EP0596360B1 - Verwendung vonAlkoxysilian- und Aminogruppen aufweisenden Verbindungen - Google Patents

Verwendung vonAlkoxysilian- und Aminogruppen aufweisenden Verbindungen Download PDF

Info

Publication number
EP0596360B1
EP0596360B1 EP93117241A EP93117241A EP0596360B1 EP 0596360 B1 EP0596360 B1 EP 0596360B1 EP 93117241 A EP93117241 A EP 93117241A EP 93117241 A EP93117241 A EP 93117241A EP 0596360 B1 EP0596360 B1 EP 0596360B1
Authority
EP
European Patent Office
Prior art keywords
groups
compounds
alkoxysilane
maleic
prepolymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP93117241A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0596360A1 (de
Inventor
Christian Dr. Zwiener
Lutz Dr. Schmalstieg
Josef Dr. Pedain
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of EP0596360A1 publication Critical patent/EP0596360A1/de
Application granted granted Critical
Publication of EP0596360B1 publication Critical patent/EP0596360B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages

Definitions

  • the present invention relates to the use of alkoxysilane and compounds having secondary amino groups, as a reaction partner for organic Polyisocyanates in the manufacture of alkoxysilane and Prepolymers containing urea groups.
  • Hydrolyzable organofunctional silanes are key building blocks for linking conventional polymer chemistry with silicone chemistry.
  • such compounds have hydrolyzable silyl groups which crosslink in the presence of moisture via a "silane polycondensation", on the other hand, the compounds have other functional groups X which enable chemical bonding to customary polymer materials (see, for example, Angew. Chem. 98 (1986 ) 237-253).
  • Hydrolyzable functional silanes of the formula mentioned in which the functional group X has zerewitinoffactive H atoms are potentially suitable for modifying polyisocyanates (cf., for example, WO 92/05212).
  • Commercially available products for this purpose contain either NH 2 and / or NH groups or SH groups.
  • Alkoxysilanes containing SH groups are e.g. described in GB-A-1 102 251, EP-A-00 18 094, DE-A-11 62 818, US-A-3 590 065, 3 849 471, 4 082 790, 4 012 403 or 4 401 286. All SH groups Alkoxysilanes is the typical uncomfortable mercaptan Own smell, so that due to remaining quantities An odor nuisance can result in the polymer.
  • Alkoxysilanes containing amino groups are e.g. described in J. Org. Chem. 36 (1971), p. 3120, DE-A-1 152 695, 1 271 712, 2 161 716, 2 408 480, 2 521 399, 2,749,316 or US-A-2,832,754, 2,971,864 or 4,481,364.
  • the amino functional silanes of the prior art common is the disadvantage of an extremely high reactivity towards isocyanate groups, so that these Compounds not with polyisocyanates due to incompatibilities, Inhomogeneities and extremely high viscosities have the implementation products implemented.
  • Moisture-crosslinkable ⁇ -aminoalkylsilane derivatives can according to the German published documents 1 812 504 and 1 812 562. Due to the the synthesis described there was complicated functional silanes, however, have no technical significance gain.
  • the object of the present invention was therefore the use technically well accessible NH groups Alkoxysilanes that do not have the disadvantages of State of the art are affected.
  • suitable aminoalkylalkoxysilanes are 2-aminoethyldimethylmethoxysilane, 3-aminopropyltrimethoxysilane, 3-aminopropyltriethoxysilane and 3-aminopropyl-methyl-diethoxysilane, 3-aminopropyltrimethoxysilane and 3-aminopropyltriethoxysilane particularly preferred.
  • maleic or fumaric acid esters are Maleic acid dimethyl ester, maleic acid diethyl ester, Maleic acid di-n-butyl ester and the corresponding Fumaric acid ester. Maleic acid dimethyl ester and maleic acid diethyl ester are particularly preferred.
  • the implementation of the maleic or fumaric acid esters with the Aminoalkylalkoxysilanes take place within a temperature range from 0 to 100 ° C, the proportions are usually chosen so that the starting compounds used in a molar ratio of 1: 1 become.
  • the implementation can be in substance or in Presence of solvents such as e.g. Dioxane carried out become. The use of solvents is however less preferred. Of course you can too Mixtures of different 3-aminoalkylalkoxysilanes with Mixtures of fumaric and / or maleic acid esters implemented become.
  • amino and alkoxysilane groups used according to the invention containing compounds are colorless to pale yellow colored compounds without further purification for modifying compounds containing isocyanate groups can be used.
  • the compounds used according to the invention are valuable Modifiers for isocyanate groups
  • Compounds for the production of alkoxysilane and Prepolymers having urea groups Such
  • prepolymers can be used for production of sealants that can be crosslinked by "silane polycondensation" be used.
  • suitable Catalysts such as dibutyltin diacetate used.
  • low molecular weight basic aminoalkyl trialkoxysilanes as in the method according to the invention used as starting material, accelerate the curing of the prepolymers and can therefore when using the prepolymers for the above Used in catalytic quantities become.
  • Example 2 179.0 g (1.0 mol) of 3-aminopropyltrimethoxysilane and 144.0 g (1.0 mol) of dimethyl maleate are analogous Example 2 implemented.
  • the viscosity of the clear, pale yellow liquid is approx. 30 mPa.s (23 ° C).
  • the Base titration gives an amine equivalent weight of approx. 331 g (theory: 323 g).
  • Example 1 179.0 g (1.0 mol) of 3-aminopropyltrimethoxysilane and 172.0 g (1.0 mol) of diethyl maleate are analogous Example 1 implemented. A clear colorless is obtained Product with a viscosity of approx. 30 mPa.s (23 ° C). The amine equivalent weight determined by base titration is approx. 359 (theory: 351 g).
  • 100 g of the product from Example 8 are 0.5 g Dibutyltin diacetate, 5 g of 3-aminopropyltriethoxysilane and 5 g of methyltrimethoxysilane mixed intimately.
  • One on one Glass plate doctored film (layer thickness 1 mm) hardens overnight to an opaque, elastic plastic.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyurethanes Or Polyureas (AREA)
EP93117241A 1992-11-06 1993-10-25 Verwendung vonAlkoxysilian- und Aminogruppen aufweisenden Verbindungen Expired - Lifetime EP0596360B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4237468A DE4237468A1 (de) 1992-11-06 1992-11-06 Alkoxysilan- und Aminogruppen aufweisende Verbindungen
DE4237468 1992-11-06

