EP0376706A1 - Composition de blanchiment - Google Patents
Composition de blanchiment Download PDFInfo
- Publication number
- EP0376706A1 EP0376706A1 EP19890313625 EP89313625A EP0376706A1 EP 0376706 A1 EP0376706 A1 EP 0376706A1 EP 19890313625 EP19890313625 EP 19890313625 EP 89313625 A EP89313625 A EP 89313625A EP 0376706 A1 EP0376706 A1 EP 0376706A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- surfactant
- composition
- hydrogen peroxide
- solution
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000203 mixture Substances 0.000 title claims description 43
- 238000004061 bleaching Methods 0.000 title claims description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 86
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000004094 surface-active agent Substances 0.000 claims abstract description 34
- 239000003792 electrolyte Substances 0.000 claims abstract description 25
- 239000000243 solution Substances 0.000 claims description 32
- 239000007788 liquid Substances 0.000 claims description 14
- 150000003606 tin compounds Chemical class 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 230000007062 hydrolysis Effects 0.000 claims description 6
- 238000006460 hydrolysis reaction Methods 0.000 claims description 6
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 5
- 239000012670 alkaline solution Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 4
- 239000003945 anionic surfactant Substances 0.000 claims description 3
- 239000002280 amphoteric surfactant Substances 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
- 239000002736 nonionic surfactant Substances 0.000 claims description 2
- 125000005270 trialkylamine group Chemical group 0.000 claims description 2
- 125000005011 alkyl ether group Chemical group 0.000 claims 1
- BTFJIXJJCSYFAL-UHFFFAOYSA-N icosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 16
- 239000003381 stabilizer Substances 0.000 description 15
- 239000007844 bleaching agent Substances 0.000 description 12
- -1 alkyl ether sulphate Chemical class 0.000 description 9
- 229910021538 borax Inorganic materials 0.000 description 8
- 239000011780 sodium chloride Substances 0.000 description 8
- 239000004328 sodium tetraborate Substances 0.000 description 8
- 235000010339 sodium tetraborate Nutrition 0.000 description 8
- FWPIDFUJEMBDLS-UHFFFAOYSA-L tin(II) chloride dihydrate Chemical compound O.O.Cl[Sn]Cl FWPIDFUJEMBDLS-UHFFFAOYSA-L 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- SFXJSNATBHJIDS-UHFFFAOYSA-N disodium;dioxido(oxo)tin;trihydrate Chemical compound O.O.O.[Na+].[Na+].[O-][Sn]([O-])=O SFXJSNATBHJIDS-UHFFFAOYSA-N 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- 230000008719 thickening Effects 0.000 description 6
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 5
- 230000002378 acidificating effect Effects 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229940079864 sodium stannate Drugs 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 150000002978 peroxides Chemical group 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 235000011150 stannous chloride Nutrition 0.000 description 4
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- ONLRKTIYOMZEJM-UHFFFAOYSA-N n-methylmethanamine oxide Chemical compound C[NH+](C)[O-] ONLRKTIYOMZEJM-UHFFFAOYSA-N 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910020212 Na2SnO3 Inorganic materials 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 239000004141 Sodium laurylsulphate Substances 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 239000001119 stannous chloride Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910000375 tin(II) sulfate Inorganic materials 0.000 description 2
- 229940120146 EDTMP Drugs 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- CDMADVZSLOHIFP-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 CDMADVZSLOHIFP-UHFFFAOYSA-N 0.000 description 1
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- FAKFSJNVVCGEEI-UHFFFAOYSA-J tin(4+);disulfate Chemical compound [Sn+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O FAKFSJNVVCGEEI-UHFFFAOYSA-J 0.000 description 1
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3937—Stabilising agents
- C11D3/394—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
Definitions
- This invention relates to liquid bleach compositions which may be thickened liquids suitable for sale and use as a domestic bleach.
- the compositions of the invention may be pourable liquids, albeit more viscous than water, or may be even more viscous liquids which cannot be poured easily. Thickening of a pourable domestic bleach helps the user to control dispensing of the composition and retards drainage from surfaces to which it is applied.
- a domestic bleach needs to be adequately stable so that a substantial proportion of the bleaching agent survives during storage between manufacture and use.
- commercial liquid bleach products have frequently utilised hypochlorite as bleaching agent.
