DE69922548D1 - Verbrückte metallocene zur olefincopolymerisation - Google Patents
Verbrückte metallocene zur olefincopolymerisationInfo
- Publication number
- DE69922548D1 DE69922548D1 DE69922548T DE69922548T DE69922548D1 DE 69922548 D1 DE69922548 D1 DE 69922548D1 DE 69922548 T DE69922548 T DE 69922548T DE 69922548 T DE69922548 T DE 69922548T DE 69922548 D1 DE69922548 D1 DE 69922548D1
- Authority
- DE
- Germany
- Prior art keywords
- polymerization
- atom
- bridged metallocene
- metallocene catalyst
- olefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/10—Heteroatom-substituted bridge, i.e. Cp or analog where the bridge linking the two Cps or analogs is substituted by at least one group that contains a heteroatom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10532998P | 1998-10-23 | 1998-10-23 | |
US105329P | 1998-10-23 | ||
US13106799P | 1999-04-26 | 1999-04-26 | |
US131067P | 1999-04-26 | ||
PCT/US1999/024944 WO2000024793A1 (en) | 1998-10-23 | 1999-10-22 | Bridged metallocenes for olefin copolymerization |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69922548D1 true DE69922548D1 (de) | 2005-01-13 |
DE69922548T2 DE69922548T2 (de) | 2006-01-05 |
Family
ID=26802468
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69922548T Expired - Lifetime DE69922548T2 (de) | 1998-10-23 | 1999-10-22 | Verbrückte metallocene zur olefincopolymerisation |
Country Status (15)
Country | Link |
---|---|
US (2) | US6528670B1 (de) |
EP (1) | EP1196464B9 (de) |
JP (1) | JP4689829B2 (de) |
KR (1) | KR100568839B1 (de) |
CN (1) | CN1138796C (de) |
AT (1) | ATE284422T1 (de) |
AU (1) | AU757241B2 (de) |
BR (1) | BR9914717A (de) |
CA (1) | CA2345628C (de) |
DE (1) | DE69922548T2 (de) |
ES (1) | ES2233109T3 (de) |
HK (1) | HK1041705A1 (de) |
MX (1) | MXPA01003978A (de) |
RU (1) | RU2232766C2 (de) |
WO (1) | WO2000024793A1 (de) |
Families Citing this family (70)
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KR20020037387A (ko) * | 1999-10-22 | 2002-05-18 | 엑손 케미칼 패턴츠 인코포레이티드 | 중합 촉매로 적합한 카베늄 양이온성 착물 |
US6476164B1 (en) | 1999-10-22 | 2002-11-05 | Exxonmobil Chemical Patents Inc. | Carbenium cationic complexes suitable for polymerization catalysts |
US6475946B1 (en) | 1999-10-22 | 2002-11-05 | Exxonmobil Chemical Patents Inc. | Olefin polymerization catalysis with aryl substituted carbenium cationic complexes |
JP4610859B2 (ja) * | 2002-09-27 | 2011-01-12 | 三井化学株式会社 | オレフィン重合用の架橋メタロセン化合物およびそれを用いたオレフィンの重合方法 |
WO2004029062A1 (ja) | 2002-09-27 | 2004-04-08 | Mitsui Chemicals, Inc. | オレフィン重合用の架橋メタロセン化合物およびそれを用いたオレフィンの重合方法 |
CN101724110B (zh) | 2002-10-15 | 2013-03-27 | 埃克森美孚化学专利公司 | 用于烯烃聚合的多催化剂体系和由其生产的聚合物 |
DE602004004222T2 (de) | 2003-08-11 | 2007-11-15 | Exxonmobil Chemical Patents Inc., Baytown | Polymere, bestehend aus Ethylen und gegebenenfalls copolimerisierbaren Estern,Filme aus diesen Polymeren und diese Filme verwendendes Strechfolienhaubenverpackungsverfahren |
CN102936304B (zh) * | 2004-03-24 | 2014-10-22 | 埃克森美孚化学专利公司 | 乙烯共聚体及其生产方法、含有乙烯共聚体的组合物和电装置 |
ATE517944T1 (de) * | 2004-10-13 | 2011-08-15 | Exxonmobil Chem Patents Inc | Elastomere reaktorblendzusammensetzungen |
EP1734059A1 (de) * | 2005-06-13 | 2006-12-20 | Total Petrochemicals Research Feluy | Kohlenstoffverbrückte Cyclopentadienyl-Fluorenyl-Liganden |
JP5252714B2 (ja) * | 2006-03-02 | 2013-07-31 | エクソンモービル・ケミカル・パテンツ・インク | プロピレンコポリマーを生産する方法 |
ES2634440T3 (es) | 2006-05-17 | 2017-09-27 | Dow Global Technologies Llc | Procedimiento de polimerización de polietileno en disolución a alta temperatura |
EP1903061A1 (de) * | 2006-09-25 | 2008-03-26 | Total Petrochemicals Research Feluy | Verfahren zur Herstellung eines Biphenyl verbrückten Cyclopentadienyl-Fluorenyl Liganden |
EP2083046A1 (de) | 2008-01-25 | 2009-07-29 | ExxonMobil Chemical Patents Inc. | Thermoplastische Elastomerzusammensetzungen |