Publications (2)

Publication Number Publication Date
EP0596360A1 EP0596360A1 (de) 1994-05-11
EP0596360B1 true EP0596360B1 (de) 1999-01-20

Family

ID=6472239

Family Applications (1)

Application Number Title Priority Date Filing Date
EP93117241A Expired - Lifetime EP0596360B1 (de) 1992-11-06 1993-10-25 Verwendung vonAlkoxysilian- und Aminogruppen aufweisenden Verbindungen

Country Status (7)

Country Link
US (1) US5364955A (es)
EP (1) EP0596360B1 (es)
JP (1) JP3342552B2 (es)
AT (1) ATE175970T1 (es)
CA (1) CA2102272C (es)
DE (2) DE4237468A1 (es)
ES (1) ES2127777T3 (es)

Families Citing this family (216)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6084106A (en) * 1994-10-21 2000-07-04 Thiokol Corporation Adhesion promoters and methods of their synthesis and use
DE19619538A1 (de) * 1996-05-15 1997-11-20 Bayer Ag Alkoxysilan- und Hydantoingruppen aufweisende Polyurethanprepolymere, ein Verfahren zu ihrer Herstellung sowie ihre Verwendung zur Herstellung von Dichtstoffen
EP0816326B1 (de) 1996-07-02 2000-05-10 Bayer Ag Verfahren zur Herstellung von Mono- und Polyasparaginsäureestern
US6001946A (en) * 1996-09-23 1999-12-14 Witco Corporation Curable silane-encapped compositions having improved performances
US5866651A (en) * 1996-10-31 1999-02-02 Minnesota Mining And Manufacturing Company Hydroxycarbamoylalkoxysilane-based poly(ether-urethane) sealants having improved paint adhesion and laminates prepared therefrom
WO1998018843A1 (en) * 1996-10-31 1998-05-07 Minnesota Mining And Manufacturing Company Moisture curable alkoxysilane functional poly(ether-urethane) based sealants
US5908948A (en) * 1997-03-11 1999-06-01 Bayer Corporation Compounds containing urea and alkoxysilane groups
DE19715427A1 (de) * 1997-04-14 1998-10-15 Bayer Ag Wäßrige 2-Komponenten Bindemittel und deren Verwendung
JP3317353B2 (ja) 1997-06-17 2002-08-26 コニシ株式会社 ウレタン系樹脂の製造方法及びウレタン系樹脂組成物
DE69722410T2 (de) * 1997-10-20 2004-01-08 Bayer Ag Alkoxysilan- und Hydantoingruppen enthaltende Verbindungen
US5919860A (en) * 1997-12-17 1999-07-06 Bayer Corporation Aqueous polyurethane/urea dispersions containing alkoxysilane groups
US5932652A (en) * 1997-12-17 1999-08-03 Bayer Corporation Aqueous polyurethane/urea dispersions containing alkoxysilane groups
US5859118A (en) * 1997-12-17 1999-01-12 Bayer Corporation Aqueous dispersions of polyurethane/ureas containing alkoxysilane groups and colloidal silicas
US5990257A (en) * 1998-01-22 1999-11-23 Witco Corporation Process for producing prepolymers which cure to improved sealants, and products formed thereby
US5952445A (en) * 1998-04-09 1999-09-14 Bayer Corporation Water dispersible compounds containing alkoxysilane groups
US6057415A (en) * 1998-04-09 2000-05-02 Bayer Corporation Water dispersible polyisocyanates containing alkoxysilane groups
US5945476A (en) * 1998-04-09 1999-08-31 Bayer Corporation Aqueous two-component coating composition
US6005047A (en) * 1998-10-14 1999-12-21 Bayer Corporation Moisture-curable compounds containing isocyanate and alkoxysilane groups
US6046270A (en) * 1998-10-14 2000-04-04 Bayer Corporation Silane-modified polyurethane resins, a process for their preparation and their use as moisture-curable resins
US6077902A (en) * 1998-10-14 2000-06-20 Bayer Corporation Moisture-curable compounds containing isocyanate and alkoxysilane groups
DE19849817A1 (de) * 1998-10-29 2000-05-04 Bayer Ag Alkoxysilan-Endgruppen aufweisende Polyurethanprepolymere, ein Verfahren zu ihrer Herstellung sowie ihre Verwendung zur Herstellung von Dichtstoffen
US6162938A (en) 1998-11-19 2000-12-19 3M Innovative Properties Company Secondary amine-functional silanes, silane-functional polymers therefrom, and resulting cured polymers
US6111010A (en) * 1998-12-23 2000-08-29 Bayer Corporation Aqueous compounds containing alkoxysilane and/or silanol groups
DE19923300A1 (de) 1999-05-21 2000-11-23 Bayer Ag Phosphatstabilisierte, kondensationsvernetzende Polyurethanmassen, ein Verfahren zu ihrer Herstellung sowie ihre Verwendung
CA2377193A1 (en) * 1999-06-25 2001-01-04 Bayer Aktiengesellschaft Piperazinone derivatives with alkoxysilane groups
US6310170B1 (en) 1999-08-17 2001-10-30 Ck Witco Corporation Compositions of silylated polymer and aminosilane adhesion promoters
US6355829B2 (en) * 1999-09-02 2002-03-12 Bayer Corporation Aspartate-terminated urea/urethane prepolymers and their use in coating compositions
US6265517B1 (en) 1999-09-07 2001-07-24 Bostik, Inc. Silylated polyether sealant
US6180745B1 (en) * 1999-11-08 2001-01-30 Bayer Corporation Moisture-curable compositions containing isocyanate and succinyl urea groups
KR20010058991A (ko) * 1999-12-30 2001-07-06 김충세 고신율 실링재로 유용한 양말단 알콕시실릴 폴리우레탄폴리머의 제조방법
IT1318639B1 (it) 2000-07-25 2003-08-27 Mapei Spa Procedimento per la preparazione di composizioni organico-sili-coniche.
DE10050137A1 (de) 2000-10-11 2002-04-18 Bayer Ag Stabilisierte Mono- und Polyasparaginsäureester
DE10053347A1 (de) * 2000-10-27 2002-05-08 Bayer Ag Formkörper und Beschichtungen auf Basis von silanfunktionellen Bindern
EP1256595A1 (de) * 2001-05-10 2002-11-13 Sika AG, vorm. Kaspar Winkler & Co. Klebstoff, gefüllt mit oberflächenbehandelter Kreide und Russ
DE10204523A1 (de) * 2002-02-05 2003-08-07 Bayer Ag Alkoxysilan- und OH-Endgruppen aufweisende Polyurethanprepolymere mit erniedrigter Funktionalität, ein Verfahren zu ihrer Herstellung sowie ihre Verwendung