- EP-B-9839 discloses that the stabilisation of hydrogen peroxide under alkaline conditions can be accomplished using certain specified phosphonate compounds. It also contains comparative results testing the effectiveness of various materials as stabilisers under alkaline conditions. These comparative results show that many materials which are known to stabilise acidic hydrogen peroxide have very little effect under alkaline conditions.
- colloidal hydrous stannic oxide One material which has been disclosed as a stabiliser for hydrogen peroxide in acidic solution is colloidal hydrous stannic oxide.
- US 3781409 and US 3607053 are examples of disclosures of the use of sodium stannate as a stabilising agent for acidic hydrogen peroxide solution.
- the sodium stannate is dissolved in an alkaline but peroxide-free solution which is then added as a stabiliser to very much larger volumes of acidic hydrogen peroxide solution.
- the sodium stannate will undergo hydrolysis to colloidal hydrous stannic oxide in the solution.
- the alkaline solution contains other salts in addition to sodium stannate but these are diluted to a very low electrolyte level when added to the acidic hydrogen peroxide solution.
- Pourable domestic liquid bleach is frequently thickened by including one or more surfactants which, in the presence of electrolyte, act to thicken the solution so that it becomes more viscous than water.
- any attempt to make a surfactant-thickened, alkaline domestic liquid bleach product using hydrogen peroxide as the bleaching agent would encounter the potential problem that the thickening of the solution would require the presence of some electrolyte but that this electrolyte would serve to accelerate decomposition of the peroxide.
- electrolyte inherently tends to bring about flocculation of colloidal suspensions. Consequently the presence of electrolyte also has the potential to bring about a reduction of the effectiveness of any stabilising agent which is in the form of a colloidal suspension.
- colloidal hydrous stannic oxide can act as a very effective stabilising agent for alkaline hydrogen peroxide solutions. It is also surprising that colloidal hydrous stannic oxide will tolerate the inclusion of surfactant and electrolyte in sufficient quantities to effect thickening.
- the present invention provides a liquid bleaching composition which is an alkaline aqueous solution containing hydrogen peroxide and also containing colloidal hydrous stannic oxide.
- the composition also contains a viscosity-increasing agent which is one or more surfactants in the presence of electrolyte.
- a composition according to the invention also contains an electrolyte other than surfactant, together with at least one surfactant which serves in the presence of electrolyte to increase the viscosity of the solution.
- the colloidal hydrous stannic oxide which is used as a stabilising agent is preferably formed in-situ in the solution as the product of hydrolysis of a soluble tin compound. Consequently in a second aspect this invention provides a method of preparing a liquid bleaching composition which comprises including in the composition, successively or together, hydrogen peroxide, sufficient alkaline material to give the solution an alkaline pH, and a tin compound capable of hydrolysis to stannic oxide, so that the tin compound is hydrolysed in the solution to colloidal hydrous stannic oxide.
- the hydrolysis may take place in a solution which is already thickened by the presence of surfactant therein, even though the peroxide may not yet have been added to the solution.
- tin compounds can be added to the solution to undergo hydrolysis to form the stannic oxide. Those preferred are tin sulphate and sodium stannate. Other tin compounds can be used, including tin dichloride and tin tetrachloride.
- concentrations of tin compound included in the composition may lie in the range from 10 ⁇ 4 molar to 10 ⁇ 2 molar, preferably 3 x 10 ⁇ 3 to 6 x 10 ⁇ 4 molar.
- the quantity of tin compound should not be substantially greater than necessary, since excess of it can itself cause peroxide decomposition.
- An optimum concentration of the tin compound can be determined by making test solutions with various concentrations of the tin compound and analytically determining the amount of peroxide retained on storage.
- compositions of this invention preferably have a pH in the range from 8.0 to 10.5, better 8.5 to 9.8 or 10.0, yet more preferably 8.7 to 9.3.
- a buffer may be included to set the pH.
- At least one surfactant to increase the viscosity of the composition. It is desirable that this surfactant or surfactants has the ability to thicken a solution in the presence of a fairly low electrolyte concentration. This may make it possible for the electrolyte to be provided by salts which are in the composition for another purpose, without deliberate addition of any salt for the sole purpose of enhancing ionic strength. Since electrolyte is known to be detrimental to hydrogen peroxide stability, it is desirable to keep the electrolyte concentration low. A further benefit of a low electrolyte concentration is a reduced tendency for the composition to leave streaks on a surface which is cleaned with it.
