DE69832209T2 - Verfahren zur Herstellung von 3,3-Dimethylbutyraldehyd durch Oxidation von 3,3-Dimethylbutanol - Google Patents

Verfahren zur Herstellung von 3,3-Dimethylbutyraldehyd durch Oxidation von 3,3-Dimethylbutanol Download PDF

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Publication number
DE69832209T2
DE69832209T2 DE69832209T DE69832209T DE69832209T2 DE 69832209 T2 DE69832209 T2 DE 69832209T2 DE 69832209 T DE69832209 T DE 69832209T DE 69832209 T DE69832209 T DE 69832209T DE 69832209 T2 DE69832209 T2 DE 69832209T2
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DE
Germany
Prior art keywords
dimethylbutanol
dimethylbutyraldehyde
oxidation
metal oxide
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69832209T
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German (de)
English (en)
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DE69832209D1 (de
Inventor
Indra Prakash
David J. Ager
Alan R. Katrizky
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Nutrasweet Co
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Nutrasweet Co
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Publication date
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Publication of DE69832209D1 publication Critical patent/DE69832209D1/de
Publication of DE69832209T2 publication Critical patent/DE69832209T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C07C45/298—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with manganese derivatives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/002—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by dehydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C07C45/294—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with hydrogen peroxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/30—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with halogen containing compounds, e.g. hypohalogenation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69832209T 1997-08-06 1998-08-04 Verfahren zur Herstellung von 3,3-Dimethylbutyraldehyd durch Oxidation von 3,3-Dimethylbutanol Expired - Lifetime DE69832209T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US907048 1997-08-06
US08/907,048 US5856584A (en) 1997-08-06 1997-08-06 Preparation of 3,3-dimethylbutyraldehyde by oxidation of 3, 3-dimethylbutanol

Publications (2)

Publication Number Publication Date
DE69832209D1 DE69832209D1 (de) 2005-12-08
DE69832209T2 true DE69832209T2 (de) 2006-07-27

Family

ID=25423434

Family Applications (2)

Application Number Title Priority Date Filing Date
DE69832209T Expired - Lifetime DE69832209T2 (de) 1997-08-06 1998-08-04 Verfahren zur Herstellung von 3,3-Dimethylbutyraldehyd durch Oxidation von 3,3-Dimethylbutanol
DE69819164T Expired - Lifetime DE69819164T2 (de) 1997-08-06 1998-08-04 Verfahren zur herstellung von 3,3-dimethylbutyraldehyd durch oxidation von 3,3-dimethylbutanol

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE69819164T Expired - Lifetime DE69819164T2 (de) 1997-08-06 1998-08-04 Verfahren zur herstellung von 3,3-dimethylbutyraldehyd durch oxidation von 3,3-dimethylbutanol

Country Status (17)

Country Link
US (1) US5856584A (enExample)
EP (2) EP1186591B1 (enExample)
JP (3) JP2001525384A (enExample)
KR (2) KR100622438B1 (enExample)
CN (2) CN1286790C (enExample)
AR (1) AR016582A1 (enExample)
AT (1) ATE252532T1 (enExample)
AU (1) AU749936B2 (enExample)
BR (1) BR9811854B1 (enExample)
CA (2) CA2299637C (enExample)
DE (2) DE69832209T2 (enExample)
ES (2) ES2205563T3 (enExample)
HU (1) HUP0003631A3 (enExample)
IL (1) IL134374A0 (enExample)
PE (1) PE96699A1 (enExample)
UY (1) UY25126A1 (enExample)
WO (1) WO1999029646A1 (enExample)