US6809170B2 (en) * 2002-05-31 2004-10-26 Bayer Materialscience Llc Moisture-curable, polyether urethanes with reactive silane groups and their use as sealants, adhesive and coatings
US7115696B2 (en) * 2002-05-31 2006-10-03 Bayer Materialscience Llc Moisture-curable, polyether urethanes with reactive silane groups and their use as sealants, adhesives and coatings
US6887964B2 (en) * 2002-05-31 2005-05-03 Bayer Materialscience Llc Moisture-curable, polyether urethanes with reactive silane groups and their use as sealants, adhesives and coatings
US20030232950A1 (en) * 2002-06-18 2003-12-18 Roesler Richard R. Moisture-curable, polyether urethanes with reactive silane groups and their use as sealants, adhesives and coatings
US6833423B2 (en) * 2002-06-18 2004-12-21 Bayer Polymers Llc Moisture-curable, polyether urethanes with reactive silane groups and their use as sealants, adhesives and coatings
US6998459B2 (en) * 2002-06-18 2006-02-14 Bayer Materialscience Llc Polyether urethanes containing one reactive silane group and their use in moisture-curable polyether urethanes
US6844413B2 (en) * 2002-06-18 2005-01-18 Bayer Materialscience Llc Moisture-curable, polyether urethanes with reactive silane groups and their use as sealants, adhesives and coatings
DE10352907A1 (de) 2002-11-15 2004-08-05 Henkel Kgaa Silylgruppen enthaltende Präpolymere, deren Herstellung und Verwendung in Montageschäumen
EP1578830B1 (en) 2002-12-20 2012-04-04 Bayer MaterialScience LLC Moisture-curable, polyether urethanes with terminal cyclic urea/reactive silane groups and their use as sealants, adhesives and coatings
US20040122200A1 (en) * 2002-12-20 2004-06-24 Roesler Richard R. Process for the preparation of moisture-curable, polyether urethanes with terminal cyclic urea/reactive silane groups
US20050059790A1 (en) * 2003-09-16 2005-03-17 Roesler Richard R. Process for preparing aspartates
US6984715B2 (en) * 2003-10-03 2006-01-10 Bayer Materialscience Llc Process for preparing aspartates
US7276572B2 (en) * 2003-10-03 2007-10-02 Bayer Materialscience Llc Process for preparing aspartates
DE10351802A1 (de) * 2003-11-06 2005-06-09 Consortium für elektrochemische Industrie GmbH alpha-Alkoxysilane sowie ihre Anwendung in alkoxysilanterminierten Prepolymeren
US20050137374A1 (en) * 2003-12-17 2005-06-23 Roesler Richard R. Two-component water-borne adhesive
US6911501B1 (en) 2004-01-21 2005-06-28 Bayer Materialscience Llc Process for preparing aspartates
EP1557455A1 (de) * 2004-01-23 2005-07-27 Sika Technology AG Thixotrope reaktive Zusammensetzung
US7482420B2 (en) 2004-03-24 2009-01-27 Construction Research & Technology Gmbh Silane-terminated polyurethanes with high strength and high elongation
US7060750B2 (en) * 2004-04-28 2006-06-13 Bayer Materialscience Llc Moisture-curable, polyether urethanes and their use in sealant, adhesive and coating compositions
JP5081448B2 (ja) 2004-06-09 2012-11-28 株式会社カネカ 硬化性組成物
CN101056945B (zh) 2004-11-10 2011-04-13 株式会社钟化 固化性组合物
US7307140B2 (en) 2004-11-16 2007-12-11 Bayer Materialscience Llc Polyaspartimides
DE102004062653A1 (de) * 2004-12-24 2006-07-06 Bayer Materialscience Ag Feuchthärtende Zusammensetzung und Schmelzklebstoff
US7417105B2 (en) 2005-02-15 2008-08-26 Momentive Performance Materials Inc. Crosslinkable silane-terminated polymer and sealant composition made with same
EP1717254A1 (de) * 2005-04-29 2006-11-02 Sika Technology AG Feuchtigkeitshärtende Zusammensetzung mit erhöhter Dehnbarkeit
DE102005041953A1 (de) * 2005-09-03 2007-03-08 Bayer Materialscience Ag Niedrigviskose alkoxysilangruppenaufweisende Prepolymere, ein Verfahren zu ihrer Herstellung sowie ihre Verwendung
DE102005041954A1 (de) * 2005-09-03 2007-03-08 Bayer Materialscience Ag Alkoxysilan- und spezielle Allophanat-und/oder Biuretgruppen aufweisende Prepolymere, ein Verfahren zu ihrer Herstellung sowie ihre Verwendung
WO2007037485A1 (ja) 2005-09-30 2007-04-05 Kaneka Corporation 硬化性組成物
JP5378684B2 (ja) 2005-09-30 2013-12-25 株式会社カネカ 硬化性組成物
WO2007040101A1 (ja) 2005-09-30 2007-04-12 Kaneka Corporation 硬化性と貯蔵安定性の改善された硬化性組成物
CN101405316B (zh) * 2006-01-26 2012-03-14 Sika技术股份公司 具有良好的粘附性的含有硅烷官能的聚合物和氨基硅烷-加合物的湿固化组合物
US20070179236A1 (en) * 2006-02-01 2007-08-02 Landon Shayne J Sealant composition having reduced permeability to gas
US20070178256A1 (en) * 2006-02-01 2007-08-02 Landon Shayne J Insulated glass unit with sealant composition having reduced permeability to gas
US7569653B2 (en) 2006-02-01 2009-08-04 Momentive Performance Materials Inc. Sealant composition having reduced permeability to gas
US8580361B2 (en) * 2006-02-01 2013-11-12 Momentive Performance Materials Inc. Insulated glass unit with sealant composition having reduced permeability to gas
US7541076B2 (en) * 2006-02-01 2009-06-02 Momentive Performance Materials Inc. Insulated glass unit with sealant composition having reduced permeability to gas
JP2007211107A (ja) * 2006-02-08 2007-08-23 Sika Technology Ag 一液型湿気硬化性組成物
EP1990370B2 (en) 2006-02-16 2015-08-12 Kaneka Corporation Curable composition
WO2007123167A1 (ja) 2006-04-20 2007-11-01 Kaneka Corporation 硬化性組成物
WO2008032539A1 (fr) 2006-09-13 2008-03-20 Kaneka Corporation POLYMÈRE DURCISSABLE À L'HUMIDITÉ COMPORTANT UN GROUPE SiF ET COMPOSITION DURCISSABLE CONTENANT UN TEL POLYMÈRE