- alkyl ether sulphate having the formula: R(OC2H4) n OSO3M where R is an alkyl group, preferably linear alkyl, containing 8 to 20 carbon atoms, n has an average value in the range from 0.5 to 12 better 1 to 6 and M is a solubilising cation, preferably alkali metal such as sodium.
- a pair of surfactants used to effect thickening may be a combination of a nonionic or amphoteric surfactant together with an anionic surfactant. Two specific possibilities are the combinations of:
- the total amount of surfactant(s) included may be a small proportion of the composition, for example the thickening surfactant(s) may constitute 0.75 to 3% of the composition. Larger amounts, giving greater viscosity, may be used but are less preferred.
- the weight ratio of amine oxide:alcohol sulphate preferably ranges from 82:18 or 80:20 to 65:35, better 80:20 to 70:30.
- Alkane sulphonate is preferred over alcohol sulphate, because the viscosity is less sensitive to changes in the composition, so making it easier to produce an end product with repeatable viscosity.
- the weight ratio of amine oxide to alkane sulphonate is preferably in the range from 80:20 to 50:50 or 65:35, better 70:30 to 65:35.
- the electrolyte concentration in a composition of this invention may be such that the total of salts other than surfactant is not more than 7% by weight, better not more than 5% or 3%.
- the electrolyte level may be such as to give a concentration of electrolyte in the range 0.05 to 0.30 molar, preferably 0.1 to 0.2 molar. Once again higher concentrations may be used but are less preferred.
- the concentration of hydrogen peroxide in compositions of this invention desirably lies in the range from 1 to 15% by weight preferably 2 to 10% by weight.
- An appropriate viscosity for a pourable composition having the appearance of a thick liquid is a dynamic viscosity in the range from 50 to 250 centipoise (0.05 to 0.25 Pa.sec), preferably about 100 centipoise (0.1 Pa.sec). More viscous liquids for example with viscosity in the range from 250 to 1000 centipoise or more are also within the scope of the invention.
- compositions of this invention are generally aqueous, they will usually have specific gravity close to unity. Consequently values of kinematic viscosities (in stokes) will be numerically approximately the same as values of dynamic viscosity (in poise). Dynamic viscosities expressed in Pascal.sec will be approximately 1000 times kinetic viscosities expressed in m2.sec ⁇ 1.
- Formulations were prepared containing the constituents set out in Table 1 below. The compositions were stored in plastic bottles at 37°C. At intervals aliquots were removed and titrated with potassium permanganate to determine the level of hydrogen peroxide remaining. Results are included in Table 1.
- the stabiliser in accordance with EP 9839 was diethylene triamine penta (methylene phosphonic acid).
- Example 1 The procedure of Example 1 was repeated, using formulations with the same amounts of hydrogen peroxide, surfactant, perfume and dye.
- Various tin compounds were used at a concentration of 6 x 10 ⁇ 3 molar, both with and without 3.0% borax decahydrate. Glass bottles were used, which are somewhat detrimental to stability. In every case pH was 9.6 initially. Proportions of hydrogen peroxide remaining after 28 days were:- SnCl2 with borax 68% Na2SnO3 with borax 47% SnSO4 with borax 45% Na2SnO3 without borax 96% SnSO4 without borax 95%
- Example 1 The procedure of Example 1 was repeated using a different surfactant and with stannous chloride as the tin salt.
- the surfactant used was a linear alkyl ether sulphate of general formula: R(OC2H4) n OSO3 Na where the alkyl group R was C11 and C13 linear alkyl groups, and n had an average value of 3.
- a comparative experiment replaced the stannous chloride with the same phosphonate stabiliser according to EP 9839 as used in Example 1.
- the formulations and results are set out in the following Table. Viscosities were determined using a Haake roto-viscometer and were approximately 100cP at a shear rate of 21 sec ⁇ 1.
- the composition was stored at 40 °C and the amount of hydrogen peroxide remaining was determined analytically at intervals. It was found that 75% of the hydrogen peroxide remained after 3 weeks.
- the quantities of surfactant and sodium chloride were such as to give viscosities well in excess of that preferred for a pourable type of bleach product. Smaller quantities could be used to give a "thick liquid" type of bleach product.
- Stannic chloride was used at a concentration of 2.3 x 10 ⁇ 3 molar.
