EP0697041A1 - Zentrifugenspinnverfahren und vorrichtung hierzu - Google Patents
Zentrifugenspinnverfahren und vorrichtung hierzuInfo
- Publication number
- EP0697041A1 EP0697041A1 EP94916192A EP94916192A EP0697041A1 EP 0697041 A1 EP0697041 A1 EP 0697041A1 EP 94916192 A EP94916192 A EP 94916192A EP 94916192 A EP94916192 A EP 94916192A EP 0697041 A1 EP0697041 A1 EP 0697041A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- centrifuge
- housing
- yarn
- spinning
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000009987 spinning Methods 0.000 title claims abstract description 77
- 238000004804 winding Methods 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims description 18
- 238000007667 floating Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 210000000056 organ Anatomy 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 2
- 230000013011 mating Effects 0.000 claims 1
- 238000007789 sealing Methods 0.000 claims 1
- 210000003739 neck Anatomy 0.000 description 12
- 238000007383 open-end spinning Methods 0.000 description 5
- 238000007378 ring spinning Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 2
- 241000239290 Araneae Species 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01H—SPINNING OR TWISTING
- D01H1/00—Spinning or twisting machines in which the product is wound-up continuously
- D01H1/08—Spinning or twisting machines in which the product is wound-up continuously cup, pot or disc type, in which annular masses of yarn are formed by centrifugal action
Definitions
- the invention relates to a centrifugal spinning method according to the preamble of claim 1, with which yarn of a classic character can be spun, and a device for this.
- a completely twisted yarn is placed in a centrifuge, which creates the problem of removing the winding from the centrifuge.
- a mandrel is inserted into the still rotating centrifuge, which leads to a rewinding process, so that at the end of the operation the yarn is on the mandrel, from which it has to be rewound in a further step to a salable presentation.
- a problem with this method is a yarn break, because the yarn end has to be found in the rotating centrifuge, which can only be solved with considerable effort.
- the invention has for its object to provide a centrifuge spinning process of the type mentioned, which works with a low capital and energy input.
- the purpose of the invention is to produce a ring yarn-like yarn of high quality with lower costs and less energy input than is possible with ring and rotor spindles of the prior art.
- the object is achieved according to the invention by a centrifugal spinning method for spinning a yarn of classic character, by either spinning and removing a completely twisted yarn in one stage or a partially twisted yarn in a centrifuge in a first stage and the same in a second stage in the case of the partially twisted yarn Step during removal by winding up the remaining rotations are given, using the centrifuge, a drafting device, a piecing element and a thread guide tube that changes into the centrifuge, according to the invention the centrifuge rotates in a room with negative pressure, but inside the centrifuge there is normal air pressure and into the centrifuge is spun in under normal air pressure, the negative pressure being set such that essentially only the bearing friction of the centrifuge occurs when the centrifuge rotates and the air friction of the outer wall of the centrifuge is largely suppressed.
- the space between the preferably bottle-shaped centrifuge and a surrounding housing is sealed from the environment and pressurized.
- the vacuum can advantageously be continuously pumped in to compensate for leaks.
- the seal is located at a point that is at a short distance from the axis of rotation of the centrifuge, that is, preferably at its neck.
- a vacuum centrifuge spinning device is characterized in that the centrifuge is rotatably arranged within a housing and the interior space between the centrifuge and the housing can be subjected to negative pressure, but within the centrifuge there is normal air pressure, the negative pressure being adjustable so that essentially only the bearing friction of the centrifuge occurs during rotation, but the air friction with respect to the housing is largely suppressed.
- the centrifuge is advantageously bottle-like or bottle-shaped with a central, narrow neck.
- the housing and / or centrifuge can consist of at least two parts which can be moved apart, one part of the centrifuge being rotatably mounted axially in one part of the housing and the other part axially in the other part of the housing. Further advantageous refinements of the invention are contained in the dependent subclaims.
- the vacuum centrifuge spinning process and the vacuum centrifuge spinning device have the salient advantage that the specific capital and energy requirements, based on a yarn of the same strength and fineness, is lower than that of the known ring and rotor spinning.