US9234093B2 (en) | 2008-03-31 | 2016-01-12 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates |
FR2934599B1 (fr) * | 2008-07-29 | 2012-12-21 | Arkema France | Fabrication de polyethylene a partir de matieres renouvelables, polyethylene obtenu et utilisations |
US8378042B2 (en) * | 2009-04-28 | 2013-02-19 | Exxonmobil Chemical Patents Inc. | Finishing process for amorphous polymers |
MX337858B (es) | 2009-12-23 | 2016-03-18 | INVISTA Technologies S à r l | Tela que incluye fibra elastica de poliolefina. |
BR112012015383A2 (pt) | 2009-12-23 | 2016-03-15 | Invista Tech Sarl | artigo e método para preparo de um fio polimérico |
WO2011087693A2 (en) | 2009-12-23 | 2011-07-21 | Invista Technologies S.A R.1. | Elastic fiber containing an anti-tack additive |
KR101852207B1 (ko) | 2009-12-23 | 2018-04-25 | 인비스타 테크놀러지스 에스.에이 알.엘. | 폴리올레핀 탄성 섬유를 포함하는 신장성 물품 |
WO2011087731A1 (en) | 2010-01-14 | 2011-07-21 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for continuous solution polymerization |
WO2011087729A2 (en) | 2010-01-14 | 2011-07-21 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for polymer finishing and packaging |
CN102190749B (zh) * | 2010-03-05 | 2013-02-20 | 中国石油天然气股份有限公司 | 一种乙烯/α-烯烃共聚合的方法 |
KR101791810B1 (ko) | 2014-03-21 | 2017-10-30 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 에틸렌 프로필렌 공중합체의 제조 방법 |
US10336845B2 (en) | 2014-09-30 | 2019-07-02 | Exxonmobil Chemical Patents Inc. | Low ethylene amorphous propylene-ethylene-diene terpolymer compositions |
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-
1999
- 1999-10-22 CN CNB998123811A patent/CN1138796C/zh not_active Expired - Lifetime
- 1999-10-22 EP EP99974265A patent/EP1196464B9/de not_active Expired - Lifetime
- 1999-10-22 DE DE69922548T patent/DE69922548T2/de not_active Expired - Lifetime
- 1999-10-22 ES ES99974265T patent/ES2233109T3/es not_active Expired - Lifetime
- 1999-10-22 JP JP2000578362A patent/JP4689829B2/ja not_active Expired - Lifetime
- 1999-10-22 MX MXPA01003978A patent/MXPA01003978A/es not_active IP Right Cessation
- 1999-10-22 CA CA2345628A patent/CA2345628C/en not_active Expired - Fee Related
- 1999-10-22 RU RU2001113445/04A patent/RU2232766C2/ru not_active IP Right Cessation
- 1999-10-22 WO PCT/US1999/024944 patent/WO2000024793A1/en active IP Right Grant
- 1999-10-22 US US09/426,099 patent/US6528670B1/en not_active Expired - Lifetime
- 1999-10-22 KR KR1020017004930A patent/KR100568839B1/ko not_active IP Right Cessation
- 1999-10-22 BR BR9914717-3A patent/BR9914717A/pt not_active IP Right Cessation
- 1999-10-22 AU AU13212/00A patent/AU757241B2/en not_active Ceased
- 1999-10-22 AT AT99974265T patent/ATE284422T1/de not_active IP Right Cessation
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2002
- 2002-03-07 US US10/092,660 patent/US6506857B2/en not_active Expired - Lifetime
- 2002-05-03 HK HK02103341.8A patent/HK1041705A1/zh unknown
Also Published As
Publication number | Publication date |
---|---|
CN1328580A (zh) | 2001-12-26 |
KR100568839B1 (ko) | 2006-04-10 |
KR20010099705A (ko) | 2001-11-09 |
JP4689829B2 (ja) | 2011-05-25 |
US6528670B1 (en) | 2003-03-04 |
JP2002528463A (ja) | 2002-09-03 |
EP1196464A1 (de) | 2002-04-17 |
ATE284422T1 (de) | 2004-12-15 |
AU757241B2 (en) | 2003-02-06 |
CA2345628C (en) | 2010-02-16 |
US6506857B2 (en) | 2003-01-14 |
RU2232766C2 (ru) | 2004-07-20 |
ES2233109T3 (es) | 2005-06-01 |
WO2000024793A8 (en) | 2001-10-11 |
EP1196464B1 (de) | 2004-12-08 |
AU1321200A (en) | 2000-05-15 |
MXPA01003978A (es) | 2003-06-06 |
DE69922548T2 (de) | 2006-01-05 |
HK1041705A1 (zh) | 2002-07-19 |
WO2000024793A1 (en) | 2000-05-04 |
US20020137959A1 (en) | 2002-09-26 |
CA2345628A1 (en) | 2000-05-04 |
CN1138796C (zh) | 2004-02-18 |
EP1196464B9 (de) | 2005-03-23 |
BR9914717A (pt) | 2001-07-10 |
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