- One surfactant system consisted of 4.5% by weight of C12-C14 alkyl dimethyl amine oxide and 4.5% by weight sodium lauryl sulphate. This was used with a sodium chloride concentration of 9% by weight.
- the second surfactant system consisted of 5% by weight of C11-C15 secondary alcohol ethoxylated with average 3 ethylene oxide residues, and 5% by weight of sodium lauryl sulphate. This combination was used with 3.37% by weight sodium chloride.
- a base solution was prepared containing tallow dimethylamine oxide, sodium alkane sulphonate and borax. This was used to make up solutions containing hydrogen peroxide and colloidal stannic oxide, but two procedures were used.
- stannous chloride dihydrate was added to the base solution and stirred until it was completely dissolved or dispersed, after which hydrogen peroxide solution was added.
- the solution pH at this stage was 6.5. It was adjusted to pH 9.9 by adding 20% w/v sodium hydroxide solution and some distilled water.
- composition contained: Hydrogen peroxide (reckoned as anhydrous) 4.98g Tallow dimethylamine oxide 0.98g Sodium alkane sulphonate 0.48g Borax (reckoned as anhydrous) 1.6 g SnCl2.2H2O 0.14g Sodium hydroxide to give: pH 9.9 Water balance to 100g total
- a suspension of stannic oxide was prepared by dissolving 5g of stannous chloride dihydrate in approximately 115g distilled water, and then adding sodium hydroxide solution to give a pH of 9.7. The resulting suspension of stannic oxide was stored overnight.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8830296 | 1988-12-28 | ||
| GB888830296A GB8830296D0 (en) | 1988-12-28 | 1988-12-28 | Bleaching composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0376706A1 true EP0376706A1 (fr) | 1990-07-04 |
| EP0376706B1 EP0376706B1 (fr) | 1995-02-15 |
Family
ID=10649218
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP89313623A Expired - Lifetime EP0376704B1 (fr) | 1988-12-28 | 1989-12-27 | Composition de blanchiment |
| EP89313625A Expired - Lifetime EP0376706B1 (fr) | 1988-12-28 | 1989-12-27 | Composition de blanchiment |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP89313623A Expired - Lifetime EP0376704B1 (fr) | 1988-12-28 | 1989-12-27 | Composition de blanchiment |
Country Status (11)
| Country | Link |
|---|---|
| EP (2) | EP0376704B1 (fr) |
| JP (2) | JP2562064B2 (fr) |
| AU (2) | AU623961B2 (fr) |
| BR (2) | BR8906844A (fr) |
| CA (2) | CA2006531C (fr) |
| DE (2) | DE68921181T2 (fr) |
| ES (2) | ES2067558T3 (fr) |
| GB (1) | GB8830296D0 (fr) |
| IN (2) | IN171127B (fr) |
| NO (2) | NO173885C (fr) |
| ZA (2) | ZA899842B (fr) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1993001270A1 (fr) * | 1991-07-12 | 1993-01-21 | Henkel Kommanditgesellschaft Auf Aktien | Produit de lavage liquide |
| US5217710A (en) * | 1992-03-05 | 1993-06-08 | Chesebrough-Pond's Usa Co. | Stabilized peroxide gels containing fluoride |
| EP2087088A2 (fr) * | 2006-10-27 | 2009-08-12 | Arkema, Inc. | Formulation de détergent liquide ayant du peroxyde d'hydrogène |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8830296D0 (en) * | 1988-12-28 | 1989-02-22 | Unilever Plc | Bleaching composition |
| GB9319943D0 (en) * | 1993-09-28 | 1993-11-17 | Solvay Interox Ltd | Thickened compositions |
| GB2286603B (en) * | 1994-02-14 | 1998-03-25 | Jeyes Group Plc | Bleach compositions |
| DE4413433C2 (de) * | 1994-04-18 | 1999-09-16 | Henkel Kgaa | Wäßrige Bleichmittel |