DE102006048041A1 (de) * 2006-10-09 2008-04-10 Henkel Kgaa Zusammensetzungen aus teilweise silylterminierten Polymeren
DE102006054289A1 (de) * 2006-11-17 2008-05-21 Bayer Materialscience Ag Nanopartikelmodifizierte Polyisocyanate
WO2008062866A1 (fr) 2006-11-22 2008-05-29 Kaneka Corporation Composition durcissable et composition de catalyseur
WO2008078654A1 (ja) 2006-12-25 2008-07-03 Kaneka Corporation 硬化性組成物
WO2008084651A1 (ja) 2007-01-12 2008-07-17 Kaneka Corporation 硬化性組成物
DE102007021630A1 (de) * 2007-05-09 2008-11-13 Bayer Materialscience Ag Hybride Polyisocyanate
DE102007023197A1 (de) 2007-05-22 2008-11-27 Bayer Materialscience Ag Polyester-Prepolymere
ES2425072T3 (es) * 2007-07-12 2013-10-11 Dow Global Technologies Llc Polímeros curables a temperatura ambiente y precursores de los mismos
DE102007032666A1 (de) 2007-07-13 2009-01-22 Bayer Materialscience Ag Allophanat- und Silangruppen enthaltende Polyisocyanate
EP2177571A4 (en) 2007-07-19 2014-01-08 Kaneka Corp HARDENING COMPOSITION
EP2058349A1 (de) * 2007-11-08 2009-05-13 Bayer MaterialScience AG Nanopartikelmodifizierte Polyisocyanate
US8372514B2 (en) * 2007-11-21 2013-02-12 Sika Technology Ag Moisture-curing composition comprising at least two polymers having silane groups
EP2119736A1 (de) * 2008-05-16 2009-11-18 Bayer MaterialScience AG Stabile nanopartikelhaltige Polyisocyanate
EP2341106B1 (en) 2008-09-29 2013-05-29 Kaneka Corporation Curable composition and cured product thereof
MY151975A (en) 2008-12-05 2014-07-31 Basf Se Cyclohexane polycarboxylic acid derivatives as plasticizers for adhesives and sealants
EP2388297B1 (en) 2009-01-16 2020-08-19 Kaneka Corporation Curable composition and cured object formed therefrom
EP2221331A1 (de) 2009-02-18 2010-08-25 Sika Technology AG Silanterminierte Polyurethanpolymere
EP2236531A1 (de) 2009-03-31 2010-10-06 Bayer MaterialScience AG Neue wäßrige 2K PUR-Beschichtungssysteme für verbesserten Korrosionsschutz
EP2236532A1 (de) 2009-03-31 2010-10-06 Bayer MaterialScience AG Nanopartikelmodifizierte hydrophile Polyisocyanate
DE102009016173A1 (de) 2009-04-03 2010-10-14 Bayer Materialscience Ag Schutzlack
DE102009047964A1 (de) 2009-10-01 2011-04-21 Bayer Materialscience Ag Hochfunktionelle Allophanat- und Silangruppen enthaltende Polyisocyanate
EP2488586B1 (en) 2009-10-16 2017-11-01 Kaneka Corporation Curable composition
WO2011054782A1 (de) 2009-11-05 2011-05-12 Basf Se Kleb- und dichtstoffe enthaltend ester auf basis von 2-propylheptanol
DE102009057584A1 (de) 2009-12-09 2011-06-16 Bayer Materialscience Ag Polyurethane-Prepolymere
DE102009057597A1 (de) 2009-12-09 2011-06-16 Bayer Materialscience Ag Polyrethan-Prepolymere
DE102009057600A1 (de) 2009-12-09 2011-06-16 Bayer Materialscience Ag Polyurethan-Prepolymere
DE102009057599A1 (de) 2009-12-09 2011-06-16 Bayer Materialscience Ag Dichtstoffe
KR101838533B1 (ko) 2010-01-19 2018-04-26 카네카 코포레이션 경화성 조성물
JP5440389B2 (ja) * 2010-05-27 2014-03-12 信越化学工業株式会社 シリル基で保護されたアミノ基とカルボン酸エステル基を有するシラン化合物及びその製造方法
US8791185B2 (en) 2010-06-21 2014-07-29 Basf Se 2-ethylhexyl methyl terephthalate as plasticizer in adhesives and sealants
WO2011161037A1 (de) 2010-06-21 2011-12-29 Basf Se 2-ethylhexyl-methyl-terephthalat als weichmacher in kleb- und dichtstoffen
JP2013534960A (ja) 2010-06-29 2013-09-09 コンストラクション リサーチ アンド テクノロジー ゲーエムベーハー チキソトロープ剤の製造法及びその使用
CN103180395B (zh) 2010-10-27 2016-03-09 株式会社钟化 固化性组合物
AU2011335113A1 (en) 2010-12-03 2013-06-20 Construction Research & Technology Gmbh Curable composition
EP2468759A1 (de) 2010-12-17 2012-06-27 Sika Technology AG Sekundäre Aminosilane
WO2012121288A1 (ja) 2011-03-09 2012-09-13 株式会社カネカ 接着剤組成物と木材からなる接着構造体
JP5993367B2 (ja) 2011-04-15 2016-09-14 株式会社カネカ 建築用外装材
WO2013042702A1 (ja) 2011-09-22 2013-03-28 株式会社カネカ 硬化性組成物およびその硬化物
DE102011087604A1 (de) * 2011-12-01 2013-06-06 Wacker Chemie Ag Vernetzbare Massen auf Basis von organyloxysilanterminierten Polyurethanen
DE102011088170A1 (de) 2011-12-09 2013-06-13 Bayer Materialscience Aktiengesellschaft Reaktive Haftklebstoffe
JP2013151645A (ja) * 2011-12-27 2013-08-08 Sumika Bayer Urethane Kk 水性ウレタン系樹脂組成物
DE102012008486A1 (de) 2012-04-26 2013-10-31 Bona Gmbh Deutschland Verwendung von silanfunktionalisierten Präpolymeren in einer Formulierung zur Estrichreparatur
WO2013186349A1 (de) * 2012-06-15 2013-12-19 Sika Technology Ag Silangruppen-haltiges polymer
US8729179B1 (en) 2012-08-20 2014-05-20 Henkel US IP LLC Moisture curable polyacrylates
ES2733959T3 (es) 2012-09-04 2019-12-03 Covestro Deutschland Ag Aglutinantes con funcionalidad silano con estructura de tiouretano
WO2014037279A1 (de) 2012-09-04 2014-03-13 Bayer Materialscience Ag Isocyanatosilane mit thiourethanstruktur
WO2014038656A1 (ja) 2012-09-10 2014-03-13 株式会社カネカ 硬化性組成物
EP2578770A1 (de) 2012-11-22 2013-04-10 Construction Research & Technology GmbH Bodenaufbau umfassend einen parkettbelag
EP2951234A2 (en) 2013-02-01 2015-12-09 3M Innovative Properties Company Coating compositions and articles made therefrom
US9085712B2 (en) * 2013-03-14 2015-07-21 Bayer Materialscience Llc Fast cure aspartate polysiloxane hybrid coating
CN105324436B (zh) 2013-05-30 2018-08-28 株式会社钟化 固化性组合物及其固化物
CN105246979B (zh) 2013-05-30 2018-12-14 株式会社钟化 固化性组合物
EP2813528B1 (de) 2013-06-11 2018-12-19 Sika Technology AG Härtbare zusammensetzung auf basis von alkoxysilangruppen-haltigen polyethern und einer phosphazen-base