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US5856584A (en) * 1997-08-06 1999-01-05 The Nutrasweet Company Preparation of 3,3-dimethylbutyraldehyde by oxidation of 3, 3-dimethylbutanol
US6573409B1 (en) 1999-07-02 2003-06-03 The Nutrasweet Company Process for the preparation of 3,3-dimethylbutanal
DE50002160D1 (de) * 1999-11-19 2003-06-18 Ciba Sc Holding Ag Verfahren zur selektiven Oxidation von Alkoholen unter Verwendung leicht abtrennbarer Nitroxylradikale
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
WO2004067484A2 (en) * 2003-01-30 2004-08-12 The Nutrasweet Company Bromine free tempo based catalyst system for oxidation of primary and secondary alcohols using naoci as an oxidant.
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
US20050038310A1 (en) 2003-07-15 2005-02-17 Lorkovic Ivan M. Hydrocarbon synthesis
US6825384B1 (en) * 2004-01-29 2004-11-30 The Nutrasweet Company Bromine free TEMPO based catalyst system for oxidation of primary and secondary alcohols using NaOCl as an oxidant
WO2005082825A1 (en) * 2004-02-26 2005-09-09 The Nutrasweet Company Catalyst system for aeorobic oxidation of primary and secondary alcohols.
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
JP2006182764A (ja) * 2004-12-03 2006-07-13 Daiso Co Ltd 第１級または第２級アルコールの新規酸化方法
DE102005030728A1 (de) * 2005-07-01 2007-01-04 Lanxess Deutschland Gmbh Verfahren zur Ruthenium-katalysierten Oxidation von Alkoholen mit Hypochlorit
EP1993979A4 (en) 2006-02-03 2011-07-06 Grt Inc CONTINUOUS PROCESS FOR CONVERTING NATURAL GAS TO LIQUID HYDROCARBONS
EP1993951B1 (en) 2006-02-03 2014-07-30 GRT, Inc. Separation of light gases from bromine
EA017699B1 (ru) 2007-05-24 2013-02-28 Грт, Инк. Зонный реактор с обратимым захватыванием и высвобождением галогеноводородов
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
CA2730934C (en) 2008-07-18 2017-07-04 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
CN101508632B (zh) * 2009-03-25 2012-06-13 东南大学 多相催化氧化制备3,3-二甲基丁醛的方法
CN102030667A (zh) * 2009-09-30 2011-04-27 昆明全新生物制药有限公司 一种4-(n,n-二烷胺基)丁醛缩二醇的制备方法
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
CN102241573B (zh) * 2010-05-10 2014-06-11 陕西天汉生物科技有限公司 一种3,3-二甲基丁醛的制备方法
CN101962327A (zh) * 2010-08-30 2011-02-02 海门慧聚药业有限公司 4-(n,n-二甲氨基)-丁醛缩二甲醇的合成新工艺
CN102030668B (zh) * 2010-10-24 2013-10-30 绍兴文理学院 二甲胺丁缩醛的制备方法
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
CN104119212B (zh) * 2013-04-27 2016-03-02 中国科学院大连化学物理研究所 一种催化氧化3,3-二甲基-1-丁醇制备3,3-二甲基-1-丁醛的方法
JP6155832B2 (ja) * 2013-05-16 2017-07-05 セイコーエプソン株式会社 センサー素子、電子機器、および移動体
CN104649874A (zh) * 2013-11-15 2015-05-27 中国科学院大连化学物理研究所 3,3-二甲基-1-丁醇脱氢制3,3-二甲基-1-丁醛的方法
EP3212601B1 (en) * 2014-10-30 2019-12-04 Organofuel Sweden AB A mild catalytic reduction of c-o bonds and c=o bonds using a recyclable catalyst system

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ES535014A0 (es) * 1983-08-11 1985-08-01 Monsanto Co Un procedimiento para preparar derivados de piridina sustituidos en las posiciones 2 y 6
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JPH0832647B2 (ja) * 1989-01-27 1996-03-29 大阪有機化学工業株式会社 １級アルコールからアルデヒドの製造法
NZ232897A (en) * 1989-04-03 1992-12-23 Squibb & Sons Inc Interphenylene 7-oxabicycloheptyl substituted heterocyclic amide prostaglandin analogues, preparation and pharmaceutical compositions thereof
JP3039025B2 (ja) * 1991-07-19 2000-05-08 吉富製薬株式会社 置換アセトアルデヒドの製造方法
JPH05310632A (ja) * 1992-04-28 1993-11-22 Sumitomo Chem Co Ltd ｍ−フェノキシベンズアルデヒドの製造方法
JP3626520B2 (ja) * 1994-12-26 2005-03-09 株式会社クラレ ３−置換−３−メチルブタナールの製造方法
US5631366A (en) * 1995-01-12 1997-05-20 Hoffmann-La Roche Inc. Process for making 3-formylcephem derivatives
JPH08198795A (ja) * 1995-01-20 1996-08-06 Kuraray Co Ltd セネシオンアルデヒドの製造方法
JPH08198893A (ja) * 1995-01-27 1996-08-06 Nippon Kayaku Co Ltd １４α−ヒドロキシ−４−アンドロステン−３，６，１７−トリオンの製造法
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US5856584A (en) * 1997-08-06 1999-01-05 The Nutrasweet Company Preparation of 3,3-dimethylbutyraldehyde by oxidation of 3, 3-dimethylbutanol

Also Published As

Publication number Publication date
ES2246978T3 (es) 2006-03-01
CA2486890C (en) 2009-03-31
BR9811854A (pt) 2000-08-15
EP1186591B1 (en) 2005-11-02
ATE252532T1 (de) 2003-11-15
CA2299637C (en) 2005-10-11
KR20010022562A (ko) 2001-03-26
CN1266419A (zh) 2000-09-13
EP1186591A3 (en) 2002-03-20
DE69819164T2 (de) 2004-07-22
KR100622438B1 (ko) 2006-09-19
EP1186591A2 (en) 2002-03-13
AR016582A1 (es) 2001-07-25
UY25126A1 (es) 1998-08-31
IL134374A0 (en) 2001-04-30
HUP0003631A3 (en) 2001-08-28
ES2205563T3 (es) 2004-05-01
BR9811854B1 (pt) 2009-08-11
EP1003703A1 (en) 2000-05-31
KR100585332B1 (ko) 2006-05-30
JP2012102113A (ja) 2012-05-31
JP2010031021A (ja) 2010-02-12
CN1238320C (zh) 2006-01-25
DE69832209D1 (de) 2005-12-08
AU749936B2 (en) 2002-07-04
PE96699A1 (es) 1999-09-29
AU9773898A (en) 1999-06-28
HUP0003631A2 (hu) 2001-05-28
EP1003703B1 (en) 2003-10-22
DE69819164D1 (de) 2003-11-27
CN1286790C (zh) 2006-11-29
US5856584A (en) 1999-01-05
KR20060010871A (ko) 2006-02-02
CA2299637A1 (en) 1999-06-17
CN1515533A (zh) 2004-07-28
WO1999029646A1 (en) 1999-06-17
CA2486890A1 (en) 1999-06-17
JP2001525384A (ja) 2001-12-11

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