| US5492540A (en) * | 1994-06-13 | 1996-02-20 | S. C. Johnson & Son, Inc. | Soft surface cleaning composition and method with hydrogen peroxide |
| WO1996001311A1 (fr) * | 1994-07-01 | 1996-01-18 | Warwick International Group Limited | Compositions de blanchiment |
| US5736497A (en) * | 1995-05-05 | 1998-04-07 | Degussa Corporation | Phosphorus free stabilized alkaline peroxygen solutions |
| DE19623571C2 (de) * | 1996-06-13 | 2000-06-08 | Cognis Deutschland Gmbh | Verdickungsmittel für wäßrige Wasserstoffperoxidlösungen |
| BR9704210A (pt) * | 1997-07-31 | 1999-02-02 | Unilever Nv | Composição detergente e processo de lavagem de pratos |
| GB9812457D0 (en) * | 1998-06-10 | 1998-08-05 | Secr Defence | Surface coatings |
| AU741580B2 (en) * | 1998-06-23 | 2001-12-06 | Saban Ventures Pty Limited | Improved disinfection |
| EP1123375B1 (fr) * | 1998-10-22 | 2005-04-20 | Colgate-Palmolive Company | Composition de blanchiment liquide epaissie a base de peroxyde d'azote |
| GB2349892A (en) * | 1999-05-13 | 2000-11-15 | Warwick Internat Group Ltd | Metal cleaning |
| GB2397823A (en) * | 2003-01-31 | 2004-08-04 | Reckitt Benckiser Nv | Aqueous cleaning compositions |
| GB2401875A (en) * | 2003-05-22 | 2004-11-24 | Reckitt Benckiser Nv | Aqueous cleaning compositions |
| ITMI20031543A1 (it) * | 2003-07-28 | 2005-01-29 | De Nora Elettrodi Spa | Elettrodo per processi elettrochimici e metodo per il suo ottenimento |
| US7169237B2 (en) | 2004-04-08 | 2007-01-30 | Arkema Inc. | Stabilization of alkaline hydrogen peroxide |
| US7045493B2 (en) | 2004-07-09 | 2006-05-16 | Arkema Inc. | Stabilized thickened hydrogen peroxide containing compositions |
| DE102005000955B4 (de) * | 2005-01-07 | 2007-08-30 | Henkel Kgaa | Flüssige Bleichmittelzusammensetzung |
| CN105925398B (zh) * | 2016-05-17 | 2018-11-23 | 河南工程学院 | 一种除菌液体洗涤剂组合物及其制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB855679A (en) * | 1958-07-10 | 1960-12-07 | Unilever Ltd | Improvements in or relating to liquid detergent compositions |
| CH356235A (de) * | 1956-11-14 | 1961-08-15 | Unilever Nv | Beständiges, synthetische waschaktive Verbindungen und eine Perverbindung enthaltendes Reinigungsmittel und seine Verwendung zum Waschen von Wäsche |
| US3701825A (en) * | 1970-10-23 | 1972-10-31 | Fmc Corp | Stabilization of hydrogen peroxide with ethylenediamine tetra (methylenephosphonic acid) |
| JPS5838800A (ja) * | 1981-09-01 | 1983-03-07 | 三菱瓦斯化学株式会社 | 液体洗浄剤 |
| EP0097305A1 (fr) * | 1982-06-14 | 1984-01-04 | FMC Corporation | Stabilisation du peroxyde d'hydrogène très pur |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1271885B (de) * | 1964-01-04 | 1968-07-04 | Henkel & Cie Gmbh | Fluessige, lagerbestaendige Wasch-, Bleich- und Oxydationsmittel |
| FR2140822A5 (en) * | 1971-06-09 | 1973-01-19 | Air Liquide | Bleaching liquids - contg hydrogen peroxide or persalts in alkaline medium with stabilisers |
| US4304762A (en) * | 1978-09-27 | 1981-12-08 | Lever Brothers Company | Stabilization of hydrogen peroxide |
| US4299802A (en) * | 1980-03-31 | 1981-11-10 | Union Carbide Corporation | Process for removing carbonyl sulfide from gaseous streams |
| DE3168426D1 (en) * | 1980-04-01 | 1985-03-07 | Interox Chemicals Ltd | Liquid detergent compositions, their manufacture and their use in washing processes |
| JPS56151798A (en) * | 1980-04-01 | 1981-11-24 | Interox Chemicals Ltd | Liquid detergent composition |
| DE3205318A1 (de) * | 1982-02-15 | 1983-08-18 | Henkel KGaA, 4000 Düsseldorf | Desinfektionsmittelkonzentrat |