- a sufficiently simple spinning device can be constructed with the vacuum centrifuge spinning device, the speed of rotation being determined only by the strength of the centrifuge, without the energy expenditure for driving the device becoming too high. In this case, speeds of up to 80,000 rpm and more can be achieved, so that the drafting system can be operated at much higher delivery speeds. It is therefore possible to spin with a specifically lower energy expenditure than is possible with ring and rotor spinning devices.
- FIG. 1 is a schematic diagram of a vacuum centrifuge spinning device according to the invention
- FIG. 2 spinning elements between drafting system and can in the case of the can
- Figure 3 shows a piecing element with auxiliary suction channel
- Figure 4a - 4e different spinning stages
- Figure 5 shows a vacuum centrifuge spinning device for step spinning with a cutting and clamping device
- FIG. 6 shows a gimbal-mounted vacuum centrifuge spinning device for pure centrifugal spinning
- FIG. 7 shows a further gimbal-mounted vacuum centrifuge spinning device, preferably for step spinning and
- Figure 8 shows another gimbal-mounted vacuum centrifuge spinning device.
- FIG. 1 shows a basic illustration of an example of a vacuum centrifuge spinning device 5 for carrying out the method.
- the emerging fiber sliver 13 arrives from a drafting unit 1 into a piecing member 2, with which spinning is automatically carried out.
- the piecing or swirl member 2 guides the yarn that forms in a thread guide tube 3 into a thread guide tube 4, which changes in the centrifuge 6 in the direction of the double arrow.
- the thread guide tube lays the yarn with a wild one Cross winding, in the case of step spinning in two steps, however, in a kind of parallel winding.
- the centrifuge 6 is in a housing 5 ', which can in principle be opened to remove the centrifuge, which is indicated by the dividing lines 73, 73', by means of a bearing 10, freely hanging or free-standing, around a bottle-like neck 62 of the centrifuge 6 stored.
- the neck 62 of the centrifuge 6 is hollow and at the same time forms the axis of rotation of the centrifuge 6 and the access for the thread guide tube 4 into the centrifuge 6, which can therefore preferably be described as bottle-shaped.
- the inner space 7 between the outer wall of the centrifuge 6 and the housing 5 ' is air-free, there is largely a vacuum there, which is indicated by the designation "pu" in FIG.
- the centrifuge neck 62 of the centrifuge 6 from the outside is suitably sealed against the interior 7 of the housing 5 'with a seal 11, but the normal air pressure "pn" prevails within the centrifuge.
- the centrifuge neck 62 has a diameter d which, based on the diameter d z of the centrifuge 6
- the centrifuge 6 is driven by means of a host ice, which is indicated by the curved reference arrow 12.
- the centrifuge 6 is filled when the inner diameter of the yarn winding 9 is approximately 40 mm. In pure centrifugal spinning, the speed is now reduced to about 1/10, the negative pressure is eliminated and the yarn package 9 is removed from the housing by opening the housing, or the yarn can be spooled out of the housing without opening the housing or the centrifuge becomes.
- spinning can be carried out directly from the jug, making good use of the capital tied up in a high drafting system.
- the transport of the tape to the drafting system is facilitated in that a false wire element is arranged in front of the drafting system.
- a sliver divider can be arranged between the false wire element and the drafting system, which supplies both drafting systems.
- FIG. 2 shows the spinning elements located between two drafting systems 1, 1 'and can 14, namely false-wire elements 15 and sliver dividers 16.
- the former gives the belt 13 wrong rotations, making a misalignment-free transport possible.
- the latter distributes the fuse emerging from the false wire element 15 over two drafting devices 1, 1 '.
- FIG. 3 shows the drafting and piecing element 2 in section.
- the intake rollers 18 of the piecing member 2 are opposite the output rollers 17 of the drafting unit 1, two tangential channels 19, 19 ′ being acted upon by air being located therein; in addition, an auxiliary suction channel 20 can be arranged in the area of the mouth of the suction channel 18.
- the diameter of the intake duct 18 is preferably less than 3 mm.
- Compressed air pü enters the thread guide tube 3 via the channels 19, 19 'and forms a vortex, in the center of which there is negative pressure. As a result, a fiber ribbon is sucked in and twisted, which is supported by the auxiliary suction 20.