EP2813529A1 (de) 2013-06-11 2014-12-17 Sika Technology AG Härtbare Zusammensetzung auf Basis von Silangruppen-haltigen Polymeren und einem Zinkkatalysator
MX2016006808A (es) 2013-12-12 2016-08-19 Dow Global Technologies Llc Promotor de adhesion del aminosilano para el sistema de uretano.
EP3088474A4 (en) 2013-12-26 2017-08-09 Kaneka Corporation Curable composition and cured product thereof
US10150895B2 (en) 2014-01-23 2018-12-11 Kaneka Corporation Curable composition
DE102014101949A1 (de) 2014-02-17 2015-08-20 Franken Systems Gmbh Verfahren zur druckwasserfesten Abdichtung von Bauwerken
US10704254B2 (en) 2014-02-18 2020-07-07 3M Innovative Properties Company Easy to apply air and water barrier articles
KR20220041946A (ko) 2014-02-18 2022-04-01 쓰리엠 이노베이티브 프로퍼티즈 캄파니 자가 밀봉 물품
CN106232576B (zh) 2014-04-16 2019-03-01 Sika技术股份公司 含脒基或含胍基的硅烷
JP6659594B2 (ja) 2014-06-16 2020-03-04 シーカ テクノロジー アクチェンゲゼルシャフト シロキサン構造単位を含む架橋触媒
EP3174946B1 (en) 2014-08-01 2018-11-28 3M Innovative Properties Company Self sealing permeable air barrier compositions
EP3026091B1 (en) 2014-11-25 2021-09-01 Sika Technology AG Two component sealant based on silane-functional polymers
EP3237699A1 (en) 2014-12-22 2017-11-01 3M Innovative Properties Company Air and water barrier articles
DE112016000869T5 (de) 2015-02-23 2018-01-18 King Industries, Inc. Härtbare Beschichtungszusammensetzungen von Silan-funktionellen Polymeren
EP3271411B8 (de) 2015-03-17 2024-02-14 Covestro Deutschland AG Silangruppen enthaltende polyisocyanate auf basis von 1,5-diisocyanatopentan
US10392480B2 (en) 2015-04-16 2019-08-27 Sika Technology Ag Catalyst containing amidine groups
EP3085719A1 (de) 2015-04-21 2016-10-26 Covestro Deutschland AG Hydrophob modifizierter polyisocyanuratkunststoff und verfahren zu dessen herstellung
US10414875B2 (en) 2015-05-11 2019-09-17 Sika Technology Ag Catalyst containing guanidine groups
EP3757094B1 (de) 2015-06-22 2023-10-11 Sika Technology Ag Amidin-katalysator für härtbare zusammensetzungen
EP3337867B1 (en) 2015-08-18 2024-04-10 3M Innovative Properties Company Air and water barrier article with porous layer and liner
AU2016328372B2 (en) 2015-09-23 2021-01-14 Sika Technology Ag Two-component composition
CN108137900B (zh) 2015-10-02 2020-06-16 株式会社钟化 固化性组合物
WO2017064139A1 (de) 2015-10-15 2017-04-20 Sika Technology Ag Katalysatorsystem für härtbare zusammensetzungen auf basis von silangruppen-haltigen polymeren
CN108473815B (zh) 2015-12-15 2021-05-28 Sika技术股份公司 用于可固化组合物的具有聚硅氧烷结构单元的催化剂
US10787765B2 (en) 2015-12-22 2020-09-29 Covestro Deutschalnd AG Low-solvent coating systems for textiles
WO2017111121A1 (ja) 2015-12-24 2017-06-29 株式会社カネカ 積層体の製造方法、および積層体
DE102016200704A1 (de) 2016-01-20 2017-07-20 Bona Gmbh Deutschland Verfahren zur Erhöhung der Anwendungssicherheit und der Alterungsbeständigkeit von Klebstoffen und anderen Produkten, enthaltend silanfunktionalisierte Präpolymere
WO2017162811A1 (de) 2016-03-23 2017-09-28 Covestro Deutschland Ag Härtbare zusammensetzungen auf basis von alkoxysilangruppen-haltigen prepolymeren
DE102016111590A1 (de) 2016-06-24 2017-12-28 Delo Industrie Klebstoffe Gmbh & Co. Kgaa Einkomponentenmasse auf Basis von Alkoxysilanen und Verfahren zum Fügen oder Vergießen von Bauteilen unter Verwendung der Masse
ES2865327T3 (es) 2016-07-18 2021-10-15 Sika Tech Ag Catalizador para composiciones que pueden curarse que contiene unidades estructurales de hexahidrotriazina
EP3487899B1 (de) 2016-07-21 2021-03-17 Sika Technology AG Flammhemmende kleb- und dichtstoffe mit verbesserten mechanischen eigenschaften
KR102442964B1 (ko) 2016-08-09 2022-09-14 코베스트로 도이칠란트 아게 실란-관능성 중합체성 폴리우레탄
CN110024174B (zh) 2016-09-06 2022-08-09 奥克斯能源有限公司 用于电化学电池的负极
EP3339295A1 (de) 2016-12-21 2018-06-27 Sika Technology Ag Amidin-katalysator für härtbare zusammensetzungen
US20190359850A1 (en) 2017-01-13 2019-11-28 Covestro Deutschland Ag Low-solvent coating systems for textiles
WO2018156631A1 (en) 2017-02-23 2018-08-30 3M Innovative Properties Company Air and water barrier article including inelastic porous layer
EP3601217A1 (de) 2017-03-24 2020-02-05 Sika Technology AG Guanidin-katalysator für härtbare zusammensetzungen
EP3395847B1 (en) 2017-04-25 2020-03-11 Henkel AG & Co. KGaA Silane coupling agents
DE102017115439A1 (de) 2017-07-10 2019-01-10 Bona Gmbh Deutschland Verfahren zur Erhöhung der Anwendungssicherheit und der Alterungsbeständigkeit von Klebstoffen und anderen Produkten, enthaltend silanfunktionalisierte Präpolymere
WO2019015808A1 (en) 2017-07-21 2019-01-24 Henkel Ag & Co. Kgaa SILYLATED POLYURETHANES AND METHODS OF PREPARATION THEREOF
EP3456706A1 (de) 2017-09-19 2019-03-20 Covestro Deutschland AG Polyasparaginsäureester-zusammensetzungen und verfahren zur reinigung
EP3456755A1 (de) 2017-09-19 2019-03-20 Covestro Deutschland AG Polyasparaginsäureester-zusammensetzungen enthaltend polyasparaginsäureester mit primären aminogruppen und geringe mengen an fumarsäuredialkylester
EP3684872B1 (en) 2017-09-20 2021-06-23 Sika Technology AG Compositions based on silane-terminated polymers with improved adhesion on thermoplastics
DE102017219755A1 (de) 2017-11-07 2019-05-09 Bona Gmbh Deutschland Verwendung von Additiven zur Erhöhung der Zugscherfestigkeit und Zusammensetzung enthaltend ein silanfunktionalisiertes Präpolymer und Additive
EP3489316A1 (de) 2017-11-22 2019-05-29 Covestro Deutschland AG Neue systeme für die grundierung und das kleben von bodenbelägen