| JPS593006A (ja) * | 1982-06-14 | 1984-01-09 | エフ・エム・シ−・コ−ポレ−シヨン | 安定化された過酸化水素水溶液 |
| FR2552124B1 (fr) * | 1983-09-20 | 1986-09-12 | Ugine Kuhlmann | Nouvelles formulations fluides pour bains alcalins de blanchiment textile stables au stockage et leur procede d'obtention |
| JP2783999B2 (ja) * | 1985-06-12 | 1998-08-06 | 花王株式会社 | 漂白剤組成物 |
| GB8830296D0 (en) * | 1988-12-28 | 1989-02-22 | Unilever Plc | Bleaching composition |
-
1988
- 1988-12-28 GB GB888830296A patent/GB8830296D0/en active Pending
-
1989
- 1989-12-21 ZA ZA899842A patent/ZA899842B/xx unknown
- 1989-12-21 ZA ZA899843A patent/ZA899843B/xx unknown
- 1989-12-22 CA CA002006531A patent/CA2006531C/fr not_active Expired - Fee Related
- 1989-12-22 AU AU47271/89A patent/AU623961B2/en not_active Ceased
- 1989-12-22 CA CA002006530A patent/CA2006530C/fr not_active Expired - Fee Related
- 1989-12-22 AU AU47272/89A patent/AU624209B2/en not_active Ceased
- 1989-12-27 NO NO895260A patent/NO173885C/no not_active IP Right Cessation
- 1989-12-27 NO NO895261A patent/NO172354C/no not_active IP Right Cessation
- 1989-12-27 DE DE68921181T patent/DE68921181T2/de not_active Expired - Fee Related
- 1989-12-27 DE DE68921182T patent/DE68921182T2/de not_active Expired - Fee Related
- 1989-12-27 ES ES89313623T patent/ES2067558T3/es not_active Expired - Lifetime
- 1989-12-27 ES ES89313625T patent/ES2067559T3/es not_active Expired - Lifetime
- 1989-12-27 EP EP89313623A patent/EP0376704B1/fr not_active Expired - Lifetime
- 1989-12-27 EP EP89313625A patent/EP0376706B1/fr not_active Expired - Lifetime
- 1989-12-27 IN IN354/BOM/89A patent/IN171127B/en unknown
- 1989-12-27 IN IN355/BOM/89A patent/IN170708B/en unknown
- 1989-12-28 BR BR898906844A patent/BR8906844A/pt not_active IP Right Cessation
- 1989-12-28 JP JP1345128A patent/JP2562064B2/ja not_active Expired - Fee Related
- 1989-12-28 BR BR898906843A patent/BR8906843A/pt not_active IP Right Cessation
- 1989-12-28 JP JP1345129A patent/JPH0735520B2/ja not_active Expired - Lifetime
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH356235A (de) * | 1956-11-14 | 1961-08-15 | Unilever Nv | Beständiges, synthetische waschaktive Verbindungen und eine Perverbindung enthaltendes Reinigungsmittel und seine Verwendung zum Waschen von Wäsche |
| GB855679A (en) * | 1958-07-10 | 1960-12-07 | Unilever Ltd | Improvements in or relating to liquid detergent compositions |
| US3701825A (en) * | 1970-10-23 | 1972-10-31 | Fmc Corp | Stabilization of hydrogen peroxide with ethylenediamine tetra (methylenephosphonic acid) |
| JPS5838800A (ja) * | 1981-09-01 | 1983-03-07 | 三菱瓦斯化学株式会社 | 液体洗浄剤 |
| EP0097305A1 (fr) * | 1982-06-14 | 1984-01-04 | FMC Corporation | Stabilisation du peroxyde d'hydrogène très pur |
Non-Patent Citations (1)
| Title |
|---|
| CHEMICAL ABSTRACTS, vol. 99, no. 22, 28 November 1983, Columbus, Ohio, US; abstract no. 177871E, page 113; column 2; * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1993001270A1 (fr) * | 1991-07-12 | 1993-01-21 | Henkel Kommanditgesellschaft Auf Aktien | Produit de lavage liquide |
| US5217710A (en) * | 1992-03-05 | 1993-06-08 | Chesebrough-Pond's Usa Co. | Stabilized peroxide gels containing fluoride |
| EP2087088A2 (fr) * | 2006-10-27 | 2009-08-12 | Arkema, Inc. | Formulation de détergent liquide ayant du peroxyde d'hydrogène |
| EP2087088A4 (fr) * | 2006-10-27 | 2010-03-31 | Arkema Inc | Formulation de détergent liquide ayant du peroxyde d'hydrogène |
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