- the thread guide tube 3 preferably has a diameter of less than 6 mm and opens into the same at the top dead center of the thread guide tube 4.
- the drafting system axis 72 and the axis of the thread guide tube are perpendicular in alignment.
- the drafting system axis 72 can, however, be tilted continuously up to an angle, preferably 45 degrees, against the axis of the thread guide tube; the fulcrum corresponds to the center of the lower roller of the drafting system.
- the character of the yarn can thus be set within limits.
- FIGS. 4a to 4c show the process steps in pure centrifuge spinning.
- the centrifuge 6 consists of two centrifuge parts, namely a centrifuge upper part 21 and a centrifuge lower part 22, the yarn winding 9 is located inside.
- a doffer 23 is assigned, which consists of a holding part 42 which can be suitably held on the machine device and which can be rotated
- Spike 67 carries, on which a sleeve 28 is rotatably arranged, which is able to carry a yarn package 9.
- the centrifuge 6 is moved apart while maintaining a residual speed of 1/10 of the operating speed, so that the doffer 23 can be inserted into the yarn package 9.
- the speed is set to zero, as a result of which the yarn winding 9 shrinks onto the sleeve 28.
- the yarn winding 9 is removed and can be rewound overhead from the sleeve 28, which is indicated in FIG. 4c by the pulling arrow 24 which pulls the thread 8.
- the centrifuge 6 is closed and continues to spin.
- the yarn winding 9 according to FIG. 4d is transferred to an auxiliary centrifuge 25 with a central mandrel 26. After delivery at a standstill, the auxiliary centrifuge 25 is brought to approximately 10,000 rpm. According to FIG. 4e, the yarn 8 can be rewound from the inside outwards with additional rotation. As a result, the yarn is given a few twists per meter if it is unwound at over 2,000 m / min. If the entire process is considered, there is again a step spinning process.
- the yarn can be pulled out of the centrifuge with continued rotation and wound onto a spool which is in the immediate vicinity of the centrifuge, which is shown in FIG. 5. It has proven to be advantageous in the case of two-stage centrifugal spinning to give the yarn at least 90 percent of the twists in the first stage, preferably 95%, and the rest of the twists in the second stage.
- the thread guide tube 4 After the centrifuge 6 is filled, the thread guide tube 4 reaches its top dead center.
- the yarn 8 is from the cutting and clamping device
- FIG. 6 shows a preferred embodiment of a vacuum centrifuge spinning device, preferably for pure centrifugal spinning. Centrifuges for pure centrifuge spinning have a capacity of approx. 100 grams of yarn.
- the vacuum centrifuge spinning device consists of a two-part housing 31, within which a bottle-shaped centrifuge 35 is arranged; in the space 40 between the housing 31 and the centrifuge 35 there is negative pressure pu; normal pressure pn prevails inside the centrifuge 35.
- the centrifuge can consist of at least two parts, which are telescopically inserted into one another or are somewhat conical in shape, the expansion behavior of the centrifuge parts under centrifugal force being matched to one another both by a suitable choice of material and by suitable shaping of the centrifuge parts so that at Rotation of the two nested centrifuge parts results in a hermetically sealed centrifuge.
- the parts can be pressed into each other by axially acting compressed air.
- One centrifuge part can be rotatably mounted in one part of the housing, the other in the other part of the housing, a drive motor being assigned to one of the centrifuge parts.
- the centrifuge is run up to an intermediate speed which is chosen so high that the two centrifuge parts are tightened airtightly against one another due to different expansions, the inner centrifuge part expanding under the centrifugal forces so that the centrifuge forms an airtight system and now the space between the housing and the centrifuge is evacuated to a vacuum pu; then the centrifuge speed is increased until it reaches its operating speed.
- the bracing is thus chosen so large that the axial forces caused by the vacuum subsequently applied are absorbed.
- the housing 31 and the centrifuge 35 each consist of two parts 32, 33 and 36, 37, the upper, outer centrifuge part 36 being mounted in the upper housing part 32 by means of an axial fixed bearing 34, 34 '.
- An axial seal 38 seals the upper centrifuge part 36 or the centrifuge neck 69 from the housing 31 in an airtight manner.