EP3501641A1 (de) 2017-12-22 2019-06-26 Covestro Deutschland AG Feuchtigkeitshärtende zusammensetzungen
EP3502185A1 (de) 2017-12-22 2019-06-26 Covestro Deutschland AG Feuchtigkeitshärtende zusammensetzungen
EP3501642A1 (de) 2017-12-22 2019-06-26 Covestro Deutschland AG Verfahren zur herstellung gemischter silanterminierter polymere
EP3505549A1 (de) 2017-12-28 2019-07-03 Covestro Deutschland AG Silanmodifizierte polyharnstoffverbindungen auf basis isocyanurat- und allophanatgruppen aufweisender polyisocyanate
EP3505548A1 (de) 2017-12-28 2019-07-03 Covestro Deutschland AG Alkoxysilanmodifizierte polyharnstoffverbindungen auf basis einer mischung von dialkoxy- und trialkoxysilanen
WO2019145420A1 (de) 2018-01-26 2019-08-01 Sika Technology Ag Härtbare zusammensetzung mit acetal-weichmacher
WO2019159972A1 (ja) 2018-02-13 2019-08-22 株式会社カネカ ワーキングジョイント用１成分型硬化性組成物
CN108913007B (zh) * 2018-05-08 2021-02-02 深圳飞扬骏研新材料股份有限公司 一种油污混凝土地面用抗油污底漆树脂的合成方法
CN112189043A (zh) 2018-06-25 2021-01-05 Sika技术股份公司 基于硅烷官能的聚合物的不含催化剂的可固化组合物
WO2020004361A1 (ja) 2018-06-27 2020-01-02 住友化学株式会社 反応性ケイ素化合物の縮合物を含むゲル
EP3613786A1 (de) 2018-08-21 2020-02-26 Covestro Deutschland AG Trocknungsmittel für feuchtigkeitshärtende zusammensetzungen
EP3613785A1 (de) 2018-08-21 2020-02-26 Covestro Deutschland AG Trocknungsmittel für feuchtigkeitshärtende zusammensetzungen
US12006394B2 (en) 2018-10-03 2024-06-11 Sika Technology Ag Curable composition of low density
KR20210080450A (ko) * 2018-10-19 2021-06-30 모멘티브 퍼포먼스 머티리얼즈 게엠베하 아스파르트산 에스테르-기능성 폴리실록산, 그것의 제조 및 그것의 용도
WO2020089019A1 (de) 2018-10-30 2020-05-07 Covestro Deutschland Ag Verfahren zur herstellung eines mehrschicht-lackaufbaus mit einer deckschicht aus silangruppen-enthaltenden prepolymeren
JP2022505990A (ja) 2018-10-30 2022-01-14 コベストロ・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング・アンド・コー・カーゲー 層接着が改善された複層ペイント構造
DE102018127854A1 (de) 2018-11-08 2020-05-14 Delo Industrie Klebstoffe Gmbh & Co. Kgaa Feuchtigkeitshärtbare Einkomponentenmasse und Verfahren zum Fügen, Vergießen und Beschichten unter Verwendung der Masse
WO2020170908A1 (ja) 2019-02-18 2020-08-27 株式会社カネカ 硬化性組成物
EP3699219A1 (de) 2019-02-22 2020-08-26 Covestro Deutschland AG Neue zweikomponenten-klarlacksysteme enthaltend polyasparaginsäureester
EP3868805A1 (de) 2020-02-18 2021-08-25 Covestro Deutschland AG Neue zweikomponenten-klarlacksysteme enthaltend polyasparaginsäureester
CN113412295B (zh) 2019-02-22 2023-08-25 科思创知识产权两合公司 包含多天冬氨酸酯的新型双组分清漆体系
EP3699218A1 (de) 2019-02-22 2020-08-26 Covestro Deutschland AG Neue zweikomponenten-deckbeschichtungssysteme enthaltend polyasparaginsäureester
WO2020179644A1 (ja) 2019-03-04 2020-09-10 株式会社カネカ ポリマーブレンド、組成物、シーラント、およびタイヤ用シーラント
EP3941958B1 (de) 2019-03-19 2023-06-07 Covestro Intellectual Property GmbH & Co. KG Sekundäre aminogruppen haltige bindemittel basierend auf cyclischen ethern
MX2021008883A (es) 2019-03-20 2021-08-19 Sika Tech Ag Metodo para unir sustratos termoplasticos a base de caucho de forma adhesiva campo tecnico.
EP3722346A1 (de) 2019-04-09 2020-10-14 Covestro Deutschland AG 2-komponenten-polyurethanbeschichtungen mit verbesserter topfzeit ohne einbusse in der witterungsstabilität
EP3744748A1 (de) 2019-05-27 2020-12-02 Covestro Deutschland AG Verfahren zur herstellung eines gemischten silanterminierten polymers
EP3760658A1 (de) 2019-07-03 2021-01-06 Covestro Deutschland AG Beständige 2k-pur-beschichtungen
WO2021024817A1 (ja) 2019-08-06 2021-02-11 株式会社カネカ 硬化性組成物
CN114206605A (zh) 2019-08-07 2022-03-18 3M创新有限公司 带材、包括带材和复合层的制品及相关方法
US11827788B2 (en) 2019-10-07 2023-11-28 Covestro Llc Faster cure polyaspartic resins for faster physical property development in coatings
US20230100021A1 (en) 2020-04-08 2023-03-30 Sika Technology Ag Compositions based on silane-functional polymers having enhanced overpaintability
EP3932986A1 (en) 2020-07-03 2022-01-05 Sika Technology Ag A thermoplastic composition having improved mechanical properties
CN115916855A (zh) 2020-07-10 2023-04-04 株式会社钟化 (甲基)丙烯酸酯系共聚物及其固化性组合物
FR3115789B1 (fr) 2020-11-03 2024-04-12 Bostik Sa polymère HYDROCARBONE à blocs POLYETHER ET POLYOLEFINE COMPRENANT AU MOINS UN groupement terminal alcoxysilane
EP4056652A1 (de) 2021-03-11 2022-09-14 Covestro Deutschland AG Alterungsbeständige feuchtigkeitshärtende zusammensetzungen
WO2022203065A1 (ja) 2021-03-26 2022-09-29 株式会社カネカ 硬化性組成物及びその硬化物
EP4079780A1 (en) 2021-04-21 2022-10-26 Sika Technology AG Sealant system for chlorinated water pools
EP4108694A1 (de) 2021-06-21 2022-12-28 Covestro Deutschland AG Beschichtungsmittel und daraus erhältliche beschichtungen mit verbesserten anschmutzungsresistenzen und (selbst-)reinigungseigenschaften
CN117616084A (zh) 2021-07-09 2024-02-27 株式会社钟化 多剂型固化性组合物
EP4137524A1 (de) 2021-08-17 2023-02-22 Covestro Deutschland AG Neue zweikomponenten-beschichtungssysteme enthaltend polyasparaginsäureester
EP4198094A1 (de) 2021-12-20 2023-06-21 Covestro Deutschland AG Mehrschichtaufbau auf metallischen untergründen basierend auf polyaspartatbeschichtungen
EP4265663A1 (de) 2022-04-21 2023-10-25 Covestro Deutschland AG Polyaspartat-basierte zweikomponenten-beschichtungszusammensetzungen zur herstellung von beschichtungen mit guten selbstheilungseigenschaften bei gleichzeitig geringer klebrigkeit
WO2024024963A1 (ja) * 2022-07-28 2024-02-01 関西ペイント株式会社 変性ポリイソシアネート、コーティング及び塗装金属材

