示裝置
DE102010049006A1 (de) * 2010-10-21 2012-04-26 Schreiner Group Gmbh & Co. Kg Sensoranordnung zur Detektion einer Annäherung und/oder Berührung sowie Verfahren zur Assemblierung einer Sensoranordnung
JP2013544296A (ja) 2010-10-25 2013-12-12 サビック・イノベーティブ・プラスチックス・アイピー・ベスローテン・フェンノートシャップ レーザダイレクトストラクチャリング材料の改善された無電解メッキ性能
WO2012056416A1 (fr) * 2010-10-26 2012-05-03 Sabic Innovative Plastics Ip B.V Matériaux de structuration directe au laser avec prise en compte de toutes les couleurs
JP2012142364A (ja) * 2010-12-28 2012-07-26 Nitto Denko Corp 封止部材、封止方法、および、光半導体装置の製造方法
KR101308763B1 (ko) * 2011-01-11 2013-09-17 (주)엘지하우시스 3차원 표면 패턴을 쉽게 형성할 수 있는 몰드를 이용한 고분자 성형물 제조 방법 및 3차원 표면 패턴을 갖는 가전제품용 성형물
DE102011108803B4 (de) 2011-07-29 2017-06-29 Polyic Gmbh & Co. Kg Touchsensor mit einer Kunststofffolie, Verwendung der Kunststofffolie und Verfahren zur Herstellung einer multimodalen Eingabevorrichtung
JP5066291B1 (ja) * 2012-01-23 2012-11-07 尾池工業株式会社 転写フィルムおよび金属調成形品の製造方法
CN103753760A (zh) * 2013-12-30 2014-04-30 青岛海永盛发展有限公司 一种注塑工艺
US10357909B2 (en) 2014-05-30 2019-07-23 Absolute Exhibits, Inc. Thermoset in-mold finishing film
EP3100915B2 (fr) * 2015-06-03 2022-09-28 WEIDPLAS GmbH Composant
JP6617501B2 (ja) * 2015-09-30 2019-12-11 大日本印刷株式会社 加飾樹脂成形品の製造方法
JP6761048B2 (ja) 2016-06-14 2020-09-23 サン−ゴバン グラス フランス プラスチック乗物付設部材の製造方法
DE102016112505A1 (de) * 2016-07-07 2018-01-11 Leonhard Kurz Stiftung & Co. Kg Transferfolie
CN108927948B (zh) * 2018-07-10 2023-08-25 长虹美菱股份有限公司 一种具有软胶注塑皮革效果的冰箱用饰条及把手的成型工艺
WO2020114924A1 (fr) * 2018-12-04 2020-06-11 Merck Patent Gmbh Procédé de production de motifs virtuels tridimensionnels dans des corps moulés en plastique
DE102019106561A1 (de) 2019-03-14 2020-09-17 Leonhard Kurz Stiftung & Co. Kg Verfahren zur Herstellung eines Bauteils und Vorrichtung zur Herstellung eines Bauteils
JP7101634B2 (ja) * 2019-03-29 2022-07-15 本田技研工業株式会社 樹脂成形品
CN110885470A (zh) * 2019-09-20 2020-03-17 捷开通讯(深圳)有限公司 塑料件及其制备方法

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5734456U (fr) * 1980-08-04 1982-02-23
JPS5734456A (en) * 1980-08-09 1982-02-24 Sumitomo Electric Ind Ltd Wheel velocity sensor
JPS58132529A (ja) * 1982-02-02 1983-08-06 Matsushita Electric Ind Co Ltd 射出同時成形工法
JPS62128720A (ja) * 1985-11-29 1987-06-11 Dainippon Printing Co Ltd 射出同時成形法
JPS62259830A (ja) * 1986-05-07 1987-11-12 Dainippon Toryo Co Ltd プラスチック成形体の製造方法
JPH07102588B2 (ja) * 1988-04-15 1995-11-08 大日本印刷株式会社 絵付成形品の製造方法
CA2022667A1 (fr) 1989-08-09 1991-02-10 Yoichi Ebina Article moule en resine de poly(terephtalate de butylene), portant des motifs picturaux; procede de fabrication
JPH03231821A (ja) * 1990-02-07 1991-10-15 Toppan Printing Co Ltd 絵付き成形品の製造方法及び転写箔
JP2981475B2 (ja) * 1990-06-29 1999-11-22 太平洋工業株式会社 ホイールキャップまたはホイールキャップのセンターエンブレム
JPH0531808A (ja) * 1991-07-31 1993-02-09 Nissha Printing Co Ltd プラスチツク接合製品の製造方法
JPH08413B2 (ja) * 1992-07-31 1996-01-10 日本写真印刷株式会社 電飾用成形品の製造方法
JP2607032B2 (ja) 1993-07-16 1997-05-07 大日本印刷株式会社 成形同時絵付転写フィルム及びその製造方法
JPH08279307A (ja) * 1995-04-05 1996-10-22 Nissha Printing Co Ltd 面発光装置用転写材と面発光装置の製造方法
JPH09262865A (ja) * 1996-03-27 1997-10-07 Taniuchi Kanagata Seisakusho:Kk 樹脂成形品のインモールド転写方法及びその金型装置並びにそれによって得られる樹脂成形品
JPH10180801A (ja) * 1996-12-26 1998-07-07 Nissha Printing Co Ltd 絵付シートとこれを用いた絵付成形品の製造方法
JPH1134064A (ja) * 1997-07-23 1999-02-09 Idemitsu Petrochem Co Ltd 表皮材付き樹脂成形品及びその製造方法
JP3099115B2 (ja) * 1997-07-28 2000-10-16 大日本印刷株式会社 転写シート及びそれを用いた転写方法
AU2881900A (en) * 1999-03-01 2000-09-21 Rexam Industries Corp. Decorative sheet material including mask layer
JP2002293094A (ja) 2001-03-29 2002-10-09 Nissha Printing Co Ltd 転写シートと積層体の製造方法
JP3993771B2 (ja) * 2002-02-01 2007-10-17 日本写真印刷株式会社 加飾シートの製造方法および加飾成形品の製造方法
DE10221482C1 (de) * 2002-05-15 2003-09-18 Kurz Leonhard Fa Vorrichtung zum Herstellen eines abgewinkelt profilierten Formteiles, das mit einer Prägefolie dekoriert wird
DE10236810A1 (de) * 2002-08-10 2004-02-26 Leonhard Kurz Gmbh & Co. Kg Teilstrukturierte IMD-fähige Mehrschichtfolie
CN1175979C (zh) * 2002-09-06 2004-11-17 汕头市东田转印有限公司 一种转印膜的生产方法及其制品

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2006021200A1 *

Also Published As

Publication number Publication date
BRPI0514700A (pt) 2008-06-24
TW200615115A (en) 2006-05-16
TWI356762B (en) 2012-01-21
JP2008510637A (ja) 2008-04-10
MX2007002152A (es) 2007-05-10
CN101018655A (zh) 2007-08-15
KR101232418B1 (ko) 2013-02-15
JP4827846B2 (ja) 2011-11-30
KR20070051923A (ko) 2007-05-18
WO2006021200A1 (fr) 2006-03-02
CN101018655B (zh) 2010-10-13
US20080095992A1 (en) 2008-04-24
DE102004041867A1 (de) 2006-03-16

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