- the lower, inner centrifuge part 37 which receives the yarn winding, is by means of an axial floating bearing 39, 39 ' lower housing part 33 mounted, which can be moved apart relative to the upper housing part 32 and the upper centrifuge part 36.
- the lower housing part 33 receives an electric motor 41, which drives the lower centrifuge part 37.
- the bearings only run under the load of the gyroscopic forces; the entire system is spring-loaded, so that in principle there is a free gyroscope.
- the centrifuge parts 36 and 37 are nested and hermetically seal when rotating.
- an overpressure pu can be applied axially from the outside to the lower housing part 33, which pushes the parts that are movable relative to one another.
- the overpressure is set to zero; the materials and dimensions of the centrifuge parts 36, 37 are matched to one another in such a way that when the centrifugal force builds up, a force-fit air-tight connection results between the jacket walls of the centrifuge parts 36, 37.
- the centrifuge 35 has reached a minimum speed and the centrifuge parts 36, 37 are pushed into one another, the space 40 is evacuated; the centrifuge 35 then reaches its operating speed within the housing 31.
- FIG. 7 shows a preferred embodiment of a vacuum centrifuge spinning device for two-stage step spinning, which deposits the yarn in parallel windings and normally has a capacity of at least 50 g of yarn.
- a centrifuge 45 having only one axis 62, which - like the centrifuge 35 in FIG. 6 - consists of two centrifuge parts 46 and 47, the upper, outer centrifuge part 46 or the centrifuge neck 70 is rotatably supported within the housing 43 by means of a fixed bearing 68, 68 'and is sealed airtight to the outside with a seal 38.
- An electric motor 41 ' is in turn an integral part of the housing 43 and the upper centrifuge part 46 and thus advantageously arranged here in a vacuum.
- the housing 43 is swinging, so that the centrifuge 45 is gimbaled.
- the housing 43 can apparently be closed airtight by means of a movable cover 44, which is indicated by the double arrow.
- the inner centrifuge part 47 is cup-shaped in the centrifuge part 46; the space 48 between the housing 43, cover 44 and centrifuge 45 can in turn be evacuated.
- This vacuum centrifuge spinning device into which one spins in and out, only needs to be opened if the remnants of a yarn package have to be removed if the thread breaks.
- the cover 44 is moved away and the housing 43 is opened.
- a plunger 49 can suck on the bottom of the lower or inner partial centrifuge 47 by means of negative pressure pu and pull it out of the upper or outer centrifuge part 46. If the plunger 49 is designed to be rotatable, the yarn package can also be removed in an orderly fashion since it remains on the wall of the centrifuge part 47 due to the centrifugal force. In the case of pure centrifuge spinning, on the other hand, you can continue spinning despite the broken thread.
- the procedure can be taken jointly so that a centrifuge part hangs on each housing part and the non-positive connection of the centrifuge parts can be established by applying an overpressure.
- the overpressure is set to zero and, with sufficient speed, the space between the housing and the centrifuge is evacuated to practically vacuum. No forces act on the bearings of the centrifuge because one of the bearings is designed as a fixed bearing, the other as a floating bearing; the centrifuge runs gimballed.
- FIG. 8 shows a further embodiment of a vacuum centrifuge spinning device.
- a centrifuge 53 which consists of two centrifuge parts 54, 55, is arranged within a housing 50, which can consist of two housing parts 51, 52; the space 56 between the housing 50 and the centrifuge 53 can be practically evacuated to a vacuum.
- the upper, outer centrifuge part 54 in the upper housing part 51 of the housing 50 has a bearing 57 which is mounted elastically for gimbal mounting in a molded rubber 58 and is sealed airtightly against the molded rubber 58 by means of a seal 59 against the centrifuge neck 71.
- the upper housing part 51 also has a braking device 60.
- the lower, inner centrifuge part 55 is suitably supported and driven at its lower, not shown end; it can be removed in the axial direction - similar to the centrifuges 35, 45 of FIGS. 6, 7 - from the upper centrifuge part 54, so that a yarn package or yarn remnants can be removed from the inner centrifuge part 55 during step spinning.