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3033815A (en) * 1959-08-28 1962-05-08 Union Carbide Corp Organosilicon compounds and process for producing same
DE1670812A1 (de) * 1967-03-01 1971-03-11 Bayer Ag Polycarbonsaeureester
US3759968A (en) * 1971-05-17 1973-09-18 Gen Electric Silyl maleates and polysiloxane maleates
DE2158945A1 (de) * 1971-11-27 1973-05-30 Horst Holfort Stickstoffhaltige harze
US3940360A (en) * 1974-02-12 1976-02-24 Union Carbide Corporation Silane containing coating compositions
CH632765A5 (de) * 1977-09-09 1982-10-29 Ciba Geigy Ag Verfahren zur herstellung von siliciummodifizierten phthalsaeurederivaten.
US4718944A (en) * 1986-10-07 1988-01-12 Dow Corning Corporation Coupling agent compositions
US5189190A (en) * 1989-02-08 1993-02-23 Henkel Research Corporation Vicinal disubstituted carboxylic acids and silylated derivatives
ATE113622T1 (de) * 1989-06-23 1994-11-15 Bayer Ag Verfahren zur herstellung von überzügen.
US5236741A (en) * 1989-06-23 1993-08-17 Bayer Aktiengesellschaft Process for the production of polyurethane coatings
US5260467A (en) * 1989-11-16 1993-11-09 Pfizer Inc. Glutaric acid derivatives and preparation thereof
DE4029505A1 (de) * 1990-09-18 1992-03-19 Henkel Kgaa Feuchtigkeitshaertende, alkoxysilanterminierte polyurethane