- a force and / or positive connection between the centrifuge parts 54, 55 is achieved in that the outermost edges or ends of the centrifuge parts fit conically into one another or are provided with threads 61, 61 'or bayonet closures, so that the ends of the Centrifuge parts 54, 55 fit into one another as shown in FIG. 8.
- the centrifuge part 54 is prevented from rotating by the brake 60, the lower centrifuge part 55 being moved axially and with rotation against the upper centrifuge part 54, so that the centrifuge 53 is closed .
- the opening of the centrifuge 53 takes place in reverse order, the same being stopped and the upper centrifuge part 54 being blocked by means of the brake 60, then the motor runs briefly in the opposite direction, so that the centrifuge parts 54, 55 separate; the yarn package inside shrinks.
- the lower partial centrifuge 55 is rotated again separately by means of a motor, as a result of which the yarn package opens and becomes stiff, so that a doffer can be inserted and the yarn removed.
- one of the housing parts of the housing can have a brake device for braking and stopping the assigned centrifuge part relative to the held, relatively movable centrifuge part of the centrifuge, this centrifuge part preferably being rotatably mounted within the assigned housing part by means of a fixed bearing.
- the doffer can be suitably arranged on the machine device of the vacuum centrifuge spinning device; for example, after the two centrifuge parts of the centrifuge have been moved apart, the same can be automatically moved into the centrifuge part having the yarn package.
- the vacuum centrifugal spinning process and the vacuum centrifugal spinning device are particularly suitable for producing yarns of a classic character, it being possible to spin with a specifically lower energy and thus capital expenditure than is possible with ring and rotor spinning devices of the prior art .
- the specific energy and capital requirements, based on a yarn of the same strength and Fineness is below that of ring and rotor spiders of the prior art.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Spinning Or Twisting Of Yarns (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Centrifugal Separators (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP9301078 | 1993-05-04 | ||
WOPCT/EP93/01078 | 1993-05-04 | ||
PCT/EP1994/001415 WO1994025650A1 (de) | 1993-05-04 | 1994-05-04 | Zentrifugenspinnverfahren und vorrichtung hierzu |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0697041A1 true EP0697041A1 (de) | 1996-02-21 |
EP0697041B1 EP0697041B1 (de) | 1997-02-12 |
Family
ID=8165729
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP94916192A Expired - Lifetime EP0697041B1 (de) | 1993-05-04 | 1994-05-04 | Zentrifugenspinnverfahren und vorrichtung hierzu |
Country Status (11)
Country | Link |
---|---|
US (1) | US5813207A (de) |
EP (1) | EP0697041B1 (de) |
JP (1) | JPH08509528A (de) |
CN (1) | CN1122618A (de) |
AT (1) | ATE148926T1 (de) |
AU (1) | AU6795394A (de) |
BR (1) | BR9406337A (de) |
CA (1) | CA2161006A1 (de) |
CZ (1) | CZ288295A3 (de) |
DE (2) | DE59401809D1 (de) |
WO (1) | WO1994025650A1 (de) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH688515A5 (de) * | 1994-07-23 | 1997-10-31 | Traxler Alfons Dr | Vakuumzentrifuge und Dichtung hierfuer. |
DE19527002A1 (de) * | 1995-07-24 | 1997-01-30 | Chemnitzer Spinnereimaschinen | Zentrierfugenspinnmaschine |
DE19548672A1 (de) * | 1995-12-23 | 1997-06-26 | Csm Gmbh | Verschlußvorrichtung für Zentrifugengehäuse |
DE19548674A1 (de) * | 1995-12-23 | 1997-06-26 | Csm Gmbh | Doffverfahren |
DE19548663A1 (de) * | 1995-12-23 | 1997-06-26 | Csm Gmbh | Anspinnorgan |
DE19548670A1 (de) * | 1995-12-23 | 1997-06-26 | Csm Gmbh | Hauptfeldverdichter |
DE19548666A1 (de) * | 1995-12-23 | 1997-06-26 | Csm Gmbh | Zentrifugenspinnmaschinengestell |
DE19548667A1 (de) * | 1995-12-23 | 1997-06-26 | Csm Gmbh | Zentrifugenspinnmaschinensteuerung |
DE19637270A1 (de) * | 1996-09-13 | 1998-03-19 | Schlafhorst & Co W | Topfspinnvorrichtung |
DE19815546C2 (de) * | 1998-04-07 | 2000-10-05 | Schiessl Helmut F | Topfspinnvorrichtung |
CH694332A5 (de) * | 2000-04-14 | 2004-11-30 | Rieter Ag Maschf | Verfahren und Vorrichtung zur Herstellung eines Garnes mit ringgarnähnlichem Charakter. |
JP6881345B2 (ja) * | 2018-02-09 | 2021-06-02 | 株式会社豊田自動織機 | ポット精紡方法およびポット精紡機 |
JP6977602B2 (ja) * | 2018-02-15 | 2021-12-08 | 株式会社豊田自動織機 | ポット精紡方法及びポット精紡機 |
JP7287126B2 (ja) * | 2019-06-05 | 2023-06-06 | 株式会社豊田自動織機 | ポット精紡機 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1642290A (en) * | 1925-12-12 | 1927-09-13 | Bassett | Method of spinning threads |
BE494421A (de) * | 1949-03-09 | |||
US2842933A (en) * | 1954-08-20 | 1958-07-15 | Pujol Carlos | Spinning and winding device for textile fibers |
GB918963A (en) * | 1959-09-03 | 1963-02-20 | W C T Hart & Zn Instr App Nfab | A plying and twisting frame adapted to deliver cross-wound yarn packages |
NL132553C (de) * | 1962-10-30 | Bobkowicz E | ||
US3217483A (en) * | 1962-10-30 | 1965-11-16 | Mitsubishi Shipbuilding & Eng | Spinning machine utilizing centrifugal force and flow of air |
DE2103717A1 (de) * | 1971-01-27 | 1972-08-17 | Wilhelm Stahlecker GmbH, 7341 Reichenbach· | Spinnturbine |
GB1489809A (en) * | 1975-08-01 | 1977-10-26 | Muschamp Ltd | Production of plied yarn |
DE4400999A1 (de) * | 1994-01-14 | 1995-07-20 | Koenig Reinhard | Vorrichtung zum Beheben der Ausbildung einer Fadensehne und/oder eines Fadenbruches eines mittels einer Spinnzentrifuge gesponnenen Fadens und Verfahren hierzu |
-
1994
- 1994-05-04 WO PCT/EP1994/001415 patent/WO1994025650A1/de not_active Application Discontinuation
- 1994-05-04 CN CN94192014.3A patent/CN1122618A/zh active Pending
- 1994-05-04 DE DE59401809T patent/DE59401809D1/de not_active Expired - Fee Related
- 1994-05-04 JP JP6523907A patent/JPH08509528A/ja active Pending
- 1994-05-04 AT AT94916192T patent/ATE148926T1/de not_active IP Right Cessation
- 1994-05-04 BR BR9406337A patent/BR9406337A/pt not_active Application Discontinuation
- 1994-05-04 EP EP94916192A patent/EP0697041B1/de not_active Expired - Lifetime
- 1994-05-04 DE DE4492664T patent/DE4492664D2/de not_active Expired - Fee Related
- 1994-05-04 CA CA002161006A patent/CA2161006A1/en not_active Abandoned
- 1994-05-04 AU AU67953/94A patent/AU6795394A/en not_active Abandoned
- 1994-05-04 CZ CZ952882A patent/CZ288295A3/cs unknown
-
1995
- 1995-11-03 US US08/552,634 patent/US5813207A/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
See references of WO9425650A1 * |
Also Published As
Publication number | Publication date |
---|---|
CA2161006A1 (en) | 1994-11-10 |
DE59401809D1 (de) | 1997-03-27 |
BR9406337A (pt) | 1995-12-26 |
JPH08509528A (ja) | 1996-10-08 |
US5813207A (en) | 1998-09-29 |
DE4492664D2 (de) | 1996-06-27 |
CZ288295A3 (en) | 1996-04-17 |
CN1122618A (zh) | 1996-05-15 |
WO1994025650A1 (de) | 1994-11-10 |
AU6795394A (en) | 1994-11-21 |
EP0697041B1 (de) | 1997-02-12 |
ATE148926T1 (de) | 1997-02-15 |
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