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Anhang zum Amtsblatt der Europäischen Gemeinschaften ISSN 0376-9461; C146A; Mitteilungen und Bekanntmachungen; Band II, Seite 1688; 15/6/90 *

Also Published As

Publication number Publication date
DE4237468A1 (de) 1994-05-11
ES2127777T3 (es) 1999-05-01
ATE175970T1 (de) 1999-02-15
DE59309327D1 (de) 1999-03-04
CA2102272A1 (en) 1994-05-07
EP0596360A1 (de) 1994-05-11
JPH06211879A (ja) 1994-08-02
US5364955A (en) 1994-11-15
CA2102272C (en) 2005-01-25
JP3342552B2 (ja) 2002-11-11

Similar Documents

Publication Publication Date Title
EP0596360B1 (de) Verwendung vonAlkoxysilian- und Aminogruppen aufweisenden Verbindungen
DE60015147T2 (de) Feuchtigkeitshärtbare Zusammensetzungen, die Silan-Endgruppen enthalten
EP1824904B1 (de) Alkoxysilanterminierte prepolymere
DE69906002T2 (de) Silanmodifizierte Polyurethanharze, Verfahren zu deren Herstellung und ihre Verwendung als feuchtigkeitshärtbare Harze
DE69728486T2 (de) Härtbare Silanendgruppen enthaltende Zusammensetzungen mit verbesserter Leistung
EP0807649B1 (de) Alkoxysilan- und Hydantoingruppen aufweisende Polyurethanprepolymere, ein Verfahren zu ihrer Herstellung sowie ihre Verwendung zur Herstellung von Dichtstoffen
EP1245601B1 (de) Metallfreie silanterminierte Polyurethane, ein Verfahren zu deren Herstellung und deren Anwendung
DE2754545A1 (de) Haertbare polyurethanpolymere
DE10355318A1 (de) Verfahren zur Herstellung von organyloxysilylterminierten Polymeren
DE10328844A1 (de) Alkoxysilanterminierte Prepolymere
DE10330288A1 (de) Alkoxysilanterminierte Prepolymere
DE10237271A1 (de) Polymermassen auf Basis alkoxysilanterminierter Polymere mit regulierbarer Härtungsgeschwindigkeit
DE602004012439T2 (de) Feuchtigkeitshärtbare polyetherurethane mit reaktiven silangruppen und ihre verwendung als dichtstoffe, klebstoffe und beschichtungen
KR20020013935A (ko) 알콕시실란기가 있는 피페라지논 유도체
EP0406160B1 (de) Haftvermittler
EP3727687B1 (de) Verfahren zur herstellung gemischter silanterminierter polymere
EP3740524B1 (de) Verfahren zur herstellung von silanterminierten polymeren
EP3027628A1 (de) Hydroxymethylcarboxamido-substituiertes silanol fur hartbare, silanterminierte polymere.
WO2020193430A1 (de) Zusammensetzung und verfahren zur herstellung silylierter polymere und deren verwendung
EP3976684B1 (de) Verfahren zur herstellung eines gemischten silanterminierten polymers
DE10235481A1 (de) Härtbare Harzmasse
EP0414640A2 (de) Iminosilane
EP0489688B1 (de) Haftvermittler
DE10351802A1 (de) alpha-Alkoxysilane sowie ihre Anwendung in alkoxysilanterminierten Prepolymeren
WO2021115621A1 (de) Verfahren zur herstellung von organyloxysilanterminierten polymeren

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE ES FR GB IT LI NL SE

17P Request for examination filed

Effective date: 19940524

17Q First examination report despatched

Effective date: 19970128

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE ES FR GB IT LI NL SE

REF Corresponds to:

Ref document number: 175970

Country of ref document: AT

Date of ref document: 19990215

Kind code of ref document: T

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: E. BLUM & CO. PATENTANWAELTE

REF Corresponds to:

Ref document number: 59309327

Country of ref document: DE

Date of ref document: 19990304

ITF It: translation for a ep patent filed

Owner name: ING. C. GREGORJ S.P.A.

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2127777

Country of ref document: ES

Kind code of ref document: T3

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 19990419

ET Fr: translation filed
PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
REG Reference to a national code

Ref country code: GB

Ref legal event code: IF02

REG Reference to a national code

Ref country code: CH

Ref legal event code: PFA

Owner name: BAYER AG

Free format text: BAYER AG# #51368 LEVERKUSEN (DE) -TRANSFER TO- BAYER AG# #51368 LEVERKUSEN (DE)

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20120925

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20121018

Year of fee payment: 20

Ref country code: CH

Payment date: 20121012

Year of fee payment: 20

Ref country code: DE

Payment date: 20121017

Year of fee payment: 20

Ref country code: FR

Payment date: 20121018

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20121019

Year of fee payment: 20

Ref country code: SE

Payment date: 20121011

Year of fee payment: 20

Ref country code: GB

Payment date: 20121024

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20121016

Year of fee payment: 20

Ref country code: AT

Payment date: 20120927

Year of fee payment: 20

REG Reference to a national code

Ref country code: DE

Ref legal event code: R071

Ref document number: 59309327

Country of ref document: DE

BE20 Be: patent expired

Owner name: *BAYER A.G.

Effective date: 20131025

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: NL

Ref legal event code: V4

Effective date: 20131025

REG Reference to a national code

Ref country code: GB

Ref legal event code: PE20

Expiry date: 20131024

REG Reference to a national code

Ref country code: SE

Ref legal event code: EUG

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK07

Ref document number: 175970

Country of ref document: AT

Kind code of ref document: T

Effective date: 20131025

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 20131024

Ref country code: DE

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 20131026

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20140925

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 20131026